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Preparation of Adsorbent with Lead Removal Ability from Paper Sludge Using Sulfur-impregnation 硫浸渍法制备造纸污泥除铅吸附剂
Pub Date : 2014-01-01 Epub Date: 2014-12-16 DOI: 10.1016/j.apcbee.2014.10.001
Takaaki Wajima

During the manufacture of recycled paper, paper sludge is discharged as an industrial waste. The amount of sludge discharged from manufacturing plants increases annually. In this study, the organic constituents, such as cellulose, in the sludge were converted into carbonaceous heavy metal absorbents using sulfur treatment, and its removal ability of lead from aqueous solution was examined. The sludge was treated with 5 M HCl to remove inorganic content, and then immersed in 1 M K2S solution to prepare sulfur-immersed sludge. The immersed-sludge was heated at 100-1000 °C for 1 hour in nitrogen gas to produce the sulfur-impregnated adsorbent by pyrolysis. The product obtained at 400 °C (Product-400) has a high removal ability for lead ion, which has high specific surface areas and high sulfur content. The product-400 shows the highest adsorption of lead from aqueous solution, and high selective removal for lead ions in low pH solution.

在再生纸生产过程中,造纸污泥作为工业废物排放。制造工厂排放的污泥量每年都在增加。本研究通过硫处理将污泥中的纤维素等有机成分转化为含碳重金属吸附剂,并考察其对水溶液中铅的去除能力。将污泥用5 M HCl处理去除无机成分,然后浸入1 M K2S溶液中制备硫浸污泥。将浸出的污泥在氮气中100-1000℃加热1小时,热解制得含硫吸附剂。在400℃下得到的产物(product -400)对铅离子的去除能力高,具有高比表面积和高硫含量。产物-400对铅在水溶液中的吸附效果最好,对低pH溶液中的铅离子有较高的选择性去除。
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引用次数: 16
Ambient Vibration Tests and Finite Element Analysis for Dynamic Properties of Brick Masonry Inverted Bell-shaped Chedi 砖砌体倒钟形车体动力特性环境振动试验及有限元分析
Pub Date : 2014-01-01 Epub Date: 2014-09-09 DOI: 10.1016/j.apcbee.2014.01.038
Chayanon Hansapinyo , Nakhorn Poovarodom

This research is aimed to study fundamental dynamic properties of an esteemed brick masonry inverted bell-shaped chedi at Phrathat Doi Suthep temple, Chiangmai, Thailand, by using full-scale ambient vibration tests associated with the finite element analysis. The study results showed that the finite element analysis indicated 3.817 Hz, 3.836 Hz and 9.294 Hz for the natural frequencies of the first modes on the x, y and torsion directions. From the ambient vibration measurements, the frequencies were 4.086 Hz, 4.025 Hz and 10.819 Hz. In comparison, the finite element gives the similar frequency values with the measured ones. The discrepancies are respectively 6.59, 4.70 and 14.09 percent. Hence, the validation of the finite element model has been made and used for vibration analysis presented in the accompanied paper (Seismic Performances of Brick Masonry Inverted Bell-Shaped Chedi)

本研究旨在通过全尺寸环境振动试验与有限元分析相结合的方法,研究泰国清迈素贴寺(Phrathat Doi Suthep temple)一座备受尊敬的砖砌体倒钟形佛塔的基本动力特性。研究结果表明,有限元分析表明,x、y和扭转方向一阶振型的固有频率分别为3.817 Hz、3.836 Hz和9.294 Hz。从环境振动测量中,频率分别为4.086 Hz、4.025 Hz和10.819 Hz。通过比较,有限元计算得到的频率值与实测值相近。差额分别为6.59%、4.70%和14.09%。因此,本文对有限元模型进行了验证,并将其用于所附论文(砖砌体倒钟形车体的抗震性能)中的振动分析。
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引用次数: 3
Chemical and Mineralogical Characterization and Soil Reactivity of Brazilian Waste Limestones 巴西废石灰石的化学矿物学特征和土壤反应性
Pub Date : 2014-01-01 Epub Date: 2014-09-09 DOI: 10.1016/j.apcbee.2014.01.002
Leyser Rodrigues Oliveira , Humberto P. Cunha , Nilvânia M. Silva , Ivani P.M. Pádua

