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DESIGN AND EVALUATION OF A SYSTEM TO OBTAIN POLYMER GRADE PROPYLENE BY MEANS OF VAPOR RECOMPRESSION DISTILLATION 蒸汽再压缩蒸馏法制备聚合物级丙烯系统的设计与评价
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0027
M. Fontana, L. Fernandes, T. A. Souza
Propylene in a purity degree above 99.5% (polymer purity grade- PPG) is a first-generation basic petrochemical that represents a vital link in refining-petrochemical integration. The strict specification of the product and the need to maximize the energy efficiency of the propylene/propane distillation process poses several challenges to the optimization of both the design and operation of the plant. Using a Petro-SIM (KBC) technology, a polymer grade general model from a propylene distillation unit was developed by means of vapor recompression. The sensitivity for feeding with different propylene fractions was analyzed, reaching a value of 0.94, which is considered the minimum propylene fraction in the feed required to the tower to generate a product with polymer purity grade. Based on the data obtained in the simulation, the tower was designed and evaluated by means of vapor recompression, showing a potential alternative way to obtain propylene at polymer grade which could be cost saving in industrial processes.
纯度在99.5%以上(聚合物纯度等级- PPG)的丙烯是第一代基础石化产品,是炼油石化一体化的重要环节。产品的严格规格和丙烯/丙烷蒸馏过程的能源效率最大化的需要对装置的设计和操作的优化提出了几个挑战。采用Petro-SIM (KBC)技术,通过蒸汽再压缩的方法,开发了丙烯蒸馏装置的聚合物级通用模型。对不同丙烯馏分进料的灵敏度进行了分析,其值为0.94,该值被认为是塔所需进料中丙烯馏分的最小值,以产生具有聚合物纯度等级的产品。根据模拟得到的数据,采用蒸汽再压缩的方法对塔进行了设计和评价,为工业生产中节省成本的聚合物级丙烯提供了一种潜在的替代方法。
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引用次数: 0
ORGANIC DEPOSITION IN PETROLEUM STORAGE TANKS AT REFINERIES DUE TO BLENDING OPERATIONS 由于混合作业,炼油厂储油罐中的有机物沉积
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0022
R. A. Camargo, A. Ramos, D. Gatto, R. Beltrame, J. Monks
Petroleum blending is viewed as a critical optimization strategy adopted by several operations of petroleum production in the refineries around the world. A persistent problem called crude oil incompatibility occurs when the mixture of different oils lead to the formation of solid phases due to the precipitation of asphaltenes. The present work investigates the relationship between the occurrence of sludge in petroleum storage tanks and petroleum blending operations. Hildebrand solubility parameters of the oils were determined, revealing that one of the samples of petroleum analyzed is at the threshold of the asphaltene flocculation parameter, with an average of 16.1 Mpa1/2. Thus, it implies that blending operations with dissimilar petroleum feedstocks must be well planned, since they can initiate the precipitation of the asphaltenes and, consequently, the formation of sludge that accumulate and deposit as sediments inside petroleum storage tanks.
石油调合被认为是世界各地炼油厂几种石油生产操作所采用的关键优化策略。当不同油的混合物由于沥青质的沉淀而导致固相的形成时,就会出现原油不相容性的持久问题。本文研究了石油储罐中油泥的产生与石油混合作业之间的关系。测定了油品的Hildebrand溶解度参数,结果表明,其中1个样品处于沥青质絮凝参数的阈值,平均为16.1 mpa /2。因此,这意味着与不同石油原料的混合操作必须精心规划,因为它们可以引发沥青质的沉淀,从而形成污泥,这些污泥积聚并沉积在石油储罐内。
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引用次数: 1
NUMERICAL SIMULATION OF DRILLING FLUID BEHAVIOR IN DIFFERENT DEPTHS OF AN OIL WELL 油井不同深度下钻井液特性的数值模拟
Pub Date : 2019-12-20 DOI: 10.5419/bjpg2019-0026
A. F. C. Gomes, J. G. O. Marinho, J. L. L. Santos
When drilling an oil well, a viscous fluid is injected to aid drilling. This fluid is also responsible for removing the cuttings and maintaining structural stability of well. The rheology of this drilling fluid has a direct influence on the cleaning of the well, on the dynamics of the fluid in pipe and annular areas. Linear mathematical extrapolations for high pressure and high temperature environments can lead to rheology errors up to 75%. In this study, a finite volume model was developed to simulate the flow of a water-based mud in annular and jetting environments in the drilling environment. Annulars were made by steel pipes and permeable formations. The fluids evaluated were developed empirically with xanthan gum and bentonite clay. The numerical results are consistent with literature and represent characteristics of a Yield Power Law fluid and a Bingham plastic. A comparison was made with water, allowing a correlation between rheological effects and fluid dynamics in annular and high vorticity regions.
