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Effect of Curing Temperature and Time on Mechanical Properties of Vinyl Polymer Material for Sealing Applications in Industry Using Machine Learning Techniques 利用机器学习技术研究固化温度和时间对工业密封用乙烯基高分子材料力学性能的影响
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-05-16 DOI: 10.1155/2023/9964610
Sudheer D. Kulkarni, B. Manjunatha, U. Chandrasekhar, G. K. Siddesh, Haiter Lenin, Sujin Jose Arul
A seal is a mechanism or a piece of material that securely shuts a hole so that air, liquid, or other substances cannot enter or exit the system. Seals are an essential component of practically all machinery and engines and have several applications in industry. The development of novel materials for sealing applications is essentially required on these days. In this research, an attempt is made to find the polymer material for the said application. Poly vinyl rubber material has been taken, and the specimens are prepared for testing the tensile properties and hardness. The specimens were prepared by using die with various temperatures and curing time. Sixteen specimens were prepared by changing the curing temperature, curing time, postcuring temperature, and postcuring time. The curing temperature 150°C and 170°C, postcuring temperature 100°C and 50°C, curing time 14 mins and 18 mins, postcuring time 120 mins and 60 mins, and the pressure of 150 kg/cm2 for all the specimens were maintained. The tensile strength and hardness analysis were done as per the ASTM standard, and it was found that the specimen prepared on 150°C curing temperature, 18 min curing time, 50°C postcuring temperature, and 120 min postcuring time provides the higher tensile strength. DOE analysis is also done to determine the best values of the factors impacting the mechanical characteristics of the seal material. Simple regression analysis is used to find the influence of curing temperature and curing time on the tensile strength and hardness for every 1°C temperature rise and 1 sec curing time.
密封件是一种机制或一块材料,可以安全地堵住一个孔,使空气、液体或其他物质无法进入或离开系统。密封件是几乎所有机械和发动机的重要组成部分,在工业中有多种应用。目前主要需要开发用于密封应用的新型材料。在这项研究中,试图找到用于上述应用的聚合物材料。采用聚乙烯橡胶材料,制备了拉伸性能和硬度的试样。通过使用模具在不同温度和固化时间下制备试样。通过改变固化温度、固化时间、后固化温度和后固化时间制备了16个试样。固化温度150°C和170°C,后固化温度100°C和50°C,固化时间14 分钟和18 分钟,后固化时间120 分钟和60 分钟,压力为150 保持所有样品的kg/cm2。根据ASTM标准进行拉伸强度和硬度分析,发现试样在150°C固化温度下制备,18 最小固化时间、50°C后固化温度和120 最短的后固化时间提供了更高的拉伸强度。DOE分析还用于确定影响密封材料机械特性的因素的最佳值。采用简单回归分析,发现每升高1°C,固化温度和固化时间对拉伸强度和硬度的影响 秒固化时间。
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引用次数: 1
Influences of Nanosilica Particles on Density, Mechanical, and Tribological Properties of Sisal/Hemp Hybrid Nanocomposite 纳米二氧化硅颗粒对剑麻/麻杂化纳米复合材料密度、力学和摩擦学性能的影响
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-05-15 DOI: 10.1155/2023/3684253
K. Dhanasekar, A. Krishnan, Gopal Kaliyaperumal, Melvin Victor De Poures, P. Chandramohan, N. Parthipan, C. Priya, R. Venkatesh, Kassu Negash
Focusing on natural fibers are the prominent substitution for synthetic fiber and reinforced into polymer matrices found unique properties such as lightweight, cost-effectiveness, and good mechanical and wear properties. Incompatibility and low adhesive behavior are the primary drawbacks found during the fabrication of natural fiber-bonded polymer matrix composites. The constant weight percentage (10 wt%) of sisal and hemp fiber is treated with a 5% NaOH solution for improving adhesive behavior and bonded with epoxy. The prepared sisal/hemp/epoxy combination is blended with 0 wt%, 3 wt%, 6 wt%, and 9 wt% silica nanoparticles, which results in reduced voids (1.32%) and increased flexural strength (56.98 MPa). Based on the compositions of fiber and reinforcement, the density of the composite varied. Samples 3-6 wt% of silica nanoparticle-blend sisal/hemp/epoxy composite offered maximum tensile and impact strength of 52.16 MPa and 2.1 J. An optical microscope analyzed the tensile fracture surface, and the failure nature was reported. The dry sliding wear performance of composite samples is tested by pin-on-disc setup with a 10 N-40 N load of 10 N interval at 0.75 m/sec. Sample 3 found good wear resistance compared to others.
