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Influence of the Rate of Cooling/Solidification on the Location of Characteristic Points on the AT and ADT Curves of Cast Iron 冷却/凝固速度对铸铁 AT 和 ADT 曲线特征点位置的影响
IF 0.6 Q3 Materials Science Pub Date : 2024-06-11 DOI: 10.24425/afe.2024.149279
J.S. Zych
The paper presents the results of the analysis of cooling curves of cast iron with approximately eutectic composition rasterized at different rates of cooling and ingot crystallization. The test samples were in the form of rods with a diameter of 30,0.mm and a coagulation modulus M = 0.75 cm. They were cast in a sand mould made of furan mass placed on a chill in the form of a cast-iron plate, with which one of the front surfaces of the rod casting was in contact. In this way, a differentiated cooling rate along the rod was achieved. At selected distances from the chiller (5, 15, 25, 25 and 45 mm) thermocouple moulds were placed in the cavity to record the cooling curves used in thermal (AT) and derivation (ATD) analysis. The solidification time of the ingot in the part farthest from the chiller was about 200s, which corresponds to the solidification time in the test cup AT. An analysis of the recorded cooling curves was performed in order to determine the values of characteristic points on the AT curve (Tsol. Tliq, ΔTrecal., τclot, etc.). Relationships between cooling time and rate and characteristic points on AT and ATD curves were developed. For example, Tsol min changes in the range of 1115 - 1145 for the range of cast iron solidification times in the selected ingot zone from ~ 70 to ~ 200 s, which corresponds to the process speed from 0.0047 to 0.014 [1/s]. The work also includes an analysis of other characteristic points on the AT and ATD curves as functions of the solidification rate of cast iron of the same composition.
本文介绍了对近似共晶成分的铸铁在不同冷却速度和铸锭结晶情况下的冷却曲线的分析结果。测试样品为棒状,直径为 30.0 毫米,凝固模量 M = 0.75 厘米。它们被浇铸在呋喃砂模中,砂模放置在铸铁板状的冷却器上,棒铸件的一个前表面与铸铁板接触。通过这种方式,可以实现沿棒的不同冷却速度。在与冷却器的选定距离(5、15、25、25 和 45 毫米)处,在型腔中放置热电偶模具,以记录用于热分析(AT)和推导分析(ATD)的冷却曲线。在离冷却器最远的部分,钢锭的凝固时间约为 200 秒,与试验杯 AT 的凝固时间一致。对记录的冷却曲线进行了分析,以确定 AT 曲线上特征点的值 (Tsol. Tliq, ΔTrecal., τclot 等)。冷却时间和冷却速率与 AT 和 ATD 曲线上的特征点之间的关系已经形成。例如,在所选铸锭区的铸铁凝固时间范围从 ~ 70 到 ~ 200 s(相当于 0.0047 到 0.014 [1/s]的工艺速度)内,Tsol min 的变化范围为 1115 - 1145。工作还包括分析 AT 和 ATD 曲线上的其他特征点作为相同成分铸铁凝固速率的函数。
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引用次数: 0
The Technique of Inorganic Core Sand Shooting with Reduced Pressure in Venting System 排气系统减压无机岩心射砂技术
IF 0.6 Q3 Materials Science Pub Date : 2024-06-11 DOI: 10.24425/afe.2024.149275
M. Skrzyński, R. Dańko, G. Dajczer
The publication presents a new shooting technique with reduced pressure in venting system for manufacturing foundry cores using inorganic sand mixture with Cordis binder. Traditional technologies for producing casting cores using blowing methods, despite their undeniable advantages, including the ability to produce cores in series, also come with some disadvantages. The primary drawbacks of the process involve uneven compaction structure of the cores, with denser areas primarily located under the blow holes, and under-shooting defects, which often occur in regions away from the blow hole or in increased core cross-sectional areas. In an effort to improve core quality, a concept was developed that involves incorporating a reduced pressure in the core box venting system to support the basic overpressure process. The solutions proposed in the publication with a vacuum method of filling the cavities of multi-chamber core boxes solve a number of technical problems occurring in conventional blowing technologies. It eliminates difficulties associated with evacuating the sand from the chamber to the shooting head and into technological cavity and increases the uniform distribution and initial degree of compacting of grains in the cavity. The additive role of this “underpressure” support is to enhance corebox venting by eliminating 'air cushions' in crevices and structural elements that obstruct the flow of evacuated air. The publication presents the results of studies on core manufacturing using blowing methods conducted in three variants: classic overpressure, utilizing the core box filling phenomenon by reducing pressure, and an integrated approach combining both these methods.