钻井时,注入一种粘性流体以帮助钻井。该流体还具有清除岩屑和保持井结构稳定性的作用。这种钻井液的流变性直接影响到井的清洁,以及管道和环空区域流体的动力学。高压和高温环境的线性数学外推可能导致流变误差高达75%。在这项研究中,建立了一个有限体积模型来模拟水基泥浆在环空和喷射环境中的流动。环管是由钢管和渗透性地层制成的。以黄原胶和膨润土为原料,进行了试验研究。数值结果与文献一致,反映了屈服幂律流体和宾汉姆塑性的特性。与水进行了比较,允许在环形和高涡度区域的流变效应和流体动力学之间存在相关性。
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引用次数: 2
MICROEMULSION-BASED FLUSHING FLUID FOR EFFECTIVE REMOVAL OF FILTER CAKE IN WELLS CEMENTATION 有效去除固井滤饼的微乳化冲洗液
Pub Date : 2019-10-08 DOI: 10.5419/bjpg2019-0012
F. Curbelo, T. T. Caminha, A. Garnica, G. Melo, E. A. Araújo, J. Freitas
The objective of this work is to evaluate the effective removal of mud cake formed by drilling fluid for microemulsion-based flushing fluid. The microemulsions were prepared with vegetable castor oil, 2%wt KCl as aqueous phase, and nonionic surfactant (Ultranex NP40). Thermal stability, rheological, removal, and wettability inversion were performed to evaluate the performance of the microemulsion-based flushing fluid. Rheological tests showed that microemulsions behaved like Newtonian fluids. The best formulation of flushing fluid was 70% surfactant/25% oil phase/5% aqueous phase, with cloudy temperature at 365.25 K, removal efficiency of mud cake of 84.85 %, and high capability of wettability inversion.
研究了微乳化冲洗液对钻井液泥饼的去除效果。以植物蓖麻油、2%wt氯化钾为水相,以非离子表面活性剂Ultranex NP40制备微乳。通过热稳定性、流变性、去除性和润湿性反演来评价微乳基冲洗液的性能。流变学试验表明,微乳具有牛顿流体的特性。最佳冲洗液配方为表面活性剂70% /油相25% /水相5%,混浊温度365.25 K,泥饼去除率84.85%,润湿性反演能力强。
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引用次数: 7
EFFECTS OF THE ADDITION OF [2HEA][HX] ON BIODIESEL SYNTHESIS USING METHANOL AND METHANOL/ETHANOL MIXTURE [2hea][hx]对甲醇及甲醇/乙醇混合物合成生物柴油的影响
Pub Date : 2019-10-08 DOI: 10.5419/bjpg2019-0015
I. ‐. Gomez, K. B. Gomes, V. M. D. Oliveira, S. Mattedi, G. Simonelli, L. C. Santos, A. Lobato
Currently, the use of ionic liquids (ILs), such as catalysts and co-solvents, in the production of biodiesel commonly demands extreme operating conditions (especially temperature and / or time). Besides the environmental benefits, these compounds have versatile physical and chemical properties. Some of these compounds also possess amphiphilic features that allow them to act as surfactants and, in this case, when employed as additives in transesterification reactions, they can overcome mass transfer limitations and, consequently, the reaction rate. This work aims at studying the effects of protic ionic liquid (PIL) 2-hydroxyethylammonium hexanoate [2HEA][Hx] in the alkaline transesterification of soybean oil using methanol and a methanol/ethanol mixture. The reaction conditions were alcohol/oil molar ratio of 6:1, 1.5% (%wt/wt) KOH as the catalyst, 2% (%wt/wt) PIL as the additive, 60 °C, and 30 min reaction time. The highest mass yield was 92.72% for both pure methanol and methanol/ethanol mixture (molar ratios 5:1), since the mean was not statistically different for those two ratios.
