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Reimagining landfills as energy hubs: A new integrated approach for biomethane and green hydrogen production 重新设想垃圾填埋场作为能源中心:生物甲烷和绿色氢生产的新综合方法
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-10-16 DOI: 10.1016/j.nexus.2025.100561
Silvia De Paola , Giuseppina Oliva , Stefano Cairone , Diego Magrini , Giorgio Cardona , Vincenzo Cimini , Roberto Zocchi , Tiziano Zarra , Vincenzo Belgiorno , Vincenzo Naddeo
Landfills have long been seen as a suboptimal waste management solution, yet innovative strategies can repurpose them as energy hubs. This study investigates an integrated valorization approach combining landfill gas (LFG) upgrading via Vacuum Pressure Swing Adsorption (VPSA), multi-stage reverse osmosis (RO) treatment of landfill leachate (LL), and green hydrogen (H2) production via electrolysis powered by renewable energy. The proposed approach has been partially validated at the Borgo Montello landfill (Latina, Italy) through the implementation of LFG upgrading, LL treatment, and photovoltaic (PV) modules installed along the basin slopes to promote energy self-sufficiency. The strategy was evaluated through site-specific mass and energy balance analyses, comparing four scenarios: A) representing the conventional approach with LFG used in combined heat and power (CHP) units and external LL management; B) featuring LFG upgrading to biomethane (bioCH4) and LL treatment via RO; C) an advanced model integrating H2 production from treated LL using a PV-powered electrolyzer; and D) which builds upon Scenario C but proposes an alternative pathway for bioCH4 valorization that eliminates the need for liquefaction. The mass balances indicated that the upgrading and liquefaction system achieved an 87 % (m/m) yield and 98 % purity in terms of methane, while the RO treatment displaced 68 % of water recovery and 99.9 % of contaminants rejection. Energy balances confirmed the viability of all configurations, with Scenario D delivering the highest energy surplus of +8938 MWh/year, followed by Scenario C (+5729 MWh/year), Scenario A (+5161 MWh/year), and Scenario B (+2418 MWh/year). Although Scenario A yields relatively high energy production, it provides limited resource valorization and circular economy benefits compared to the other scenarios, which integrate bioCH4 and H2 production within a more resource-efficient model. Overall, the results demonstrate that landfills can be repurposed into multi-functional energy hubs, contributing to circular economy goals, decarbonization, and resource recovery.
长期以来,垃圾填埋场一直被视为一种次优的废物管理解决方案,但创新的策略可以将其重新定位为能源中心。本研究研究了一种综合增值方法,结合真空变压吸附(VPSA)、多级反渗透(RO)处理垃圾渗滤液(LL)和可再生能源电解生产绿色氢(H2)的垃圾填埋气(LFG)升级。提议的方法已经在Borgo Montello垃圾填埋场(意大利Latina)通过实施LFG升级、LL处理和沿盆地斜坡安装光伏(PV)模块来促进能源自给自足,部分得到了验证。通过特定地点的质量和能量平衡分析,对该策略进行了评估,比较了四种情况:A)代表传统方法,即在热电联产(CHP)机组和外部LL管理中使用LFG;B) LFG转化为生物甲烷(bioCH4),并通过反渗透处理LL;C)一种先进的模型,利用pv供电的电解槽将处理后的LL集成为H2生产;D)建立在方案C的基础上,但提出了一种替代途径来实现生物甲烷增值,从而消除了液化的需要。质量平衡表明,升级和液化系统的产率达到87% (m/m),甲烷纯度达到98%,而反渗透处理的水回收率为68%,污染物截除率为99.9%。能量平衡证实了所有配置的可行性,其中方案D提供最高的能量盈余+8938 MWh/年,其次是方案C (+5729 MWh/年),方案A (+5161 MWh/年)和方案B (+2418 MWh/年)。尽管情景A产生了相对较高的能源产量,但与其他情景相比,它提供的资源增值和循环经济效益有限,其他情景将生物ch4和H2的生产整合在一个资源效率更高的模型中。总体而言,研究结果表明,垃圾填埋场可以被改造成多功能能源中心,有助于实现循环经济目标、脱碳和资源回收。
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引用次数: 0
Nexus between CO2 emissions, economic growth, and energy consumption with special reference to BRICS: A panel data approach 二氧化碳排放、经济增长和能源消耗之间的关系——以金砖国家为例:面板数据方法
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-10-16 DOI: 10.1016/j.nexus.2025.100556
Ahmad Raza , Majed Alharthi , Moonis Shakeel , Md Imran Khan
