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Geologic setting of mineral licks and availability of trace element nutrients: case study of the Dewar Creek geothermal spring site in the Canadian Cordillera 矿物舔舔的地质背景和微量元素营养物质的可用性:加拿大科迪勒拉地区杜瓦溪地热温泉遗址的案例研究
Pub Date : 2025-04-13 DOI: 10.1016/j.jtemin.2025.100243
Paul L. Broughton

Background

The link between the geology and development of mineral licks involves the mineralogy and availability of metallic elements that are necessary for mammalian nutritional requirements. The chemistries of natural mineral licks have been widely documented, but their constituent elements necessary for mammalian nutrition have usually not been linked to regional tectono-stratigraphic controls on their mineralogy and element availability. The extensive mineral lick emplaced along the Dewar Creek geothermal spring area in southeast British Columbia of the Canadian Cordillera has a dominant carbonate mineralogy that has been a longstanding attraction to ungulates. This case study provides insight into how the geologic context directly controls the availability of various trace metal nutrient ions and thereby attracts mammalian wildlife.

Materials and methods

Sediments collected along the Dewar Creek geothermal spring are analyzed for their mineralogy and trace element concentration to further our understanding as to why the site is attractive to ungulates as a mineral lick.

Results and conclusions

The geologic framework provides the overall context for the location of mineral licks that result in the availability of metallic elements necessary for the nutritional requirements of mammals, and furthers our understanding on how the geologic framework controls the location of mineral licks that provide specific elements necessary for the health of ungulates. High concentrations of Sr (3000–12,000 ppm) and Mn (4000–9000 ppm) are incorporated into different carbonate minerals that accumulated as bottom sediment and overlying crust along the geothermal spring. The unusually high concentration of bioactive strontium in particular at this mineral lick facilitates the attractiveness to ungulates because of the impact on mammalian bone osteoporosis.
地质和矿物舔舐之间的联系涉及矿物学和金属元素的可用性,这些元素是哺乳动物营养需求所必需的。天然矿物岩石的化学成分已被广泛记载,但其构成哺乳动物营养所必需的元素通常没有与区域构造地层对其矿物学和元素可用性的控制联系起来。在加拿大科迪勒拉省东南部的不列颠哥伦比亚省,沿着杜瓦溪地热温泉区,分布着广阔的矿物lick,其主要的碳酸盐矿物学长期以来一直吸引着有蹄类动物。这个案例研究提供了地质环境如何直接控制各种微量金属营养离子的可用性,从而吸引哺乳动物野生动物的见解。材料和方法沿着杜瓦溪地热泉收集的沉积物进行了矿物学和微量元素浓度分析,以进一步了解为什么这个地方对有蹄类动物有吸引力。结果和结论地质框架为矿物舔舐的位置提供了总体背景,从而导致哺乳动物营养需求所需的金属元素的可用性,并进一步加深了我们对地质框架如何控制矿物舔舐的位置的理解,而矿物舔舐为有蹄类动物的健康提供了必要的特定元素。高浓度的锶(3000 - 12000 ppm)和锰(4000-9000 ppm)被合并到不同的碳酸盐矿物中,这些矿物作为底部沉积物和沿着地热泉的上覆地壳积累。由于对哺乳动物骨质疏松症的影响,这种矿物质舔舐处异常高浓度的生物活性锶促进了对有蹄类动物的吸引力。
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引用次数: 0
Contamination status and toxicity risk assessment of selected potentially toxic elements in surface soils under the influence of different land uses in Midwestern Burkina Faso, West Africa 西非布基纳法索中西部受不同土地用途影响的表层土壤中某些潜在有毒元素的污染状况和毒性风险评估
Pub Date : 2025-04-09 DOI: 10.1016/j.jtemin.2025.100241
Michel Bembamba , Aboubakar Sako

Background

As land use transitions from rain-fed farming to market gardening and artisanal gold mining in Burkina Faso, soil contamination with potentially toxic elements (PTEs) has become a major environmental concern.

Objective

This study investigates the PTE pollution status of highly anthropized soil in Midwestern Burkina Faso.

Methods

A total of 226 topsoil samples were collected, and their PTE concentrations were determined using inductively coupled plasma mass spectrometry (ICP-MS). Enrichment factors and ecological and toxicity risk indices were used to evaluate the soil's contamination status.

Results

The results revealed that artisanal gold mining mainly contributed to Ag, As, Cd, Cu, Ni, and Zn loadings in the soils, whereas agricultural practices might have partially contributed to Pb concentrations. Based on the spatial distribution maps of the ecological risk index (RI), the studied soils exhibited low (23–104), moderate (150 ≤ RI < 300), and very high (RI>600) risk levels. Samples with high toxicity units (ΣTU > 4) and toxicity risk index (TRI > 20) were clustered around artisanal gold mining sites. The strong spatial and linear correlations between ΣTU and RI (r² = 0.79), and between RI and TRI (r² = 0.90), suggest that the newly developed toxicity indices are suitable for assessing PTE toxicity in soils.

Conclusion

The study's findings demonstrate that, in addition to chemical weathering, uncontrolled artisanal gold mining activities and, to a lesser degree, agricultural practices are likely to threaten soil functioning and food security. The study provides valuable insights into the ongoing global discourse on PTE distribution and its effects on soil environmental quality.
背景在布基纳法索,随着土地利用从雨养农业向市场园艺和手工金矿的转变,潜在有毒元素(pte)的土壤污染已成为一个主要的环境问题。目的调查布基纳法索中西部高度人类活动土壤PTE污染状况。方法采集226份表层土壤样品,采用电感耦合等离子体质谱法(ICP-MS)测定其PTE浓度。利用富集因子和生态毒性风险指标评价土壤污染状况。结果手工采金对土壤中Ag、As、Cd、Cu、Ni和Zn的富集起主要作用,而农业活动对土壤中Pb的富集可能起部分作用。土壤生态风险指数(RI)空间分布图显示:低(23-104)、中等(150≤RI <);300)和非常高(600)的风险水平。含有高毒性单位的样品(ΣTU >;4)和毒性风险指数(TRI >;20座城市聚集在手工金矿附近。ΣTU与RI (r²= 0.79)、RI与TRI (r²= 0.90)具有较强的空间相关性和线性相关性,表明新建立的毒性指标适合于评价PTE在土壤中的毒性。研究结果表明,除了化学风化外,不受控制的手工采金活动以及在较小程度上的农业实践也可能威胁土壤功能和粮食安全。该研究为正在进行的关于PTE分布及其对土壤环境质量影响的全球讨论提供了有价值的见解。
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引用次数: 0
Discovery of heavy mineral sand in Djiboutian coastline (Obock area, SE Afar rift) 吉布提海岸线(阿法尔裂谷东南部奥博克地区)重矿砂的发现
Pub Date : 2025-04-08 DOI: 10.1016/j.jtemin.2025.100242
N. Moussa , J. Etoubleau , T. Mohamed , J. Langlade , M.O. Awaleh

