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Foliar application of rice husk derived nanosilica for mitigating drought stress in hybrid maize by boosting antioxidant defense system 叶面喷施稻壳提取的纳米二氧化硅,通过增强抗氧化防御系统缓解杂交玉米的干旱胁迫
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-24 DOI: 10.1016/j.hazadv.2024.100482
Rakesh Bekkam , Chitdeshwari Thiyagarajan
The increasing frequency and intensity of drought magnified by the climate change, pose significant challenge to global food security and agricultural productivity. Chemically synthesized nanosilica have emerged as a promising solution for managing drought stress, enhancing crop growth and stress resilience but, its production involves harmful chemicals which results in adverse impacts on soil, plant and environment. Hence, the present study aimed to green synthesize and characterize silicon nanoparticles from rice husk and to evaluate their potential for improving plant growth, development and stress mitigation in hybrid maize. The rice husk derived nanosilica has spherical morphology, amorphous nature, siloxane bonds and high purity (99 %). Five different levels of nanosilica (0.05, 0.10, 0.15, 0.20 and 0.25 %) were sprayed on hybrid maize grown under irrigated and drought conditions and the results revealed that, nanosilica spray has improved the stress tolerance, growth and photosynthetic parameters. An optimum response was noted with the nanosilica spray upto 0.10 % in irrigated plants and 0.15 % in drought stressed plants, where greater increase in plant height (27.7 and 28.9 %), total biomass (55.7 and 39.1 %), chlorophyll a (36.7 and 54.5 %), relative water content (12.5 and 24.9 %) and superoxide dismutase (23.0 and 35.7 %) activity was observed. This was ascribed to the alleviation of membrane damage by reduced melondialdehyde content (18.9 and 21.4 %) and electrolyte leakage (21.9 and 26.7 %) under irrigated and drought regimes. However, higher doses of nanosilica caused slight reduction in plant growth and antioxidant activity. We conclude that, foliar spraying of nanosilica synthesized from rice husk at a concentration of 0.10 % for irrigated and 0.15 % for hybrid maize exposed to drought stress has shown a positive effect on plant growth and stress mitigation. Nanosilica synthesised from rice husk is economical, environmentally feasible and efficiently boosts plant growth and stress tolerance. Further, to confirm the role of rice husk derived nanosilica in plant stress tolerance, the comprehensive molecular mechanisms underpinning the stress mitigation has to be studied in detail.
气候变化加剧了干旱的频率和强度,对全球粮食安全和农业生产力构成了重大挑战。化学合成纳米二氧化硅已成为管理干旱胁迫、提高作物生长和抗逆性的一种有前途的解决方案,但其生产涉及有害化学物质,会对土壤、植物和环境造成不利影响。因此,本研究旨在从稻壳中绿色合成和表征纳米硅颗粒,并评估其改善杂交玉米植物生长、发育和胁迫缓解的潜力。从稻壳中提取的纳米二氧化硅具有球形形态、无定形性质、硅氧烷键和高纯度(99%)。在灌溉和干旱条件下对杂交玉米喷洒了五种不同浓度的纳米二氧化硅(0.05%、0.10%、0.15%、0.20% 和 0.25%),结果表明,喷洒纳米二氧化硅提高了玉米的抗逆性、生长和光合作用参数。在灌溉植物和干旱胁迫植物中,纳米二氧化硅喷雾的最佳反应分别为 0.10 % 和 0.15 %,观察到植株高度(27.7 % 和 28.9 %)、总生物量(55.7 % 和 39.1 %)、叶绿素 a(36.7 % 和 54.5 %)、相对含水量(12.5 % 和 24.9 %)和超氧化物歧化酶(23.0 % 和 35.7 %)活性均有较大提高。这是因为在灌溉和干旱条件下,三聚氰胺含量(18.9 % 和 21.4 %)和电解质渗漏(21.9 % 和 26.7 %)的减少减轻了膜损伤。然而,较高剂量的纳米二氧化硅会导致植物生长和抗氧化活性略有下降。我们的结论是,在灌溉和干旱胁迫下,叶面喷洒由稻壳合成的纳米二氧化硅(浓度分别为 0.10 % 和 0.15 %)对植物生长和胁迫缓解有积极作用。用稻壳合成纳米二氧化硅既经济又环保,还能有效促进植物生长和抗逆性。此外,要证实稻壳提取的纳米二氧化硅在植物抗逆性中的作用,还需要详细研究缓解胁迫的综合分子机制。
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引用次数: 0
Interaction of benzene, toluene, ethylbenzene, and xylene with human’s body: Insights into characteristics, sources and health risks 苯、甲苯、乙苯和二甲苯与人体的相互作用:洞察特征、来源和健康风险
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-23 DOI: 10.1016/j.hazadv.2024.100459
Meysam Saeedi , Bahram Malekmohammadi , Shahram Tajalli
