This article provides a comprehensive overview of the spatiotemporal variation, chemical characteristics, and source identification of PM2.5 in the coastal and island regions of East Asia. We aimed to comprehensively ascertain the mass concentration and chemical signature of PM2.5 in these distinctive maritime environments. To begin with, the inter-comparison of PM2.5's sampling and analytical methods applied by previous researches were extensively employed. The spatial distribution of PM2.5's mass concentrations and chemical composition were explored throughout the coasts and islands in East Asia. Coastal regions commonly exhibited considerably higher PM2.5 concentrations (152.40 ± 51.20 μg/m3 in North China to 8.34 ± 4.60 μg/m3 in South Taiwan) than those at the island sites (63.08 ± 39.04 μg/m3 in Bohai Sea to 8.82 ± 4.09 μg/m3 in Western Pacific Ocean) with the distinct chemical fingerprints of PM2.5 originated from continental and maritime sources, respectively. The source identification of PM2.5 in the coastal and island regions clarify their distinct chemical characteristics and dominant sources. Coastal regions were predominantly influenced by industrial emissions, vehicular exhausts, and shipping activities, whereas island regions showed greater contributions from long-range transport, oceanic spray, and ship emissions. This article further investigated three major influential factors specifically affecting PM2.5 levels in coastal regions and at islands of East Asia, including pollution sources, weather patterns, and transporting pathways. The study identified three distinct transport channels, namely the West, East, and South Channels which exhibited markedly different PM2.5 levels: the West Channel (38.65 ± 17.07 μg/m3), East Channel (11.28 ± 5.11 μg/m3), and South Channel (9.16 ± 2.71 μg/m3). Anthropogenic sources were the major contributors to PM2.5, while weather patterns and meteorological phenomena also played essential roles in shaping its spatiotemporal variation in East Asia. Moreover, this article further addressed the cluster of transport pathways in assessing three transport channels of PM2.5. By synthesizing the findings from previous investigations, it provided a comprehensive understanding of PM2.5 pollution dynamics in the coastal regions and at the islands of East Asia. It underscored the needs for targeting the interventions and pollution control measures to address the diverse sources and the complex atmospheric conditions.
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