该出版物介绍了一种新的喷射技术,它可降低排气系统中的压力,使用无机砂混合物和 Cordis 粘结剂制造铸造型芯。使用吹气法生产铸造型芯的传统技术尽管具有不可否认的优点,包括能够批量生产型芯,但也存在一些缺点。该工艺的主要缺点是型芯的压实结构不均匀,密度较高的区域主要位于吹气孔的下方,以及射出不足的缺陷,这些缺陷通常发生在远离吹气孔的区域或型芯横截面面积增大的区域。为了提高岩心质量,我们提出了一个概念,即在岩心箱排气系统中加入一个减压装置,以支持基本的超压过程。出版物中提出的解决方案采用真空方法填充多腔芯盒的空腔,解决了传统吹制技术中出现的一系列技术问题。它消除了将砂子从腔室抽空到射孔头和技术腔室的困难,并提高了砂粒在腔室中的均匀分布和初始压实度。这种 "欠压 "支撑的附加作用是通过消除缝隙中的 "气垫 "和阻碍排空气流的结构件来增强芯盒排气。该出版物介绍了使用吹气方法制造芯材的三种变体的研究结果:传统的超压、通过减压利用芯盒填充现象以及结合这两种方法的综合方法。
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引用次数: 0
Analysis of Fragmentation Phenomenon of Composite Layers of Fe-TiC Type Obtained “in situ” in Steel Casting 分析铸钢过程中 "原位 "获得的 Fe-TiC 型复合层的碎裂现象
IF 0.6 Q3 Materials Science Pub Date : 2024-06-11 DOI: 10.24425/afe.2024.149280
J. Marosz, S. Sobula
A method for fabrication of a composite layer on the surface of a steel casting using coating containing TiC substrates was presented. The reaction of the synthesis of the ceramic phase was based on the SHS method (Self-propagating High-temperature Synthesis) and was triggered by the heat of molten steel. High hardness titanium carbide ceramic phases were obtained, which strengthened the base material improving its performance properties presented in this article. Microstructural examinations carried out by light microscopy (LM) on the in-situ produced composite layers showed that the layers were the products of reaction of the TiC synthesis – the phenomenon called “fragmentation” by the authors of study. The examinations carried out by scanning electron microscopy (SEM) have revealed the presence of spheroidal precipitated and free of impurities. The presence of titanium carbide was twofold increase in hardness in the area of the composite layer as compared to the base alloy which was carbon cast steel.
本文介绍了一种利用含 TiC 基底涂层在钢铸件表面制造复合层的方法。陶瓷相的合成反应基于 SHS 法(自蔓延高温合成法),由熔融钢水的热量引发。结果获得了高硬度的碳化钛陶瓷相,从而增强了基体材料的强度,提高了其性能。用光学显微镜(LM)对原位生产的复合材料层进行的微观结构检查显示,这些层是碳化钛合成反应的产物--研究作者称这种现象为 "破碎"。用扫描电子显微镜(SEM)进行的检查显示,复合层呈球状沉淀,不含杂质。与碳铸钢基合金相比,碳化钛的存在使复合层区域的硬度提高了两倍。
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引用次数: 0
Study on Mn Volatilization Behavior During Vacuum Melting of High-manganese Steel 高锰钢真空熔炼过程中的锰挥发行为研究
IF 0.6 Q3 Materials Science Pub Date : 2024-06-11 DOI: 10.24425/afe.2024.149277
Jialiu Lei, Yongjun Fu, Li Xiong
As an alloying element in steel, manganese can considerably enhance the mechanical properties of structural steel. However, the Mn volatilisation loss in vacuum melting is severe because of the high saturated vapour pressure, resulting in an unstable Mn yield and Mn content fluctuation. Therefore, a systematic study of the volatilisation behaviour of Mn in vacuum melting is required to obtain a suitable Mn control process to achieve precise control of Mn composition, thereby providing a theoretical basis for industrial melting of high-Mn steel. In order to explore the Mn volatilization behavior, the volatilization thermodynamics and volatilisation rate of Mn, as well as the influence factors are discussed in this study. The results shows that Mn is extremely volatilised into the vapour phase under vacuum, the equilibrium partial pressure is closely related to Mn content and temperature. With an increase in the Mn content, a higher C content has a more obvious inhibitory effect on the equilibrium partial pressure of Mn. The maximum theoretical volatilisation rate of Mn shows a linear upward trend with an increase in Mn content. However, a higher C content has a more obvious effect on the reduction of the maximum theoretical volatilisation rate with the increase of Mn content. This study provides an improved understanding of Mn volatilisation behaviour as well as a theoretical foundation for consistent Mn yield control during the vacuum melting process of high-Mn steel.