The BRICS nations are now undergoing rapid economic growth, which has led to apprehensions over the increase in CO2 emissions and energy consumption. The research tries to identify heterogeneity in carbon dioxide emissions, energy use, and GDP growth paths among BRICS nations and further explores using a technique of cointegration between the long-run relationship of these variables. The study employs secondary data obtained from World Development Indicators and panel data analysis to examine the interplay of the variables over the period 2009–2022. The analysis utilizes some of the following variables, that is, CO2 emissions per capita in metric tons, GDP per capita, and energy consumption per capita in oil equivalent. The techniques that will be utilized include those associated with the literature review (text analytics techniques) and other panel data models used for the data analysis, such as Pooled Ordinary Least Squares (OLS), Breusch-Pagan Lagrange Multiplier (BP) test, Random Effects Model (REM), Fixed Effects Model (FEM), and Hausman test. The study also applies the first-generation and second-generation panel unit root tests to determine data stationarity, cross-sectional dependency, serial correlation, heteroscedasticity, Pedroni cointegration tests, and the Dumitrescu-Hurlin Granger causality test to check causality. The findings are that there is no heterogeneity in the dispersion of CO2 emissions, energy consumption, and GDP growth across the BRICS countries. The cointegration tests further reveal the long-run relationship between these variables. This study finally looks for interlinkages between CO2 emissions, economic growth, and energy consumption for BRICS countries. Using an approach with panel data analysis, it contributes to ongoing policy debates on sustainable development and offers guidelines to policymakers in terms of reaching an expedient balance between economic growth and the preservation of the environment.
金砖国家目前正处于经济快速增长时期,这引发了人们对二氧化碳排放和能源消耗增加的担忧。本研究试图确定金砖国家之间二氧化碳排放、能源使用和GDP增长路径的异质性,并进一步探索使用这些变量的长期关系之间的协整技术。该研究采用从《世界发展指标》获得的二手数据和面板数据分析来检验2009-2022年期间各变量的相互作用。该分析利用了以下一些变量,即以公吨为单位的人均二氧化碳排放量、人均国内生产总值和以石油当量为单位的人均能源消耗。将使用的技术包括与文献综述(文本分析技术)相关的技术和用于数据分析的其他面板数据模型,如汇集普通最小二乘法(OLS), Breusch-Pagan拉格朗日乘数(BP)检验,随机效应模型(REM),固定效应模型(FEM)和Hausman检验。本研究还采用第一代和第二代面板单位根检验确定数据平稳性、横截面依赖性、序列相关性、异方差、Pedroni协整检验和dumitrescue - hurlin Granger因果检验检验因果关系。研究结果表明,金砖国家的二氧化碳排放、能源消耗和GDP增长的分散性不存在异质性。协整检验进一步揭示了这些变量之间的长期关系。本研究最后寻找金砖国家二氧化碳排放、经济增长和能源消耗之间的相互联系。该报告采用小组数据分析的方法,促进了正在进行的关于可持续发展的政策辩论,并为决策者提供了在经济增长和保护环境之间达到适当平衡的指导方针。
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引用次数: 0
Evaluating the multifaceted separative role of cellulose acetate supported zinc oxide nanocomposite reverse osmosis membrane towards water decontamination and desalination 评价醋酸纤维素负载氧化锌纳米复合反渗透膜在水净化和脱盐中的多方面分离作用
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-10-16 DOI: 10.1016/j.nexus.2025.100555
Mohd Arsalan , Rhithuparna D․ , Suzain Akhtar , Javeria Shoeb Alam , Wasi Ur Rahman , Mohamed Fahad Alajmi , Afzal Hussain , Bon-Heun Koo , Dibyajyoti Haldar , Gopinath Halder
This study explores the development of a novel reverse osmosis (RO) membrane composed of cellulose acetate (CA) and zinc oxide nanoparticles (ZnO). The main objective was to fabricate a multifunctional membrane, synthesized through the phase inversion method, capable of low-cost simultaneous desalination with high ion selectivity, efficient dye removal under optimized conditions, and significant elimination of heavy metal ions and organic contaminants for enhanced water purification. Density functional theory (DFT) analysis was further employed to examine the electronic properties, including band structure, density of states, and charge distribution, thereby linking nanoscale behavior to observed performance. The CA@ZnO membrane exhibited excellent efficiency in removing dissolved salts (Na+, Ca2+, Mg2+), achieving 60 % rejection for NaCl, 44.03 % for CaCl2, and 43.34 % for MgCl2. It further enabled the removal of 70–80 % oil from oily wastewater and showed high adsorption efficiency for methylene blue dye in the visible spectrum range. In addition, the membrane exhibited substantial removal of toxic heavy metals (Ni2+, Zn2+, Cd2+, Cr3+, Fe3+) under optimized conditions. Compared to conventional polymeric RO membranes, the CA@ZnO composite showed enhanced stability, antimicrobial activity, and cost-effectiveness, addressing the challenges of fouling and limited selectivity. The novelty of this study lies in the dual role of ZnO nanoparticles, which not only improve ion rejection but also introduce photocatalytic activity for dye degradation, enabling multifunctional water purification in a single platform. These findings underscore the potential of the CA@ZnO membrane for advanced desalination, pollutant removal, and water purification applications.
