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OPERATIONAL ASSESSMENTS TO IMPROVE THE MONITORING OF PETROLEUM CATALYTIC HYDRODESULFURIZATION PROCESSING 改进石油催化加氢脱硫过程的运行评价监测
Pub Date : 2020-05-06 DOI: 10.5419/bjpg2020-0001
M. Abreu, C. Abreu
The present research evaluates the operational status of hydrodesulphurization oil processing based on the monitoring of the feed oil filtration system. The system is identified as a prognostic module, designed to predict the remaining catalyst activity in the trickle bed reactor. The influence of the oil feeding flow rate of the process was evaluated with focus on the level of activity of the catalyst bed of the reactor affected by content of soluble and fine contaminants of fed oil. During an operation campaign (45 days) of the HDS unity (filter, reactor) variations of LHSV (0.5 – 1.5 h-1) and pressure differential in the filter (110 – 200 Mpa) reflected in the reactor, where the activity of the catalyst diminished from 60 % to 54.0 %. The predictions, extrapolated to 700 campaign days, indicated a catalyst deactivation of about 50%, allowing a conversion of sulfur compounds around 43% to be maintained.
本研究在对进料油过滤系统进行监测的基础上,对加氢脱硫油处理的运行状况进行了评价。该系统被确定为一个预测模块,用于预测滴流床反应器中剩余的催化剂活性。考察了进油流量对反应器催化剂床层活性的影响,重点考察了进油中可溶性污染物和细污染物含量对反应器床层活性的影响。在HDS系统(过滤器,反应器)运行期间(45天),LHSV (0.5 - 1.5 h-1)和过滤器压差(110 - 200 Mpa)的变化反映在反应器中,其中催化剂活性从60%下降到54.0%。根据700天的预测,催化剂失活率约为50%,硫化合物转化率维持在43%左右。
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引用次数: 0
ANALYSIS OF THE INCLINATION INFLUENCE IN A COALESCER COLUMN FOR OIL/WATER TREATMENT VIA COMPUTATIONAL FLUID DYNAMICS 油水处理凝聚柱倾角影响的计算流体力学分析
Pub Date : 2020-05-06 DOI: 10.5419/bjpg2020-0003
R. D. A. Albuquerque, M. C. Souza, J. G. O. Marinho, L. M. T. D. Oliveira
Among the equipments used in the separation of water from oil, bed coalescers stands out. Even after decades of bed coalescer development, the role of some variables, such as apparatus inclination, in its behavior remains underexplored within the field. Thus, using the ANSYS CFX 13.0 software, a modeling was proposed to determine the influence of bed coalescer inclination in the separation rate of oil from produced water. The software analyzes four inclinations relative to the horizontal axis (0°, 15°, 30° and 60°). The results from simulations identified oil accumulating zones and presence of recirculation zones. It also compared the pressure drop throughout the apparatus in all inclinations established, noting that a more favorable state occurs when the bed is at horizontal, presenting higher oil accumulation, fewer vorticity, and lower pressure drop. The less desirable scenario occurs with 60° inclination, displaying a lower separation efficiency, greater pressure drop, and higher turbulence effect.
在用于油水分离的设备中,床层聚结器是最引人注目的。即使经过数十年的地层聚结剂开发,一些变量(如仪器倾角)在其行为中的作用仍未在现场得到充分探讨。因此,利用ANSYS CFX 13.0软件,建立了床层凝聚器倾角对采出水油分离速率影响的模型。该软件分析相对于水平轴的四种倾角(0°,15°,30°和60°)。模拟结果确定了油气聚集带和再循环带的存在。研究人员还比较了整个设备在所有倾角下的压降,注意到当床层处于水平状态时,会出现更有利的状态,表现出更高的油藏、更小的涡度和更低的压降。当倾角为60°时,分离效率较低,压降较大,湍流效应较强。
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引用次数: 0
THE USE OF COBALT/RUTHENIUM CATALYST SUPPORTED IN SBA-15 IN THE PROMOTION OF FISCHER-TROPSCH SYNTHESIS sba-15负载钴/钌催化剂在促进费托合成中的应用
Pub Date : 2020-05-06 DOI: 10.5419/bjpg2020-0002
J. J. Rodrigues, F. Fernandes, M. Rodrigues
The aim of this work is to produce a cobalt/ruthenium catalyst supported in SBA-15, for Fischer-Tropsch synthesis (FTS). The synthesis was carried out in a slurry reactor operating at 513 K, 20 atm, and CO:H2 molar ratio of 1:1. The addition of cobalt in SBA-15 decreased the specific superficial area of the molecular sieve. The ranges of temperature reduction typical of iron oxides phases were found using RTP results. Fischer-Tropsch synthesis activity and C5+ hydrocarbon selectivity increased with the addition of Ru. The increase in activity and selectivity were attributed to the increased number of active sites as a result of the higher reducibility.