Background

In this paper, we present the first study of black sand deposits collected along the coastline of the Obock area, which is located in the North East part of Djibouti (SE Afar Rif). This area consists mainly of uplifted madrepores, sand dunes and alluvial deposits.

Materials and Methods

Geochemical studies were carried out using techniques such as X-ray fluorescence (XRF) to quantify the heavy mineral sands. Electron microprobe and X-ray diffraction (XRD) techniques were used to identify minerals.

Results

Mineral sands have been identified in coastal backshore deposits, containing light minerals (calcite, aragonite, quartz, anorthite, augite, microcline, albite, enstatite, nontronite and diopside) and heavy minerals (hematite, ilmenite, chromite and magnetite). In general, titanium dioxide (TiO2) and iron oxide (Fe2O3) are found in the backshore, with averages of TiO2 (23.9 %) and Fe2O3 (53.9 %) in the total of heavy mineral fraction.

Conclusions

Although, titanomagnetite is not widely exploited in the world due of the treatment to enrich ores with Fe and Ti, the presence of ilmenite and vanadium as trace elements in the subsurface and in titanomagnetite respectively, even at very low grades may potentially justify further of the lateral extent and depth geochemical and drilling investigations in order to upgrade the concentration of titanium oxide in the Obock coastal sands.
本文首次对吉布提东北部(阿法尔裂谷东南部)奥博克地区海岸线上的黑砂沉积进行了研究。该地区主要由隆起的泥蚶、沙丘和冲积沉积物组成。材料和方法利用x射线荧光(XRF)等技术进行了地球化学研究,以量化重矿砂。采用电子探针和x射线衍射(XRD)技术对矿物进行了鉴定。结果在沿海后海岸矿床中发现了矿砂,包括轻矿物(方解石、文石、石英、钙长石、辉长石、微斜长石、钠长石、顽辉石、非辉长石和透辉石)和重矿物(赤铁矿、钛铁矿、铬铁矿和磁铁矿)。一般情况下,后滩中主要存在二氧化钛(TiO2)和氧化铁(Fe2O3),重矿物组分中TiO2和Fe2O3的平均含量分别为23.9%和53.9%。结论虽然钛磁铁矿在世界范围内由于对矿石进行了铁、钛富集处理而未得到广泛开发,但在地下和钛磁铁矿中分别存在微量元素钛铁矿和钒,即使含量很低,也可能进一步进行横向和深度的地球化学和钻探调查,以提高奥博克海岸砂中氧化钛的浓度。
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引用次数: 0
Speciation of arsenic and concentration of cadmium and arsenic in rice (Oryza sativa L.) cultivated under co-exposure of cadmium/arsenic and different water ponding 镉/砷与不同水塘共暴露栽培水稻中砷的形态及镉和砷的浓度
Pub Date : 2025-03-27 DOI: 10.1016/j.jtemin.2025.100240
Tatiana Pedron, Valmir Silva, Fernanda Pollo Paniz, Bruno Lemos Batista
Over three billion people consume rice (Oryza sativa L), an important cereal in the human diet. It is cultivated typically in flooded soils. However, it is also grown in soils with limited water (upland or dryland). There are few studies on the concomitant translocation of As and Cd from soil to rice in different irrigation systems. The present work aimed to verify the influence of 3 irrigation systems (dry soil, semi-dry, and flooded soil) on the absorption and translocation of arsenic (As) and cadmium (Cd) in the rice cultivar GURI INTA CL. Four different soil treatments were used in each of these irrigation regimes: As 10 mg kg-1 only, Cd 10 mg kg-1 only, 10 mg kg-1 of As + Cd, and the control group (no As/Cd additions). Arsenic treatment affected the agronomic parameters (stem masses and heights and the mass of grains) of the plants cultivated in dry soil and semi-dry soil. It was observed that the co-exposure in flooded soil presented a higher concentration of total As with the lowest percentage of inorganic As (iAs 37.6 %) in grains. Co-exposure or only As had a similar iAs percentage in grains from plants cultivated under other irrigation systems ( ̴ 55 %). The highest Cd concentration was observed in the dry soil irrigation system, for both roots and grains, mainly in co-exposure treatment. Thus, the rice cultivar GURI INTA CL raised in flooded soils absorb higher amounts of As and lesser amounts of Cd. On the contrary, in dry soil there is higher and lesser absorption of Cd and As, respectively. Therefore, this new knowledge on the dynamics of absorption and translocation of As and Cd in Brazilian rice cultivars can provide mitigation strategies for the contamination of rice grains by toxic elements.
超过30亿人食用水稻(Oryza sativa L),这是人类饮食中重要的谷物。它通常在淹水土壤中种植。然而,它也生长在水分有限的土壤中(高地或旱地)。不同灌溉方式下砷和镉从土壤向水稻的同步转运研究较少。本研究旨在验证3种灌溉方式(干土、半干土和淹水土)对水稻砷(As)和镉(Cd)吸收和转运的影响。在每个灌溉方案中使用了四种不同的土壤处理:仅添加10 mg kg-1的砷、仅添加10 mg kg-1的镉、10 mg kg-1的砷+镉和对照组(不添加As/Cd)。砷处理影响了干、半干土壤中栽培植物的农艺参数(茎质量、茎高和籽粒质量)。结果表明,共暴露在淹水土壤中,总砷含量较高,籽粒中无机砷含量最低(37.6%)。在其他灌溉系统下种植的植物的籽粒中,共暴露或仅暴露a的a百分比相似(55%)。旱地灌溉系统中,根和籽粒Cd浓度最高,主要在共暴露处理中。因此,水稻品种GURI INTA CL在淹水土壤中对砷的吸收量较高,对镉的吸收量较低,而在干燥土壤中对镉和砷的吸收量分别较高和较低。因此,这一关于巴西水稻品种砷和镉吸收和转运动力学的新知识可以为缓解有毒元素对稻米的污染提供策略。
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引用次数: 0
Assessment of toxic elements contamination in cigarettes sold in algeria and associated health risks 评估在阿尔及利亚销售的香烟中有毒元素的污染情况及相关的健康风险
Pub Date : 2025-03-24 DOI: 10.1016/j.jtemin.2025.100239
A.I. CHEBLI , Z. CHELIGHEM , A. ZERGUI , A. AMZIANE , Y. ZEBBICHE , A. BELLOUM , S. ABDENNOUR