重点突出天然纤维是合成纤维的替代品,并被增强为聚合物基体,具有轻质、低成本、良好的机械和耐磨性能等独特性能。在制备天然纤维结合聚合物基复合材料的过程中,相容性差和粘接性能差是主要的缺点。恒定重量百分比(10 wt%)的剑麻和大麻纤维用5% NaOH溶液处理,以改善粘合性能,并与环氧树脂粘合。将制备的麻/麻/环氧复合材料与0 wt%、3 wt%、6 wt%和9 wt%的二氧化硅纳米颗粒共混,使材料的孔隙减少了1.32%,抗折强度提高了56.98 MPa。根据纤维和增强材料的组成,复合材料的密度有所不同。二氧化硅纳米颗粒-剑麻/大麻/环氧复合材料的最大拉伸和冲击强度为52.16 MPa和2.1 J。利用光学显微镜对拉伸断口进行了分析,并报道了断裂的破坏性质。在10 N-40 N、10 N间隔、0.75 m/sec的载荷作用下,采用针盘式装置测试复合材料的干滑动磨损性能。与其他样品相比,样品3具有良好的耐磨性。
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引用次数: 4
Nontraditional Natural Filler-Based Biocomposites for Sustainable Structures 用于可持续结构的非传统天然填料基生物复合材料
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-05-02 DOI: 10.1155/2023/8838766
K. Mohan kumar, Venkatesh Naik, Vijayananda Kaup, S. Waddar, N. Santhosh, H. V. Harish
In recent years, there has been a growing awareness and demand for global sustainability, as well as a mandate for the use of renewable and environmentally sustainable materials and processes. Due to which, massive efforts are being made to develop and nurture the next generation of composite materials that are energy efficient, environmentally friendly, and biodegradable. Light weight, lower coefficient of thermal expansion, and comparable tensile strength exhibited by natural fibers render them the choice for use in several industrial products and applications over the last decade. Natural fibers as the reinforcing entity are pitted against their synthetic variants primarily because of the superior aspects like biodegradability and excellent strength-to-weight ratio. This article presents the review on various nonconventional natural fibers such as tamarind seed and shell, Luffa cylindrica, groundnut shell, coconut coir, papaya bast, okra, and Ashoka tree seed. The flow of the chapter includes the introduction, extraction methodologies, and fabrication, and investigations of mechanical properties, applications, and sustainability are dealt in detail for nontraditional natural fibers. The okra fibers possess greater tensile strength of up to 262.8 MPa in comparison with other fibers, while the Ashoka tree seed fibers are known to possess a maximum flexural strength of up to 125 MPa. Further, these fibers are used as reinforcements in potential applications in interiors and automobile and aircraft panels and wood-based particle board composites owing to the increase in tensile and flexural strengths of composites.
近年来,人们对全球可持续发展的认识和需求日益增长,并要求使用可再生和环境可持续的材料和工艺。因此,人们正在大力开发和培育下一代节能、环保、可生物降解的复合材料。天然纤维重量轻,热膨胀系数低,抗拉强度相当,使其在过去十年中成为几种工业产品和应用的选择。天然纤维作为增强实体与它们的合成变体相竞争,主要是因为其优越的方面,如生物降解性和优异的强度重量比。本文综述了罗望子壳、丝瓜壳、花生壳、椰壳、木瓜皮、秋葵、阿育王树种子等多种非传统天然纤维的研究进展。本章的流程包括介绍、提取方法和制造,并详细讨论了非传统天然纤维的机械性能、应用和可持续性的研究。与其他纤维相比,秋葵纤维具有更高的抗拉强度,最高可达262.8 MPa,而众所周知,阿育王树种子纤维具有高达125 MPa的最大弯曲强度。此外,由于复合材料的拉伸和弯曲强度的增加,这些纤维在内饰、汽车和飞机面板以及木基刨花板复合材料的潜在应用中用作增强材料。
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引用次数: 1
Utilization of Plastic Waste for Developing Composite Bricks and Enhancing Mechanical Properties: A Review on Challenges and Opportunities 利用塑料废弃物开发复合砖提高力学性能:挑战与机遇综述
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-05-02 DOI: 10.1155/2023/6867755
Aditya Singh, A. Srivastava, G. Singh, Ashutosh Kumar Singh, Hritik Kumar Singh, Ajay Mahaputra Kumar, Gyanendra Kumar Singh
The population increases demand for plastic in every sector along with single-use plastic rapidly increasing, but it still has a low recycling rate. The use of plastic in the form of brick is challenging and overall has a better impact on the ecosystem, economy, and industrial revolution. In this paper, a study has been done of the available research work on plastic bricks from different plastic waste materials. It discusses the processes used to make bricks from plastic waste materials, the possibility of contamination from the waste materials utilized, the lack of pertinent standards, and the public adoption of waste materials-based bricks. Furthermore, it focused on research and development required for the widespread production and use of bricks made from waste materials, not only in terms of technical, economic, and environmental considerations but also in terms of standardization, governmental policy, and public awareness of waste recycling and sustainable development. It has been observed from the study that PET has mostly recycled plastic with greater efficiency compared to other plastics. However, worldwide global production is followed by PE, PVC, and PP. PET has only 5% contribution to the global recycling of plastics.