本研究的目的是制备一种以SBA-15为载体的钴/钌催化剂,用于费托合成(FTS)。在513 K, 20 atm, CO:H2摩尔比为1:1的料浆反应器中进行了合成。在SBA-15中加入钴降低了分子筛的比表面积。利用RTP结果找到了氧化铁相的典型温度还原范围。钌的加入提高了费托合成活性和C5+的选择性。活性和选择性的增加归因于活性位点数量的增加,这是由于更高的还原性。
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引用次数: 2
CALCULATION OF THERMAL RADIATION FOR THE DESIGN OF PROTECTION AND FIRE FIGHTING SYSTEMS FOR LPG STORAGE PARKS 液化石油气储存库防护及消防系统设计的热辐射计算
Pub Date : 2020-05-06 DOI: 10.5419/bjpg2020-0004
R. M. S. T. Martins, R. F. Vianna
Liquefied petroleum gas (LPG) is industrially stored in spherical or cylindrical vessels. These follow strict construction standards to prevent accidents that may be caused by fire or explosions in neighboring equipment. The heat transfer by thermal radiation is LPG’s main fire propagator. However, even with standards in place, design and operational failures can still occur. In this context, the installation of firefighting systems to avert major disasters becomes critical. The design of these systems must follow national and international standards and codes, which indicate prescriptive criteria for the selection of equipment to be cooled in case of fire in a LPG storage park. The present paper presents a case study for a LPG spherical vessel storage park. It uses the ALOHA simulator to calculate the action radius of thermal radiation and subsequent selection of spheres to be cooled. It also compares standards adopted in Brazil to international standards, demonstrating that Brazilian standards are more conservative and obsolete in regards to the advances in Fire Engineering. The work has the potential to be used as the basis for reviewing Brazilian’s standards.
工业上,液化石油气(LPG)储存在球形或圆柱形容器中。这些都遵循严格的施工标准,以防止附近设备发生火灾或爆炸事故。热辐射传热是液化石油气主要的火灾传播方式。然而,即使有了适当的标准,设计和操作失败仍然可能发生。在这种情况下,安装消防系统以避免重大灾害变得至关重要。这些系统的设计必须遵循国家和国际标准和规范,这些标准和规范规定了在液化石油气储存园区发生火灾时选择冷却设备的规定标准。本文介绍了一个液化石油气球形容器储存库的案例研究。它使用ALOHA模拟器来计算热辐射的作用半径,并随后选择待冷却的球体。它还将巴西采用的标准与国际标准进行了比较,表明巴西的标准在消防工程方面更加保守和过时。这项工作有可能被用作审查巴西标准的基础。
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引用次数: 1
AUTOMATED METHODOLOGY FOR DETECTING BORDER IN CT-SCAN IMAGES OF NON-CIRCULAR ROCK SAMPLES 非圆形岩石样品ct扫描图像边界检测的自动方法
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0023
L. F. Lamas, E. Ruidiaz, A. Vidal
X-ray computed tomography, CT-scan, is a very important tool in special core analysis, because it allows the visualization of the interior of cores, providing information such as porosity, saturations, and changes on these parameters with time. CT-scan images are usually square, and contain information not only the core, but also parts of the core-holder, the water used to pressurize the system, and the rubbers that hold the cores in place. Software available to process these images are usually very expensive, or do not allow reasonable automation of the process of treating images. This paper proposes a simplified methodology to isolate the core in a CT image, allowing the processing of multiple images without the interference of the user. This methodology can be implemented easily in any computer language, it saves operation time, and reduces the risk of human error.