Benzene, toluene, ethylbenzene, and xylene (BTEX) compounds, notably benzene, pose health risks, necessitating monitoring and mitigation strategies. Anthropogenic and natural sources of BTEX compounds are detailed across industrial, residential, transport, and natural environments. Human exposure to Benzene, Toluene, Ethylbenzene, and Xylenes (BTEX) occurs predominantly through inhalation, constituting over ninety percent of exposures in the general population. Upon inhalation, BTEX compounds are swiftly absorbed, impacting various physiological systems adversely. Understanding the diverse impacts of BTEX exposure is crucial for developing effective mitigation strategies and safeguarding public health. This paper elucidates the mechanisms underlying BTEX impacts on the respiratory, cardiovascular, digestive, urinary, hematologic, hematopoietic, immune, reproductive, and nervous systems. Inhalation primarily affects the respiratory system, leading to lung tissue damage, decreased lung function, inflammation, and asthma. Cardiovascular impacts include arrhythmias, heart failure, and myocardial infarction. BTEX exposure induces hepatic and genetic toxicity, hematologic disorders, immune dysfunction, and reproductive effects. Neurological effects encompass alterations in brain structure, neurotransmitter levels, cognitive function, anxiety, impulsivity, and depression.
苯、甲苯、乙苯和二甲苯(BTEX)化合物,尤其是苯,会对健康造成危害,因此有必要采取监测和缓解策略。BTEX 化合物的人为和自然来源详见工业、住宅、运输和自然环境。人类主要通过吸入的方式接触苯、甲苯、乙苯和二甲苯(BTEX),占普通人群接触量的 90% 以上。吸入后,BTEX 化合物会被迅速吸收,对各种生理系统产生不利影响。了解 BTEX 暴露的各种影响对于制定有效的缓解策略和保障公众健康至关重要。本文阐明了 BTEX 对呼吸系统、心血管系统、消化系统、泌尿系统、血液系统、造血系统、免疫系统、生殖系统和神经系统的影响机制。吸入主要影响呼吸系统,导致肺组织损伤、肺功能下降、炎症和哮喘。对心血管的影响包括心律失常、心力衰竭和心肌梗塞。暴露于 BTEX 会诱发肝脏和遗传毒性、血液病、免疫功能障碍和生殖影响。对神经系统的影响包括改变大脑结构、神经递质水平、认知功能、焦虑、冲动和抑郁。
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引用次数: 0
Silver nanoparticles synthesized from marine algae Spatoglossum asperum: Antioxidant properties and seed germination enhancement 由海洋藻类 Spatoglossum asperum 合成的银纳米粒子:抗氧化性和种子发芽率的提高
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-23 DOI: 10.1016/j.hazadv.2024.100478
Disha Patel , Bhakti Patel , Virendra Kumar Yadav , M.P. Sudhakar , Sulaiman Ali Alharbi , Saleh H. Salmen , Illa Patel , Nisha Choudhary , Ashish Patel
Biosynthesized silver nanoparticles (AgNPs) have shown promising potential in plant growth under stressed conditions but marine algae synthesized AgNPs still remain least explored. In the current study, AgNPs have been synthesis by using the aqueous extract of marine brown alga Spatoglossum asperum as a reducing medium and their application in the growth of Vigna radiata seeds under salt stress conditions was studied. The antioxidant potential of AgNPs in comparison with algal extract was also assessed. The AgNPs synthesized using the algal extract was characterized by means of UV–Vis spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray (XRD) diffraction analysis, Field emission scanning electron microscopy (FE-SEM) and Energy dispersive X-ray spectroscopy (EDS). The FE-SEM and EDS results confirmed the formation of multi-shaped (spherical, cubical and nano-clusters) particles with average size of 43.65 nm. Developed AgNPs showed a surface plasmon resonance band at 425 nm and a face-centric cubic crystallographic structure with an average crystallite size of 23.05 nm. The FTIR spectrum ensured the involvement of di and polysulphides in the synthesis of nanoparticles. The results revealed that the algal synthesized AgNPs showed superior antioxidant activity compared to the algal extract alone and significantly enhanced seed germination in Vigna radiata under both normal and saline conditions. These findings suggest that Spatoglossum asperum derived AgNPs could play a pivotal role in agriculture and environmental sustainability.