Introduction

Tobacco consumption remains a critical public health concern globally, with Algeria among the highest tobacco-consuming countries in Africa. Cigarettes contain toxic elements like lead, cadmium, mercury, chromium, and nickel, contributing to severe health risks, including cancer and cardiovascular diseases. This study aimed to (i) determine their concentrations in Algerian cigarettes and (ii) evaluate associated non-carcinogenic and carcinogenic health risks in smokers.

Materials and Method

A total of 200 samples from 25 brands were randomly collected from various retail outlets, then analyzed using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). To assess their health risks, Average Daily Dose (ADD), the Hazard Quotient; (HQ), the Hazard Index (HI), and the lifetime average daily dose (LADDi) were calculated and compared with international Studies.

Results and Discussion

Analysed tobacco brands sold in Algeria have found to be contaminated by Pb, Cd, Hg, Cr, and Ni. The highest levels of Pb, Cd, Hg, Cr, and Ni were 19.02 ± 0.26, 0.72 ± 0.02, 0.450 ± 0.05, 8.96 ± 0.18, and 4.93 ± 0.06 μg.g−1 respectively. The limits of quantification (LOQ) were determined as follows: 0.0011 μg/g for Pb, 0.0018 μg/g for Cd, 0.0017 μg/g for Hg, 0.0013 μg/g for Cr, and 0.0014 μg/g for Ni. Recovery rates exceeded 80 % for all elements, ensuring the reliability of the analytical method. The Brand n°06 had the highest content in Pb, Hg, and Cr. This metallic contamination can be due to soil pollution as tobacco plants are highly capable of absorbing toxic elements, but also the manufacturing process and the use of flavours.The non-carcinogenic risk with HI > 1 was found in 96 % of the brands, primarily from lead and cadmium while 44 % had acceptable carcinogenic risks, mainly related to chromium.

Conclusion

This study highlights the presence of toxic elements in cigarettes sold in Algeria at levels that could pose significant health risks. Given the scarcity of data on this issue in the region, our findings emphasize the need for stricter regulations and further studies to better assess and mitigate the exposure of Algerian smokers to these toxic elements.
烟草消费仍然是全球一个严重的公共卫生问题,阿尔及利亚是非洲烟草消费量最高的国家之一。香烟含有铅、镉、汞、铬和镍等有毒元素,会造成严重的健康风险,包括癌症和心血管疾病。本研究旨在(i)确定阿尔及利亚香烟中这些物质的浓度,(ii)评估吸烟者的相关非致癌性和致癌性健康风险。材料与方法随机抽取25个品牌的200份样品,采用电感耦合等离子体质谱法(ICP-MS)进行分析。评估其健康风险,平均日剂量(ADD),危害商数;计算危害指数(HI)和终生平均日剂量(LADDi),并与国际研究结果进行比较。结果和讨论经分析,在阿尔及利亚销售的烟草品牌被发现受到Pb、Cd、Hg、Cr和Ni的污染。Pb、Cd、Hg、Cr、Ni的最高浓度分别为19.02±0.26、0.72±0.02、0.450±0.05、8.96±0.18、4.93±0.06 μg。分别g−1。测定的定量限为:Pb 0.0011 μg/g、Cd 0.0018 μg/g、Hg 0.0017 μg/g、Cr 0.0013 μg/g、Ni 0.0014 μg/g。所有元素的回收率均超过80%,保证了分析方法的可靠性。n°06品牌的铅、汞和铬含量最高。这种金属污染可能是由于土壤污染,因为烟草植物吸收有毒元素的能力很强,但也可能是由于生产过程和香精的使用。HI >的非致癌风险;1在96%的品牌中被发现,主要来自铅和镉,而44%的品牌具有可接受的致癌风险,主要与铬有关。结论:本研究强调了在阿尔及利亚销售的香烟中有毒元素的存在,其含量可能构成重大健康风险。鉴于该地区关于这一问题的数据缺乏,我们的研究结果强调需要更严格的法规和进一步的研究,以更好地评估和减轻阿尔及利亚吸烟者对这些有毒元素的暴露。
{"title":"Assessment of toxic elements contamination in cigarettes sold in algeria and associated health risks","authors":"A.I. CHEBLI ,&nbsp;Z. CHELIGHEM ,&nbsp;A. ZERGUI ,&nbsp;A. AMZIANE ,&nbsp;Y. ZEBBICHE ,&nbsp;A. BELLOUM ,&nbsp;S. ABDENNOUR","doi":"10.1016/j.jtemin.2025.100239","DOIUrl":"10.1016/j.jtemin.2025.100239","url":null,"abstract":"<div><h3>Introduction</h3><div>Tobacco consumption remains a critical public health concern globally, with Algeria among the highest tobacco-consuming countries in Africa. Cigarettes contain toxic elements like lead, cadmium, mercury, chromium, and nickel, contributing to severe health risks, including cancer and cardiovascular diseases. This study aimed to (i) determine their concentrations in Algerian cigarettes and (ii) evaluate associated non-carcinogenic and carcinogenic health risks in smokers.</div></div><div><h3>Materials and Method</h3><div>A total of 200 samples from 25 brands were randomly collected from various retail outlets, then analyzed using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). To assess their health risks, Average Daily Dose (ADD), the Hazard Quotient; (HQ), the Hazard Index (HI), and the lifetime average daily dose (LADDi) were calculated and compared with international Studies.</div></div><div><h3>Results and Discussion</h3><div>Analysed tobacco brands sold in Algeria have found to be contaminated by Pb, Cd, Hg, Cr, and Ni. The highest levels of Pb, Cd, Hg, Cr, and Ni were 19.02 ± 0.26, 0.72 ± 0.02, 0.450 ± 0.05, 8.96 ± 0.18, and 4.93 ± 0.06 μg.<em>g</em><sup>−1</sup> respectively. The limits of quantification (LOQ) were determined as follows: 0.0011 μg/g for Pb, 0.0018 μg/g for Cd, 0.0017 μg/g for Hg, 0.0013 μg/g for Cr, and 0.0014 μg/g for Ni. Recovery rates exceeded 80 % for all elements, ensuring the reliability of the analytical method. The Brand n°06 had the highest content in Pb, Hg, and Cr. This metallic contamination can be due to soil pollution as tobacco plants are highly capable of absorbing toxic elements, but also the manufacturing process and the use of flavours.The non-carcinogenic risk with HI &gt; 1 was found in 96 % of the brands, primarily from lead and cadmium while 44 % had acceptable carcinogenic risks, mainly related to chromium.</div></div><div><h3>Conclusion</h3><div>This study highlights the presence of toxic elements in cigarettes sold in Algeria at levels that could pose significant health risks. Given the scarcity of data on this issue in the region, our findings emphasize the need for stricter regulations and further studies to better assess and mitigate the exposure of Algerian smokers to these toxic elements.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100239"},"PeriodicalIF":0.0,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716139","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corn (Zea mays L.) production and chlorophyll fluorescence affected by drought stress, N fertilization, and genotype 干旱胁迫、施氮和基因型对玉米产量和叶绿素荧光的影响
Pub Date : 2025-03-21 DOI: 10.1016/j.jtemin.2025.100237
Mansour Halimi Soufi, Hamid Reza Mobasser, Ahmad Mehraban, Hamid Reza Ganjali, Khaled Miri