This paper evaluated four waste limestones mined in the Minas Gerais State, Brazil, and its potential as soil acidity amendments and its effects upon soil fertility attributes. Laboratory and greenhouse experiments were performed at the University Centre of Formiga (UNIFOR), with Oxisols collected under native conditions. A randomly experimental design was set with four replications, five liming materials (four waste limestones products + a mix pure product, to comparison) applied in two liming rates (50% and 70% of base saturation), and a control plot (no lime applied). Each liming material was characterized with respect to CaO(%), MgO(%), and micronutrients Ca, Mg, Fe, Cu, Mn, Zn contents by atomic absorption spectrophotometer and the mineralogy by X-ray diffractometry. Results indicated that all liming materials tested could be classified as supplemental source of calcium and magnesium and caused an increase in soil pH, soil Ca and Mg, and base saturation levels, whereas aluminum saturation decreased. Dolomite, calcite and quartz are major minerals. Cu, Fe, Mn, and Zn were found in trace-amounts in all waste limestones, which was considered typical for such products. Considering the improvement of chemical characteristics and increase soil fertility, the use of waste limestone is an alternative that allows the use of commercial discarded material in small properties.

本文评价了在巴西米纳斯吉拉斯州开采的四种废石灰石及其作为土壤酸度改良剂的潜力及其对土壤肥力属性的影响。在Formiga大学中心(UNIFOR)进行了实验室和温室实验,并在当地条件下收集了Oxisols。采用随机试验设计,设4个重复,5种石灰化材料(4种废石灰石产品+ 1种混合纯产品进行比较)以两种石灰化率(50%和70%的碱性饱和度)施用,并设置一个对照区(不施用石灰)。采用原子吸收分光光度计和x射线衍射对各石灰材料的CaO(%)、MgO(%)和微量元素Ca、Mg、Fe、Cu、Mn、Zn含量进行了表征。结果表明,所有石灰材料均可作为钙、镁的补充源,导致土壤pH、钙、镁和碱饱和度升高,而铝饱和度降低。白云石、方解石和石英是主要矿物。在所有废石灰石中都发现了微量的铜、铁、锰和锌,这被认为是此类产品的典型特征。考虑到改善化学特性和增加土壤肥力,使用废石灰石是一种替代方案,允许在小型物业中使用商业废弃材料。
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引用次数: 7
Combination of Chitosan and Bentonite as Coagulant Agents in Dissolved Air Flotation 壳聚糖与膨润土复合作为溶气浮选混凝剂的研究
Pub Date : 2014-01-01 Epub Date: 2014-12-16 DOI: 10.1016/j.apcbee.2014.10.044
M.A.Z. Mohd Remy Rozainy , M. Hasif , Syafalny , P. Puganeshwary , A. Afifi

The experiment was carried out to study the dissolved air flotation (DAF) process in a tank involving mainly velocity distribution and turbidity removal. Chitosan and Bentonite were known as coagulant agents thus were used in the study. Measurements were carried out on four cases with different inlet velocities of 0.3m/s, 0.6m/s, 0.9m/s and 1.2m/s. Laboratory tests were conducted to test the water quality based on turbidity values and basic drinking water parameters. From the test results, it was found that the inlet velocity gave impacts on the distribution of flow in the tank and thus affected the efficiency of the flotation process. Chitosan and Bentonite can be applied to the flotation tank resulting in an average of 97% turbidity removal. This study successfully proved the effectiveness of the combination of Chitosan and Bentonite as a coagulating agent in the DAF tank for raw water treatment process.

对溶气浮选(DAF)工艺进行了实验研究,主要包括速度分布和除浊。壳聚糖和膨润土被称为混凝剂,因此在研究中使用。分别在0.3m/s、0.6m/s、0.9m/s和1.2m/s四种不同进口速度的情况下进行了测量。根据浊度值和基本饮用水参数进行了室内水质测试。试验结果表明,入口速度对浮选池内的气流分布有影响,从而影响浮选过程的效率。壳聚糖和膨润土可用于浮选槽,平均浊度去除率达97%。本研究成功地验证了壳聚糖与膨润土复合作为混凝剂在DAF池原水处理工艺中的有效性。
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引用次数: 20
Recovery of Tantalum Sintered Compact from Used Tantalum Condenser Using Steam Gasification with Sodium Hydroxide 用氢氧化钠蒸汽气化法回收废钽冷凝器中的钽烧结坯
Pub Date : 2014-01-01 Epub Date: 2014-12-16 DOI: 10.1016/j.apcbee.2014.10.022
Shigeyuki Katano, Takaaki Wajima, Hideki Nakagome