作为钢中的一种合金元素,锰能大大提高结构钢的机械性能。然而,由于饱和蒸汽压较高,真空熔炼中的锰挥发损失严重,导致锰收得率和锰含量波动不稳定。因此,需要对真空熔炼中锰的挥发行为进行系统研究,以获得合适的锰控制流程,实现对锰成分的精确控制,从而为高锰钢的工业熔炼提供理论依据。为了探索锰的挥发行为,本研究讨论了锰的挥发热力学和挥发速率以及影响因素。结果表明,锰在真空条件下极易挥发到气相中,其平衡分压与锰含量和温度密切相关。随着锰含量的增加,较高的 C 含量对锰的平衡分压有更明显的抑制作用。随着锰含量的增加,锰的最大理论挥发率呈线性上升趋势。然而,随着锰含量的增加,较高的 C 含量对最大理论挥发率的降低有更明显的影响。这项研究加深了对锰挥发行为的理解,并为在高锰钢真空熔炼过程中实现一致的锰屈服控制奠定了理论基础。
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引用次数: 0
Impact of Aging Time on the Metallurgical Properties and Hardness Characteristics of an Al-Si-Mg-Cr Hypoeutectic Alloy Intended for Automotive Applications 老化时间对汽车用铝硅镁铬低共晶合金的冶金特性和硬度特征的影响
IF 0.6 Q3 Materials Science Pub Date : 2024-06-11 DOI: 10.24425/afe.2024.149281
V.V. Ramalingam, K.V. Shankar, B. Shankar, R. Abhinandan, A. Dineshkumar, P.A. Adhithyan, K. Velusamy, A. Kapilan, N. Sudheer
This research investigates the microstructural evolution and mechanical properties of LM25 (Al-Si-Mg) alloy and Cr-modified LM25-Cr (Al-Si-Mg-Cr) alloy. Microstructural analysis reveals distinctive ε-Si phase morphologies, with Cr addition refining dendritic structures and reducing secondary dendrite arm spacing in the as-cast condition. Cr modification results in smaller-sized grains and a modified ε-Si phase, enhancing nucleation sites and reducing ε-Si size. Microhardness studies demonstrate significant increases in hardness for both alloys after solutionising and aging treatments. Cr-enriched alloy exhibits superior hardness due to solid solution strengthening, and prolonged aging further influences ε-Si particle size and distribution. The concurrent rise in microhardness, attributed to refined dendritic structures and unique ε-Si morphology, underscores the crucial role of Cr modification in tailoring the mechanical properties of aluminium alloys for specific applications.
