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PRODUCTION OF HYDROGEN BY WATER-GAS SHIFT REACTION ON Ru/C CATALYST Ru/C催化剂上水煤气移位反应制氢的研究
Pub Date : 2018-07-11 DOI: 10.5419/BJPG2018-0009
Germana Arruda de Queiroz, C. Barbosa, C. Abreu
This work explores the catalytic performance of a 2% ruthenium carbon (Ru/C) catalyst in the low temperature water-gas shift reaction (WGSR). The catalyst synthetized was characterized with X-ray diffraction (XRD) and specific surface area (BET) methods. The gas mixture of 15% carbon monoxide + argon and water were used as reagents. The operations catalytic were performed in a fixed bed reactor over a temperature range of 453–553 K. A numerical fitting algorithm was developed for the estimation of the kinetic parameters in a power-law model for the rate velocity. At 553K, 80% CO conversion was achieved, under steady state. For the empirical rate equation, the activation energy determined from the experimental data, was 190 kJ/mol.
研究了2%钌碳(Ru/C)催化剂在低温水气转换反应(WGSR)中的催化性能。用x射线衍射(XRD)和比表面积(BET)方法对合成的催化剂进行了表征。以15%一氧化碳+氩气和水的混合气为试剂。催化操作在固定床反应器中进行,温度范围为453-553 K。提出了一种用于估计速率速度幂律模型中动力学参数的数值拟合算法。在553K时,稳态下的CO转化率达到80%。对于经验速率方程,由实验数据确定的活化能为190 kJ/mol。
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引用次数: 1
DYNAMIC ADSORPTION OF H2S IN A FIXED BED OF SEWAGE SLUDGE PYROLYSIS CHAR 污泥热解炭固定床对h2s的动态吸附研究
Pub Date : 2018-07-11 DOI: 10.5419/BJPG2018-0008
R. D. Possa, J. F. Sousa, J. A. Oliveira, P. F. Nascimento, M. Lima, I. Brandão, M. Bezerra
In this work, sewage sludge char was tested as a H2S adsorbent in a fixed-bed column, at 25 °C. The char was activated physically and chemically (with HCl or KOH) to enhance textural properties. Commercial activated carbon impregnated with iron was also tested for comparison. The column was filled with 18.24 g of char and, then, fed H2S (600 ppm) under 50 mL/min. The effluent gas composition was measured via photocolorimetry and the data was used to plot breakthrough curves. A mathematical modeling was used to estimate parameters such as axial diffusivity, effective intraparticle diffusivity, and external mass transfer coefficient. The main results show that the adsorption capacities varied from 7.2 to 657.60 mgH2S/gads. The percentages of H2S adsorbed varied from 43.36 to 59.04%. HCl proved to be more efficient than KOH. Due to improved textural properties, the commercial activated carbon outperformed (69.15%, 12,527.80 mgH2S/gads) all char samples.
在这项工作中,污水污泥焦炭作为H2S吸附剂在固定床柱上进行了测试,温度为25℃。用物理和化学方法(用盐酸或氢氧化钾)活化焦炭以增强其结构性能。还对浸渍铁的商品活性炭进行了比较试验。柱内填充18.24 g炭,然后以50 mL/min的速度加注H2S (600 ppm)。利用光比色法测定了出水气体组成,并绘制了突破曲线。利用数学模型估计了轴向扩散系数、有效粒子内扩散系数和外传质系数等参数。主要结果表明:吸附量在7.2 ~ 657.60 mgH2S/gads之间;H2S吸附率为43.36% ~ 59.04%。HCl被证明比KOH更有效。由于结构性能的改善,商品活性炭的性能优于所有炭样(69.15%,12527.80 mgH2S/gads)。
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引用次数: 6
THE USE OF FACTORIAL DESIGN TO EVALUATE SYSTEMATIC CHANGES IN THE OPERATING CONDITIONS OF A THREE-PHASE SEPARATOR USING SIMULATION AS A TOOL 使用析因设计,以模拟为工具评估三相分离器操作条件的系统变化
Pub Date : 2018-04-16 DOI: 10.5419/BJPG2018-0002
C. Araujo, H. Nascimento, C. Cavalcanti, M. A. M. Sobrinho, M. Pimentel
This work aims to use factorial designs to evaluate changes in the operating conditions of a three-phase separator. It performs experiments using a Hysys simulation software. It evaluates the influences of temperature, working pressure, and type of separator for light and heavy oils. To find the best operating conditions theoretically, higher oil flow rate (outlet stream) and smaller amount of water in the oil stream are used as reference goals. After performing simulations, the data is analyzed, and one can observe that the effect type of separator does not have a statistically significant influence in the results. The best operating condition occurs with the temperature at 30oC and the pressure at 9 bar, lowest and highest levels suited, respectively.