目前,在生物柴油生产中使用离子液体(ILs),如催化剂和助溶剂,通常需要极端的操作条件(特别是温度和/或时间)。除了环境效益外,这些化合物还具有多种物理和化学性质。这些化合物中的一些还具有两亲性特征,使它们能够充当表面活性剂,在这种情况下,当用作酯交换反应中的添加剂时,它们可以克服传质限制,从而提高反应速率。研究了质子离子液体(PIL) 2-羟乙基己酸铵[2HEA][Hx]在甲醇和甲醇/乙醇混合物中对大豆油碱性酯交换反应的影响。反应条件为醇油摩尔比为6:1,KOH为催化剂1.5% (%wt/wt), PIL为添加剂2% (%wt/wt),反应温度60℃,反应时间30 min。纯甲醇和甲醇/乙醇混合物(摩尔比为5:1)的质量收率最高,为92.72%,因为这两种比例的平均值没有统计学差异。
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引用次数: 3
EVALUATION OF THE LUBRICATION OF ETHYL OLEATE AND ETHYL OCTANOATE AS GASOLINE ADDITIVE 油酸乙酯和辛酸乙酯作为汽油添加剂的润滑性能评价
Pub Date : 2019-10-08 DOI: 10.5419/bjpg2019-0011
Suzara R.C. Sena, E. Neto, C. G. Pereira
The present study assesses the effects of ethyl octanoate and ethyl oleate on the gasoline lubricity. Samples of gasoline fuel were prepared with different amounts of esters (0%, 2.5%, 5%, 10%, and 15%) and then evaluated. The lubricity tests were carried out using a High Frequency Reciprocating Test Rig (HFRR) equipment. The Wear Scar Diameter (WSD) values decreased as ester proportions increased in the samples. The percentage of lubricant film presented values above 85% for formulations with 10% and 15% ester concentration. Coefficient of friction values showed a similar behavior, they decreased as the esters fractions have increased. Results demonstrate that the esters when added to gasoline can improve the fuel lubricity.
研究了辛酸乙酯和油酸乙酯对汽油润滑性的影响。以0%、2.5%、5%、10%和15%的酯含量制备汽油燃料样品,并进行评价。在高频往复试验台(HFRR)上进行了润滑试验。磨损疤痕直径(WSD)值随着酯比例的增加而降低。在酯浓度为10%和15%的配方中,润滑油膜的百分比在85%以上。摩擦系数随酯类分数的增加而减小。结果表明,在汽油中加入酯类化合物可以改善燃油的润滑性。
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引用次数: 2
EFFECTS OF HIGH FLUID VISCOSITY ON PRESSURE LOSSES OF THE SINGLE-PHASE FLOW INSIDE AN ESP STAGE 高流体粘度对esp级内单相流压力损失的影响
Pub Date : 2019-10-08 DOI: 10.5419/bjpg2019-0018
J. Siqueira, P. Steiner, A. Bueno
The Electrical Submersible Pump (ESP) system is among the most widely used artificial lift methods in the world. This work studies the effects of high fluid viscosity on pressure losses of the flow in an ESP stage. A theoretical model was applied to four different flow cases. First, curves for head and pressure losses at the pump stage were generated and, based on literature formulations available in the model, as well as on adjusted empirical coefficients (for highly viscous fluids), implemented in the model. Subsequently, the heads were estimated and evaluated using experimental data and statistical analyses based on mean square error. The results showed that high fluid viscosity impacted considerably pressure losses and pump performance. In 50% of the cases studied, statistical analyses alone could estimate the head in the pump stage with good accuracy. However, in the remaining cases, it was also necessary to consider the physical behavior of the highly viscous fluids studied. The variability of the selected formulations from the literature (for pump head and pressure losses) with pump rotation, and especially with high fluid viscosity, was considerably larger than the ones found in previous studies for less viscous fluids.