随着人口的增长,每个行业对塑料的需求都在增加,一次性塑料也在迅速增加,但它的回收率仍然很低。以砖的形式使用塑料是具有挑战性的,总体上对生态系统、经济和工业革命有更好的影响。本文对现有的利用不同塑料废弃物制备塑料砖的研究工作进行了综述。它讨论了用塑料废料制砖的过程,所使用的废料污染的可能性,缺乏相关标准,以及公众采用废料制砖。此外,它侧重于广泛生产和使用废砖所需的研究和开发,不仅从技术、经济和环境方面考虑,而且从标准化、政府政策和公众对废物回收和可持续发展的认识方面考虑。从研究中可以观察到,与其他塑料相比,PET回收塑料的效率更高。然而,在全球范围内,PE、PVC和PP的产量紧随其后。PET对全球塑料回收的贡献仅为5%。
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引用次数: 3
The Synergy of Nanosilica and Zinc Diethyl Hypophosphite Influences the Flame Retardancy and Foaming Performance of Poly(Ethylene Terephthalate) 纳米二氧化硅与次亚磷酸二乙酯锌的协同作用对聚对苯二甲酸乙二醇酯阻燃发泡性能的影响
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-04-28 DOI: 10.1155/2023/4319998
Jiaxin Zheng, Congxiao Wang, Yuyin Zhao, Meng-Hao Guo, Yadong He, C. Xin
In order to improve the flame retardancy of poly(ethylene terephthalate) (PET) and maintain its excellent foamability, nanosilica (nano-SiO2), and zinc diethyl hypophosphite (ZDP) were selected as synergistic flame retardants, and pyromellitic dianhydride (PMDA) was used as a chain extender to carry out flame retardant and chain extension modification of PET simultaneously. The flame retardancy and flame-retardant mechanism of modified PET were characterized by limiting oxygen index, vertical combustion test, thermogravimetric analysis, and SEM. Dynamic rheological test and DSC were used to analyze the rheological and thermal properties. The foaming ability was also studied by batch foaming experiments. The test results indicated that nano-SiO2 and ZDP had a synergistic effect, which could significantly improve flame retardancy of PET. The vertical combustible grade of modified PET reached V-0 grade, and the limiting oxygen index increased from 21% to about 30%. The role of nano-SiO2 on the flame retardancy of PET was mainly to increase compactness and strength of the carbon layer, which could block combustible gas produced by the pyrolysis of PET and resist dripping behavior. At the same time, the addition of nano-SiO2 increased the crystallization temperature and crystallinity of PET. Otherwise, nano-SiO2 could act as a bubble-nucleating agent and improve the foaming ability of modified PET. When the addition amount was 1 wt%, not only did the maximum foaming ratio increase but the foaming temperature zone was also widened from 225°C-235°C to 225°C-250°C. Finally, a flame-retardant PET system with good foaming property was proposed.