这项工作旨在使用析因设计来评估三相分离器操作条件的变化。利用Hysys仿真软件进行实验。评价了温度、工作压力、分离器类型对稠油和轻油分离的影响。为了从理论上找到最佳的操作条件,以较高的油流量(出口流量)和较小的油流量为参考目标。在进行模拟后,对数据进行了分析,可以看到分离器的效果类型对结果的影响在统计上并不显著。最佳工作条件是温度为30℃,压力为9 bar,最低和最高水平分别适合。
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引用次数: 0
CHEMIOMETRIC STUDY ON THE INFLUENCE OF CAROTENOIDS AND SATURATED FATTY ACIDS IN BIODIESEL STORAGE STABILITY 类胡萝卜素和饱和脂肪酸对生物柴油贮存稳定性影响的化学计量学研究
Pub Date : 2018-04-16 DOI: 10.5419/BJPG2018-0001
K. S. Figueredo, C. P. Prados, L. V. Milhomem, A. R. Silva
Biodiesel is a fuel derived from renewable raw materials with the potential to change the world's energy matrix, and reduce the damage caused by fossil fuels to the environment and human health. The disadvantage of biodiesel is its low oxidative stability which affects its storage time. In this study, experimental biodiesel blends were used to identify the influences of carotenoid and free fatty acid contents on storage stability by using UV-VIS spectroscopy. Binary biodiesel blends were prepared blending buriti biodiesel contents ranging from 30% (v/v), 60% (v/v), and 90% (v/v) with soybean, sunflower, and beef tallow biodiesel. The blends were stored up to 45 days to compare the oxidative stabilities. The binary biodiesel blend composed by 90% buriti biodiesel and 10% beef tallow one presented the highest oxidative stability during the evaluated storage time.
生物柴油是一种从可再生原料中提取的燃料,有可能改变世界的能源矩阵,并减少化石燃料对环境和人类健康造成的损害。生物柴油的缺点是氧化稳定性低,影响了其贮存时间。本研究以实验生物柴油混合物为研究对象,利用紫外-可见光谱法研究了类胡萝卜素和游离脂肪酸含量对生物柴油贮存稳定性的影响。将含有30% (v/v)、60% (v/v)和90% (v/v)的buriti生物柴油与大豆、向日葵和牛脂生物柴油共混制备二元生物柴油混合物。将混合物保存45天,以比较其氧化稳定性。由90% buriti生物柴油和10%牛油生物柴油组成的二元生物柴油混合物在评估的储存时间内表现出最高的氧化稳定性。
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引用次数: 0
A REVIEW OF THE MAIN TECHNIQUES TO AVOID THE FORMATION OF HYDRATES 综述了避免水合物形成的主要技术
Pub Date : 2018-04-16 DOI: 10.5419/BJPG2018-0006
Suelem Sá Dela Fonte, G. Simonelli, L. Santos
Natural gas hydrates are crystalline solids composed of water molecules and light hydrocarbons. The most favorable conditions for the formation of hydrates are high pressure and low temperature. The accumulation of hydrates is a significant problem for the oil industry, as it can result in blockages in the transportation and production lines, or hamper the drilling of wells. Thus, it is imperative to avoid the formation of hydrates. Different techniques have been developed and improved over the years seeking to prevent hydrates formation. The present paper aims to review the literature with the goal of gathering information on the main techniques used to prevent the formation of hydrates. This study also highlights the technological advancement of the main prevention techniques, considering that those techniques use chemicals or heat transfer to prevent or delay the formation of hydrates.