生物合成的银纳米粒子(AgNPs)在压力条件下的植物生长中显示出了巨大的潜力,但海洋藻类合成的 AgNPs 仍然是探索最少的。本研究以海洋褐藻 Spatoglossum asperum 的水提取物为还原介质,合成了 AgNPs,并研究了其在盐胁迫条件下对 Vigna radiata 种子生长的应用。此外,还评估了 AgNPs 与海藻提取物相比的抗氧化潜力。利用海藻提取物合成的 AgNPs 通过紫外-可见光谱、傅立叶变换红外光谱、X 射线衍射分析、场发射扫描电子显微镜(FE-SEM)和能量色散 X 射线光谱(EDS)进行了表征。场发射扫描电子显微镜(FE-SEM)和能量色散 X 射线光谱(EDS)的结果证实了多形状(球形、立方体和纳米簇)颗粒的形成,平均粒径为 43.65 nm。研制出的 AgNPs 在 425 nm 处显示出表面等离子体共振带,并呈现出面心立方晶体结构,平均晶粒大小为 23.05 nm。傅立叶变换红外光谱确保了二硫化物和多硫化物参与了纳米粒子的合成。研究结果表明,藻类合成的 AgNPs 与单独的藻类提取物相比,具有更强的抗氧化活性,并能在正常和盐碱条件下显著提高黑木耳的种子萌发率。这些研究结果表明,从 Spatoglossum asperum 中提取的 AgNPs 可在农业和环境可持续发展方面发挥关键作用。
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引用次数: 0
The ability of UWWTP to remove NSAIDs: Impact on water quality in the Odra River Czech Republic concerning incoming European legislation UWWTP 去除非甾体抗炎药的能力:对捷克共和国奥德拉河水质的影响,涉及即将出台的欧洲立法
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-23 DOI: 10.1016/j.hazadv.2024.100477
Karla Placová , Silvie Heviánková , Jan Halfar , Kateřina Brožová , Oldřich Motyka , Kristina Čabanová , Silvie Drabinová , Jitka Chromíková
Increased consumption of pharmaceuticals has resulted in their detection in wastewater. If wastewater treatment plants (WWTPs) fail to eliminate these substances adequately, they can seep into the environment, posing potential risks. As non-steroidal anti-inflammatory drugs (NSAIDs) belong to the pharmaceuticals most frequently examined in wastewater, this study aimed to monitor wastewater from the municipal wastewater treatment plant in Ostrava (UWWTP) over the course of a year, specifically assessing how the presence of these substances in discharged wastewater could contaminate the Odra River. To further understand the impact of NSAIDs, we evaluated the effectiveness of UWWTP technology in removing the following selected drugs: diclofenac (DCF), ibuprofen (IBU), naproxen (NAP) and ketoprofen (KET) - as well as their main metabolites: 4′-hydroxydiclofenac (hydroxyDCF), carboxyibuprofen (carboxyIBU), desmethylnaproxen (desmethylNAP), and ketoprofen glucuronide (glucuronideKET).
Wastewater samples were collected at both the inflow and outflow of the urban wastewater treatment plant (UWWTP) Ostrava from October 2022 to September 2023. The analysis was performed using liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). The concentrations of the monitored substances at the UWWTP inflow varied significantly, ranging from 79 ng/L to 112,125 ng/L, with the highest levels detected for ibuprofen (IBU), diclofenac (DCF), and their metabolites. The UWWTP demonstrated impressive treatment efficiency for IBU, exceeding 98%, while for DCF, it ranged between 56% and 87%. Building on these findings, a monitoring campaign was initiated along the Odra River to evaluate the concentrations of IBU and DCF - substances that had not been measured before. Water samples were taken from various locations along the Odra River from October to November 2023 and analyzed using the same methodology as the wastewater samples. The results indicate that, in line with the proposed environmental quality standards (EQS), IBU and DCF do not pose a significant contamination risk to the Odra River.