本研究探讨了一种由醋酸纤维素(CA)和氧化锌纳米颗粒(ZnO)组成的新型反渗透(RO)膜的开发。主要目的是制备一种多功能膜,通过相转化法合成,能够低成本同时脱盐,具有高离子选择性,在优化条件下有效去除染料,并显著消除重金属离子和有机污染物,以增强水净化。密度泛函理论(DFT)分析进一步研究了电子特性,包括能带结构、态密度和电荷分布,从而将纳米尺度的行为与观察到的性能联系起来。CA@ZnO膜对溶解盐(Na+, Ca2+, Mg2+)的去除率很高,对NaCl的去除率为60%,对CaCl2的去除率为44.03%,对MgCl2的去除率为43.34%。对含油废水的去除率达到70 - 80%,在可见光谱范围内对亚甲基蓝染料有较高的吸附效率。此外,在优化的条件下,该膜对有毒重金属(Ni2+, Zn2+, Cd2+, Cr3+, Fe3+)有较好的去除效果。与传统的聚合物反渗透膜相比,CA@ZnO复合膜具有更高的稳定性、抗菌活性和成本效益,解决了污染和有限选择性的挑战。本研究的新颖之处在于氧化锌纳米颗粒的双重作用,它不仅提高了离子的吸附性,而且还引入了染料降解的光催化活性,从而在单一平台上实现了多功能的水净化。这些发现强调了CA@ZnO膜在高级海水淡化、污染物去除和水净化应用方面的潜力。
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引用次数: 0
Optimized solar conversion achieved with double halide X2NaIrCl6 (X = Rb, Cs) perovskites for optoelectronic and photovoltaic applications 光电和光伏应用的双卤化物X2NaIrCl6 (X = Rb, Cs)钙钛矿实现了优化的太阳能转换
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-09-25 DOI: 10.1016/j.nexus.2025.100549
Md. Shahazan Parves , Md. Abu Bakkar Siddique , Md. Tarekuzzaman , Nazmul Shahadath , Sohail Ahmad , Md. Rasheduzzaman , M. Moazzam Hossen , Yasir Arafat , Md. Zahid Hasan
Considering the environmental concerns of lead Hazardousness and durability concerns in lead-based perovskite solar cells (PSCs), lead-free alternatives like X2NaIrCl6 (X = Rb, Cs) have gained significant attention. This investigation carries out an analysis of the structural and optoelectronic behaviour of X2NaIrCl6 (X = Rb, Cs) using DFT to assess its potential for absorber material for solar cells (SCs). Structural stability of X2NaIrCl6 (X = Rb, Cs) double perovskites was analysed using tolerance factors (τ1, μ, τ2), with dynamical stability ensured through phonon dispersion. Negative and binding energy (Eb) and formation energy (Ef) further validated their stability. Direct band gaps, determined utilizing the TB-mBJ (GGA-PBE) approach, the values were determined to be 2.02 eV (0.97 eV) for Rb2NaIrCl6 and 1.93 eV (0.92 eV) for Cs2NaIrCl6, placing them in the recommended range (0.8- 2.2 eV) for photoelectric conversion. X2NaIrCl6 (X = Rb, Cs) double perovskites exhibit remarkable potential for photovoltaic applications, driven by their high absorption coefficients (∼104) and favourable optical properties, including low energy loss and minimal reflectivity (<15 %). These attributes highlight their promise for high efficiency and low-cost materials for advanced optoelectronic and solar energy devices. SCAPS-1D software employed to identify the most efficient solar cell designs by incorporating various HTLs and ETLs. Among 40 tested configurations, the ITO/ZnO/Cs2NaIrCl6/Cu2O structure attains the maximum PCE of ∼20.39 %, while ITO/ZnO/Rb2NaIrCl6/Cu2O achieves ∼19.16 %. Additionally, the study examines the effects of varying ETL/absorber thicknesses and series and shunt resistances, and temperature on photovoltaic performance. A detailed investigation was conducted on the principal photovoltaic indicators, such as current-voltage characteristics, capacitance, quantum efficiency, Mott Schottky parameters, and the processes governing photocarrier generation and recombination. These findings highlight X2NaIrCl6 (X = Rb, Cs) as a suitable material for high-performance optoelectronic and photovoltaic real-world applications.