天然气水合物是由水分子和轻烃组成的结晶固体。形成水合物的最有利条件是高压和低温。对于石油行业来说,水合物的积累是一个严重的问题,因为它可能导致运输和生产线的堵塞,或者阻碍油井的钻探。因此,必须避免水合物的形成。多年来,人们开发和改进了不同的技术来防止水合物的形成。本文旨在回顾文献,目的是收集用于防止水合物形成的主要技术的信息。本研究还强调了主要预防技术的技术进步,考虑到这些技术使用化学物质或传热来防止或延迟水合物的形成。
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引用次数: 3
DEVELOPMENT OF A GUI INTERFACE FOR GEOPRESSURE DETECTION DURING WELL DRILLING 开发钻井过程中压力检测GUI界面
Pub Date : 2018-04-16 DOI: 10.5419/BJPG2018-0005
D. Santos, D. Santos, W. Souza
Geopressure studies are one of the most important activities in the upstream sector of oil industry. The geological formation analysis of the existing prospectus of a sedimentary basin enables the measurement of overload, fracture, and pore pressures. Geopressure can be understood as any pressure or stress on a geological formation, whether on macro or microscopic scale. The estimate of geopressure is one of the most important steps for the establishment of an engineering design of drilling operations and well design. The aim of this work is to present the development of a GUI developed for geopressure analysis, i.e. pore pressure curves, fracture curves, and collapse curves. This work presents the definition of geopressure and GUI interface development protocols for a petroleum engineer, as well as real examples and windows of absorption tests with the appropriate operating depths where they are seated shoes.
地压研究是石油工业上游部门最重要的活动之一。通过对沉积盆地现有剖面的地质构造分析,可以测量过载、断裂和孔隙压力。地质压力可以理解为地质构造上的任何压力或应力,无论是宏观的还是微观的。地层压力的估算是制定钻井作业和油井设计方案的重要步骤之一。这项工作的目的是展示开发一个GUI用于地压分析,即孔隙压力曲线,破裂曲线和崩溃曲线。这项工作提出了一个石油工程师的地压和GUI界面开发协议的定义,以及真实的例子和吸收测试的窗口与适当的操作深度,他们坐在鞋子。
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引用次数: 1
LONG-RANGE PLANNING FOR THE BRAZILIAN PETROCHEMICAL INDUSTRY USING MIXED-INTEGER PROGRAMMING 利用混合整数规划方法对巴西石化工业进行长期规划
Pub Date : 2017-12-21 DOI: 10.5419/BJPG2017-0019
K. M. Boaventura, F. Peixoto, H. L. Sanches, F. Pessoa
A mixed-integer multiperiod model is used to propose a long-range planning for the Brazilian petrochemical industry. The specific aims of this work are to present a model to select the petrochemical processes capable of increasing over the next 20 years and carry out a sensitivity analysis of this selection if there are changes in demands for products or in the purchase prices of chemicals. The optimization model seeks to minimize the cost and the constraints related to demand, supply, and plant capacities in the petrochemical industry. The long-range planning was suggested for six scenarios, which differ according to the investment constraints, demands for products, and chemicals purchase prices imposed. Among the 295 processes considered, 26 were selected for investment in new process units through the optimization procedure in all scenarios, such as the processes for the production of polyurethane and acrylic fibers. These results are consistent with previous studies of investment assessment of the Brazilian petrochemical industry.