Background

Corn (Zea mays L.) physiology and production in drought stress conditions may be importantly affected by soil N and plant genotype.

Objective

So, more has yet to be indicated on how drought stress and N fertilization may affect production and chlorophyll florescence of corn genotypes as the objective of the present research.

Methods

The experiment was a split plot on the basis of a randomized complete block design (RCBD) with four replicates conducted in two research sites in 2020. Drought stress levels (main plots) including irrigation after 70 mm evaporation from evaporating pan Class A, irrigation stoppage at flowering, grain filling and both flowering and grain filling, N chemical fertilization (sub plots) including control (0), 100, 200, 300 kg ha-1 and corn genotypes (sub-sub plots) including Kusha 201 (G1), Fajr 260 (G2), and Dehghan 400 (G3) were tested. Different corn morphological (cob diameter, CDM), yield (biological yield, BY, and harvest index, HI) and florescence indices (Fo, Fm, Fv, and Fv/Fm) were determined.

Results

Although drought stress significantly decreased CDM, biological yield, and fluorescence indices, N fertilization (N300) alleviated the stress and G1 had higher BY, and G3 had less CDM (medium) and higher HI and Fo. The significant interaction of drought stress and N fertilization indicates, depending on the level of drought stress, the response of corn genotypes to N fertilization is different.

Conclusion

Depending on stress intensity, determination of appropriate level of N feralization and genotype may result in the most optimum yield production.
干旱胁迫条件下玉米(Zea mays L.)的生理和生产受到土壤氮和植株基因型的重要影响。因此,干旱胁迫和施氮对玉米产量和叶绿素荧光的影响尚不清楚,这是本研究的目的。方法采用随机完全区组设计(RCBD)的分割图,于2020年在两个试验点进行4个重复试验。试验了干旱胁迫水平(主区),包括蒸发盘A级蒸发70 mm后灌溉、开花时停止灌溉、灌浆和开花灌浆同时灌浆、施氮(小区),包括对照(0)、100、200、300 kg ha-1和玉米基因型(小区),包括Kusha 201 (G1)、Fajr 260 (G2)和Dehghan 400 (G3)。测定了不同玉米形态(穗轴直径,CDM)、产量(生物产量,BY和收获指数,HI)和荧光指数(Fo, Fm, Fv和Fv/Fm)。结果尽管干旱胁迫显著降低了CDM、生物产量和荧光指标,但施氮(N300)缓解了胁迫,G1具有较高的BY, G3具有较低的CDM(中等)和较高的HI和Fo。干旱胁迫与施氮显著的交互作用表明,不同干旱胁迫水平下,玉米基因型对施氮的响应不同。结论根据不同的胁迫强度,确定适宜的施氮水平和基因型可获得最优产量。
{"title":"Corn (Zea mays L.) production and chlorophyll fluorescence affected by drought stress, N fertilization, and genotype","authors":"Mansour Halimi Soufi,&nbsp;Hamid Reza Mobasser,&nbsp;Ahmad Mehraban,&nbsp;Hamid Reza Ganjali,&nbsp;Khaled Miri","doi":"10.1016/j.jtemin.2025.100237","DOIUrl":"10.1016/j.jtemin.2025.100237","url":null,"abstract":"<div><h3>Background</h3><div>Corn (<em>Zea mays</em> L.) physiology and production in drought stress conditions may be importantly affected by soil N and plant genotype.</div></div><div><h3>Objective</h3><div>So, more has yet to be indicated on how drought stress and N fertilization may affect production and chlorophyll florescence of corn genotypes as the objective of the present research.</div></div><div><h3>Methods</h3><div>The experiment was a split plot on the basis of a randomized complete block design (RCBD) with four replicates conducted in two research sites in 2020. Drought stress levels (main plots) including irrigation after 70 mm evaporation from evaporating pan Class A, irrigation stoppage at flowering, grain filling and both flowering and grain filling, N chemical fertilization (sub plots) including control (0), 100, 200, 300 kg ha<sup>-1</sup> and corn genotypes (sub-sub plots) including Kusha 201 (G1), Fajr 260 (G2), and Dehghan 400 (G3) were tested. Different corn morphological (cob diameter, CDM), yield (biological yield, BY, and harvest index, HI) and florescence indices (Fo, Fm, Fv, and Fv/Fm) were determined.</div></div><div><h3>Results</h3><div>Although drought stress significantly decreased CDM, biological yield, and fluorescence indices, N fertilization (N300) alleviated the stress and G1 had higher BY, and G3 had less CDM (medium) and higher HI and Fo. The significant interaction of drought stress and N fertilization indicates, depending on the level of drought stress, the response of corn genotypes to N fertilization is different.</div></div><div><h3>Conclusion</h3><div>Depending on stress intensity, determination of appropriate level of N feralization and genotype may result in the most optimum yield production.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100237"},"PeriodicalIF":0.0,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comprehensive assessment of trace element pollution and its distribution in surface and groundwater around the Ishwardi export processing zone, Bangladesh 孟加拉国Ishwardi出口加工区周边地表水和地下水微量元素污染及其分布的综合评价
Pub Date : 2025-03-20 DOI: 10.1016/j.jtemin.2025.100238
Nitu Islam , A. H. M. Selim Reza , Md. Abdur Rahman , Md. Shazzadur Rahman