药品消费量的增加导致在废水中检测到这些物质。如果废水处理厂(WWTP)不能充分消除这些物质,它们就会渗入环境,造成潜在风险。由于非甾体抗炎药(NSAIDs)属于废水中最常检测到的药物,因此本研究旨在对俄斯特拉发市污水处理厂(UWWTP)一年来的废水进行监测,特别是评估排放废水中存在的这些物质会如何污染奥德拉河。为了进一步了解非甾体抗炎药的影响,我们评估了 UWWTP 技术在去除以下选定药物方面的效果:双氯芬酸 (DCF)、布洛芬 (IBU)、萘普生 (NAP) 和酮洛芬 (KET) 及其主要代谢物:4′-hydroxydiclofenac (hydroxyDCF)、carboxyibuprofen (carboxyIBU)、desmethylnaproxen (desmethylNAP) 和 ketoprofen glucuronide (glucuronideKET)。2022 年 10 月至 2023 年 9 月期间,在俄斯特拉发城市污水处理厂(UWWTP)的入水口和出水口采集了废水样本。分析采用液相色谱-串联质谱法(LC-MS/MS)进行。西乌克兰城市污水处理厂进水口的监测物质浓度变化很大,从 79 纳克/升到 112,125 纳克/升不等,其中布洛芬 (IBU)、双氯芬酸 (DCF) 及其代谢物的浓度最高。西湖污水处理厂对 IBU 的处理效率非常高,超过 98%,而对 DCF 的处理效率则在 56% 至 87% 之间。在这些研究结果的基础上,奥德拉河沿岸启动了一项监测活动,以评估 IBU 和 DCF 的浓度--这些物质以前从未测量过。2023 年 10 月至 11 月,在奥德拉河沿岸的不同地点采集了水样,并采用与废水样本相同的方法进行分析。结果表明,根据拟议的环境质量标准 (EQS),IBU 和 DCF 不会对奥德拉河造成重大污染风险。
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引用次数: 0
Exploring soil pollution patterns in Ghana's northeastern mining zone using machine learning models 利用机器学习模型探索加纳东北部矿区的土壤污染模式
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-22 DOI: 10.1016/j.hazadv.2024.100480
Daniel Kwayisi , Raymond Webrah Kazapoe , Seidu Alidu , Samuel Dzidefo Sagoe , Aliyu Ohiani Umaru , Ebenezer Ebo Yahans Amuah , Prosper Kpiebaya
This study assessed the pollution status and effectiveness of machine learning models in predicting pollution indices in soils from a mining area in Northeastern Ghana. 552 soil samples were analysed with an Energy Dispersive X-ray Fluorescence (ED-XRF) spectrometer for their elemental concentrations. Four pollution indices; Nemerow Integrated Pollution Index (NIPI), degree of contamination (Cdeg), modified degree of contamination (mCdeg) and Pollution Load Index (PLI). Additionally, the Multivariate Adaptive Regression Splines (MARS) machine learning approach were used. The high CV%, skewness, and kurtosis values show a high degree of variability and uneven distribution patterns which denotes dispersed hotspots that can be interpreted as an influence of gold anomalies and illegal mining activities in the area. V (120.86 mg/L), Cr (242.42 mg/L), Co (30.92 mg/L) Ba (337.62 mg/L), and Zn (35.42 mg/L) recorded values higher than the global and regional contaminant thresholds. The NIPI shows that 46.74% and 26.81% of samples are slightly and moderately polluted respectively. The Cdeg analysis supports these findings, with 36.96% and 41.49% of samples classified as having “moderate” to “considerable” contamination, respectively. The PLI indicates progressive soil quality deterioration (43.84%) of samples reflecting substantial environmental disturbance. The pollution indices show the effect of illegal mining on Shaega, Buin and other areas in the eastern boundary of the study. The MARS models developed for the study demonstrated high predictive capabilities with an R2 value of 0.9665 for model 1 (NIPI), and RMSE and MAE values of 0.8227 and 0.4287 respectively. For model 2 (Cdeg), R2 value of 0.9863, RMSE and MAE of 1.0416 and 0.6181, respectively. Model 3 (mCdeg) produced an R2 value of 0.9844, RMSE and MAE of 0.1225 and 0.0670. These findings suggest MARS models can be an integral tool for soil quality analysis in cooperation with pollution indices. The study suggests that remedial and legislative measures be implemented to address the issue of illegal mining in the area.