本研究调查了 LM25(Al-Si-Mg)合金和铬改性 LM25-Cr(Al-Si-Mg-Cr)合金的微观结构演变和机械性能。微观结构分析显示了独特的ε-Si 相形态,添加的铬细化了树枝状结构,减少了铸造状态下的次生树枝状晶臂间距。铬改性导致晶粒尺寸变小,ε-Si 相发生改性,增加了成核点,减小了ε-Si 尺寸。显微硬度研究表明,经过固溶和时效处理后,两种合金的硬度都有显著提高。由于固溶强化作用,富铬合金显示出更高的硬度,而长时间的时效则进一步影响了ε-Si 的粒度和分布。由于细化的树枝状结构和独特的ε-Si 形态,显微硬度也同时提高,这突出表明了铬改性在为特定应用定制铝合金机械性能方面的关键作用。
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引用次数: 0
Study on Preparation Technology and Heat Conduction Mechanism of High-Purity & Ultra-Fine Alumina Powder from Scrap Aluminum Cans 从废铝罐中提取高纯超细氧化铝粉的制备技术及热传导机理研究
IF 0.6 Q3 Materials Science Pub Date : 2024-03-26 DOI: 10.24425/afe.2024.149264
Chengmin Wang, Anatoly Politov, Xiuhui Wang, Jinlong Yang
In view of the increasing scarcity of bauxite resources in China, the high energy consumption and high pollution of electrolytic aluminum, and the requirements for energy conservation and environmental protection, aluminum recycling and high-value utilization of its derivatives have evolved into a crucial development requirement for the aluminum industry in the future. As an important part of the development of recycled aluminum resources, the high-value application of scrap aluminum cans has always been a hot research topic in various recycled aluminum processing enterprises and scientific research units. The traditional regeneration system of waste cans includes a series of complex technological processes such as pretreatment, paint removal, smelting system and casting system, which is difficult to control in the middle of the process. Most of the recycled scrap aluminum cans are cast and downgraded for later use, except for a part of them used as alloy materials for new cans. In this paper, combined with the research on the preparation of metal aluminum alkoxide, combined with recrystallization heat conduction to further study the effective dissolution or adsorption how to remove impurity elements to obtain high-purity aluminum alcohol salt mechanism research, and thermal effect of alcohols with different carbon chains on the synthesis of high-purity aluminum alkoxide was further investigated. Moreover, the changes in morphology and pore size distribution of hydrolyzed alumina precursor materials under different hydrothermal temperature conditions were discussed by means of the alkoxide hydrolysis-sol-gel process. Eventually, the aluminum alkoxide was obtained by the reaction of waste cans with isopropanol and heavy crystal thermal conductivity, and the high-purity aluminum alkoxide was purified by vacuum distillation. Under the hydrothermal condition of 160°C, the high-purity alumina material with a purity of 99.99% and an original crystal size of 200nm was prepared.
鉴于中国铝土矿资源的日益匮乏,电解铝的高能耗、高污染,以及节能环保的要求,铝的回收及其衍生品的高值化利用已演变成未来铝工业的重要发展要求。作为再生铝资源开发的重要组成部分,废铝罐的高值化应用一直是各再生铝加工企业和科研单位的研究热点。传统的废易拉罐再生系统包括预处理、除漆、熔炼系统、浇铸系统等一系列复杂的工艺流程,中间过程难以控制。回收的废铝罐除一部分用作新罐的合金材料外,大部分被铸造降级后使用。本文结合金属铝氧化物的制备研究,结合重结晶热传导进一步研究了如何有效溶解或吸附去除杂质元素获得高纯度铝醇盐的机理研究,并进一步研究了不同碳链的醇对合成高纯度铝氧化物的热效应。此外,还通过氧化铝水解-溶胶-凝胶过程,探讨了水解氧化铝前驱体材料在不同水热温度条件下的形貌和孔径分布变化。最终,通过废易拉罐与异丙醇和重晶导热反应得到氧化铝,并通过真空蒸馏提纯出高纯度的氧化铝。在 160°C 水热条件下,制备出纯度为 99.99%、原始晶体尺寸为 200nm 的高纯氧化铝材料。
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引用次数: 0
Remelting of Aluminum Scrap Into Billets Using Direct Chill Casting 利用直接冷铸法将铝废料重熔成铝棒
IF 0.6 Q3 Materials Science Pub Date : 2024-01-04 DOI: 10.24425/afe.2024.149250
Kardo Rajagukguk, S. Suyitno, H. Saptoadi, I. Kusumaningtyas, B. Arifvianto, M. Mahardika
An as-cast aluminum billet with a diameter of 100 mm has been successfully prepared from aluminum scrap by using direct chill (DC) casting method. This study aims to investigate the microstructure and mechanical properties of such as-cast billets. Four locations along a cross-section of the as-cast billet radius were evaluated. The results show that the structures of the as-cast billet are a thin layer of coarse columnar grains at the solidified shell, feathery grains at the half radius of the billet, and coarse equiaxed grains at the billet center. The grain size tends to decrease from the center to the surface of the as-cast billet. The ultimate tensile strength (UTS) and the hardness values obtained from this research slightly increase from the center to the surface of the as-cast billet. The distribution of Mg, Fe, and Si elements over the cross-section of the as-cast billet is inhomogeneous. The segregation analysis shows that Si has negative segregation towards the surface, positive segregation at the middle, and negative segregation at the center of the as-cast billet. On the other hand, the Mg element is distributed uniformly in small quantities in the cross-section of the as-cast billet.