x射线计算机断层扫描(ct)是一种非常重要的特殊岩心分析工具,因为它可以可视化岩心内部,提供孔隙度、饱和度等信息,以及这些参数随时间的变化。ct扫描图像通常是方形的,不仅包含岩心的信息,还包含岩心固定器的部分信息,用于给系统加压的水,以及固定岩心的橡胶。可用于处理这些图像的软件通常非常昂贵,或者不允许处理图像过程的合理自动化。本文提出了一种简化的方法来分离CT图像中的核心,允许在不受用户干扰的情况下处理多幅图像。这种方法可以很容易地在任何计算机语言中实现,它节省了操作时间,减少了人为错误的风险。
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引用次数: 2
EVALUATING THE IMPACT OF PETROPHYSICAL IMAGES PARAMETERIZATION IN DATA ASSIMILATION FOR UNCERTAINTY REDUCTION 评价岩石物理图像参数化在数据同化中降低不确定性的影响
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0021
Ricardo Vasconcellos Soares, H. Formentin, C. Maschio, D. Schiozer
Parameterization is a crucial step during uncertainty reduction of reservoir properties using dynamic data. It establishes the search space based on prior knowledge of the model and can have a significant influence on the final response. A less-appropriate parameterization might fail to have a reasonable representation of the reservoir and lead to models unable to predict the correct reservoir characteristics. Parameterization of petrophysical images (as facies, porosities, and permeabilities) plays an essential role during data assimilation processes due to the strong influence in fluid flow in the porous media. This work shows how important the parameterization of petrophysical images is and how a less-appropriate parameterization can affect history-matching and uncertainty reduction process. Using a benchmark case, we compare two parameterization techniques, one capable of treating all blocks in the model (distance-dependent covariance localization), which is considered more appropriate, and one that considers a group of blocks under the same update rule (zonation) (less-appropriate). Results show that parameterization of petrophysical images has a high impact on the final response, and a less-appropriate parameterization, as the zonation, can generate higher data mismatches and fail to represent the real reservoir response. The analysis carried in this work quantifies and qualifies the impact of the parameterization of the petrophysical images in the data assimilation for the uncertainty reduction process.
参数化是利用动态数据降低储层物性不确定性的关键步骤。它根据模型的先验知识建立搜索空间,对最终的响应有很大的影响。不适当的参数化可能无法合理地表示储层,并导致模型无法预测正确的储层特征。岩石物性图像(如相、孔隙度和渗透率)的参数化在数据同化过程中起着至关重要的作用,因为多孔介质中的流体流动具有很强的影响。这项工作表明了岩石物理图像参数化的重要性,以及不合适的参数化如何影响历史匹配和减少不确定性的过程。使用基准测试案例,我们比较了两种参数化技术,一种能够处理模型中的所有块(距离相关协方差定位),这被认为是更合适的,另一种能够考虑相同更新规则下的一组块(分区)(不太合适)。结果表明,岩石物理图像的参数化对最终响应有很大的影响,而参数化不当(如分带)会产生更高的数据不匹配,不能代表真实的储层响应。本工作中进行的分析量化和定性了岩石物理图像参数化在数据同化过程中对不确定性降低过程的影响。
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引用次数: 0
IMPACT OF NUMBER OF FRACTURES ON OIL RECOVERY DURING ELECTROMAGNETIC HEATING 电磁加热过程中裂缝数量对采收率的影响
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0020
C. P. Ruiz, J. M. Tarifa
Thermal recovery methods are used typically to produce heavy oil and bitumen. During this process, the temperature is raised to reduce oil viscosity. Conventional thermal methods may not be effective on deep wells or thin zones. An alternative to the thermal process is electromagnetic heating, which is a process based on the transformation of electric energy into thermal energy due to the electromagnetic field and electrically sensitive particles interacting on the medium. In this paper, reservoir simulations with similar characteristics to those found in the sedimentary basins of the Brazilian Northeast were performed. The purpose of this work is to analyze the impact of the number of fractures, fracture configurations and number of producer wells during electromagnetic heating over the oil recovery factor (ORF) value. The results revealed an oil production increment with increasing number of producer wells and when fractures are located at the center of the oil production zone. However, oil production did not show an evident increase connected to the number fractures.