为了提高聚对苯二甲酸乙酯(PET)的阻燃性能并保持其优异的发泡性能,选择纳米二氧化硅(nano-SiO2)和次磷酸锌(ZDP)作为协同阻燃剂,并以邻苯二甲酸二酐(PMDA)作为扩链剂,对PET进行阻燃和扩链改性同时进行。通过极限氧指数、垂直燃烧试验、热重分析和扫描电子显微镜对改性PET的阻燃性能和阻燃机理进行了表征。采用动态流变学试验和DSC分析了材料的流变学和热性能。通过间歇式发泡实验对其发泡性能进行了研究。实验结果表明,纳米sio2与ZDP具有协同作用,能显著提高PET的阻燃性。改性PET的垂直可燃等级达到V-0级,极限氧指数由21%提高到30%左右。纳米sio2对PET的阻燃作用主要是增加了碳层的致密性和强度,可以阻断PET热解产生的可燃气体,抵抗滴燃行为。同时,纳米sio2的加入提高了PET的结晶温度和结晶度。另外,纳米sio2可以作为气泡成核剂,提高改性PET的发泡能力。当添加量为1 wt%时,不仅最大发泡比增加,而且发泡温度范围从225℃~ 235℃扩大到225℃~ 250℃。最后,提出了一种发泡性能良好的阻燃PET体系。
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引用次数: 0
Challenges and Opportunities in Additive Manufacturing Polymer Technology: A Review Based on Optimization Perspective 增材制造聚合物技术的挑战与机遇:基于优化视角的综述
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-04-19 DOI: 10.1155/2023/8639185
S. Raja, A. John Rajan
In the emerging modern technology of additive manufacturing, the need for optimization can be found in literature in many places. Additive manufacturing (AM) is making an object layer by layer directly from digital data. Previous works of literature have classified additive manufacturing processes into seven types. However, there is a lack of comprehensive review describing the optimization challenges and opportunities in the material extrusion process (polymer technology) and also the need for FDM polymer materials application in impeller making. In this review paper, a specific optimization method called multicriteria decision-making (MCDM) from the mathematical programming technique used in additive manufacturing polymer technology (AMPT) is discussed. The other topics such as different types of optimization techniques, applications of different MCDM tools and their applications in different fields including AM, and the optimization challenges and opportunities in AMPT particularly impeller application are discussed.
在新兴的现代增材制造技术中,在许多地方的文献中都可以找到对优化的需求。增材制造(AM)是直接从数字数据逐层制造物体。以往的文献将增材制造工艺分为七种类型。然而,材料挤出工艺(聚合物技术)的优化挑战和机遇以及FDM聚合物材料在叶轮制造中的应用需求缺乏全面的综述。本文从增材制造聚合物技术(AMPT)的数学规划技术出发,讨论了一种具体的优化方法——多准则决策(MCDM)。讨论了不同类型的优化技术,不同MCDM工具的应用及其在AM等不同领域的应用,以及AMPT特别是叶轮应用中的优化挑战和机遇。
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引用次数: 1
Preparation and Properties of Boron Nitride or Aluminum Nitride Reinforced Glass Fiber/Modified Polyphenylene Sulfide Composites 氮化硼或氮化铝增强玻璃纤维/改性聚苯硫醚复合材料的制备及性能
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-04-11 DOI: 10.1155/2023/7484634
Jingxian Zhao, Shijie Cai, Xiaolu Chen, Hao-hao Ren, Yonggang Yan
In this work, polyphenylene sulfide (PPS) containing carboxyl group was synthesized and used to prepare PPS-2COOH/LGF/AlN and composites with high-temperature resistance, corrosion resistance, low dielectric constant, and low dielectric loss were prepared with boron nitride/aluminum nitride (BN/AlN) and glass fiber (LGF). The results showed that the introduction of carboxyl groups did not affect the structure and thermal properties of PPS. The composites exhibited good mechanical properties with a tensile strength of 65 MPa~97 MPa and flexural strength of 112 MPa~154 MPa. The TGA results showed that the composites had good thermal stability, and the T5% of PPS-2COOH/LGF/AlN (20) and PPS-2COOH/LGF/BN (20) reached up to 511.6°C and 506.3°C, respectively. They were insoluble in some organic solvents, such as NMP and DMF at room temperature, and they exhibited excellent chemical resistance. The dielectric performance results showed that with the increase of frequency, the dielectric constant and dielectric loss gradually decreased, the dielectric constant of PPS-2COOH/LGF/BN (15) was 3.9, and the dielectric loss of PPS-2COOH/LGF/BN (15) was 0.01. From the above results, it can be concluded that the composite materials PPS-2COOH/LGF/AlN and PPS-2COOH/LGF/BN have potential application prospects in the field of 5G high thermal conductivity materials.
