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Guleman Kromit Yatağı Çevresindeki İnci Çayı Sedimentlerindeki Metal Kirliliğinin Temel Değer ve Ortalama Yerkabuğu Değerleri Tarafından Değerlendirilmesi (Alacakaya-Elazığ), Türkiye
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1180088
H. Kara
The total concentration of elements in the Inci stream sediments on the drainage network of chromite deposits was determined to evaluate the level of contamination by natural background, the average of ultramafic and mafic rocks in this study. The average concentration shows that toxic heavy metals originated from mineraliszing in the Inci stream sediments that have a controlling influence on accumulation and transportation both lithologically and anthropogenically. The metal enrichment factors of Pb, As, Ni, Sr, and Ba, and geoaccumulation factor values (Igeo) of Pb, As, Sr, Ba, and Rb indicated that these values are higher than background values and heavily contaminated. The highest metal concentrations and assessments of contaminants were obtained from ultramafic rock normalization. Enrichment factor (EF), contamination factor (CF), and Igeo values indicate that primary ore metals are represented by Pb, Cu, Mn, Ni, and Cr. Cr's enrichment factor (EF) is moderate contamination due to the high Cr concentration in the host rock. However, Cr is extremely contaminated according to the Earth's average in the stream sediments around the chromites deposit. The calculated Cu, Ni, and Cr threshold values are higher than the probable effect level (PEL) and threshold effect level (TEL). That is why these regions should be evaluated for relationships between human health and geochemistry in further multidisciplinary studies and considered important in terms of potential Cr, Cu, Mn, Ni, Pb and Zn mineralization.
利用自然背景、超镁铁质和基性岩石的平均值,测定了印溪溪铬铁矿水系沉积物中元素的总浓度,评价了污染程度。平均浓度表明,印溪河沉积物中有毒重金属来源于矿化作用,对其聚集和运移具有岩性和人为控制作用。Pb、As、Ni、Sr、Ba的金属富集因子和Pb、As、Sr、Ba、Rb的地质富集因子(Igeo)值均高于背景值,污染严重。最高的金属浓度和污染物的评估是由超镁质岩石标准化获得的。富集因子(EF)、污染因子(CF)和Igeo值表明,原生矿石金属主要以Pb、Cu、Mn、Ni和Cr为代表,Cr的富集因子(EF)为中度污染,主要受寄主岩石中Cr含量较高的影响。而铬铁矿周围的水系沉积物中铬的污染程度按地球平均值计算为极严重。计算得到的Cu、Ni和Cr阈值均高于可能效应水平(PEL)和阈值效应水平(TEL)。因此,在进一步的多学科研究中,应评估这些区域的人类健康与地球化学之间的关系,并认为这些区域在潜在的Cr、Cu、Mn、Ni、Pb和Zn矿化方面具有重要意义。
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引用次数: 0
Yeni Bir Schiff Bazı Molekülüne in Siliko Tıbbi ve Hesaplamalı Yöntemlerle Bir Bakış
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1237445
Songül Şahi̇n, Necmi Dege
In this study, the synthesis and characterization of a new Schiff base molecule, (E)-1-(5-nitro-2-(piperidin-1-yl) phenyl)-N-(4-phenoxyphenyl) methanimine, were aimed. In addition, the molecular surface area, crystalline structure, intermolecular forces, electronic and spectroscopic properties of the molecule were investigated. Docking studies were also performed on the active sites of the main protease (Mpro) of SARS-CoV-2, and the docking result was compared with the efficacy of the native ligand N3 inhibitor. The main findings for the title molecule can be summarized as follows: The space group is P-1 and it crystallizes in the triclinic system. The unit cell consists of two monomeric units (Z=2). There are strong electrophilic attack sites in the molecule, but nucleophilic centers have low efficiency. According to the FMO analysis, the title compound is a soft, kinetically and chemically unstable and highly reactive material. The value of the binding free energy calculated by docking experiments (-9.28 kcal mol-1) is lower than that of the native inhibitor (-7.11 kcal/mol) and thus can be considered as a potential inhibitor candidate for the main protease of SARS-CoV-2.
