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ASETH-18,ACABES-18 & EBHSSS-18 Nov. 19-20 2018 Cape Town (South Africa)最新文献

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Pretreatment of Coal Power Plant RO Retentate using AR floc 100 AR絮凝剂100对燃煤电厂反渗透剩余物的预处理
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118241
E. Fosso-Kankeu, L. V. Schalkwyk, F. Waanders, G. Gericke
The water purification process at Eskom includes a reverse osmosis (RO) treatment plant. There are several limitations to this process depending on the water characteristics. The most common problems limiting the success of water purification include scaling, biological fouling and corrosion. This study is mainly focused on reducing scale forming agents in the RO system. Scaling is the precipitation of calcium and magnesium salts onto the equipment, primarily the RO membrane. These salts start to precipitate once the salt concentration in the water is higher than the allowable solubility constant. These salts can be removed from the water by a process called coagulation-flocculation. The success of such process is partly dependent on the type of flocculant and the dosage used. In this study the performances of one coagulant namely Rheofloc 5023 in combination with three flocculants including Rheofloc 5414, Genesys genefloc and AR floc 100 were tested at various dosages for the reduction of conductivity assimilated with ions in the RO retentate from coal power plant was investigated at 40 and 60C. The AR floc 100 was determined to be the optimum flocculant required for the RO reject treatment. The optimum flocculant dosage resulted in 1 ppm along with a Rheofloc 5023 coagulant dosage of 0.7 ppm. Keywords—AR floc 100, RO retentate, flocculation, conductivity.
Eskom的水净化过程包括一个反渗透(RO)处理厂。根据水的特性,这个过程有几个限制。限制水净化成功的最常见问题包括结垢、生物污染和腐蚀。本研究主要针对反渗透系统中的降垢剂进行研究。结垢是钙和镁盐在设备上的沉淀,主要是反渗透膜。一旦水中的盐浓度高于允许的溶解度常数,这些盐就开始沉淀。这些盐可以通过一种叫做混凝-絮凝的方法从水中去除。该工艺的成功与否部分取决于絮凝剂的种类和用量。在本研究中,研究了一种混凝剂(Rheofloc 5023)与三种絮凝剂(Rheofloc 5414、Genesys genefloc和AR絮凝剂100)在不同剂量下的性能,以降低40℃和60℃下燃煤电厂RO保留液中离子吸收的电导率。确定了AR絮凝剂100为反渗透废水处理所需的最佳絮凝剂。最佳絮凝剂投加量为1ppm, Rheofloc 5023投加量为0.7 ppm。关键词:ar絮凝剂100;反渗透;絮凝;
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引用次数: 0
Removal of COD from Biodiesel Wastewater using a Hydrophobic Polymer 疏水聚合物去除生物柴油废水中的COD
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118242
E. Fosso-Kankeu, M. Berg, F. Waanders, S. Pandey
Biodiesel production is increasing internationally as an alternative fuel. This is due to the rapid depletion of non-renewable energy sources. Pure biodiesel product can be obtained by washing the product with hot water. This results in a huge quantity of wastewater that is unsafe for disposal in normal drainage systems. Treatment of this wastewater is thus important for reuse or safe disposal in the environment. There are a lot of existing treatment methods, but they are costly, produce large quantities of excessive sludge and are not economically feasible. Flocculation is widely used in water treatment as it is easy to use and affordable. Flocculants can be synthesized to treat the specific wastewater type focusing on the reduction of certain impurities. The reduction of Chemical Oxygen Demand (COD) in the biodiesel wastewater was investigated through jar-tests using hydrophobic, non-hydrophobic and a combination of hydrophobic and non-hydrophobic polymers that were synthesized. Almost 68% COD removal was obtained with the non-hydrophobic polymer and about 56% COD removal was obtained with the hydrophobic polymer. The non-hydrophobic polymer has a better removal efficiency, as the wastewater contains a large quantity of hydrophilic organic matters. Although the hydrophobic polymer also removes COD, it could be seen that the hydrophobic polymer attracted the unreacted oil in the biodiesel wastewater.