采用混合整数多周期模型对巴西石化工业进行了长期规划。这项工作的具体目的是提出一个模型来选择能够在未来20年内增加的石化过程,并在产品需求或化学品购买价格发生变化时对这种选择进行敏感性分析。优化模型寻求最小化成本以及石化行业中与需求、供应和工厂产能相关的约束。根据投资限制、产品需求和化学品购买价格的不同,提出了六种方案的长期规划。在考虑的295个工艺中,通过所有场景的优化程序选择了26个用于投资新工艺单元,例如聚氨酯和丙烯酸纤维的生产工艺。这些结果与以往对巴西石化行业投资评价的研究结果一致。
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引用次数: 1
USING MICROEMULSION-MODIFIED DIATOMITE FOR REMOVING SULFUR FROM COMMERCIAL DIESEL 微乳液改性硅藻土用于商业柴油脱硫
Pub Date : 2017-12-21 DOI: 10.5419/BJPG2017-0020
T. Dantas, A. Neto, M. Moura, K. Oliveira
Diatomite or diatomaceous earth is a sedimentary rock composed mainly of diatom siliceous skeletons with high porosity that is often used in adsorption processes. This work investigates the enhancement of diatomite properties using microemulsion systems in the removal of sulfur from commercial diesel. Nonionic surfactants containing microemulsions were used to modify its surface. The adsorbents were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray fluorescence (XRF), thermogravimetry (TG), and N2 adsorption-desorption. A 23 full factorial design was performed to assess the influence of salt concentration on adsorption capacities in the microemulsion aqueous phase (from 20 to 1500 mg/kg). The experiments were carried out at batch temperature (25 to 60 °C) and using a commercial diesel fuel with sulfur concentration from 300 to 1100 mg/kg. Sulfur adsorption capacity increased from 0.436 mg/g to 1.23 mg/g with the optimization of the microemulsion system and with the salt addition. The microemulsion-modified diatomite was able to remove up to 26.53% sulfur from commercial diesel.
硅藻土或硅藻土是一种主要由硅藻硅质骨架组成的沉积岩,具有高孔隙率,常用于吸附过程。本工作研究了微乳液系统在商业柴油中去除硫的硅藻土性能的增强。采用含微乳液的非离子表面活性剂对其表面进行改性。采用扫描电镜(SEM)、x射线衍射(XRD)、x射线荧光(XRF)、热重(TG)、N2吸附-脱附等方法对吸附剂进行了表征。采用23全因子设计来评估盐浓度对微乳液水相(20 ~ 1500mg /kg)吸附能力的影响。实验在批量温度(25 ~ 60℃)下进行,使用硫浓度为300 ~ 1100 mg/kg的商业柴油。优化微乳液体系和添加盐后,硫的吸附量由0.436 mg/g提高到1.23 mg/g。微乳液改性硅藻土对商业柴油的硫去除率可达26.53%。
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引用次数: 2
COMBINING MIXED-COMPOSITION PETROLEUM STREAMS USING PROXY MODELS OF EQUATION OF STATE FOR COMPOSITIONAL INTEGRATED PRODUCTION MANAGEMENT 利用状态方程代理模型组合混合成分油气流进行组合综合生产管理
Pub Date : 2017-12-21 DOI: 10.5419/BJPG2017-0018
S. F. Mello, J. C. H. Filho, D. Schiozer
When two distinct offshore reservoirs produce in the same region, the same gathering system for both reservoirs may be used. It is recommended that the gas/oil composition is modeled because its effects can impact reservoir forecasting. An incorrectly-modeled Integrated Production Management (IPM), i.e. one with insufficient data, can impact system management negatively due to the lack of a rigorous compositional modeling impact assessment. To fully study this problem, there need to be a method to model mixed-composition petroleum streams. Most proposed methods to carry this task are Pseudo-Compositional (based on K-values) or are based on Black-Oil models. The objective of this work is to develop a method for mixed-composition petroleum streams to be used in future compositional IPM optimization studies. This paper implements, validates, and discusses the limitations and reproducibility of a mixed-composition petroleum stream. It models a methodology based on an Equation of State (EoS) and PVT data, and combines concepts proposed by Carpio (2012) to automate the process. This work compares the proposed method with two mixing methods from the literature. The three mixing methods studied are based on concepts of tuned EoS and the well-known methods of EoS from Peng-Robinson (1978), and volume translation from Jhaveri-Youngren (1988). The analysis and comparison of the methods are based on conventional data and simulated tuned experiments, when applicable. The results of this study show a small but significant variability of mixed-stream properties from the three proxy methods with the potential to impact optimal reservoir control conditions. Therefore, the deviation potential of mixed-stream models is worth further investigation, thus, justifying a subsequent sensitivity study, with focus on closed-loop IPM.