本文合成并表征了一种新的希夫碱分子(E)-1-(5-硝基-2-(胡椒碱-1-基)苯基)- n-(4-苯氧苯基)甲亚胺。此外,还研究了该分子的分子表面积、晶体结构、分子间力、电子和光谱性质。对SARS-CoV-2主要蛋白酶(Mpro)活性位点进行对接研究,并将对接结果与天然配体N3抑制剂的疗效进行比较。标题分子的主要发现如下:空间群为P-1,在三斜体系中结晶。单元胞由两个单体组成(Z=2)。分子中有很强的亲电攻击位点,但亲核中心的攻击效率较低。根据FMO分析,标题化合物是一种柔软,动力学和化学不稳定的高活性材料。对接实验计算的结合自由能值(-9.28 kcal mol-1)低于天然抑制剂(-7.11 kcal/mol),可以认为是SARS-CoV-2主要蛋白酶的潜在候选抑制剂。
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引用次数: 1
Characterization of Stimuli-Responsive Acrylamide/Sodium Methacrylate/Kaolin Semi-Interpenetrating Polymer Network Composite Hydrogels 刺激响应型丙烯酰胺/甲基丙烯酸钠/高岭土半互穿聚合物网络复合水凝胶的表征
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1247090
Gülcihan GÜZEL KAYA, H. Deveci
With the advantages of their self-healing, stimuli-response ability, water sorption capacity and shape memory, hydrogels have been commonly utilized. However, new strategies have been developed to enhance mechanical and thermal properties of hydrogels in addition to increase their water sorption. In this study, stimuli-responsive acrylamide/sodium methacrylate based hydrogels were synthesized with the optimization of sodium methacrylate amount by free radical polymerization. With the incorporation of optimum amount of polyethylene glycol 400 (PEG-400) into the hydrogel network, semi-interpenetrating polymer network (semi-IPN) hydrogels were prepared. With the addition of kaolin, swelling properties of the semi-IPN composite hydrogels were investigated in water under the effect of different pH and temperature. Maximum swelling percent of the semi-IPN composite hydrogels was determined as 24214% at pH 7 and 25 °C. Fourier transform infrared spectroscopy (FTIR) analyses revealed that hydrogel samples were successfully synthesized. Morphological structure of hydrogel samples was examined by scanning electron microscopy (SEM) analyses. Both of the water motion through the hydrogel layered structure and water diffusion into the pores made the semi-IPN composite hydrogel more swollen material compared to the acrylamide/sodium methacrylate based hydrogel.
水凝胶具有自愈、刺激反应能力、吸水能力和形状记忆等优点,已被广泛应用。然而,除了增加水凝胶的吸水性外,还开发了新的策略来提高水凝胶的机械和热性能。本研究以甲基丙烯酸钠用量为优化条件,采用自由基聚合法制备了刺激响应型丙烯酰胺/甲基丙烯酸钠基水凝胶。在水凝胶网络中掺入一定量的聚乙二醇400 (PEG-400),制备了半互穿聚合物网络水凝胶。在添加高岭土的情况下,研究了半ipn复合水凝胶在不同pH和温度下在水中的膨胀性能。在pH 7和25℃条件下,半ipn复合水凝胶的最大溶胀率为24214%。傅里叶变换红外光谱(FTIR)分析表明,水凝胶样品成功合成。用扫描电镜(SEM)分析了水凝胶样品的形态结构。水在水凝胶层状结构中的运动和水在孔隙中的扩散使得半ipn复合水凝胶比丙烯酰胺/甲基丙烯酸钠基水凝胶更具膨胀性。
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引用次数: 0
Modeling of Surface Modification of Stainless Steel by Halide Activated Pack Cementation Method 卤化物活化填料胶结法对不锈钢表面改性的建模
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1175101
F. Kahriman
In high-temperature applications, ferrous-based materials are important due to their excellent combination of desirable mechanical properties, ease of production, corrosion resistance at room temperature and cost-effectiveness. However, mechanical properties must be optimized against environmental effects. Depending on the industrial applications, various corrosion types may also occur. An approach to preserve the mechanical properties of the structural alloy being protected against corrosion is the application of protective coatings to the surfaces. Diffusion coatings are an effective method to obtain corrosion, oxidation and abrasion resistance against detrimental conditions of high temperature. According to the literature, the halide activated pack cementation method has been widely used for ferrous-based materials for a long time. However, most studies concerned with developing coating applications are based on experimental investigations that include microscopic, chemical, and mechanical analyses. Limited studies have been conducted based on computational alloy approaches. In this study, Cr coating of the AISI 316L steel by halide activated pack cementation method was considered as a diffusional problem and the kinetics of the coating deposition process were examined. The effect of process variables such as temperature, time and the compositions of coating layers formed on the surfaces were investigated thermodynamically with Thermo-Calc software and kinetically with DICTRA module. This approach provides insight into the dependence of solid-state diffusions on the processing parameters, and a better understanding of the phases that form along the coating and substrate material.