电潜泵(ESP)系统是世界上应用最广泛的人工举升方法之一。本文研究了高粘度流体对ESP级流动压力损失的影响。理论模型应用于四种不同的流动情况。首先,根据模型中可用的文献公式以及调整后的经验系数(针对高粘性流体),生成泵阶段的扬程和压力损失曲线,并在模型中实现。随后,利用实验数据和基于均方误差的统计分析对头部进行估计和评价。结果表明,高流体粘度对压力损失和泵性能有较大影响。在50%的研究案例中,仅靠统计分析就能很准确地估计出泵段的扬程。然而,在其他情况下,还需要考虑所研究的高粘性流体的物理行为。从文献中选择的配方(针对泵扬程和压力损失)随泵旋转的变异性,特别是在高流体粘度的情况下,比之前在低粘度流体的研究中发现的变异性要大得多。
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引用次数: 0
REMOVAL OF ORGANIC CONTAMINANTS FROM A SYNTHETIC OILFIELD PRODUCED WATER BY ADSORPTION PROCESS USING VEGETABLE AND BONE BOVINE ACTIVATED CARBONS 植物和骨牛活性炭吸附法去除合成油田采出水中的有机污染物
Pub Date : 2019-10-08 DOI: 10.5419/bjpg2019-0017
P. D. C. Carvalho, E. Foletto, G. Dotto, C. K. O. S. Rackov, E. Neto, O. Chiavone-Filho
The production of oil and gas is usually accompanied by the production of waste water, which contains several organic pollutants. The objective of this work is to investigate the removal of organic load from synthetic oilfield produced water by adsorption process, using activated carbons from vegetable and animal origin. The synthetic oilfield produced water was constituted by a mixture of xylene, n–heptane, phenol, and NaCl in aqueous solution. The structural properties of the samples were investigated by X–ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), N2 adsorption–desorption isotherms, and scanning electron microscopy (SEM). Effects of temperature and type of adsorbent on the adsorption process were investigated. According to the results, the temperature of 25 °C was more favorable in adsorption of organic load from synthetic oilfield produced water. Pseudo–first order, pseudo–second order, and Elovich equations were able to represent the adsorption kinetics. The vegetable activated carbon delivered the best results, being the most efficient to remove the organic load due its high surface area. The adsorption capacities were 28 and 15 mgTOC g–1, for vegetable and animal activated carbons, respectively.