当两个不同的海上储层在同一地区生产时,两个储层可以使用相同的收集系统。建议对油气组成进行建模,因为其影响会影响储层预测。建模不正确的集成生产管理(IPM),即数据不足的集成生产管理,由于缺乏严格的组成建模影响评估,可能会对系统管理产生负面影响。为了充分研究这一问题,需要一种模拟混合成分油气流的方法。大多数提出的完成这项任务的方法是伪成分(基于k值)或基于Black-Oil模型。这项工作的目的是开发一种混合成分石油流的方法,用于未来的成分IPM优化研究。本文实现、验证并讨论了混合成分油气流的局限性和可重复性。它基于状态方程(EoS)和PVT数据对方法进行建模,并结合Carpio(2012)提出的概念来实现过程自动化。本工作将提出的方法与文献中的两种混合方法进行了比较。所研究的三种混合方法是基于Peng-Robinson(1978)的调谐微分方程和著名的微分方程方法的概念,以及Jhaveri-Youngren(1988)的体积翻译。分析和比较的方法是基于常规数据和模拟调优实验,如果适用。该研究结果表明,三种替代方法的混流性质具有较小但显著的可变性,有可能影响最佳油藏控制条件。因此,混合流模型的偏差潜力值得进一步研究,因此,有必要进行后续的敏感性研究,重点关注闭环IPM。
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引用次数: 0
OPTIMIZATION FOR DRILLING SCHEDULE OF WELLS IN THE DEVELOPMENT OF HEAVY OIL RESERVOIRS 稠油油藏开发中钻井进度的优化
Pub Date : 2017-10-16 DOI: 10.5419/BJPG2017-0014
L. F. Lamas, V. Botechia, D. Schiozer, M. Delshad
During the development stage of a petroleum field, one important decision is to define the schedule for drilling the wells. Several general rules were listed for light and heavy oils. However, these rules are not always applicable and it may be important to use simulation models to test and choose the schedule. This paper consists of the development, implementation, and application of two different algorithms for optimization of wells drilling schedule. The first algorithm seeks, for each period, which well brings the best economic output. Once this well is selected, the second period of time is tested considering the remaining wells and this procedure is repeated until the last well. The second procedure is based on the reduction of search space where random schedules are generated and the best results maintained for the subsequent generation of scenarios, only allowing the wells to be drilled in the period that produced the best values of the objective function in the previous step. This procedure is repeated until each well converges to the period that results in the best economic return. Both algorithms were tested in two synthetic fields, based on the characteristics of offshore heavy oil and high average permeability reservoirs. To generate a benchmark for the solutions, a large amount of random schedules were tested and a normal distribution for net present values was generated. Both algorithms can be applied in any type of reservoirs, resulting in a very time consuming process in the cases where simulation time is very high. The results from both algorithms lead to net present values higher than at least 95% of the values from random schedules. For both cases, economic results were significantly better than those found for selecting strategy using wells ranking based in economic indicators, which is a common procedure. Both algorithms are also easy to implement and they can be inserted in a cycle of automated or assisted optimization process.
在油田开发阶段,一个重要的决策是确定钻井计划。列出了一些关于轻油和重油的一般规则。然而,这些规则并不总是适用的,使用模拟模型来测试和选择时间表可能很重要。本文包括两种不同的优化钻井进度算法的开发、实现和应用。第一种算法在每个周期内寻求最优经济产出。一旦选择了这口井,将考虑剩余的井进行第二段时间的测试,并重复该过程,直到最后一口井。第二个步骤是基于搜索空间的缩减,其中生成随机调度,并为后续场景保留最佳结果,仅允许在前一步中产生最佳目标函数值的时间段内钻井。这一过程反复进行,直到每口井收敛到产生最佳经济回报的时期。根据海上稠油和高平均渗透率油藏的特点,在两个合成油田对两种算法进行了测试。为了生成解决方案的基准,对大量随机时间表进行了测试,并生成了净现值的正态分布。这两种算法都可以应用于任何类型的油藏,但在模拟时间非常长的情况下,这一过程非常耗时。两种算法的结果导致净现值至少高于随机调度值的95%。在这两种情况下,经济效果都明显好于基于经济指标的井排名选择策略,后者是一种常用的方法。这两种算法也很容易实现,它们可以插入到自动或辅助优化过程的循环中。
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引用次数: 4
期刊
Brazilian Journal of Petroleum and Gas
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