考虑到铅基钙钛矿太阳能电池(PSCs)中铅的环境危害和耐久性问题,X2NaIrCl6 (X = Rb, Cs)等无铅替代品受到了广泛关注。本研究利用DFT分析了X2NaIrCl6 (X = Rb, Cs)的结构和光电子行为,以评估其作为太阳能电池(SCs)吸收材料的潜力。利用容差因子τ1, μ, τ2分析了X2NaIrCl6 (X = Rb, Cs)双钙钛矿的结构稳定性,并通过声子色散保证了结构的动态稳定性。负结合能(Eb)和地层能(Ef)进一步验证了它们的稳定性。利用TB-mBJ (GGA-PBE)方法确定的直接带隙,Rb2NaIrCl6的值为2.02 eV (0.97 eV), Cs2NaIrCl6的值为1.93 eV (0.92 eV),使其处于光电转换的推荐范围(0.8- 2.2 eV)。X2NaIrCl6 (X = Rb, Cs)双钙钛矿由于其高吸收系数(~ 104)和良好的光学性质,包括低能量损失和最小反射率(< 15%),在光伏应用中表现出显着的潜力。这些特性凸显了它们为先进光电和太阳能器件提供高效率和低成本材料的前景。SCAPS-1D软件用于通过结合各种HTLs和ETLs来识别最有效的太阳能电池设计。在所测试的40种结构中,ITO/ZnO/Cs2NaIrCl6/Cu2O结构的PCE最大值为~ 20.39%,而ITO/ZnO/Rb2NaIrCl6/Cu2O结构的PCE最大值为~ 19.16%。此外,该研究还考察了不同的ETL/吸收器厚度、串联和分流电阻以及温度对光伏性能的影响。详细研究了主要的光伏指标,如电流电压特性、电容、量子效率、莫特肖特基参数以及控制光载流子产生和重组的过程。这些发现突出了X2NaIrCl6 (X = Rb, Cs)作为高性能光电和光伏实际应用的合适材料。
{"title":"Optimized solar conversion achieved with double halide X2NaIrCl6 (X = Rb, Cs) perovskites for optoelectronic and photovoltaic applications","authors":"Md. Shahazan Parves ,&nbsp;Md. Abu Bakkar Siddique ,&nbsp;Md. Tarekuzzaman ,&nbsp;Nazmul Shahadath ,&nbsp;Sohail Ahmad ,&nbsp;Md. Rasheduzzaman ,&nbsp;M. Moazzam Hossen ,&nbsp;Yasir Arafat ,&nbsp;Md. Zahid Hasan","doi":"10.1016/j.nexus.2025.100549","DOIUrl":"10.1016/j.nexus.2025.100549","url":null,"abstract":"<div><div>Considering the environmental concerns of lead Hazardousness and durability concerns in lead-based perovskite solar cells (PSCs), lead-free alternatives like X<sub>2</sub>NaIrCl<sub>6</sub> (X = Rb, Cs) have gained significant attention. This investigation carries out an analysis of the structural and optoelectronic behaviour of X<sub>2</sub>NaIrCl<sub>6</sub> (X = Rb, Cs) using DFT to assess its potential for absorber material for solar cells (SCs). Structural stability of X<sub>2</sub>NaIrCl<sub>6</sub> (<em>X</em> = Rb, Cs) double perovskites was analysed using tolerance factors (<span><math><msub><mi>τ</mi><mn>1</mn></msub></math></span>, <em>μ</em>, <span><math><msub><mi>τ</mi><mn>2</mn></msub></math></span>), with dynamical stability ensured through phonon dispersion. Negative and binding energy (<span><math><msub><mi>E</mi><mi>b</mi></msub></math></span>) and formation energy (<span><math><msub><mi>E</mi><mi>f</mi></msub></math></span>) further validated their stability. Direct band gaps, determined utilizing the TB-mBJ (GGA-PBE) approach, the values were determined to be 2.02 eV (0.97 eV) for Rb<sub>2</sub>NaIrCl<sub>6</sub> and 1.93 eV (0.92 eV) for Cs<sub>2</sub>NaIrCl<sub>6</sub>, placing them in the recommended range (0.8- 2.2 eV) for photoelectric conversion. X<sub>2</sub>NaIrCl<sub>6</sub> (X = Rb, Cs) double perovskites exhibit remarkable potential for photovoltaic applications, driven by their high absorption coefficients (∼10<sup>4</sup>) and favourable optical properties, including low energy loss and minimal reflectivity (&lt;15 %). These attributes highlight their promise for high efficiency and low-cost materials for advanced optoelectronic and