Introduction

Due to industrial development and rapid urbanization, the discharge of industrial effluents significantly impacts the environment and ecosystems, particularly affecting surface and groundwater systems. This study assesses trace element contamination near the Ishwardi Export Processing Zone (IEPZ) in Bangladesh, with the aim of evaluating trace element concentrations in both surface and groundwater and their potential environmental impacts in and around the IEPZ.

Materials and methods

Fourteen samples, including industrial waste, groundwater, and river water, were collected from the IEPZ. The concentrations of trace elements like Pb, Cd, Cr, Ni, Cu, and Co in the collected samples were measured. Statistical analyses, including principal component analysis (PCA), were performed with a confidence level of 95 % and a significance threshold of p < 0.05.

Results and discussion

Levels of Pb, Cu, and Ni exceeded World Health Organization (WHO) guidelines in some samples, with Pb ranging from 4.3 to 34.3 µg l-1, indicating potential health risks. The Contamination Index (Cd) varied from -2.696 to 0.277, reflecting low contamination, while the Metal Pollution Index (MPI) was 1.603, suggesting generally satisfactory water quality. PCA highlighted two components which explained 36.182 % and 28.161 % cumulative variance for PCA1 and PCA2, respectively.

Conclusion

This study investigates the impact of industrial effluent discharge on surface and groundwater quality around the IEPZ, Bangladesh. Among the trace elements, Pb showed the highest concentration, likely due to battery recycling/manufacturing at one of the factories in the IEPZ. The wastewater flows into nearby rivers and also leaches into the surrounding groundwater. These findings emphasize the need for ongoing monitoring and improved waste management to mitigate the environmental impacts of industrial discharges in the IEPZ.
导言由于工业发展和快速城市化,工业废水的排放对环境和生态系统产生了重大影响,特别是对地表水和地下水系统的影响。本研究评估了孟加拉国Ishwardi出口加工区(IEPZ)附近的微量元素污染,目的是评估地表水和地下水中的微量元素浓度及其在IEPZ及其周围的潜在环境影响。材料与方法从IEPZ收集了14个样品,包括工业废水、地下水和河水。测定了样品中Pb、Cd、Cr、Ni、Cu、Co等微量元素的浓度。统计分析包括主成分分析(PCA),置信水平为95%,显著性阈值为p <;0.05.结果与讨论部分样品的Pb、Cu和Ni含量超过世界卫生组织(WHO)的指导标准,Pb含量在4.3 ~ 34.3µg -1之间,表明存在潜在的健康风险。污染指数(Cd)为-2.696 ~ 0.277,污染程度较低;金属污染指数(MPI)为1.603,水质基本满意。PCA突出了两个分量,分别解释了PCA1和PCA2的36.182%和28.161%的累积方差。结论本研究调查了工业废水排放对孟加拉国IEPZ周边地表水和地下水水质的影响。在微量元素中,铅的浓度最高,可能是由于在IEPZ的一个工厂回收/制造电池。废水流入附近的河流,也渗入周围的地下水。这些调查结果强调需要不断监测和改进废物管理,以减轻国际环境保护区内工业排放对环境的影响。
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引用次数: 0
Comparative effect of dietary fortification of raw and roasted seeds of pumpkin (Cucurbita pepo L) on fertility biomolecules in cisplatin-induced spermatotoxic rats 膳食中添加生南瓜和烤南瓜对顺铂诱导的精子中毒大鼠生育能力生物分子的影响
Pub Date : 2025-03-16 DOI: 10.1016/j.jtemin.2025.100236
Seun Funmilola Akomolafe , Mary Aderonke Bola Ogundare , Ibikunle Akinlua , Oluwadamilare Oluwaseun Ajayi , Elijah Olalekan Odesanmi , Olusola Bolaji Adewale

Introduction

Cisplatin is a known chemotherapeutic/anticancer drug, reported to induce oxidative stress, a major risk factor in male infertility. However, studies have shown that dietary pattern plays a pivotal role in the protection of chemotherapy-induced testicular damage, and till date no report on the comparative effect of raw and roasted pumpkin seeds against chemotherapy-induced male infertility and reproductive dysfunction. Therefore, this study sought to evaluate how raw and roasted pumpkin seed enriched diets affect reproductive function biomarkers in adult male Wistar rats that had been exposed to a single dose (7 mgkg-1 i.p) of cisplatin-induced testicular damage.