本研究评估了加纳东北部矿区土壤的污染状况以及机器学习模型预测污染指数的有效性。使用能量色散 X 射线荧光 (ED-XRF) 光谱仪分析了 552 个土壤样本的元素浓度。四个污染指数:内梅罗综合污染指数 (NIPI)、污染程度 (Cdeg)、修正污染程度 (mCdeg) 和污染负荷指数 (PLI)。此外,还使用了多变量自适应回归样条曲线(MARS)机器学习方法。高 CV%、偏斜度和峰度值显示了高度的变异性和不均匀的分布模式,这表明存在分散的热点,可以解释为该地区金矿异常和非法采矿活动的影响。钒(120.86 毫克/升)、铬(242.42 毫克/升)、钴(30.92 毫克/升)、钡(337.62 毫克/升)和锌(35.42 毫克/升)的数值高于全球和区域污染物阈值。国家污染指数显示,分别有 46.74% 和 26.81% 的样本受到轻度和中度污染。Cdeg 分析也支持这些结果,分别有 36.96% 和 41.49% 的样本被归类为 "中度 "至 "严重 "污染。PLI 显示,43.84% 的样本土壤质量逐渐恶化,反映出环境受到严重干扰。污染指数显示了非法采矿对 Shaega、Buin 和研究东部边界其他地区的影响。为该研究开发的 MARS 模型具有很高的预测能力,模型 1(NIPI)的 R2 值为 0.9665,RMSE 和 MAE 值分别为 0.8227 和 0.4287。模型 2(Cdeg)的 R2 值为 0.9863,RMSE 和 MAE 分别为 1.0416 和 0.6181。模型 3(mCdeg)的 R2 值为 0.9844,RMSE 和 MAE 分别为 0.1225 和 0.0670。这些研究结果表明,MARS 模型可以与污染指数合作,成为土壤质量分析的一个不可或缺的工具。研究建议采取补救和立法措施来解决该地区的非法采矿问题。
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引用次数: 0
Evaluation of azo dyes degradation potential of Aspergillus strains: A strategy for waste management 评估曲霉菌株降解偶氮染料的潜力:废物管理策略
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-19 DOI: 10.1016/j.hazadv.2024.100475
Sidra Ghafoor , Eeman Ali , Fazal Rahim , Dilara Abbas Bukhari , Shaista Shafiq , Syed Zajif Hussain , Abdul Rehman

The negative impact of azo dye emission on the lifestyle of humans, germination of plants, and the survival of marine life forms disturbs the whole food chain. The current investigation uses Aspergillus fumigatus and Aspergillus flavus to evaluate their degradation potential for Sumifex Tourqi Blue and Navy Blue dyes. The loss of the original dye peaks in the visible region by UV–Vis spectra showed the potential of Aspergillus strains to decolorize and degrade azo dyes. The respective decolorization percentages were 75 % and 48 % for Sumifex Tourqi Blue and Navy Blue by A. fumigatus, whereas 63 % and 85 % for both azo dyes by A. flavus. The GC-MS analysis of the degraded product exhibited different compounds such as Furo[2,3-c] pyridine-2-carboxylic acid, 5-(methylthio)-, ethyl ester, Ethanone, 1-(5,6,7,8-tetrahydro-2,8,8-trimethyl-4H-cyclohepta[b]furan-5-yl), Oxazole, 2-[1,1′-biphenyl]-4-yl-5-phenyl, etc. The efficient production of laccase by the fungal strains proved that the enzyme played a crucial role in decolorizing the harmful azo dyes. The most enzyme activity was recorded by A. flavus, 393 % for Sumifex Tourqi Blue and 299 % for Navy Blue by A. fumigatus. Based on their ability to decolorize and degrade such dyes, Aspergillus strains can be a good bioresource for green chemistry to eradicate azo dyes from the environment.

