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Si‐Doping Effects in AlGaN Channel Layer on Performance of N‐Polar AlGaN/AlN FETs AlGaN通道层中Si掺杂对N极AlGaN/AlN fet性能的影响
Pub Date : 2023-07-15 DOI: 10.1002/pssa.202200872
Taketo Kowaki, W. Matsumura, Koki Hanasaku, Ryo Okuno, Daisuke Inahara, S. Matsuda, S. Kurai, Yongzhao Yao, Y. Ishikawa, N. Okada, Y. Yamada
The nitrogen‐polar (N‐polar) AlGaN/AlN structure is expected to have higher carrier density than conventional metal‐polar AlGaN/GaN electronic devices, and the AlN substrate offers various advantages, such as high breakdown voltage and high‐temperature operation. Herein, a N‐polar AlGaN/AlN‐heterostructured field‐effect transistor (FET) with static FET characteristics is successfully fabricated. However, the drain current density, IDS, remains significantly small. This study aims to improve IDS by doping Si in the topmost AlGaN channel layer under various conditions.
氮极性(N极性)AlGaN/AlN结构有望比传统的金属极性AlGaN/GaN电子器件具有更高的载流子密度,并且AlN衬底具有各种优势,例如高击穿电压和高温工作。本文成功制备了具有静态场效应晶体管特性的N极AlGaN/AlN异质结构场效应晶体管(FET)。然而,漏极电流密度IDS仍然非常小。本研究旨在通过在各种条件下在最上层的AlGaN通道层中掺杂Si来改善IDS。
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引用次数: 0
Triboelectric Nanogenerator with Nanofiber Dielectric Layer Enriched through Novel Zinc Phthalocyanine Carrying Four O‐Carboranyl Units 新型含4个O -碳硼基单位的酞菁锌富集纳米纤维介电层的摩擦电纳米发电机
Pub Date : 2023-07-14 DOI: 10.1002/pssa.202300191
A. Ozen, A. Karabiber, Sevinc Sener, O. İpek, F. Ozel
Triboelectric nanogenerator (TENG) technology is one of the new, low‐cost, and simple methods used to convert mechanical energy into electrical energy. Despite having so many advantages, the energy efficiency of this technology is extremely low. Therefore, their current performance needs to be improved so that they can be used more in daily life. Nanofibers (NFs) are one of the most important material groups that can be used for this technology due to their large surface area–volume ratio, easy production, low cost, and simplicity. Herein, Nylon 6.6 and polyacrylonitrile are used as tribopositive and tribonegative dielectric layers, respectively. To increase the output performances of the TENG system, different weight ratios (1, 2, 3 wt%) of phthalocyanine containing zinc‐based carborane units (ZnPc) are added into the Nylon 6.6 NFs. In accordance with the obtained results, the maximum open circuit voltage and power are measured as 228 V and 7.76 mW, respectively. These results correspond for the TENG system with 1% by weight ZnPc doped into the NFs. These results show that high‐efficiency TENG systems can be obtained with nanofiber‐based dielectric layers and can be used effectively in self‐powered systems.