solar energy devices. SCAPS-1D software employed to identify the most efficient solar cell designs by incorporating various HTLs and ETLs. Among 40 tested configurations, the ITO/ZnO/Cs<sub>2</sub>NaIrCl<sub>6</sub>/Cu<sub>2</sub>O structure attains the maximum PCE of ∼20.39 %, while ITO/ZnO/Rb<sub>2</sub>NaIrCl<sub>6</sub>/Cu<sub>2</sub>O achieves ∼19.16 %. Additionally, the study examines the effects of varying ETL/absorber thicknesses and series and shunt resistances, and temperature on photovoltaic performance. A detailed investigation was conducted on the principal photovoltaic indicators, such as current-voltage characteristics, capacitance, quantum efficiency, Mott Schottky parameters, and the processes governing photocarrier generation and recombination. These findings highlight X<sub>2</sub>NaIrCl<sub>6</sub> (X = Rb, Cs) as a suitable material for high-performance optoelectronic and photovoltaic real-world applications.</div></div>","PeriodicalId":93548,"journal":{"name":"Energy nexus","volume":"20 ","pages":"Article 100549"},"PeriodicalIF":9.5,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145222641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Economic viability of crop-specific solar irrigation designs under diverse agricultural management and grid-connected conditions: Insights from Qazvin Plain, Iran 在不同农业管理和并网条件下,特定作物太阳能灌溉设计的经济可行性:来自伊朗Qazvin平原的见解
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-09-24 DOI: 10.1016/j.nexus.2025.100550
Mohammad Reza Mirahmad, Atefeh Parvaresh Rizi
The depletion of fossil fuels as the primary energy source and the associated environmental impacts contradicts sustainable development goals. A viable global solution involves harnessing renewable solar energy. With growing emphasis on pressurized irrigation systems in water-intensive agriculture and their significant energy demands, solar-powered irrigation has emerged as a promising alternative. However, financial viability remains a key challenge. This study examines solar irrigation systems tailored to the Qazvin Plain, Iran, focusing on fixed rain and strip sprinklers across three cultivated area scales for two crops—fodder corn and wheat—under single-season and double-season scenarios. Results highlight the critical role of crop type, cultivation scale, and irrigation methods in economic feasibility. Optimal system design prioritizing minimal energy use is essential, considering each agricultural plot's specific attributes. Notably, surplus electricity sales to the national grid could generate income 35–45 times the initial cost over 20 years for single-season plans and 31–38 times for double-season plans, with the initial investment recouped within six years. The net present value in all scenarios confirms the financial rationale for adopting solar irrigation systems, underscoring their potential to align agricultural practices with sustainability and economic efficiency.