热采方法通常用于开采稠油和沥青。在这个过程中,温度升高以降低油的粘度。常规的热采方法对深井或薄层可能不太有效。热过程的另一种替代方法是电磁加热,它是由于电磁场和电敏感粒子在介质上相互作用,将电能转化为热能的过程。本文进行了与巴西东北部沉积盆地相似特征的储层模拟。研究了电磁加热过程中裂缝数量、裂缝构型和生产井数量对采收率(ORF)值的影响。结果表明,随着生产井数量的增加,当裂缝位于产油区的中心时,石油产量会增加。然而,原油产量并没有随着裂缝数量的增加而明显增加。
{"title":"IMPACT OF NUMBER OF FRACTURES ON OIL RECOVERY DURING ELECTROMAGNETIC HEATING","authors":"C. P. Ruiz, J. M. Tarifa","doi":"10.5419/bjpg2019-0020","DOIUrl":"https://doi.org/10.5419/bjpg2019-0020","url":null,"abstract":"Thermal recovery methods are used typically to produce heavy oil and bitumen. During this process, the temperature is raised to reduce oil viscosity. Conventional thermal methods may not be effective on deep wells or thin zones. An alternative to the thermal process is electromagnetic heating, which is a process based on the transformation of electric energy into thermal energy due to the electromagnetic field and electrically sensitive particles interacting on the medium. In this paper, reservoir simulations with similar characteristics to those found in the sedimentary basins of the Brazilian Northeast were performed. The purpose of this work is to analyze the impact of the number of fractures, fracture configurations and number of producer wells during electromagnetic heating over the oil recovery factor (ORF) value. The results revealed an oil production increment with increasing number of producer wells and when fractures are located at the center of the oil production zone. However, oil production did not show an evident increase connected to the number fractures.","PeriodicalId":9312,"journal":{"name":"Brazilian Journal of Petroleum and Gas","volume":"17 1","pages":"241-247"},"PeriodicalIF":0.0,"publicationDate":"2019-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83446425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PARTICLE-SCALE SIMULATION OF THE SEDIMENTATION AND FILTRATION OF DRILLING FLUIDS USING THE DISCRETE ELEMENT METHOD 用离散元法模拟钻井液沉降和过滤的颗粒尺度
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0024
J. M. S. Alvim, K. Sepehrnoori, C. Scheid, L. Calçada, L. Meleiro
This paper presents the development of a computational code based on Discrete Element Method (DEM) to simulate the process of solid particles sedimentation and fluid filtration in drilling operations. For both phenomena, the adequate knowledge of the properties and characteristics of the underlying particulate systems represents an aspect of fundamental importance for the safe and efficient design of new drilling fluids and equipment. In this context, this paper presents a particle-scale simulation study, based on DEM, to describe the mechanics of cake formation and growth during the deposition of particulates. Three dimensional (3D) simulations of both processes were carried out to evaluate the proposed algorithm. The cake and the sediment properties, such as thickness, porosity and permeability were quantified and compared, qualitatively and quantitatively, to literature data. The cake properties obtained in this work showed good agreement with data found in similar conditions.
本文提出了一种基于离散元法(DEM)的模拟钻井作业中固体颗粒沉降和流体过滤过程的计算程序。对于这两种现象,充分了解潜在颗粒系统的特性和特征,对于安全高效地设计新钻井液和设备具有重要意义。在此背景下,本文提出了基于DEM的颗粒尺度模拟研究,以描述颗粒沉积过程中饼的形成和生长机制。对这两个过程进行了三维仿真来评估所提出的算法。定量分析了泥饼和沉积物的厚度、孔隙度、渗透率等特性,并与文献数据进行了定性和定量对比。所得的饼性质与在类似条件下得到的数据吻合较好。
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引用次数: 0
ADSORPTION OF CRUDE OIL IN AQUEOUS ENVIRONMENT USING WILD CANE FIBER: EQUILIBRIUM AND KINETIC STUDIES 野生甘蔗纤维在水中对原油的吸附:平衡和动力学研究
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0028
P. M. França, A. P. Santos, C. Queiroz, K. C. A. Santos, A. Silva, S. Mattedi
This work evaluates the adsorption capacity of the wild cane fiber (Gynerium Sagittatum) in crude oil. Both untreated biomass and treated with ionic liquid [2HEA][Ac] and acetylated were studied for oil spill cleanup in aqueous environment. Crude oil adsorption tests were performed in a thermostatic bath, varying the time for the kinetic study and the amount of oil for isotherm model. Kinetic study of oil adsorption allowed us to identify that the untreated fiber reached saturation in 90 minutes, while the fiber treated with acetylated and ionic liquid reached saturation in 30 minutes. In equilibrium, the total amount of oil adsorbed by the untreated fiber was 3.8g, whereas in acetylated and ionic liquid treated fiber, the obtained maximum adsorption capacity was 4.4 and 3.7 g, respectively. The remediation process using wild cane fiber followed a second order kinetic rate and Sips and Toth isotherm models provided the best fit to experimental data.