在高温应用中,基于铁的材料是重要的,因为它们具有理想的机械性能,易于生产,在室温下耐腐蚀和成本效益的优异组合。然而,机械性能必须针对环境影响进行优化。根据工业应用的不同,还可能发生各种腐蚀类型。保护结构合金的机械性能的一种方法是在表面涂上保护涂层。扩散涂层是在高温条件下获得耐腐蚀、抗氧化和抗磨损的有效方法。据文献报道,卤化物活化充填胶结法长期以来被广泛应用于含铁基材料。然而,大多数与开发涂层应用有关的研究都是基于实验研究,包括微观、化学和力学分析。基于计算合金方法进行了有限的研究。本研究将aisi316l钢卤化物活化包埋法的Cr涂层视为扩散问题,并对涂层沉积过程进行动力学研究。利用hot - calc软件和DICTRA模块分别研究了温度、时间和涂层成分等工艺变量对表面形成的影响。这种方法可以深入了解固态扩散对工艺参数的依赖,并更好地了解沿涂层和衬底材料形成的相。
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引用次数: 0
Physical Model and Performance Analysis of Switched Reluctance Machine 开关磁阻电机的物理模型及性能分析
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1261675
E. Öksüztepe
Son yıllarda ulaşım araçlarında elektrik makinaların hem itki hem de generatör olarak kullanılması gittikçe yaygınlaşmaktadır. Ulaşım aracının özel gereksinimleri ve çalışma şartları hangi elektrik makinasının kullanılmasının uygun olacağını belirlemektedir. Zorlu çalışma şartlarında, kullanılan elektrik makinasının performans analizi gerçek ortam yerine bilgisayar ortamında gerçekleştirilmesi prototip imalat giderlerinin azaltılması bakımından gereklidir. Bu çalışmada zorlu çalışma şartlarının olduğu ulaşım araçlarında hata toleransı yüksek olması, basit yapı ve yüksek verime sahip olması nedeniyle Anahtarlamalı Relüktans Makina ele alınmış ve fiziksel modeli Matlab Simscape Toolbox’da modellenmiştir. Sonlu Elemanlar Analizi’den elde edilen veriler kullanılarak modellenen makina hem motor hem de generatör olarak kontrol edilmiş ve performans analizi gerçekleştirilmiştir. Benzetim sonuçları ile önerilen yöntemin doğruluğu ispatlanmıştır.
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引用次数: 0
Best-Worst Yöntemi ile Arazilerin Tarımsal Kullanıma Uygunluklarının Belirlenmesi
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1229833
Gamze Akyüz, Şükran Yalpir, E. Ertunç
The interaction of agricultural activities with the land starts with soil in the production part and continues until the consumption stage. Sustainable agricultural land for their use, a database regarding their current potential should be created and the land prepared based on this database should be evaluated by considering the use planning. The suitability of Ankara province lands for agricultural use by making use of the Geographical Information System analysis was carried out. To determine the suitability for agricultural use; Major Soil Groups, Land Use Capability Classes, soil depth, degree of erosion, elevation, slope, aspect, precipitation, and temperature criteria were used. This was done with the Best-Worst method, which is one of the multi-criteria decision-making approaches. It was ensured that the best and worst of the nine factors were determined by the decision makers. In the last layer, because of the analyzes made for the province of Ankara, the most appropriate land use map was created based on the natural abilities and capabilities of the lands. It has been determined that the most affecting criterion is Large Soil Groups, and Ankara's Kızılcahamam, Çankaya and Mamak districts are not very suitable for agricultural use, but other districts are generally suitable for use.