Methods

Rats were fed with basal diets (CTRL), cisplatin-induced rats fed with basal diet (CIS); cisplatin-induced rats fed diet supplemented with raw (5 % and 10 %) and cisplatin-induced rats fed roasted (5 % and 10 %) pumpkin seeds for 14 days. A single administration of cisplatin was done 14th day after treatment with supplemented diet, and the rats were euthanized 24 h later for the evaluation of reproductive hormones, epidydimal sperm parameters, nitric oxide level, testicular and epididymal total thiol level and non-protein thiol level, catalase, glutathione-S-transferase and steroidogenic enzymes activities.

Results

Reproductive hormones, epidydimal sperm parameters, and both testicular and epididymal levels of nitric oxide, total thiol and non-protein thiol, as well as glutathione-S-transferase, catalase and steroidogenic enzyme activities were significantly elevated (p < 0.05), with a reduction in arginase activity, and levels of malondialdehyde and reactive oxygen species in testes and epididymis of cisplatin- spermatotoxic rats pre-fed with pumpkin seed in comparison with untreated cisplatin-induced testicular damage rats. Testes architectures were efficiently restored in cisplatin-intoxicated rats pre-fed with pumpkin seed. In the immunohistochemistry assay, there were fewer caspase-3 expressions in cisplatin-intoxicated rats pre-fed with roasted pumpkin seed than in those pre-treated with raw pumpkin seed and untreated cisplatin-intoxicated group.

Conclusion

The ameliorative effects of raw and roasted pumpkin seeds on various biochemical parameters associated with fertility may suggest its role in enhancing male fertility in rats exposed to cisplatin. However, the roasted pumpkin seeds was noted to possess more ameliorative effect than raw seed.
顺铂是一种已知的化疗/抗癌药物,据报道可诱导氧化应激,这是男性不育的主要危险因素。然而,研究表明,饮食模式在化疗引起的睾丸损伤的保护中起着关键作用,迄今为止还没有关于生南瓜子和烤南瓜子对化疗引起的男性不育和生殖功能障碍的比较效果的报道。因此,本研究旨在评估在暴露于单剂量(7 mg -1 i.p)顺铂诱导睾丸损伤的成年雄性Wistar大鼠中,生南南籽和烤南南籽丰富的饮食如何影响生殖功能生物标志物。方法大鼠饲喂基础饲粮(CTRL),顺铂诱导大鼠饲喂基础饲粮(CIS);顺铂诱导大鼠饲喂添加生南瓜子(5%和10%)的日粮,顺铂诱导大鼠饲喂烤南瓜子(5%和10%)14天。在给药后第14天添加顺铂单次给药,24 h后处死大鼠,测定生殖激素、附睾精子参数、一氧化氮水平、睾丸和附睾总硫醇和非蛋白硫醇水平、过氧化氢酶、谷胱甘肽- s转移酶和甾体生成酶活性。结果生殖激素、附睾精子参数、睾丸和附睾一氧化氮、总硫醇和非蛋白硫醇水平以及谷胱甘肽- s转移酶、过氧化氢酶和甾体生成酶活性均显著升高(p <;0.05),与未治疗的顺铂致睾丸损伤大鼠相比,预先喂食南瓜籽的顺铂精子中毒大鼠睾丸和附睾精氨酸酶活性、丙二醛和活性氧水平降低。顺铂中毒大鼠预先喂食南瓜子后,睾丸结构得到有效恢复。免疫组化结果显示,预喂烤南瓜子的顺铂中毒大鼠的caspase-3表达量低于预喂生南瓜子和未喂顺铂中毒大鼠。结论生南瓜子和烤南瓜子对顺铂暴露大鼠生殖力相关生化指标的改善作用可能提示其具有提高雄性生殖力的作用。然而,焙烧南瓜子比生南瓜子具有更大的改善作用。
{"title":"Comparative effect of dietary fortification of raw and roasted seeds of pumpkin (Cucurbita pepo L) on fertility biomolecules in cisplatin-induced spermatotoxic rats","authors":"Seun Funmilola Akomolafe ,&nbsp;Mary Aderonke Bola Ogundare ,&nbsp;Ibikunle Akinlua ,&nbsp;Oluwadamilare Oluwaseun Ajayi ,&nbsp;Elijah Olalekan Odesanmi ,&nbsp;Olusola Bolaji Adewale","doi":"10.1016/j.jtemin.2025.100236","DOIUrl":"10.1016/j.jtemin.2025.100236","url":null,"abstract":"<div><h3>Introduction</h3><div>Cisplatin is a known chemotherapeutic/anticancer drug, reported to induce oxidative stress, a major risk factor in male infertility. However, studies have shown that dietary pattern plays a pivotal role in the protection of chemotherapy-induced testicular damage, and till date no report on the comparative effect of raw and roasted pumpkin seeds against chemotherapy-induced male infertility and reproductive dysfunction. Therefore, this study sought to evaluate how raw and roasted pumpkin seed enriched diets affect reproductive function biomarkers in adult male Wistar rats that had been exposed to a single dose (7 mgkg<sup>-1</sup> i.p) of cisplatin-induced testicular damage.</div></div><div><h3>Methods</h3><div>Rats were fed with basal diets (CTRL), cisplatin-induced rats fed with basal diet (CIS); cisplatin-induced rats fed diet supplemented with raw (5 % and 10 %) and cisplatin-induced rats fed roasted (5 % and 10 %) pumpkin seeds for 14 days. A single administration of cisplatin was done 14th day after treatment with supplemented diet, and the rats were euthanized 24 h later for the evaluation of reproductive hormones, epidydimal sperm parameters, nitric oxide level, testicular and epididymal total thiol level and non-protein thiol level, catalase, glutathione-S-transferase and steroidogenic enzymes activities.</div></div><div><h3>Results</h3><div>Reproductive hormones, epidydimal sperm parameters, and both testicular and epididymal levels of nitric oxide, total thiol and non-protein thiol, as well as glutathione-S-transferase, catalase and steroidogenic enzyme activities were significantly elevated (<em>p</em> &lt; 0.05), with a reduction in arginase activity, and levels of malondialdehyde and reactive oxygen species in testes and epididymis of cisplatin- spermatotoxic rats pre-fed with pumpkin seed in comparison with untreated cisplatin-induced testicular damage rats. Testes architectures were efficiently restored in cisplatin-intoxicated rats pre-fed with pumpkin seed. In the immunohistochemistry assay, there were fewer caspase-3 expressions in cisplatin-intoxicated rats pre-fed with roasted pumpkin seed than in those pre-treated with raw pumpkin seed and untreated cisplatin-intoxicated group.</div></div><div><h3>Conclusion</h3><div>The ameliorative effects of raw and roasted pumpkin seeds on various biochemical parameters associated with fertility may suggest its role in enhancing male fertility in rats exposed to cisplatin. However, the roasted pumpkin seeds was noted to possess more ameliorative effect than raw seed.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100236"},"PeriodicalIF":0.0,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143683012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metallic contaminants in foodstuff consumed in Algeria and associated health risks: A systematic review 阿尔及利亚消费的食品中的金属污染物及其相关的健康风险:系统审查
Pub Date : 2025-03-16 DOI: 10.1016/j.jtemin.2025.100235
Anissa ZERGUI , Akli Islam CHEBLI , Mohamed Amine KERDOUN , Fatiha HAMITRI-GUERFI , Rahma MAYOUF , Houaria TOUER , Bilel CHEFIRAT , Sofiane BOUDALIA