摩擦纳米发电机(TENG)技术是一种新的、低成本的、简单的将机械能转化为电能的方法。尽管有这么多的优点,这种技术的能源效率是极低的。因此,它们目前的性能需要改进,以便在日常生活中更多地使用。纳米纤维(NFs)由于其大的表面积体积比、易于生产、低成本和简单性而成为可用于该技术的最重要的材料组之一。其中,尼龙6.6和聚丙烯腈分别作为摩擦正、摩擦负介质层。为了提高TENG系统的输出性能,在尼龙6.6 NFs中加入不同重量比(1、2、3 wt%)的含锌碳硼烷单元(ZnPc)。根据所得结果,测得最大开路电压为228 V,最大开路功率为7.76 mW。这些结果对应于在纳米颗粒中掺入1%重量ZnPc的TENG体系。这些结果表明,基于纳米纤维的介质层可以获得高效率的TENG系统,并且可以有效地用于自供电系统。
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引用次数: 0
On the Role of Nuclear Motion in Singlet Exciton Fission: The Case of Single‐Crystal Pentacene 核子运动在单重态激子裂变中的作用:以单晶五苯为例
Pub Date : 2023-07-14 DOI: 10.1002/pssa.202300304
A. Neef, M. Rossi, M. Wolf, R. Ernstorfer, H. Seiler
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引用次数: 0
Utilizing Hydrazine and Hydrogen as Reducing Agents to Control the Nanoscale Surface Morphology of the Palladium Thin Films 利用肼和氢作为还原剂控制钯薄膜的纳米级表面形貌
Pub Date : 2023-07-14 DOI: 10.1002/pssa.202200645
B. S. Mpofu, Musindo R. T. Madhovi, Tanaka Majuru, K. Munjeri, Timothy Gutu
A key challenge facing fabrication of nanomaterials is the ability to precisely control the surface morphology of the nanostructures through exploitation of process parameters. In this study, palladium thin films with carefully controlled surface morphologies are obtained through the careful choice of the reducing agent used during the pre‐plating activation step in the three‐step autocatalytic electroless plating consisting of 1) surface functionalization; 2) surface activation; and 3) deposition of the film onto alumina substrates. It is important to note that the reducing agents that influenced the surface morphology of the palladium thin films are employed in the pre‐plating activation step instead of the widely utilized electroless deposition step. It is revealed in the high‐resolution scanning electron microscope results that the hydrogen reducing agent yields a dense film with 3D spheroidal morphologies with an average cluster size of ≈415 nm while the hydrazine reducing agent produces a very smooth uniform surface morphology consisting of extremely small grains. The obtained results can be exploited in controlling and tailoring the surface‐dependent properties of the palladium thin film for applications in gas sensors, detectors, or palladium‐based membranes.
纳米材料制造面临的一个关键挑战是如何通过利用工艺参数来精确控制纳米结构的表面形貌。在本研究中,通过仔细选择镀前活化步骤中使用的还原剂,在三步自催化化学镀中获得了表面形貌精心控制的钯薄膜,包括:1)表面功能化;2)表面活化;3)在氧化铝基板上沉积薄膜。值得注意的是,影响钯薄膜表面形貌的还原剂是在镀前活化步骤中使用的,而不是广泛使用的化学沉积步骤。高分辨率扫描电镜结果显示,氢还原剂形成致密的三维球形膜,平均簇尺寸约为≈415 nm,而肼还原剂形成非常光滑均匀的表面形貌,由极小的颗粒组成。所获得的结果可以用于控制和定制钯薄膜的表面依赖特性,用于气体传感器,探测器或钯基膜。
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引用次数: 0
Numerical Study of Silicon and Tungsten Diselenide Nanomaterial‐Based Surface Plasmon Resonance Sensor for Refractive Index Sensing 折射率传感用硅钨二硒化纳米材料表面等离子体共振传感器的数值研究
Pub Date : 2023-07-11 DOI: 10.1002/pssa.202300340
Annu Yadav, P. Lohia, Sachin Singh, S. Yadav, A. Mishra, D. K. Dwivedi
A Kretschmann configuration‐based surface plasmon resonance sensor is proposed. The sensor is made up of calcium fluoride prism, silver, silicon, and tungsten di selenide nanolayer. The theoretical and numerical study of surface plasmon resonance sensor is analyzed by angle interrogation method with the help of MATLAB 2017b. The transfer matrix method (TMM) is the foundation for simulation and a monochromatic light of wavelength 633 nm is considered as source. In the proposed device structure, each layer is arranged in vertical format to improve the electrical and optical properties. The refractive index for analyte is considered as 1.330 to 1.335. Silver (Ag) metal is used for the generation of surface plasmons. It has good chemical properties like metallic conductivity, chemical stability, bandgap, small work function, and acts as an adhesive layer between calcium fluoride prism and silicon layer. To improve the molecular contact and absorption, the transition metal dichalcogenide nanofilm tungsten di selenide (WSe2) is applied at the top. The sensitivity of 367.4 deg RIU−1, detection accuracy of 0.4169 deg−1, quality factor of 193.58, and full‐width half maximum of 1.8985 deg are obtained optimized performance parameters of the proposed device structure.