Recovery of tantalum resource from used tantalum capacitor in electric equipment is important because the production of tantalum have not been stable for the price and the quantity. However, recovery of tantalum sintered compact from tantalum capacitor is difficult since the compact strongly covered with the flame retardant resin made of halogenated compounds (mold resin). In this study, steam gasification with sodium hydroxide was applied for recovery of tantalum sintered compact by destroying mold resin and stabilization of halogenated compounds in sodium hydroxide to prevent exhausting halogenated gas. Mold resin can be decomposed by steam gasification with NaOH to recover the sintered compact of tantalum. Furthermore, most halogen gas generated from decomposition of mold resin can be trapped in sodium hydroxide not to exhaust halogen gas. These results suggested that recovery process of tantalum sintered compact from the used condenser using steam gasification with sodium hydroxide is expected as a feasible way to recycle the rare metal in electric equipment.

从电力设备中使用过的钽电容器中回收钽资源具有重要意义,因为钽的生产一直处于价格和数量不稳定的状态。然而,由于钽电容器中的钽烧结压块被卤化化合物制成的阻燃树脂(模具树脂)强烈地覆盖,因此回收钽烧结压块是困难的。本研究采用氢氧化钠蒸汽气化的方法,通过破坏模具树脂和稳定氢氧化钠中的卤化化合物来回收钽烧结坯,防止卤化气体的排放。用氢氧化钠蒸汽气化法分解模具树脂,回收烧结后的钽。此外,大多数由模具树脂分解产生的卤素气体可以被氢氧化钠捕获,而不会排出卤素气体。上述结果表明,利用氢氧化钠蒸汽气化回收废旧冷凝器中的钽烧结坯有望成为回收电气设备中稀有金属的一种可行方法。
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引用次数: 30
Household Fuel Consumption Based on Multiple Fuel Use Strategies: A Case Study in Kibera Slums 基于多种燃料使用策略的家庭燃料消费:基贝拉贫民窟的案例研究
Pub Date : 2014-01-01 Epub Date: 2014-12-16 DOI: 10.1016/j.apcbee.2014.10.062
Aya Yonemitsu , Mary Njenga , Miyuki Iiyama , Shusuke Matsushita

Recently, it has been argued that, contrary to earlier energy ladder thinking, households in developing countries do not switch to modern energy sources but instead tend to consume a combination of fuels. This article aimed to gather a better understanding of the relative importance of fuel substitution and fuel complementation, especially among charcoal, fuel briquettes and kerosene, and the factors associated with these choices. In this paper we present results of a household survey conducted during October 2010 in Kibera slums in Nairobi, Kenya. The results revealed that widely various household characteristics influence demand for charcoal and briquettes for cooking. In addition to these factors, the household income level affects the use of kerosene for cooking. At the same time, we found the fact households tend to switch to multiple fuels strategy as their increasing in income instead of completely switching from the consumption of traditional fuels to modern energy sources.

最近,有人认为,与早期的能源阶梯思维相反,发展中国家的家庭并不转向现代能源,而是倾向于消耗多种燃料。本文旨在更好地了解燃料替代和燃料补充的相对重要性,特别是在木炭,燃料压块和煤油之间,以及与这些选择相关的因素。本文介绍了2010年10月在肯尼亚内罗毕基贝拉贫民窟进行的住户调查结果。结果显示,各种各样的家庭特征影响了烹饪用木炭和煤块的需求。除了这些因素外,家庭收入水平也会影响煤油烹饪的使用。与此同时,我们发现随着家庭收入的增加,他们倾向于转向多种燃料策略,而不是完全从传统燃料的消费转向现代能源。
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引用次数: 19
Removal of Phenol from Water Different Types of Carbon – A Comparative Analysis 不同类型碳对水中苯酚去除的比较分析
Pub Date : 2014-01-01 Epub Date: 2014-12-16 DOI: 10.1016/j.apcbee.2014.10.031
Muataz Ali Atieh

Toxic organic substances are considered among the pollutants that have direct effect on humans and animals. Industrial wastewaters containing dissolved phenol can contaminate groundwater resources and thus lead to a serious groundwater pollution problem. In the present research, the adsorption technique for the efficient removal of phenol pollutants at trace level in water was employed. Four type of micro and nanocarbon materials including carbon nanotubes (CNTs) and carbon nanofibers (CNFs) as nano carbon adsorbents, activated carbon (AC) and industrial carbon fly ash (CFA) as micro carbon adsorbents were used to remove phenol from water. Characterization of these adsorbents was performed by Field Emission Scanning Electron Microscopy (FE-SEM), Transmission Electron Microscopy(TEM), Thermogravimetric Analysis (TGA), BET specific surface area while the concentration of phenol in water before and after treatment was analyzed using UV-Spectroscopy. The pH (3-9) of the solution, was varied in order to determine their effect on the removal of phenol from water and hence on the adsorption rate.