Introduction

For decades, metallic trace elements contamination in food has posed a significant public health risk, as these metals accumulate in the body, affecting food safety and human health. This review examines the toxicity of trace elements in foodstuffs, focusing on their contamination sources and the associated health risks.

Methodology

Keywords such as Algeria, Food, Beverages, trace elements, and Metallic Contaminants were used to search related databases.

Results and discussion

A total of 22 original articles were reviewed. Data showed that trace elements were recorded in foodstuffs, which were related to geographic location (proximity to mining, industrial or highway areas), use of pesticides, and techniques in food processing. In adults, Targeted Hazard Quotient (THQ) values exceeded 1 for lead in raw cow milk, aluminum in coffee beans and packaged coffee, cadmium and aluminum in coffee capsules, and lead in fruits and vegetables. The Hazard Index (HI) was above 1 for raw cow milk, coffee, and fruits and vegetables. For infants, THQ values also exceeded 1 for raw cow milk, poultry eggs, honey, and food dyes, with elevated HI values for these items as well. These results suggest potential adverse health effects of trace elements exposure from consuming these foodstuffs.

Conclusion

It is crucial to regularly update data and conduct ongoing monitoring to assess the impact of trace elements in future research. Additionally, continued investigation into the long-term health effects of chronic low-level trace elements exposure will be vital for creating more precise mitigation strategies and regulatory policies to reduce metallic contamination in food.
几十年来,食品中的金属微量元素污染已构成重大的公共健康风险,因为这些金属在体内积累,影响食品安全和人体健康。本文综述了食品中微量元素的毒性,重点介绍了其污染源和相关的健康风险。方法以阿尔及利亚、食品、饮料、微量元素、金属污染物等关键词进行数据库检索。结果与讨论共回顾了22篇原创文章。数据显示,食品中记录了微量元素,这与地理位置(靠近采矿、工业或高速公路区域)、杀虫剂的使用和食品加工技术有关。在成人中,生牛奶中的铅、咖啡豆和包装咖啡中的铝、咖啡胶囊中的镉和铝以及水果和蔬菜中的铅的目标危害商(THQ)值超过1。生牛奶、咖啡、水果和蔬菜的危害指数(HI)都在1以上。对婴儿来说,生牛奶、禽蛋、蜂蜜和食用色素的THQ值也超过了1,这些物品的HI值也有所升高。这些结果表明,从食用这些食品中接触微量元素可能对健康产生不利影响。结论定期更新数据和开展持续监测是评价微量元素对未来研究影响的关键。此外,继续调查长期低水平微量元素接触对健康的长期影响,对于制定更精确的缓解战略和监管政策以减少食品中的金属污染至关重要。
{"title":"Metallic contaminants in foodstuff consumed in Algeria and associated health risks: A systematic review","authors":"Anissa ZERGUI ,&nbsp;Akli Islam CHEBLI ,&nbsp;Mohamed Amine KERDOUN ,&nbsp;Fatiha HAMITRI-GUERFI ,&nbsp;Rahma MAYOUF ,&nbsp;Houaria TOUER ,&nbsp;Bilel CHEFIRAT ,&nbsp;Sofiane BOUDALIA","doi":"10.1016/j.jtemin.2025.100235","DOIUrl":"10.1016/j.jtemin.2025.100235","url":null,"abstract":"<div><h3>Introduction</h3><div>For decades, metallic trace elements contamination in food has posed a significant public health risk, as these metals accumulate in the body, affecting food safety and human health. This review examines the toxicity of trace elements in foodstuffs, focusing on their contamination sources and the associated health risks.</div></div><div><h3>Methodology</h3><div>Keywords such as Algeria, Food, Beverages, trace elements, and Metallic Contaminants were used to search related databases.</div></div><div><h3>Results and discussion</h3><div>A total of 22 original articles were reviewed. Data showed that trace elements were recorded in foodstuffs, which were related to geographic location (proximity to mining, industrial or highway areas), use of pesticides, and techniques in food processing. In adults, Targeted Hazard Quotient (THQ) values exceeded 1 for lead in raw cow milk, aluminum in coffee beans and packaged coffee, cadmium and aluminum in coffee capsules, and lead in fruits and vegetables. The Hazard Index (HI) was above 1 for raw cow milk, coffee, and fruits and vegetables. For infants, THQ values also exceeded 1 for raw cow milk, poultry eggs, honey, and food dyes, with elevated HI values for these items as well. These results suggest potential adverse health effects of trace elements exposure from consuming these foodstuffs.</div></div><div><h3>Conclusion</h3><div>It is crucial to regularly update data and conduct ongoing monitoring to assess the impact of trace elements in future research. Additionally, continued investigation into the long-term health effects of chronic low-level trace elements exposure will be vital for creating more precise mitigation strategies and regulatory policies to reduce metallic contamination in food.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100235"},"PeriodicalIF":0.0,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143645027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Availability and mobilisation of potentially harmful elements in contaminated mining sites: A systematic review of using soil amendments and plants for remediation 受污染矿区潜在有害元素的可得性和动员:使用土壤改良剂和植物进行修复的系统审查
Pub Date : 2025-03-15 DOI: 10.1016/j.jtemin.2025.100234
Albert Kobina Mensah , Ephraim Sekyi-Annan , Emmanuel Amoakwah