作为一种替代燃料,生物柴油的产量在国际上不断增加。这是由于不可再生能源的迅速枯竭。用热水洗涤可得到纯净的生物柴油产品。这导致大量的废水在正常的排水系统中处理是不安全的。因此,这种废水的处理对于在环境中重复使用或安全处置非常重要。现有的处理方法很多,但成本高,产生大量过量污泥,经济上不可行。絮凝因其操作简便、经济实惠等优点,在水处理中得到了广泛的应用。可以合成絮凝剂来处理特定的废水类型,重点是减少某些杂质。采用制备的疏水、非疏水以及疏水和非疏水聚合物的组合聚合物,对生物柴油废水中的化学需氧量(COD)进行了还原实验研究。非疏水聚合物的COD去除率约为68%,疏水聚合物的COD去除率约为56%。由于废水中含有大量亲水性有机物,非疏水聚合物的去除率较好。虽然疏水聚合物也能去除COD,但可以看出疏水聚合物吸附了生物柴油废水中未反应的油。
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引用次数: 1
Modeling Acceptance and Usability for Educational Technology: The Conceptual Gaps 教育技术的建模接受度和可用性:概念差距
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118448
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引用次数: 0
Biological Reduction of COD and Sulphate by SRB in Anaerobic Moving Bed Biofilm Reactor under High Metal Loading Conditions 厌氧移动床生物膜反应器中高金属负荷条件下SRB生物还原COD和硫酸盐的研究
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118236
E. Akinpelu, E. Fosso-Kankeu, F. Waanders, S. K. Ntwampe
The performance of an anaerobic moving bed biofilm reactor (MBBR) containing AnoxKaldnes K5 model for the treatment of raw acid mine drainage (AMD) was investigated for the reduction of sulphate and chemical oxygen demand using a consortium of sulphate reducing bacteria (SRB) dominated by Proteobacteria. The MBBR was enriched for 4 weeks, followed by introduction of raw AMD and sampling at intervals for 7 weeks. Maximum removal efficiency of COD was 99 % followed by 75 % sulphate reduction. The results showed that the bio-carrier is more suited for the COD reduction. Keywords— Acid mine drainage; Chemical oxygen demand; Heavy metals; moving bed biofilm reactor; Sulphate reducing bacteria.
研究了含AnoxKaldnes K5模型的厌氧移动床生物膜反应器(MBBR)处理原酸性矿山废水(AMD)的性能,利用以变形菌属(Proteobacteria)为主的硫酸盐还原菌(SRB)组合,研究了硫酸盐和化学需氧量的减少。MBBR富集4周,然后引入生AMD,每隔7周采样一次。COD去除率最高可达99%,硫酸盐还原率最高可达75%。结果表明,生物载体更适合于COD的还原。关键词:酸性矿山排水;化学需氧量;重金属;移动床生物膜反应器;硫酸盐还原菌。
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引用次数: 3
The Effect of Aqueous Phase Recirculation During Hydrothermal Liquefaction of Spent Coffee Grounds 水相循环对废咖啡渣水热液化的影响
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118260
J. Grobler, C. J. Schabort
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引用次数: 0
Brewery Effluent Sludge Characterization and Dewatering to Increase Potential Water Recycling Capabilities 啤酒废水污泥的特性和脱水,以增加潜在的水回收能力
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118234
E. Fosso-Kankeu, Christiaan Van der Vyver, Dumisane Moyakhe, F. Waanders, C. D. Klerk
Abstract—In this study various coagulants and flocculants were tested for optimum removal of COD from brewery wastewater. The coagulants used were ferric chloride and an organic coagulant mixture obtained from the brewery company. The flocculants used were a cationic flocculant (Genesys’ genefloc, polyquaternary amine), an anionic flocculant (Senfloc 5210), a non-ionic flocculant (Senfloc 5330) and a cationic acrylamide copolymer in aqueous dispersion (Brewery flocculant) for comparison. The organic coagulant mixture in aqueous solution was more effective than the ferric chloride at the same optimal dosage of 25 ppm. The ferric chloride and organic coagulant mixture used alone achieved COD removal efficiencies of 32.7% and 48.5% at a pH of 5.65 respectively while their performances for turbidity