有毒有机物质被认为是对人类和动物有直接影响的污染物之一。含溶解酚的工业废水会污染地下水资源,造成严重的地下水污染问题。本研究采用吸附技术对水中痕量酚类污染物进行了高效去除。采用碳纳米管(CNTs)和碳纳米纤维(CNFs)作为纳米碳吸附剂,活性炭(AC)和工业碳粉煤灰(CFA)作为微碳吸附剂对水中苯酚进行了去除。采用场发射扫描电镜(FE-SEM)、透射电镜(TEM)、热重分析(TGA)、BET比表面积等对吸附剂进行了表征,并采用紫外光谱法对处理前后水中苯酚的浓度进行了分析。改变溶液的pH值(3-9),以确定它们对苯酚从水中去除的影响,从而影响吸附率。
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引用次数: 29
Biodiversity of Adult Trichoptera and Water Quality Variables in Streams, Northern Thailand 泰国北部河流成虫毛翅目生物多样性及水质变量
Pub Date : 2014-01-01 Epub Date: 2014-12-16 DOI: 10.1016/j.apcbee.2014.10.055
Taeng-On Prommi , Pongsak Laudee , Theeraphap Chareonviriyaphap

The diversity of adult Trichoptera was surveyed at Mae Tao and Mae Ku watersheds, northern Thailand during July 2011 to May 2012. The aim of the study was to determine the relationship between physicochemical parameters of water quality and adult Trichoptera for monitoring of water quality. A total of 9,475 adult Trichoptera representing 14 families and 126 species were collected. The correlation between the biodiversity of adult Trichoptera and water quality showed that the Ecnomus jojachin, Cheumatopsyche carmentis, C. chryseis, C. lucida, C. chrysothemis, C. dhanikari, Potamyia dryope, Leptocerus dirghachuka, L. trophonios, L. ganymedes, Oecetis scutulata, O. armadillo, O. raghava, O. asmada, O. tripunctata, Setodes flivialis, S. neptunus, S. endymion, S. okypete, Chimarra chiangmaiensis, Paduniella semarangensis, Lepidostoma doligung, Polyplectropus ahas, Psychomyia lak, Marilia sumatrana, Hydroptila thuna and Orthrotrichia typhoeus depended on some physicochemical factors including air temperature, pH, electrical conductivity, turbidity, sulfate, nitrate-nitrogen, orthrophosphate, ammonia-nitrogen and alkalinity in water.

2011年7月至2012年5月在泰国北部梅道和梅库流域调查了毛翅目成虫的多样性。研究的目的是确定水质理化参数与成毛翅虫之间的关系,为水质监测提供依据。共收集成毛翅目昆虫14科126种9475只。成虫生物多样性与水质的相关性表明:jojachin、Cheumatopsyche carmentis、chryseis、lucida、chrysothemis、chanikari、poamyia dryope、Leptocerus dirghachuka、L. trophonios、L. ganymedes、Oecetis culculata、O. armadillo、O. raghava、O. asmada、O. tripunctata、Setodes flivialis、S. neptunus、S. endymion、S. okypete、Chimarra jiangmaiensis、Paduniella semarangensis、Lepidostoma doligung、Polyplectropus ahas、水蚤、苏门答腊鱼、水蚤和伤寒赤毛菌的生长依赖于空气温度、pH、电导率、浊度、硫酸盐、硝酸盐氮、正磷酸盐、氨氮和碱度等理化因素。
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引用次数: 9
Rheological and Swelling Behavior of pH Sensitive Hydrogel Particles pH敏感水凝胶颗粒的流变和膨胀行为
Pub Date : 2014-01-01 Epub Date: 2014-09-09 DOI: 10.1016/j.apcbee.2014.01.034
Lomas K. Tomar, Charu Tyagi, Yahya E. Choonara, Pradeep Kumar, Viness Pillay