本文合成了含羧基的聚苯硫醚(PPS),并将其用于制备PPS- 2cooh /LGF/AlN,并以氮化硼/氮化铝(BN/AlN)和玻璃纤维(LGF)制备了耐高温、耐腐蚀、低介电常数和低介电损耗的复合材料。结果表明,羧基的引入对PPS的结构和热性能没有影响。复合材料具有良好的力学性能,抗拉强度为65 MPa~97 MPa,抗折强度为112 MPa~154 MPa。TGA结果表明,复合材料具有良好的热稳定性,PPS-2COOH/LGF/AlN(20)和PPS-2COOH/LGF/BN(20)的T5%分别达到511.6℃和506.3℃。在室温下,它们不溶于NMP和DMF等有机溶剂,具有优异的耐化学性。介电性能结果表明,随着频率的增加,介电常数和介电损耗逐渐减小,PPS-2COOH/LGF/BN(15)的介电常数为3.9,PPS-2COOH/LGF/BN(15)的介电损耗为0.01。综上所述,PPS-2COOH/LGF/AlN和PPS-2COOH/LGF/BN复合材料在5G高导热材料领域具有潜在的应用前景。
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引用次数: 1
A Decision-Making Carbon Reinforced Material Selection Model for Composite Polymers in Pipeline Applications 管道应用中复合聚合物碳增强材料的决策选择模型
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-04-11 DOI: 10.1155/2023/6344193
M. Mustafa, S. Raja, Layth Abdulrasool A. L. Asadi, N. Jamadon, N. Rajeswari, Avvaru Praveen Kumar
Pipes are manufactured primarily through the extrusion process. One of the material extrusion processes in recent digital manufacturing is additive manufacturing’s fusion deposition modeling. Pipes are made from various materials such as metal and plastic/polymers, and the main challenge has been in selecting the pipe material for the customized application. For the creation of water-passing tubes, this research has chosen appropriate carbon-reinforced polymers that can be used with filament made of polyether ether ketone (PEEK) and polyethylene terephthalate glycol (PETG). For this goal, the analytical hierarchy process, also known as the AHP, is used to choose the best material based on factors such as cost, temperature resistance, printing speed, and mechanical properties of the material. The results revealed that PEEK-CF is a better material for the customized impeller application than PETG-CF. The PEEK-CF obtains the higher priority value of 0.6363, and the PETG-CF obtains 0.2791. This decision-making technique can be used to select other comparable customized applications.
管材主要是通过挤压工艺制造的。在最近的数字制造中,材料挤压工艺之一是增材制造的熔融沉积建模。管道由各种材料制成,如金属和塑料/聚合物,主要挑战是为定制应用选择管道材料。为了制造通水管,这项研究选择了合适的碳增强聚合物,可以与聚醚醚酮(PEEK)和聚对苯二甲酸乙二醇酯(PETG)制成的长丝一起使用。为了实现这一目标,层次分析法(AHP)用于根据成本、耐温性、印刷速度和材料的机械性能等因素选择最佳材料。结果表明,PEEK-CF是一种比PETG-CF更好的定制叶轮材料。PEEK-CF的优先级较高,为0.6363,PETG-CF的优先级较高,为0.2791。这种决策技术可用于选择其他类似的定制应用程序。
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引用次数: 1
Characteristics of Biofoam Cups Made from Sugarcane Bagasse with Rhizopus oligosporus as Binding Agent 以少孢根霉为粘结剂的甘蔗渣生物泡沫杯的特性研究
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-03-30 DOI: 10.1155/2023/8257317
E. Indarti, S. Muliani, D. Yunita
This study is aimed at producing a biofoam cup made from sugarcane bagasse with tempeh mold (Rhizopus oligosporus). Soybean flour (SF) was added to promote the growth of mycelia, which could bind the bagasse fiber matrix. The main materials were whole bagasse (B) and depithed bagasse (DB). The SF weight ratios to bagasse were 1 : 1 (SF1) and 1.5 : 1 (SF1.5). Therefore, the studied specimens were labeled B-SF1, DB-SF1, B-SF1.5, and DB-SF1.5. All biofoam cups were analyzed for their physical properties (water absorption and porosity), mechanical properties (puncture and compressive strengths), biodegradability, and thermal properties (thermogravimetric analysis). The lowest water absorption rates were obtained from the B biofoam cups ( 23 % ± 2.45 % ) and the SF1.5 biofoam cups ( 25.83 % ± 5.19 % ). Both B-SF1 and B-SF1.5 had lower porosity ( 8.72 % ± 0.88 % and 10.77 % ± 1.54 % , respectively) than the DB biofoam cups. Moreover, the B biofoam cups had smoother biofoam surfaces, smaller voids, and lower porosity compared with the DB samples. However, the DB biofoam cups showed the highest puncture strength ( 2.95 ± 0.37  kg cm−2) among all samples. Nevertheless, the B-SF1.5 biofoam cup had the highest compressive strength ( 3.98 ± 0.39  MPa) and the DB-SF1.5 exhibited the slowest degradation rate ( 27 % ± 0.7 % ) after 14 days of soil burial. The highest thermal stability was obtained from B-SF1.5, which had a thermal degradation temperature of 264°C. Overall, B-SF1.5 had the smoothest surface, good thermal stability, and high compressive strength.