removal at pH 5.65 were 63.3% and 91.9% respectively. The best results were achieved when using the ferric chloride in combination with the cationic acrylamide copolymer in aqueous dispersion (Brewery flocculant) at an optimum dosage of 30 ppm and when using the organic coagulant mixture in aqueous solution in combination with the cationic acrylamide copolymer in aqueous dispersion (Brewery flocculant) at an optimum dosage of 10 ppm. When using ferric chloride in combination with the cationic acrylamide copolymer in aqueous dispersion (Brewery flocculant) and the organic coagulant mixture in aqueous solution in combination with the cationic acrylamide copolymer in aqueous dispersion (Brewery flocculant), COD removal efficiencies of 79.6% and 78.2% at a pH of 5.85 respectively was achieved, while they exhibited similar performance for turbidity removal at pH 5.85 of 99.7%. The optimization tests carried out in this study have allowed to improve the understanding of turbidity and COD removal mechanisms and achieved lower dosages of coagulants and flocculants for better treatment, therefore suggesting a more economical approach. Comparing the achieved results with the standard disposal values, it can be seen that the results gathered in
摘要/ abstract摘要:本研究考察了不同混凝剂和絮凝剂对啤酒废水COD的去除效果。使用的混凝剂是氯化铁和从啤酒公司获得的有机混凝剂混合物。用于比较的絮凝剂有阳离子絮凝剂(Genesys的genefloc,聚季胺)、阴离子絮凝剂(Senfloc 5210)、非离子絮凝剂(Senfloc 5330)和阳离子丙烯酰胺共聚物(Brewery絮凝剂)。在最佳投加量为25ppm时,有机混凝剂水溶液的混凝效果优于氯化铁。单独使用氯化铁和有机混凝剂在pH为5.65时,COD去除率分别为32.7%和48.5%;在pH为5.65时,混凝剂对浊度的去除率分别为63.3%和91.9%。氯化铁与阳离子丙烯酰胺共聚物水溶液(Brewery絮凝剂)的最佳用量为30 ppm时,有机混凝剂水溶液与阳离子丙烯酰胺共聚物水溶液(Brewery絮凝剂)的最佳用量为10 ppm时,取得了最佳效果。当氯化铁与阳离子丙烯酰胺共聚物水溶液(Brewery絮凝剂)和有机混凝剂水溶液与阳离子丙烯酰胺共聚物水溶液(Brewery絮凝剂)混合使用时,在pH为5.85时,COD去除率分别为79.6%和78.2%,而在pH为5.85时,它们对浊度的去除率相似,为99.7%。本研究中进行的优化试验提高了对浊度和COD去除机理的理解,并实现了更低剂量的混凝剂和絮凝剂的更好处理,从而提出了一种更经济的方法。将获得的结果与标准处置值进行比较,可以看出
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引用次数: 0
Mathematical Exposition of Simultaneous Nitrification and Aerobic Denitrification 同时硝化和好氧反硝化的数学阐述
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118258
S. G. Kanyenda, S. K. Ntwampe, N. Mpongwana, B. Godongwana
Traditional nitrogen removal techniques include sequential nitrification and aerobic denitrification processes. Recent technologies on nitrogen removal have shown that nitrification and denitrification processes can occur simultaneously in one bioreactor. However, models that ascertain the stoichiometric conversion ratios have not been developed for such systems. In this study simultaneous nitrification and aerobic denitrification data was used in models to describe the substrate consumption and product formation, with simplification using Simpson's rule being used to develop a suitable model. The stoichiometric conversion ratio from NH4-N to NO3-N to NO2-N where approximately found to be ranging from 0.035 0.05 mol: 0.677 – 0.35mol: 1 mol, respectively, indicating that the biological stoichiometric ratios of the simultaneous nitrification and aerobic denitrification processes are not equivalent as previously suggested in theoretical chemical stoichiometric ratios associated with traditional nitrification and denitrification. Keywords— Aerobic denitrification, Biological Stoichiometry, Nitrification, Simultaneity.