农业活动与土地的相互作用从生产阶段的土壤开始,一直持续到消费阶段。应建立一个关于其目前潜力的数据库,并应通过考虑使用规划来评价根据该数据库编制的土地。利用地理信息系统分析了安卡拉省土地的适宜性。确定土地是否适合作农业用途;主要土壤类群、土地利用能力等级、土壤深度、侵蚀程度、高程、坡度、坡向、降水和温度标准被使用。采用多准则决策方法之一的“最佳-最差”方法进行决策。这确保了九个因素中最好和最差的是由决策者决定的。在最后一层,由于对安卡拉省进行了分析,因此根据土地的自然能力和能力创建了最合适的土地使用地图。已确定影响最大的标准是大土壤群,安卡拉的Kızılcahamam、Çankaya和Mamak区不太适合农业用途,但其他地区一般适合使用。
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引用次数: 0
Mikrodizi Veri Kümesi Üzerinde Doğadan İlham Alan Optimizasyon ile Birleştirilen Uyarlanabilir Ağ Tabanlı Bulanık Çıkarım Sistemi Kullanılarak T-ALL, B-ALL ve T-LL Malignitelerinin Sınıflandırılması
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1259929
Fatma Akalin, Nejat Yumuşak
Leukemia is the formation of cancer with different characteristic findings. According to the progress type of disease in the body is called acute or chronic. Acute leukemias are characterized by the presence of blast cells that proliferate uncontrollably in the bone marrow and then go into the blood and tissues. Determination of T/B or non T/B cell class is important in the immunophenotypic evaluation related to subtypes of blast cells. Because the diagnosis and treatment processes of B-ALL, T-ALL and T-LL subtypes, which are composed of B and T cell lines, are different. Therefore, correct diagnosis is vital. In this study, the molecular diagnosis was provided for the accurate detection of T-ALL, B-ALL and T-LL subtypes through microarray datasets. But, microarray datasets have a multidimensional structure. Because it contains information related to the disease as well as information not related to the disease. This situation also affects the training situation and computational cost of the model. For this, the whale optimization algorithm was used in the first stage of the study. Thus, related genes were selected from the data set. Secondly, the selected potential genes were given as input to the ANFIS structure. Then, in order to improve the inference power, parameter optimization related to the membership function of the ANFIS structure was provided with ABC and PSO optimization algorithms. Finally, the predictions obtained from the ANFIS, ANFIS+ABC, and ANFIS+PSO methods for each sample were classified using the logistic regression algorithm and, an accuracy rate of 86.6% was obtained.
白血病是一种具有不同特征性表现的癌症。根据病情的进展类型,在体内被称为急性或慢性。急性白血病的特点是骨髓中存在不受控制的增殖母细胞,然后进入血液和组织。确定T/B或非T/B细胞类别在与胚细胞亚型相关的免疫表型评估中是重要的。由于由B细胞系和T细胞系组成的B- all、T- all和T- ll亚型的诊断和治疗过程不同。因此,正确的诊断至关重要。本研究通过微阵列数据集,为T-ALL、B-ALL和T-LL亚型的准确检测提供分子诊断。但是,微阵列数据集具有多维结构。因为它既包含与疾病相关的信息,也包含与疾病无关的信息。这种情况也会影响模型的训练情况和计算成本。为此,在第一阶段的研究中使用了鲸鱼优化算法。因此,从数据集中选择相关基因。其次,将选择的潜在基因作为输入输入到ANFIS结构中。然后,为了提高推理能力,采用ABC和PSO优化算法对ANFIS结构的隶属度函数进行参数优化。最后,将ANFIS、ANFIS+ABC和ANFIS+PSO方法对每个样本的预测结果进行logistic回归算法分类,准确率为86.6%。
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引用次数: 0
Viscosity Values of Ternary Au-Ag-Cu, Al-Cu-Si and Quaternary Al-Cu-Mg-Si Alloy Systems 三元Au-Ag-Cu、Al-Cu-Si和季系Al-Cu-Mg-Si合金体系的粘度值
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1198907
H. Arslan
Bu çalışmada, üçlü Au-Ag-Cu sıvı alaşım sisteminin, Al-Cu-Si sıvı alaşım sisteminin ve dörtlü Al-Cu-Mg-Si sıvı alaşım sisteminin viskoziteleri altının, aliminyumun ve bakırın bir fonksiyonu olarak Au-Ag-Cu (xAg / xCu=0.543) 1373 K de, Alx(Cu50-Si50)(1-x), Cux(Al50-Si50)(1-x) 1375 K de ve Al-Cu7.6-Mg1.99-Si34.76 1500 K de farklı geometrik modeller kullanılarak hesaplanmıştır. Tüm sonuçlar, özellikle de Muggianu modeli ile hesaplanan sonuçlar, deneysel sonuçlarla iyi bir uyum göstermiştir. xSi = xCu, xMg / xCu = r ve r = 0.1, 0.5, 1 oranlarda Al-Cu-Mg-Si alaşımlarının viskozitelerinin alüminyumun bir fonksiyonu olarak büyük bileşimsel bağımlılık gösterdiği ve Al kompozisyonunun (0.4-0.8) arasındaki değerlerine eşlik eden viskozite değerlerinin max. ve min. (1.4-0.3) mPas olduğu görüldü.