石油和天然气的生产通常伴随着废水的产生,废水中含有几种有机污染物。本研究的目的是研究利用植物源活性炭和动物源活性炭吸附法去除油田合成采出水中的有机负荷。合成油田采出水由二甲苯、正庚烷、苯酚和NaCl组成。采用x射线粉末衍射(XRD)、傅里叶变换红外光谱(FTIR)、N2吸附-脱附等温线和扫描电镜(SEM)研究了样品的结构性质。考察了吸附剂种类和温度对吸附过程的影响。结果表明,25℃的温度对合成油田采出水中有机负荷的吸附较为有利。拟一级方程、拟二级方程和Elovich方程均能表示吸附动力学。蔬菜活性炭提供了最好的结果,是最有效的去除有机负荷,由于其高表面积。植物活性炭和动物活性炭的吸附量分别为28 mgTOC g-1和15 mgTOC g-1。
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引用次数: 2
COMPARISON OF PVT CORRELATIONS FOR PREDICTING CRUDE OIL PROPERTIES: THE BRAZILIAN CAMPOS BASIN CASE STUDY PVT相关性预测原油性质的比较:巴西campos盆地案例研究
Pub Date : 2019-10-08 DOI: 10.5419/bjpg2019-0013
P. V. Mangili, V. Ahón
Pressure-Volume-Temperature correlations are essential for estimating the required parameters necessary for the identification of reservoir fluid properties when experimental laboratory data are not readily available. Although several models have been published for different oil fields, there is a lack of studies addressing the Brazilian pre-salt region. Hence, in this paper we compared twenty empirical correlations for the determination of the solution gas-oil ratio, oil formation-volume-factor, and under-saturated oil viscosity for Brazilian pre-salt oil samples collected from the Campos Basin region, originally evaluated by Elias and Trevisan (2016). From our statistical results, some models presented good estimation performances when compared to said reference’s results. In fact, through a statistical analysis, Al-Shammasi (2001)’s correlation proved to be the best estimation method for solution gas-oil ratio, whereas Al-Marhoun (1985) and Beal’s (1946) correlations were deemed the most accurate for the prediction of oil formation-volume-factor and under-saturated oil viscosity, respectively.
压力-体积-温度相关性对于估计识别储层流体性质所需的参数是必不可少的,当实验实验室数据不容易获得时。尽管针对不同油田已经发表了几种模型,但针对巴西盐下区域的研究还很缺乏。因此,在本文中,我们比较了20种经验相关性,以确定从Campos盆地地区收集的巴西盐下油样品的溶液气油比、油层体积因子和欠饱和油粘度,最初由Elias和Trevisan(2016)评估。从我们的统计结果来看,与上述参考文献的结果相比,一些模型表现出良好的估计性能。事实上,通过统计分析,Al-Shammasi(2001)的相关性被证明是溶液气油比的最佳估计方法,而Al-Marhoun(1985)和Beal(1946)的相关性分别被认为是预测油层体积因子和不饱和油粘度的最准确方法。
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引用次数: 1
INTEGRATED EVALUATION OF CEMENT AND KICK SCENARIOS IN OIL WELL DESIGN 油井设计中固井和井涌的综合评价
Pub Date : 2019-10-08 DOI: 10.5419/bjpg2019-0019
J. M. F. Melo, J. Tenorio, A. G. Oliveira, J. P. L. Santos
The present work aims to develop a case study using the casing well interface (CWELL), developed by the Federal University of Alagoas, Brazil. Considering the well critical environment during the gas kick along with wait on cement (WOC) test and cement displacement, we sought to observe the behavior of different casing pipes regarding the stress submitted. The case study analyzes an offshore vertical well, with a water depth of 1574 meters. The well was subjected to a kick of 50 bbl and with an inflow gradient of 2.0 lb/gal. Triaxial loads were obtained through the von-Mises and American Petroleum Institute (API) envelopes, which can be used to analyze the integrity of the tubes. Through the analysis between the resistances returned by Petroleum Engineering Applications System (SAEP), it is possible to verify the possibility of failure of the tubes for each project scenario. This analysis is important for determining the sizing of the columns to obtain the best performance of the structures.
目前的工作旨在利用由巴西Alagoas联邦大学开发的套水井界面(CWELL)进行案例研究。考虑到气涌过程中的井临界环境,以及等待水泥(WOC)测试和水泥置换,我们试图观察不同套管在承受应力时的行为。该案例分析了一口水深1574米的海上直井。该井的井涌为50桶,流入梯度为2.0 lb/gal。通过von-Mises和美国石油协会(API)包络仪获得三轴载荷,可用于分析油管的完整性。通过分析石油工程应用系统(SAEP)返回的阻力之间的关系,可以验证每个项目场景下油管失效的可能性。这种分析对于确定柱的尺寸以获得结构的最佳性能是重要的。
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引用次数: 0
期刊
Brazilian Journal of Petroleum and Gas
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