传统的脱氮技术包括顺序硝化和好氧反硝化工艺。最近的脱氮技术表明,硝化和反硝化过程可以在一个生物反应器中同时发生。然而,确定这种体系的化学计量转化率的模型还没有开发出来。在本研究中,同时硝化和好氧反硝化数据被用于模型来描述底物消耗和产物形成,并使用辛普森规则进行简化以建立合适的模型。NH4-N - NO3-N - NO2-N的化学计量转化率约为0.035 - 0.05 mol: 0.677 - 0.35mol: 1 mol,表明同时硝化和好氧反硝化过程的生物化学计量比并不像传统硝化和反硝化的理论化学计量比那样相等。关键词:好氧反硝化;生物化学计量;硝化;
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引用次数: 2
Free Cyanide Degradation Kinetics of Cyanide Degrading Bacteria 氰化物降解菌对游离氰化物的降解动力学
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118251
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引用次数: 1
Sol-gel Preparations of ZnO/SnO2 Composite Photocatalysts Applied for the Degradation of PAH’s under Visible Light 可见光下降解多环芳烃的ZnO/SnO2复合光催化剂的溶胶-凝胶制备
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118245
Nthambeleni Mukwevho, E. Fosso-Kankeu, F. Waanders, J. Bunt, D. Bruyn
Wastewater treatment challenges faced by conventional methods have necessitated the need for alternative/complementary methods that are environmentally benign and efficient especially toward recalcitrant organic pollutants. In this regard, ZnO/SnO2 composite photocatalysts were synthesized using sol-gel method and employed in the photocatalytic degradation of Phenanthrene, benzo(a)pyrene and naphthalene, typical PAH’s in water solution. The photocatalyst material was characterized with scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR) to confirm the properties of the nanocomposite. The photocatalytic degradation activities of these nanocomposites towards phenanthrene, naphthalene and Benzo(a)pyrene were then investigated by measuring the effects irradiation time. In addition, the first-order kinetic model was used to determine the rate constant for the degradation reaction. The photocatalytic degradation data exhibited a trend fitting the pseudo first-order kinetics as defined by the Langmuir-Hinshelwood model, which allowed prediction of the faster degradation rate by the ZnO/SnO2 nanohybrid (NH). Keywords: Photocatalyst, Polycyclic aromatic hydrocarbons, composite
传统方法所面临的废水处理挑战使得人们需要对环境无害且高效的替代/补充方法,特别是对顽固的有机污染物。为此,采用溶胶-凝胶法制备了ZnO/SnO2复合光催化剂,并将其应用于光催化降解水溶液中典型的多环芳烃类化合物菲、苯并(a)芘和萘。利用扫描电子显微镜(SEM)和傅里叶变换红外光谱(FTIR)对光催化剂材料进行了表征,以确定纳米复合材料的性能。通过测定辐照时间,研究了纳米复合材料对菲、萘和苯并(a)芘的光催化降解活性。采用一级动力学模型确定了降解反应的速率常数。光催化降解数据符合Langmuir-Hinshelwood模型定义的准一级动力学,可以预测ZnO/SnO2纳米杂化物(NH)更快的降解速率。关键词:光催化剂,多环芳烃,复合材料
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引用次数: 0
Colouring of Dolomite, Quartzite and Dolerite Mine Dump Rocks 白云岩、石英岩和白云岩矿山排土石的着色
Pub Date : 2018-11-19 DOI: 10.17758/eares4.eap1118225
Z. Easton, F. Waanders, E. Fosso-Kankeu
For environmental and aesthetic purposes it has become essential that mine dump rocks either blend into the environment or be used in the production of other products. Lately, there has been a constant need to produce more durable road and construction material and to develop an alternative for granite countertops and flooring. For the visibility of road surface material and the aesthetic aspect of countertops, the colouring of mine dump rocks was considered. A cost effective and environmentally friendly process was suggested to colour mine dump rocks. In this study different colouring agents for three mine dumping rocks, dolomite, quartzite and dolerite, were investigated. The aim was to create lasting colours that have a high wear resistance to weather conditions. Coloured dolomite can be used as road and construction material, coloured quartzite as countertops while coloured dolerite can serve as a replacement for road surfaces. Keywords— Dolerite, Dolomite, Mine dump rocks, Quartzite, Rock colouring
出于环境和美观的目的,矿山排土场的岩石要么融入环境,要么用于生产其他产品,这已经变得至关重要。最近,一直需要生产更耐用的道路和建筑材料,并开发花岗岩台面和地板的替代品。为了路面材料的可视性和台面的美观性,考虑了矿山排土场岩石的着色。提出了一种经济、环保的彩色矿山排土石处理工艺。本文对白云岩、石英岩和白云岩三种矿山排土石的着色剂进行了研究。其目的是创造持久的颜色,对天气条件具有很高的耐磨性。彩色白云石可以用作道路和建筑材料,彩色石英岩可以用作台面,而彩色白云石可以用作路面的替代品。关键词:白云岩,白云岩,矿山排土石,石英岩,岩石着色
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引用次数: 0
期刊
ASETH-18,ACABES-18 & EBHSSS-18 Nov. 19-20 2018 Cape Town (South Africa)
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