偶氮染料的排放对人类的生活方式、植物的发芽和海洋生物的生存产生了负面影响,扰乱了整个食物链。目前的研究使用烟曲霉和黄曲霉来评估它们对 Sumifex Tourqi Blue 和 Navy Blue 染料的降解潜力。紫外可见光谱显示,在可见光区域原有染料峰的消失表明曲霉菌株具有脱色和降解偶氮染料的潜力。烟曲霉对 Sumifex Tourqi Blue 和 Navy Blue 的脱色率分别为 75% 和 48%,而黄曲霉对这两种偶氮染料的脱色率分别为 63% 和 85%。降解产物的气相色谱-质谱分析显示出不同的化合物,如呋喃并[2,3-c]吡啶-2-羧酸 5-甲硫基乙酯、乙酮、1-(5,6,7,8-四氢-2,8,8-三甲基-4H-环庚烷并[b]呋喃-5-基)、噁唑、2-[1,1′-联苯]-4-基-5-苯基等。真菌菌株高效产生的漆酶证明,该酶在有害偶氮染料的脱色过程中发挥了关键作用。黄曲霉的酶活性最高,对 Sumifex Tourqi Blue 的脱色率为 393%,对海军蓝的脱色率为 299%。基于其脱色和降解此类染料的能力,曲霉菌株可以成为绿色化学中消除环境中偶氮染料的良好生物资源。
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引用次数: 0
Association between serum levels of 4-tertiary-octylphenol and thyroid function in a young cohort study 一项年轻队列研究中 4-叔辛基苯酚血清水平与甲状腺功能之间的关系
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-19 DOI: 10.1016/j.hazadv.2024.100476
Chien-Yu Lin , Hui-Ling Lee , Ching-Way Chen , Fung-Chang Sung , Ta-Chen Su
4-tertiary-octylphenol (4-t-OP) is a commonly used alkylphenol present in a variety of consumer products. Earlier experimental investigations have suggested that 4-t-OP leads to thyroid dysfunction. However, it is unclear whether these effects translate to humans. We recruited 886 adolescents and young adults (aged 12–30 years) from Taiwan and explored the associations between serum levels of 4-t-OP and various thyroid panel parameters including free and total thyroxine (T4) and triiodothyronine (T3), thyroid-stimulating hormone (TSH), and thyroxine-binding globulin (TBG). Our findings indicated that a one-unit increase in the natural logarithm (ln) of 4-t-OP levels was positively associated with both total T3 and ln free T4, with β values of 3.122 (SE = 1.400, P = 0.026) and 0.046 (SE = 0.015, P = 0.002), respectively. Furthermore, we observed a statistically significant upward trend in the mean values of total T3 and ln free T4 as the quartiles of 4-t-OP exposure increased (P for trend = 0.001 and 0.025, respectively). Nevertheless, our analysis did not uncover any differences in the odds ratio of thyroid diseases based on exposure to 4-t-OP in the logistic regression analysis. In conclusion, our study reveals an association between serum concentrations of 4-t-OP and biomarkers of thyroid function. However, these effects may manifest as subclinical. Further investigations are essential to establish a causal relationship between 4-t-OP exposure and thyroid function in human subjects.
4-叔辛基苯酚(4-t-OP)是一种常用的烷基酚,存在于多种消费品中。早期的实验研究表明,4-t-OP 会导致甲状腺功能紊乱。然而,目前还不清楚这些影响是否适用于人类。我们从台湾招募了 886 名青少年和年轻人(12-30 岁),探讨了血清中 4-t-OP 水平与游离甲状腺素(T4)、总甲状腺素(T4)、三碘甲状腺原氨酸(T3)、促甲状腺激素(TSH)和甲状腺素结合球蛋白(TBG)等各种甲状腺指标之间的关系。我们的研究结果表明,4-t-OP 水平的自然对数(ln)每增加一个单位都与总 T3 和游离 T4 呈正相关,β 值分别为 3.122(SE = 1.400,P = 0.026)和 0.046(SE = 0.015,P = 0.002)。此外,我们还观察到,随着 4-t-OP 暴露量四分位数的增加,总 T3 和 ln 游离 T4 的平均值呈统计学意义上的显著上升趋势(趋势的 P 值分别为 0.001 和 0.025)。尽管如此,在逻辑回归分析中,我们的分析并未发现甲状腺疾病的几率因暴露于 4-t-OP 而存在任何差异。总之,我们的研究揭示了血清中 4-t-OP 浓度与甲状腺功能生物标志物之间的关系。不过,这些影响可能表现为亚临床症状。要确定人体暴露于 4-t-OP 与甲状腺功能之间的因果关系,还需要进一步的研究。
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引用次数: 0
Policy pathways to sustainable E-waste management: A global review 可持续电子废物管理的政策途径:全球审查
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-16 DOI: 10.1016/j.hazadv.2024.100473
Sai Preetham Grandhi , Pranav Prashant Dagwar , Deblina Dutta

Electronic waste (E-waste) is a critical challenge of today's period, with around 57 million tons generated in 2021, of which only about 9 million tons were properly recycled, E-waste tends to affect the globe with issue like, illegal recycling, improper landfill disposal, illicit exports and others. Addressing this issue requires sustained, well-structured efforts, with effective policy interventions which are key towards reducing E-waste, by providing a framework for minimizing its generation and safeguarding the environment. These policies can ensure proper disposal methods, public awareness, device repair and refurbishment, and recycling rates with E-waste management monetizing the efforts of E-waste management startups. The study examines innovative E-waste policies across various countries which includes Extended Producer Responsibility (EPR), WEEE directives, regional laws, and State level laws, highlighting successful strategies such as incentivized recycling programs and stricter regulations on hazardous materials. The aim of the paper is to update information with an emphasis on global trends of E-waste, emphasizing the importance of robust policies in reducing environmental harm and lowering the cost of new electronics through efficient recycling.