提出了一种基于克雷茨曼构形的表面等离子体共振传感器。该传感器由氟化钙棱镜、银、硅和二硒化钨纳米层组成。借助MATLAB 2017b,采用角度询问法对表面等离子体共振传感器的理论和数值研究进行了分析。以波长为633 nm的单色光为光源,以传递矩阵法(TMM)为模拟基础。在所提出的器件结构中,每层以垂直格式排列以改善电学和光学性能。分析物的折射率为1.330 ~ 1.335。银(Ag)金属用于产生表面等离子体。具有金属导电性好、化学稳定性好、带隙大、功函数小等化学性能,是氟化钙棱镜与硅层之间的粘接层。为了改善分子接触和吸收,在顶部采用过渡金属二硫系二硒化钨(WSe2)纳米膜。优化后的器件结构性能参数灵敏度为367.4°RIU−1,检测精度为0.4169°g−1,品质因子为193.58,全宽半最大值为1.8985°。
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引用次数: 0
Extremely High Ferromagnetic Resonance Frequency Induced by Triclinic Lattice Distortion in Epitaxial FeCo/MgAl2O4 (001) Films 外延FeCo/MgAl2O4(001)薄膜中三斜晶格畸变诱导的极高铁磁共振频率
Pub Date : 2023-07-11 DOI: 10.1002/pssa.202300438
Congying Ding, Le Wang, Rabiul Islam, Shouheng Zhang, Xia Wang, Hongli Li, W. He, Xing-hua Zhu, Zhao Yao, Zhejun Jin, Guoxia Zhao, Yong Peng, G. Miao, Shandong Li
Theoretically, tetragonal lattice distortion of FeCo epitaxial films can result in a very large in‐plane magnetic anisotropy field, leading to an extremely high ferromagnetic resonance (FMR) frequency. Herein, Fe 75 Co 25 $left(text{Fe}right)_{75} left(text{Co}right)_{25}$ thin films are epitaxially grown on (001) MgAl2O4 single‐crystal substrates. A triclinic lattice distortion with a ≠ b ≠ c $a neq b neq c$ , instead of a tetragonal one, is found in the FeCo films. The cubic symmetry breaking leads to a deviation of easy axes from the 100 $100$ directions, forming a distribution of magnetic moments with a strong perpendicular magnetic anisotropy (PMA) along the out‐of‐plane [001] directions and a deviation of the in‐plane components from the ([10 100]) directions. The effective field of the former is as high as 1.5–2.5 T, enough to overcome the thin film shape anisotropy, while that of the latter stays at a low value of around 0.05 T. The strain‐induced PMA gradually relaxes to in‐plane for thicker films with a strained sublayer remaining. As a result, an extremely high out‐of‐plane FMR frequency over 40 GHz is achieved, accompanied by a lower in‐plane FMR frequency around 8 GHz. This study provides a possible approach to prepare self‐biased soft magnetic films with extremely high‐resonance frequency for applications in microwave‐integrated circuits.