Aim

Environmental contamination in Ghana constitutes both a political and sustainability challenge. This study offers a contemporary analysis of the influence and prevalence of potentially harmful elements (PHEs) in the environment related to mining activities. Additionally, we examine soil remediation initiatives and research conducted in the previous decade to tackle soil contamination and pollution issues within the mining industry.

Material and methods

The study focused on peer-reviewed publications in the last decade (i.e., 2014–2024) identified in the Scopus database. The search included articles written in English at the final stage of publication and all open-access content, including those published in gold. The study context was in Ghana. A total of 185 publications related to topics such as biochar, iron oxides, compost, charcoal, phytoremediation, organic amendments, inorganic fertilisers, and soil amendments were identified within the aforementioned time frame.

Results and discussions

We found 2,175 global document results from 2014 to 2024 related to soil amendments and phytoremediation for remediating harmful elements in mine-soils. We identified 524 documents in Ghana, which accounted for 24% of global research articles on these topics. The 185 studies that were included made up 35% of all studies on mine-contaminated soils in Ghana that used organic amendments and phytoremediation strategies. Consequently, the 185 documents constituted 9% of all research articles published in the world.

Conclusions and implications

We emphasise the importance of implementing strategies to mitigate PHE contamination to protect the health of humans, plants, and animals. Overall, green remediation can effectively tackle PHEs contamination problems, minimise the spread of metals and metalloids in the food chain, prevent their transfer into surface water and groundwater resources, and ensure a clean environment.
加纳的环境污染既是一项政治挑战,也是一项可持续性挑战。本研究对与采矿活动有关的环境中潜在有害元素的影响和普遍程度进行了当代分析。此外,我们还研究了过去十年中为解决采矿业土壤污染和污染问题而进行的土壤修复倡议和研究。材料和方法本研究的重点是Scopus数据库中最近十年(即2014-2024年)同行评议的出版物。搜索包括在出版的最后阶段用英文写的文章和所有开放获取的内容,包括那些用金字发表的文章。研究背景是在加纳。在上述时间框架内,共确定了185份与生物炭、氧化铁、堆肥、木炭、植物修复、有机修正、无机肥料和土壤修正等主题相关的出版物。结果与讨论我们从2014年到2024年收集了2175份与土壤修复和植物修复有关的全球文献结果,以修复矿山土壤中有害元素。我们在加纳确定了524篇文献,占全球关于这些主题的研究文章的24%。纳入的185项研究占加纳所有使用有机改剂和植物修复策略的地雷污染土壤研究的35%。因此,这185篇论文占世界上发表的所有研究论文的9%。结论和意义我们强调实施策略以减轻PHE污染对保护人类、植物和动物健康的重要性。总体而言,绿色修复可以有效解决多环芳烃污染问题,最大限度地减少金属和类金属在食物链中的扩散,防止其向地表水和地下水资源转移,确保环境清洁。
{"title":"Availability and mobilisation of potentially harmful elements in contaminated mining sites: A systematic review of using soil amendments and plants for remediation","authors":"Albert Kobina Mensah ,&nbsp;Ephraim Sekyi-Annan ,&nbsp;Emmanuel Amoakwah","doi":"10.1016/j.jtemin.2025.100234","DOIUrl":"10.1016/j.jtemin.2025.100234","url":null,"abstract":"<div><h3>Aim</h3><div>Environmental contamination in Ghana constitutes both a political and sustainability challenge. This study offers a contemporary analysis of the influence and prevalence of potentially harmful elements (PHEs) in the environment related to mining activities. Additionally, we examine soil remediation initiatives and research conducted in the previous decade to tackle soil contamination and pollution issues within the mining industry.</div></div><div><h3>Material and methods</h3><div>The study focused on peer-reviewed publications in the last decade (i.e., 2014–2024) identified in the Scopus database. The search included articles written in English at the final stage of publication and all open-access content, including those published in gold. The study context was in Ghana. A total of 185 publications related to topics such as biochar, iron oxides, compost, charcoal, phytoremediation, organic amendments, inorganic fertilisers, and soil amendments were identified within the aforementioned time frame.</div></div><div><h3>Results and discussions</h3><div>We found 2,175 global document results from 2014 to 2024 related to soil amendments and phytoremediation for remediating harmful elements in mine-soils. We identified 524 documents in Ghana, which accounted for 24% of global research articles on these topics. The 185 studies that were included made up 35% of all studies on mine-contaminated soils in Ghana that used organic amendments and phytoremediation strategies. Consequently, the 185 documents constituted 9% of all research articles published in the world.</div></div><div><h3>Conclusions and implications</h3><div>We emphasise the importance of implementing strategies to mitigate PHE contamination to protect the health of humans, plants, and animals. Overall, green remediation can effectively tackle PHEs contamination problems, minimise the spread of metals and metalloids in the food chain, prevent their transfer into surface water and groundwater resources, and ensure a clean environment.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100234"},"PeriodicalIF":0.0,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143683083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of trace elements and minerals
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