电子废物(E-waste)是当今时代面临的一项严峻挑战,2021 年产生的电子废物约为 5700 万吨,其中仅有约 900 万吨得到妥善回收,电子废物往往会影响全球,如非法回收、不当填埋处置、非法出口等问题。要解决这一问题,就必须做出持续的、结构合理的努力,采取有效的政策干预措施,通过提供一个最大限度减少电子废物产生和保护环境的框架,这是减少电子废物的关键所在。这些政策可以确保正确的处置方法、公众意识、设备维修和翻新以及回收率,并通过电子废物管理将电子废物管理初创企业的努力货币化。本研究探讨了各国创新的电子废弃物政策,包括生产者延伸责任(EPR)、WEEE 指令、地区性法律和国家级法律,重点介绍了激励性回收计划和更严格的有害物质法规等成功策略。本文旨在更新信息,重点介绍全球电子废物的发展趋势,强调强有力的政策在减少环境危害和通过高效回收降低新电子产品成本方面的重要性。
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引用次数: 0
Real-time nitrogen monitoring and management to augment N use efficiency and ecosystem sustainability–A review 实时氮监测和管理,提高氮利用效率和生态系统可持续性--综述
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-15 DOI: 10.1016/j.hazadv.2024.100466
Swathy Ravikumar , Geethalakshmi Vellingiri , Pazhanivelan Sellaperumal , Kannan Pandian , Annamalai Sivasankar , Hwang Sangchul
Agriculture faces the pressing challenge of feeding a growing population while preserving the environment and natural resources. Nitrogen (N) is an essential nutrient for plant growth, and its availability in soil is a key indicator of fertility. However, the indiscriminate use of N fertilizers can lead to nutrient imbalances and soil degradation, underscoring the need for accurate and efficient soil N management. Traditional sampling and analysis methods are time-consuming and prone to error, making real-time soil N assessments crucial for effective management. Moreover, precise estimation of soil N is vital for monitoring losses, developing targeted fertilizer strategies, and enhancing crop productivity and N use efficiency. Real-time N management, which involves applying N as needed during critical growth stages, can significantly improve its usage efficiency. To achieve this, the leaf color chart offers a simple, inexpensive, and user-friendly solution for assessing N needs based on leaf color, facilitating real-time management. Furthermore, sensors and the Internet of Things (IoT) play a key role in sustainable soil management and crop productivity, contributing to the development of resilient food systems and reducing uncertainty in global food markets. Accurate, rapid, cost-effective methods for assessing soil N levels are essential to achieve these sustainable goals. This review delves into the current status, limitations, and future of N-sensing in precision agriculture, highlighting cutting-edge technologies such as real-time monitoring using remote and proximal sensors, ground-based canopy sensors, drones, and Unmanned Aerial Vehicle (UAV) equipped with high-resolution cameras or multispectral/hyperspectral sensors, Geographic Information Systems (GIS)- Global Positioning Systems (GPS) integration (GIS-GPS), data analysis, Variable Rate Technology (VRT) and crop models for precise N management. By harnessing these innovations, we can revolutionize agriculture, benefiting plant health and promoting a more sustainable future.