化石燃料作为主要能源的枯竭及其相关的环境影响与可持续发展目标相矛盾。一个可行的全球解决方案是利用可再生太阳能。随着用水密集型农业越来越重视加压灌溉系统及其巨大的能源需求,太阳能灌溉已成为一种有希望的替代方案。然而,财务可行性仍然是一个关键挑战。本研究考察了为伊朗Qazvin平原量身定制的太阳能灌溉系统,重点研究了在单季和双季情况下,针对两种作物(饲料玉米和小麦)的三种种植面积规模的固定降雨和条形洒水装置。结果强调了作物类型、种植规模和灌溉方式对经济可行性的关键作用。考虑到每个农地的具体属性,优先考虑最小能源使用的优化系统设计是必不可少的。值得注意的是,出售给国家电网的剩余电力,单季计划可在20年内产生35-45倍于初始成本的收入,双季计划可产生31-38倍的收入,初始投资可在6年内收回。所有情况下的净现值都证实了采用太阳能灌溉系统的财政理由,强调了它们使农业实践与可持续性和经济效率相一致的潜力。
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引用次数: 0
Geopolitical shocks and carbon pricing: Do clean energy assets act as a hedge? 地缘政治冲击与碳定价:清洁能源资产能起到对冲作用吗?
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-09-24 DOI: 10.1016/j.nexus.2025.100538
Anupam Dutta , Sourav Mukharjee , Gazi Salah Uddin
While the interaction between geopolitical events and emission trading system (ETS) is somewhat complex, very little is known about how geopolitical shocks impact global carbon prices. In this study, we extend this scant literature by exploring the linkage between geopolitical risk (GPR) and the Chinese carbon markets. Given that geopolitical shocks may influence the Chinese ETS in several ways, such linkage merits an empirical investigation. Methodologically, we combine the Markov regime switching (MRS) model with the vector autoregressive (VAR) process and apply it to the Shenzhen and Hubei carbon markets. The results suggest that while the standard VAR model fails to capture any connection between geopolitical shocks and carbon returns, employing the MRS-VAR process reveals that GPR in fact exerts significant effects on the Chinese carbon markets implying that such effects appear to be regime-dependent. More specifically, the impact of geopolitical shocks is negative in the high volatility regime, but statistically insignificant in the low volatility regime. Further investigations show that higher geopolitical risk leads to higher hedging costs and that clean energy equities could be a suitable hedge for the Chinese carbon markets amid the periods of high geopolitical uncertainties. These outcomes have key implications which would be crucial for reaching the net-zero goals.
虽然地缘政治事件与排放交易体系之间的相互作用有些复杂,但人们对地缘政治冲击如何影响全球碳价格知之甚少。在本研究中,我们通过探索地缘政治风险(GPR)与中国碳市场之间的联系来扩展这一文献。鉴于地缘政治冲击可能以多种方式影响中国的ETS,这种联系值得实证研究。在方法上,我们将马尔可夫状态切换(MRS)模型与向量自回归(VAR)过程相结合,并将其应用于深圳和湖北的碳市场。结果表明,尽管标准VAR模型未能捕捉地缘政治冲击与碳回报之间的任何联系,但采用MRS-VAR过程显示,GPR实际上对中国碳市场产生了显著影响,这意味着这种影响似乎与政权有关。更具体地说,地缘政治冲击的影响在高波动机制中是负面的,但在低波动机制中统计上不显著。进一步的调查表明,较高的地缘政治风险导致较高的对冲成本,在地缘政治高度不确定的时期,清洁能源股票可能是中国碳市场的合适对冲工具。这些结果对实现净零排放目标至关重要。
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引用次数: 0
Biomass-derived porous carbon-supported MnWO4/CeVO4 nanocomposites: Influence of solvent and natural surfactant on morphology and electrochemical hydrogen storage performance 生物质衍生多孔碳负载MnWO4/CeVO4纳米复合材料:溶剂和天然表面活性剂对形貌和电化学储氢性能的影响
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-09-24 DOI: 10.1016/j.nexus.2025.100548
Farideh Sedighi, Maryam Ghiyasiyan-Arani, Mohsen Behpour
This work introduces a new and green way to the hydrothermal synthesis of MnWO4/CeVO4 nanocomposites (NCs) in the presence of Ginseng extract as a natural surfactant. The nanocomposites were evaluated as novel candidates for electrochemical hydrogen storage using charge-discharge chronopotentiometry technique. Three different molar ratios of monoclinic MnWO4 phase to tetragonal CeVO4 phase (1:1, 2:1, and 4:1) were studied, among which the 4:1 composition showed superior storage capacity (672 mAhg⁻¹ at current of 1 mA after 15 cycles). The influence of different solvents such as ethanol and ethylene glycol on the morphology and performance was also examined. The sample synthesized in ethanol medium displayed a porous morphology and delivered a higher hydrogen storage capacity (845 mAhg⁻¹ at current of 1 mA after 15 cycles) compared to those prepared in other solvents. To enhance performance, the optimized MnWO4/CeVO4 nanostructures were further composited with biomass-derived porous carbon (PC) synthesized using green source of jujuba powder. The ternary composite containing 70 wt% porous carbon with BET surface area of 15.89 m2g−1 exhibited the highest capacity, reaching up to 1100 mAhg⁻¹ at current of 1 mA after 15 cycles. All samples characterized in terms of phase purity, crystallite structure, chemical bonding, morphology, and surface area using XRD, FT-IR, EDS, SEM, TEM and BET-BJH analyses. These findings suggest that structure control through natural surfactants and solvent selection, coupled with carbon incorporation, can significantly boost hydrogen storage efficiency in transition metal-based nanocomposites.