利用直接冷却(DC)铸造法,成功地从铝废料中制备出了直径为 100 毫米的铸坯。本研究旨在探究这种铸坯的微观结构和机械性能。对铸坯半径横截面上的四个位置进行了评估。结果表明,现浇坯的结构是凝固外壳处有一薄层粗柱状晶粒,坯体半径处有羽毛状晶粒,坯体中心处有粗等轴晶粒。晶粒大小从铸坯中心向表面逐渐减小。本研究获得的极限拉伸强度(UTS)和硬度值从铸坯中心到表面略有增加。镁、铁和硅元素在铸坯横截面上的分布不均匀。偏析分析表明,硅在铸坯表面呈负偏析,在中间呈正偏析,在中心呈负偏析。另一方面,镁元素在铸坯横截面上均匀分布,数量很少。
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引用次数: 0
Evaluation of the Possibility to Improve the Scratch Resistance of the AZ91 Alloy by Applying a Coating 评估通过涂层提高 AZ91 合金抗划伤性的可能性
IF 0.6 Q3 Materials Science Pub Date : 2023-12-28 DOI: 10.24425/afe.2023.146690
M. Mróz, S. Olszewska, P. Rąb
This paper presents the possibility of improving the scratch resistance of the AZ91 magnesium alloy by applying a WCCoCr coating using the Air Plasma Spraying (APS) method. The coating thickness ranged from 140 to 160  m. Microstructural studies of the AZ91 magnesium alloy were performed. The chemical composition of the WCCoCr powder was investigated. The quality of the bond at the substrate–coating interface was assessed and a microanalysis of the chemical composition of the coating was conducted. The scratch resistance of the AZ91 alloy and the WCCoCr coating was determined. The scratch resistance of the WCCoCr powder-based coating is much higher than the AZ91 alloy, as confirmed by scratch geometry measurements. The scratch width in the coating was almost three times smaller compared to the scratch in the substrate. Observations of the substrate–coating interface in the scratch area indicate no discontinuities. The absence of microcracks and delamination at the transition of the scratch from the substrate to the coating indicates good adhesion. On the basis of the study, it was found that there was great potential to use the WCCoCr powder coating to improve the abrasion resistance of castings made from the AZ91 alloy.