研究了野生甘蔗纤维(Gynerium Sagittatum)对原油的吸附性能。研究了离子液体[2HEA][Ac]和乙酰化处理的生物质能和未处理的生物质能对水中溢油的清除效果。在恒温浴中进行了原油吸附试验,改变了动力学研究的时间和等温模型的油量。通过油吸附动力学研究,我们发现未经处理的纤维在90分钟内达到饱和,而经乙酰化和离子液体处理的纤维在30分钟内达到饱和。在平衡状态下,未经处理的纤维吸附油总量为3.8g,而在乙酰化和离子液体处理的纤维中,获得的最大吸附量分别为4.4和3.7 g。野蔗纤维的修复过程符合二级动力学速率,Sips和Toth等温线模型与实验数据最吻合。
{"title":"ADSORPTION OF CRUDE OIL IN AQUEOUS ENVIRONMENT USING WILD CANE FIBER: EQUILIBRIUM AND KINETIC STUDIES","authors":"P. M. França, A. P. Santos, C. Queiroz, K. C. A. Santos, A. Silva, S. Mattedi","doi":"10.5419/bjpg2019-0028","DOIUrl":"https://doi.org/10.5419/bjpg2019-0028","url":null,"abstract":"This work evaluates the adsorption capacity of the wild cane fiber (Gynerium Sagittatum) in crude oil. Both untreated biomass and treated with ionic liquid [2HEA][Ac] and acetylated were studied for oil spill cleanup in aqueous environment. Crude oil adsorption tests were performed in a thermostatic bath, varying the time for the kinetic study and the amount of oil for isotherm model. Kinetic study of oil adsorption allowed us to identify that the untreated fiber reached saturation in 90 minutes, while the fiber treated with acetylated and ionic liquid reached saturation in 30 minutes. In equilibrium, the total amount of oil adsorbed by the untreated fiber was 3.8g, whereas in acetylated and ionic liquid treated fiber, the obtained maximum adsorption capacity was 4.4 and 3.7 g, respectively. The remediation process using wild cane fiber followed a second order kinetic rate and Sips and Toth isotherm models provided the best fit to experimental data.","PeriodicalId":9312,"journal":{"name":"Brazilian Journal of Petroleum and Gas","volume":"1 1","pages":"333-354"},"PeriodicalIF":0.0,"publicationDate":"2019-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77225183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
STRUCTURAL RELIABILITY APPLIED TO ANALYTICAL MODELING OF THE TENSILE STRENGTH OF STANDARD API CASING CONNECTIONS 结构可靠性应用于标准API套管接头抗拉强度的分析建模
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0025
Thiago Barbosa da Silva, E. T. L. Junior, L. P. Gouveia
In oil and gas wells scenario, casing design is a crucial stage of the project, representing the major structural elements responsible for maintaining well integrity through its lifetime and allowing adequate production activities. The occurrence of failures in casing systems can lead to irreversible safety problems in well operation. It is estimated that between 85% to 95% of the failures in well tubulars are related to joints (Payne et al., 2006). This work aims to analyze mechanical models of API casing connections in a probabilistic framework. The formulation for evaluating the strength of tubulars, under various load conditions, is presented by the code API TR 5C3 (2008), widely used by oil and gas companies worldwide. The reliability analysis is performed by the Monte Carlo simulation and First Order Reliability Method (FORM), considering failure modes by fracture in round and buttress connections, beyond failures by pull-out in round connections.
在油气井中,套管设计是项目的关键阶段,它代表了主要的结构元素,负责在整个生命周期内保持油井的完整性,并允许充分的生产活动。套管系统故障的发生会导致井作业中出现不可逆转的安全问题。据估计,85%至95%的井管柱失效与节理有关(Payne et al., 2006)。这项工作的目的是在概率框架下分析API套管连接的力学模型。在各种载荷条件下评估管柱强度的公式由API TR 5C3(2008)规范提出,该规范被世界各地的石油和天然气公司广泛使用。可靠性分析采用蒙特卡罗模拟和一阶可靠性方法(FORM)进行,考虑了圆形连接和支撑连接的断裂失效模式,以及圆形连接的拔出失效模式。
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引用次数: 3
期刊
Brazilian Journal of Petroleum and Gas
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