本文介绍了以人参提取物为天然表面活性剂,水热合成MnWO4/CeVO4纳米复合材料的绿色新方法。利用充放电计时电位技术评价了纳米复合材料作为电化学储氢的新候选材料。研究了三种不同的单斜MnWO4相与四方CeVO4相的摩尔比(1:1,2:1和4:1),其中4:1的组成显示出更好的存储容量(15次循环后电流为1ma时为672 mAhg⁻¹)。考察了乙醇、乙二醇等不同溶剂对其形貌和性能的影响。与在其他溶剂中制备的样品相比,在乙醇介质中合成的样品显示出多孔的形态,并提供了更高的储氢容量(15次循环后电流为1ma时的845马赫⁻¹)。为了提高性能,进一步将优化后的MnWO4/CeVO4纳米结构与以枣粉为绿色原料合成的生物质衍生多孔碳(PC)进行复合。含有70 wt%多孔碳的三元复合材料,其BET表面积为15.89 m2 - 1,表现出最高的容量,在1 mA电流下15次循环后达到1100 mAhg - 1。通过XRD, FT-IR, EDS, SEM, TEM和BET-BJH分析,对所有样品的相纯度,晶体结构,化学键,形貌和表面积进行了表征。这些发现表明,通过天然表面活性剂和溶剂选择来控制结构,再加上碳的掺入,可以显著提高过渡金属基纳米复合材料的储氢效率。
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引用次数: 0
Harnessing agricultural waste and microbial synergy to improve soil function and fruit quality in ‘Amrapali’ mango 利用农业废弃物和微生物协同作用改善“Amrapali”芒果的土壤功能和果实品质
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-09-24 DOI: 10.1016/j.nexus.2025.100547
O P Meena , V B Patel , S K Singh , Kanhaiya Singh , Vishal B Mhetre , Shiva Dhar , M C Meena , Seema Sanghwan , Shalini Gaur Rudra , Ram Asrey , B R Vinod , Swati Saha
This study assessed the impact of various organic manures, alone and combined with microbial consortia, on soil health, tree growth, yield, and fruit quality in ‘Amrapali’ mango orchards. Among 12 treatments, vermicompost with microbial consortia (T8) significantly improved soil biochemical properties—including cation exchange capacity, enzymatic activity, and nutrient availability. T8-treated trees showed increased canopy volume, shoot length, and fruit yield, along with reduced malformed panicles. Enhanced leaf physiological and biochemical traits (photosynthesis, transpiration, proline, phenolics, and nutrient content) were also observed. Fruit quality improved under T8, with higher levels of ascorbic acid, flavonoids, carotenoids, sugars, and antioxidant activity. Correlation and PCA confirmed positive relationships among soil, leaf, and fruit parameters. Compost treatments using rice waste, neem, and mixed leaves performed comparably to synthetic fertilizers. These results highlight vermicompost-microbial integration as a sustainable strategy to enhance productivity and resource efficiency in mango cultivation, thereby supporting soil fertility and reducing dependence on synthetic inputs.