以甘蔗渣为原料,利用豆豉霉(根霉寡孢霉)制备生物泡沫杯。添加大豆粉促进菌丝体生长,菌丝体与甘蔗渣纤维基质结合。主要原料为全甘蔗渣(B)和深度甘蔗渣(DB)。SF与甘蔗渣的质量比分别为1:1 (SF1)和1.5:1 (SF1.5)。因此,所研究的标本被标记为B-SF1、DB-SF1、B-SF1.5和DB-SF1.5。分析了所有生物泡沫杯的物理性能(吸水率和孔隙率)、机械性能(穿刺和抗压强度)、生物降解性和热性能(热重分析)。B型生物泡沫杯吸水率最低(23%±2.45%),SF1.5型生物泡沫杯吸水率最低(25.83%±5.19%)。B-SF1和B-SF1.5的孔隙率均低于DB生物泡沫杯(分别为8.72%±0.88%和10.77%±1.54%)。此外,与DB样品相比,B生物泡沫杯具有更光滑的生物泡沫表面,更小的空隙和更低的孔隙率。然而,DB生物泡沫杯在所有样品中表现出最高的穿刺强度(2.95±0.37 kg cm−2)。然而,B-SF1.5生物泡沫杯在14天后的抗压强度最高(3.98±0.39 MPa),而DB-SF1.5的降解率最低(27%±0.7%)。B-SF1.5的热稳定性最高,热降解温度为264℃。总体而言,B-SF1.5表面光滑,热稳定性好,抗压强度高。
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引用次数: 2
Studying the Fabrication and Characterization of Polymer Composites Reinforced with Waste Eggshell Powder 废蛋壳粉增强聚合物复合材料的制备及性能研究
IF 3.1 4区 工程技术 Q2 Chemical Engineering Pub Date : 2023-03-29 DOI: 10.1155/2023/7640478
Wasan A. Alkaron, Sameer F. Hamad, M. Sabri
Polymeric and plastic materials currently have numerous positive impacts due to their unique properties that make them important for various engineering applications. However, sustainability is a vital factor that should be considered, because of environmental issues. Eggshells (ES) are an important way to reduce the impact of nondegradable materials when applied to reinforce different types of polymer matrices, whether natural or synthetic polymers. Therefore, this study is an attempt to explore the potential application of waste eggshell fillers for the first time as a natural reinforcement in polyamide 12 (PA) composites. PA was loaded with three different ratios (3, 5, and 10 wt. %) of eggshell powder. Morphological studies of the PA powder, ES powder, and their composites were carried out by scanning electron microscopy (SEM). Furthermore, differential scanning calorimetry (DSC) and Fourier transform infrared (FTIR) spectroscopy were performed to study the thermal and chemical properties of the raw materials and the produced composites. The results indicate ES fillers’ potential usage as a reinforcement material to develop the thermal and chemical properties of the PA polymer matrix composites, thereby reducing costs and minimizing the environmental pollution caused by waste eggshells and petroleum-based polymers.
聚合物和塑料材料由于其独特的性能而对各种工程应用具有重要意义,因此目前具有许多积极影响。然而,由于环境问题,可持续性是应该考虑的一个重要因素。蛋壳(ES)是减少不可降解材料影响的重要方法,用于加固不同类型的聚合物基体,无论是天然聚合物还是合成聚合物。因此,本研究首次尝试探索废弃蛋壳填料作为天然增强材料在聚酰胺12(PA)复合材料中的潜在应用。PA以三种不同的比率(3、5和10 wt.%)蛋壳粉。用扫描电子显微镜(SEM)对PA粉末、ES粉末及其复合材料进行了形态研究。此外,通过差示扫描量热法(DSC)和傅立叶变换红外光谱(FTIR)研究了原料和制备的复合材料的热性能和化学性能。结果表明,ES填料作为增强材料的潜在用途是开发PA聚合物基复合材料的热性能和化学性能,从而降低成本并最大限度地减少废弃蛋壳和石油基聚合物对环境的污染。
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引用次数: 4
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