从理论上讲,FeCo外延膜的四方晶格畸变会导致非常大的面内磁各向异性场,从而导致极高的铁磁共振(FMR)频率。本文中,Fe 75 Co 25 $left(text{Fe}right)_{75} left(text{Co}right)_{25}$薄膜被外延生长在(001)MgAl2O4单晶衬底上。在FeCo薄膜中发现了A≠b≠c $a neq b neq c$的三斜晶格畸变,而不是四方晶格畸变。立方对称破缺导致易轴偏离100 $100$方向,形成沿面外[001]方向具有强垂直磁各向异性(PMA)的磁矩分布,面内分量偏离([10 100])方向。前者的有效场高达1.5-2.5 T,足以克服薄膜形状的各向异性,而后者的有效场保持在0.05 T左右的低值。应变诱导的PMA在较厚的薄膜中逐渐松弛到平面内,并留下一个应变亚层。因此,实现了超过40 GHz的极高面外FMR频率,同时伴随着8 GHz左右的较低面内FMR频率。该研究提供了一种可能的方法来制备具有极高谐振频率的自偏置软磁薄膜,用于微波集成电路。
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引用次数: 0
Simple Thermal Annealing‐Assisted Direct Synthesis and Optical Property Study of CuO Nanoparticles Incorporated Polyvinyl Alcohol Films 简单热退火辅助直接合成CuO纳米颗粒聚乙烯醇膜及其光学性能研究
Pub Date : 2023-07-09 DOI: 10.1002/pssa.202300328
Ram Sevak Singh, R. D. Patidar, Ashutosh Kumar Singh, Kalim Deshmukh, K. Thakur, A. Gautam
This article reports a simple thermal annealing‐assisted direct synthesis method to prepare copper oxide (CuO) nanoparticles incorporated in polyvinyl alcohol (PVA) films and a systematic study of their optical properties. CuO‐PVA nanocomposite films are prepared with a different weight percentage of CuO in the PVA matrix. Scanning electron microscopy (SEM), X‐ray diffraction (XRD), UV‐visible spectroscopy, and photoluminescence spectroscopy are employed to study the prepared films. XRD confirms the formation of crystalline CuO nanoparticles in PVA, while the SEM analysis shows uniformly distributed spherical nanoparticles in PVA. The findings show that thermal annealing at a mild temperature plays a crucial role in improving the crystallinity and optical properties of the nanocomposite film. In comparison to PVA, CuO‐PVA nanocomposite exhibits improved absorption with a new absorption band in the lower wavelength region. The nanocomposite samples excited with 300 nm show intense photoluminescence (PL) at 365 nm and an increase of PL intensity with CuO concentration in the PVA matrix. In contrast, samples excited with 425 nm show green emission at 550 nm in the visible region of the electromagnetic spectrum. The PL in CuO‐PVA nanocomposites can be originated due to the transitions associated with acceptor and donor defects in the material. The study opens up a new route to fabricate CuO‐PVA nanocomposites with superior optical properties.
本文报道了一种简单的热退火辅助直接合成方法,制备了聚乙烯醇(PVA)薄膜中的氧化铜(CuO)纳米颗粒,并对其光学性质进行了系统的研究。在PVA基体中加入不同重量百分比的CuO,制备CuO - PVA纳米复合膜。采用扫描电镜(SEM)、X射线衍射(XRD)、紫外可见光谱(UV - visible spectroscopy)和光致发光光谱(photoluminescence spectroscopy)对制备的薄膜进行了研究。XRD证实PVA中形成了结晶状的CuO纳米颗粒,SEM分析表明PVA中形成了均匀分布的球形纳米颗粒。研究结果表明,在温和温度下进行热退火对提高纳米复合薄膜的结晶度和光学性能起着至关重要的作用。与PVA相比,CuO‐PVA纳米复合材料在较低波长区域具有新的吸收带,具有更好的吸收性能。300 nm激发的纳米复合材料在365 nm处表现出较强的光致发光(PL),且发光强度随PVA基体中CuO浓度的增加而增加。相比之下,425 nm激发的样品在电磁波谱可见区显示550 nm的绿色发射。CuO - PVA纳米复合材料中的PL可能是由于材料中受体和给体缺陷相关的转变而产生的。该研究为制备具有优异光学性能的CuO - PVA纳米复合材料开辟了一条新途径。
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引用次数: 1
Smart phone based Non‐Invasive Glucose Monitoring in Diabetic patients utilizing Enhanced Chemiluminescence Imaging Technique. 利用增强型化学发光成像技术,基于智能手机的糖尿病患者无创血糖监测。
Pub Date : 2023-07-08 DOI: 10.1002/pssa.202300077
Priya Singh, Nupur Kumari, Ravi Prakash Ojha, Narsingh Raw Nirala, R. Prakash
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引用次数: 0
Transparent Conducting Oxide Nanocrystals: Synthesis, Challenges, and Future Prospects for Optoelectronic Devices 透明导电氧化物纳米晶体:光电子器件的合成、挑战和未来展望
Pub Date : 2023-07-08 DOI: 10.1002/pssa.202300351
Averi Guha, Tapas K. Paira, Sanjit Sarkar
Flexible transparent electrodes are prerequisites of next‐generation electronic devices. Most of the synthesis process of conventional transparent conducting oxides (TCOs) require high vacuum and high temperature, which hinder its application in flexible devices. Colloidal TCO nanocrystals (NCs) can be potential candidates in this regard. But till date, the electrical performances are not promising for commercial applications. Therefore, a detailed understanding of synthesis, electrical transport, and challenges is required for further development of colloidal NC‐based transparent electrode. Herein, notable works with emphasis on synthesis, postsynthesis modification, along with film deposition techniques are summarized. The comparative studies of electrical performance of promising TCO materials with its thin‐film counterpart are presented to draw future prospects of TCO NCs as commercial transparent electrodes.