本文介绍了使用空气等离子喷涂(APS)方法涂覆 WCCoCr 涂层以提高 AZ91 镁合金抗划伤性的可能性。涂层厚度范围为 140 至 160  m。对 AZ91 镁合金进行了微观结构研究。研究了 WCCoCr 粉末的化学成分。评估了基体-涂层界面的结合质量,并对涂层的化学成分进行了微观分析。测定了 AZ91 合金和 WCCoCr 涂层的抗划伤性。划痕几何测量结果证实,WCCoCr 粉末涂层的抗划痕能力远远高于 AZ91 合金。涂层上的划痕宽度几乎是基体上划痕的三倍。对划痕区域的基体-涂层界面进行的观察表明,划痕区域没有出现不连续性。从基材到涂层的划痕过渡处没有微裂缝和分层,这表明附着力良好。研究发现,使用 WCCoCr 粉末涂层提高 AZ91 合金铸件的耐磨性具有很大的潜力。
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引用次数: 0
Changes in the Microstructure and Abrasion Resistance of Tool Cast Steel after the Formation of Titanium Carbides in the Alloy Matrix 合金基体中形成碳化钛后工具铸钢微观结构和耐磨性的变化
IF 0.6 Q3 Materials Science Pub Date : 2023-12-28 DOI: 10.24425/afe.2023.148961
G. Tęcza
Cast martensitic alloy steel is used for the production of parts and components of machines operating under conditions of abrasive wear. One of the most popular grades is cast steel GX70CrMnSiNiMo2 steel, which is used in many industries, but primarily in the mining and material processing sectors for rings and balls operating in the grinding sets of coal mills. To improve the abrasion resistance of cast alloy tool steel, primary titanium carbides were produced in the metallurgical process by increasing the carbon content to 1.78 wt.% and adding 5.00 wt.% of titanium to test castings. After alloy solidification, the result was the formation of a microstructure consisting of a martensitic matrix with areas of residual austenite and primary titanium carbides evenly distributed in this matrix. The measured as-cast hardness of the samples was 660HV and it increased to as much as 800HV after heat treatment. The abrasion resistance of the sample hardened in a 15% polymer solution increased at least three times compared to the reference sample after quenching and
铸马氏体合金钢用于生产在磨料磨损条件下工作的机器零部件。GX70CrMnSiNiMo2 铸钢是最受欢迎的钢种之一,它被用于许多行业,但主要是采矿和材料加工行业,用于煤磨磨环和磨球。为了提高铸造合金工具钢的耐磨性,在冶金过程中,将碳含量提高到 1.78 重量%,并在试验铸件中添加 5.00 重量%的钛,从而生产出初级碳化钛。合金凝固后,形成了由马氏体基体、残余奥氏体区域和均匀分布在基体中的原始碳化钛组成的微观结构。样品的铸造硬度测量值为 660HV,经过热处理后可提高到 800HV。在 15% 聚合物溶液中硬化的样品在淬火和热处理后的耐磨性比参考样品至少提高了三倍。
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引用次数: 0
Microstructure and Properties of Experimental Mg-9Al-5RE-1Zn-Mn Magnesium Alloy 实验性 Mg-9Al-5RE-1Zn-Mn 镁合金的显微结构和性能
IF 0.6 Q3 Materials Science Pub Date : 2023-12-28 DOI: 10.24425/afe.2023.148960
K. Braszczyńska-malik
In this paper, an experimental Mg-Al-RE-type magnesium alloy, named AEZ951, is presented. The chemical composition of the investigated alloy was ca. 9 wt% Al, 5 wt% RE (rare earth elements), 0.7 wt% Zn and 3 wt% Mn. The experimental material was gravity cast into a cold steel mould. Microstructure analyses were carried out by light microscopy, along with X-ray phase analysis and scanning electron microscopy with an energy-dispersive X-ray spectrometer (SEM + EDX). Detailed investigations disclosed the presence of primary dendrites of an  (Mg) solid solution and Al 11 RE 3 ,  and Al 10 RE 2 Mn 7 intermetallic compounds in the alloy microstructure. The volume fraction of the Al 11 RE 3 phase and  +  eutectic was also presented. The hardness, impact strength, tensile strength as well as the yield strength of the alloy were examined in tests at room temperature. The examined experimental Mg-Al-RE-type magnesium alloy exhibited higher mechanical properties than the commercial AZ91 alloy (cast in the same conditions).
本文介绍了一种名为 AEZ951 的实验性 Mg-Al-RE 型镁合金。所研究合金的化学成分约为 9 wt% Al、5 wt% RE(稀土元素)、0.7 wt% Zn 和 3 wt% Mn。实验材料被重力浇铸到冷钢模中。通过光学显微镜、X 射线相分析和扫描电子显微镜与能量色散 X 射线光谱仪(SEM + EDX)进行了微观结构分析。详细研究表明,合金微观结构中存在  (Mg) 固溶体的原生枝晶以及 Al 11 RE 3、 和 Al 10 RE 2 Mn 7 金属间化合物。此外,还介绍了 Al 11 RE 3 相和  +  共晶的体积分数。合金的硬度、冲击强度、拉伸强度和屈服强度在室温下的测试中进行了检验。与商用 AZ91 合金(在相同条件下铸造)相比,实验中的 Mg-Al-RE 型镁合金具有更高的机械性能。
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引用次数: 0
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Archives of Foundry Engineering
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