农业面临着既要养活不断增长的人口,又要保护环境和自然资源的紧迫挑战。氮(N)是植物生长所必需的养分,土壤中氮(N)的含量是衡量肥力的关键指标。然而,氮肥的滥用会导致养分失衡和土壤退化,因此需要对土壤中的氮进行准确有效的管理。传统的取样和分析方法耗时且容易出错,因此实时土壤氮评估对有效管理至关重要。此外,精确估算土壤氮对监测损失、制定有针对性的施肥策略、提高作物产量和氮利用效率也至关重要。实时氮肥管理包括在关键生长阶段按需施用氮肥,可显著提高氮肥的使用效率。为此,叶色图提供了一种简单、廉价、用户友好的解决方案,可根据叶色评估氮的需求,从而促进实时管理。此外,传感器和物联网(IoT)在可持续土壤管理和作物生产力方面发挥着关键作用,有助于发展具有抗灾能力的粮食系统,减少全球粮食市场的不确定性。要实现这些可持续目标,必须采用准确、快速、具有成本效益的方法来评估土壤氮含量。本综述深入探讨了精准农业中氮传感技术的现状、局限性和未来,重点介绍了一些前沿技术,如利用远程和近距离传感器、地面冠层传感器、无人机和配备高分辨率相机或多光谱/高光谱传感器的无人机(UAV)、地理信息系统(GIS)-全球定位系统(GPS)集成(GIS-GPS)、数据分析、可变速率技术(VRT)和作物模型进行实时监测,以实现精确的氮管理。通过利用这些创新技术,我们可以彻底改变农业,使植物健康受益,并促进未来的可持续发展。
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引用次数: 0
Prediction of particulate matter during the combustion of wood pellets with the addition of face mask waste 预测木质颗粒燃烧过程中的颗粒物质,并添加口罩废料
IF 5.4 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-15 DOI: 10.1016/j.hazadv.2024.100474
Nikola Čajová Kantová , Radovan Nosek , Alexander Čaja , Michal Holubčík

The amount of plastic waste has increased enormously due to the using of protective equipment in order to slow down the viral transmission of COVID-19. The usage of protective face masks brought a huge environmental burden. Moreover, a lot of disposed masks enter the ocean or end on landfills, where they threaten the ecosystem. It is still necessary to deal with environmental-friendly disposal or to reuse and recycle of these masks. This article is focused on the disposal of FFP2 face masks by their co-combustion with wood. Due to the possibility of produced emissions, disintegrated masks were blended with spruce and beech sawdust and compared with pure wood. These materials were compressed into pellets with the aim of higher density. The emissions such as carbon monoxide, nitrogen oxides, sulphur oxides and particulate matter were measured during pellet combustion. The heat output of the automatic pellet boiler was also determined. The filters with captured particulate matter were sent to the investigation of dioxin and furan concentration. Except for this, the regression model has been created for the prediction the concentration of particulate matter. The results confirmed that the co-combustion of wood with FFP2 masks could be one of the environmental-friendly ways of face mask disposal when they are used as an additive in a small percentage. The fuel composition and operational conditions are also very important parameters during the combustion process. However, the concentration of gas emissions and particulate matter, as well as heat output, did not change significantly, when the content of FFP2 masks of 5 % or 10 % was used.

为了减缓 COVID-19 病毒的传播,人们使用了防护设备,因此塑料垃圾的数量大大增加。防护口罩的使用带来了巨大的环境负担。此外,大量废弃口罩进入海洋或被填埋,威胁着生态系统。因此,仍有必要对这些口罩进行环保处置或再利用和回收。本文主要介绍 FFP2 口罩与木材共燃的处理方法。由于可能会产生废气,因此将分解的口罩与云杉和山毛榉锯屑混合,并与纯木材进行比较。这些材料被压缩成颗粒,目的是提高密度。在颗粒燃烧过程中,对一氧化碳、氮氧化物、硫氧化物和颗粒物等排放物进行了测量。此外,还测定了自动颗粒锅炉的发热量。捕获颗粒物的过滤器被送去调查二恶英和呋喃的浓度。除此之外,还建立了一个回归模型,用于预测颗粒物的浓度。结果证实,如果将 FFP2 口罩作为添加剂小比例使用,木材与 FFP2 口罩共同燃烧可能是一种环保的口罩处理方式。在燃烧过程中,燃料成分和操作条件也是非常重要的参数。然而,当 FFP2 面具的含量为 5% 或 10% 时,气体排放和颗粒物的浓度以及热量输出并没有显著变化。
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引用次数: 0
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Journal of hazardous materials advances
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