pH sensitive hydrogel particles were characterized for their rheological and swelling behaviour at various pH values specific to the gastrointestinal tract simulated conditions. Scanning electron microscopy was used to view the surface morphology of the hydrogels at different pHs. Swelling at pH 7.4 and shrinkage at pH 1.2 confirmed the pH sensitive behaviour of the hydrogel particles. The Linear Viscoelastic (LVE) range was determined by considering G’, one of the strain amplitude. Furthermore frequency sweep tests were performed in the LVE range where the storage modulus and loss modulus were determined at constant strain. It was observed that the loss modulus was higher at basic pH while the storage modulus was higher at lower pH. This rheological method can be used to explain the pH sensitive behaviour of hydrogels.

pH敏感水凝胶颗粒的特点是其流变和膨胀行为在不同的pH值特定于胃肠道模拟条件。用扫描电镜观察了不同ph值下水凝胶的表面形貌。pH值为7.4时的膨胀和pH值为1.2时的收缩证实了水凝胶颗粒的pH敏感行为。考虑应变幅值之一G′确定了线性粘弹性(LVE)范围。此外,在LVE范围内进行了频率扫描测试,在恒定应变下确定了存储模量和损耗模量。观察到,在碱性pH下,损失模量较高,而在较低pH下,储存模量较高。这种流变学方法可以用来解释水凝胶的pH敏感行为。
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引用次数: 13
Gas Transmission Rates Across ‘Carabao’ Mango (Mangifera Indica L.) Peel at Different Stages of Maturity and Ripeness “卡拉宝”芒果(Mangifera Indica L.)的天然气传输速率不同成熟和成熟阶段的果皮
Pub Date : 2014-01-01 Epub Date: 2014-09-16 DOI: 10.1016/j.apcbee.2014.03.032
Fidelina T. Flores , Kevin F. Yaptenco , Engelbert K. Peralta , Edralina P. Serrano

Gas transmission rate through fruit peel is needed to understand gas exchange between fruit and the environment. It can be used to design packaging material and formulate edible coatings to be used by the fruit. It can also be used to predict oxygen consumption and possible carbon dioxide injury which could affect ripening and could predict the internal gas level inside the fruit. Oxygen and carbon dioxide transmission rates (O2TR and CO2TR) of mango (Mangifera indica, L.) peel at different stages of maturity and ripeness which were stored under two temperature regimes were measured using gas diffusion chamber. Nitrogen gas was flushed inside the chamber to decrease the oxygen level. Then a gas mixture of known concentration was flushed in the chamber and the concentration inside the chamber was measured through time. The Exponential Decay Method of Gas Transmission Rate of Films as described by Moyls (1992) was used to relate partial pressure of the gas concentration inside the chamber and the outside condition. Results showed that overmature fruit peel-PCI3 under 27 °C had the highest O2TR and CO2TR (1.636 mLO2/cm2-hr - 4.744 mLCO2/cm2-hr) while immature fruit peel-PCI1 under 14 °C had the lowest O2TR and CO2TR (1.104 mLO2/cm2-hr - 3.321 mLO2/cm2-hr). At constant temperature, gas transmission rates increase with maturity and as the fruit peel turns yellow.

通过果皮的气体传输速率来了解水果与环境之间的气体交换。它可以用于设计包装材料和配制可食用涂层的水果。它还可以用来预测影响成熟的耗氧量和可能的二氧化碳伤害,并可以预测果实内部的气体水平。利用气体扩散室测定了芒果(Mangifera indica, L.)果皮在两种温度下不同成熟期和成熟期的氧和二氧化碳透射率(O2TR和CO2TR)。氮气被冲进舱内以降低氧气含量。然后将已知浓度的气体混合物冲进室内,并随时间测量室内的浓度。采用Moyls(1992)描述的薄膜气体透射率的指数衰减法,将腔内气体浓度的分压与外部条件联系起来。结果表明,27℃下过熟果皮pci3的O2TR和CO2TR最高(1.636 ~ 4.744 mLCO2/cm2-hr), 14℃下未熟果皮pci1的O2TR和CO2TR最低(1.104 ~ 3.321 mLO2/cm2-hr)。在恒定温度下,气体的传输率随着成熟和果皮变黄而增加。
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引用次数: 0
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APCBEE Procedia
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