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引用次数: 0
An Anatomical and Caryological Investigation On Monotypic Pallenis spinosa (L.) Cass. in Turkey 单型棘蕨(L.)的解剖学和牙学研究卡斯。在土耳其
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1269577
Bahattin Bozdağ
Pallenis spinosa (L.) Cass., which has an annual and herbacous life form, is represented by a single species (monotypic) in Turkey. There are 1-2 rows of epidermis cells in the root cross section of the taxon. Between the epidermis and the central cylinder is the cortex, which consists of parenchymatic cells. Root has a radial vasculer bundle. The cross-section of the stem has a round shape with single row and regular lined of cortex cell over the vascular bundle as a starch sheath. The sclerenchyma cells is cover the top of floem cells in the collateral vascular bundle. The leaves is a bifacial type. There are stomas and eglandular hairs both side of the leaves. Sclerenchyma cells are both side of vascular bundles in the leaves. We determined 2x = 2n = 10 chromosome number and made chromosome measurement and haploid idiogram of species.
白叶菊(L.)卡斯。它有一年生和草本的生命形式,在土耳其以单一物种(单型)为代表。根横切面上有1 ~ 2行表皮细胞。表皮和中央圆筒之间是皮层,由实质细胞组成。根有放射状维管束。茎的横切面呈圆形,单排排列规则的皮层细胞在维管束上形成淀粉鞘。在侧枝维管束中,厚壁细胞覆盖在花细胞的顶部。叶子是双面型的。叶片两侧有气孔和腺毛。厚壁组织细胞位于叶片维管束的两侧。测定了物种的2x = 2n = 10染色体数,并进行了染色体测定和单倍体示图。
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引用次数: 0
Production of Si3N4/SiC Composite Powder by Dynamic Thermochemical Method 动态热化学法制备氮化硅/碳化硅复合粉体
Pub Date : 2023-08-29 DOI: 10.35414/akufemubid.1242691
Betül Arslan, Nazlı Erken, N. Canikoğlu
Bu çalışmada, silisyum nitrür/silisyum karbür (Si3N4/SiC) kompozit tozu, 2 adımlı dinamik termokimyasal yöntem ile azot ve argon atmosferlerinde silisyum oksit ve karbonun reaksiyonuyla sentezlenmiştir. Bu amaçla farklı reçeteler hazırlanmış olup nitrürlenme ve karbürlenme sıcaklıkları (1400, 1450 ve 1500°C) ile işlem süresi (1 ve 2 saat) üzerine çalışmalar yapılmıştır. Öncelikle farklı reçeteler FactSage programı yardımıyla termodinamik olarak incelenmiştir. Uygun olabilecek reçeteler belirlendikten sonra hammadde karışımları, SiO2 ve karbon siyahı kullanılarak C/SiO2 oranı 2.25 ve 3 olacak şekilde hazırlanmıştır. Toz karışımlarından elde edilen granüllere uygulanan termokimyasal işlemler sonrasında kompozit toz üretimi için en optimum sonuç, 1450°C’de 2 saat N2 atmosferinde nitrürleme ve 1450°C’de 1 saat Ar atmosferinde karbürleme işlemleriyle 4 rpm dönme hızında sağlanmıştır. Üretilen tozların mikroyapı ve faz incelemeleri SEM-EDS ve XRD yöntemleriyle gerçekleştirilmiştir.
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引用次数: 0
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Afyon Kocatepe University Journal of Sciences and Engineering
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