柔性透明电极是下一代电子器件的先决条件。传统透明导电氧化物(tco)的合成工艺大多要求高真空和高温,这阻碍了其在柔性器件中的应用。胶体TCO纳米晶体(NCs)可能是这方面的潜在候选者。但到目前为止,其电气性能还不能用于商业应用。因此,需要对合成、电传输和挑战的详细了解,以进一步开发胶体NC基透明电极。本文总结了合成、合成后修饰以及薄膜沉积技术方面的重要研究成果。通过对TCO材料与薄膜材料电性能的比较研究,展望了TCO纳米材料作为商业透明电极的未来前景。
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引用次数: 0
Fabrication and Damping Property of Porous Cu–Al–Ni Shape Memory Alloys Fabricated using Different Raw Materials 不同原料制备多孔Cu-Al-Ni形状记忆合金的制备及其阻尼性能
Pub Date : 2023-07-08 DOI: 10.1002/pssa.202300229
Huan-Yeuh Chu, G. Hao, Puguang Ji, Jianjun Zhang, Tianyuan Zheng, Qingzhou Wang
Porous Cu–Al–Ni shape memory alloys (SMAs) are fabricated via powder metallurgy method using Cu, Al, Ni powders and Cu–Al–Ni alloy powder as raw materials, respectively. It is found that the two kinds of specimens have similar macroscopic morphologies: connected pores are uniformly distributed in the Cu–Al–Ni matrix, forming a 3D network structure. By comparison, the specimen fabricated using alloy powder has much finer microstructures than the specimens fabricated using Cu, Al, Ni powders. After adding Ce element to the latter, the microstructure of the Cu–Al–Ni matrix is significantly refined because of the formation of Ce‐rich particles. Damping tests show that the latter has superior damping capacity than the former. With the increase of Ce content, the damping of the latter increases first and then decreases. When the Ce content reaches 0.05 wt%, the highest damping can be achieved. Correlated mechanisms are discussed based on the microstructural observations.
以Cu、Al、Ni粉末和Cu - Al - Ni合金粉末为原料,采用粉末冶金法制备了多孔Cu - Al - Ni形状记忆合金。结果发现,两种试样具有相似的宏观形貌:连通孔隙均匀分布在Cu-Al-Ni基体中,形成三维网状结构。通过比较,合金粉末制备的试样比Cu、Al、Ni粉末制备的试样具有更精细的显微组织。在Cu-Al-Ni基体中加入Ce元素后,Cu-Al-Ni基体的微观结构明显细化,形成了富Ce颗粒。阻尼试验表明,后者的阻尼能力优于前者。随着Ce含量的增加,后者的阻尼先增大后减小。当Ce含量达到0.05 wt%时,阻尼达到最大。根据微观结构观察,讨论了相关机理。
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引用次数: 0
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Physica status solidi (A): Applied research
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