本研究评估了不同有机肥料单独施用和与微生物群落联合施用对Amrapali芒果果园土壤健康、树木生长、产量和果实品质的影响。在12个处理中,添加微生物群落(T8)的蚯蚓堆肥显著改善了土壤的生化特性,包括阳离子交换能力、酶活性和养分有效性。经t8处理的树木冠层体积、梢长和果实产量增加,畸形穗数减少。叶片的生理生化性状(光合作用、蒸腾作用、脯氨酸、酚类物质和养分含量)也有所增强。果实品质在T8下得到改善,抗坏血酸、类黄酮、类胡萝卜素、糖含量和抗氧化活性均有所提高。相关分析和主成分分析证实土壤、叶片和果实参数之间存在正相关关系。使用水稻废料、楝树和混合叶子的堆肥处理效果与合成肥料相当。这些结果强调了蚯蚓-微生物整合是提高芒果种植生产力和资源效率的可持续战略,从而支持土壤肥力并减少对合成投入品的依赖。
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引用次数: 0
Advancements and integration strategies of solar water heaters in buildings: A comprehensive review 太阳能热水器在建筑中的应用进展及集成策略综述
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-09-23 DOI: 10.1016/j.nexus.2025.100535
Walid Zaafouri , Walid Ben Amara , Abdallah Bouabidi , Saif Ali Kadhim , Ali Habeeb Askar
The integration of renewable energy into buildings is a key strategy to reduce energy consumption and heating costs. This review comprehensively examines solar water heater (SWH) systems, focusing on their major components such as storage tanks, solar collectors (flat plate, evacuated tube, parabolic trough, and others), and heat transfer fluids. Two integration strategies are discussed: building-integrated systems (roof and façade applications) and standalone thermosiphon systems. Recent advancements in SWHs include the use of selective coatings, nanofluids, and phase change materials (PCMs), which significantly enhance thermal efficiency. Key factors influencing performance such as collector orientation, tilt angle, and thermal losses are analyzed. The review concludes with design optimization recommendations and integration strategies that support higher system efficiency and broader adoption in both residential and commercial applications.
将可再生能源整合到建筑中是降低能源消耗和供暖成本的关键策略。本文综述了太阳能热水器(SWH)系统,重点介绍了其主要部件,如储罐、太阳能集热器(平板、真空管、抛物面槽等)和传热流体。讨论了两种集成策略:建筑集成系统(屋顶和外墙应用)和独立的热虹吸系统。SWHs的最新进展包括使用选择性涂层、纳米流体和相变材料(PCMs),这些材料显著提高了热效率。分析了影响集热器定向、倾角、热损耗等性能的关键因素。该综述总结了设计优化建议和集成策略,以支持更高的系统效率和更广泛的住宅和商业应用。
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引用次数: 0
Hybrid deep learning models for water demand forecasting in greenhouses: Exploring the energy Nexus in Urban agriculture 温室用水需求预测的混合深度学习模型:探索都市农业中的能源关系
IF 9.5 Q1 ENERGY & FUELS Pub Date : 2025-09-23 DOI: 10.1016/j.nexus.2025.100546
Arash Moradzadeh , Lazhar Ben-Brahim , Ali Arefi , Arman Oshnoei , S.M. Muyeen
Precise water demand forecasting (WDF) is crucial for sustainable irrigation and resource efficiency in urban greenhouse systems. This study introduces a cutting-edge hybrid deep learning approach designed for short-term WDF, while also considering the energy nexus between water, energy, and environmental factors. The model integrates the least squares generative adversarial network (LSGAN) for data pre-processing and noise reduction, convolutional neural networks (CNN) for feature selection, and bidirectional long short-term memory (BiLSTM) for time-series state modeling, and named as LSGANCBiLSTM. Using real-world data from the Wageningen Research Centre in Bleiswijk, Netherlands, the model significantly outperformed benchmark approaches, achieving an R-value of 99.57 % with minimal forecasting errors. The model demonstrated exceptional stability, minimal bias, and strong handling of environmental variability, improving short-term WDF accuracy, optimizing water management in urban agriculture, enhancing sustainable irrigation, and addressing the energy nexus for efficient resource use.
精确的需水量预测对城市温室系统的可持续灌溉和资源效率至关重要。本研究引入了一种尖端的混合深度学习方法,用于短期WDF,同时也考虑了水、能源和环境因素之间的能量联系。该模型集成了用于数据预处理和降噪的最小二乘生成对抗网络(LSGAN)、用于特征选择的卷积神经网络(CNN)和用于时间序列状态建模的双向长短期记忆(BiLSTM),命名为LSGANCBiLSTM。使用来自荷兰bliswijk的Wageningen研究中心的真实数据,该模型显著优于基准方法,r值达到99.57%,预测误差最小。该模型表现出卓越的稳定性、最小的偏差和对环境变化的强大处理能力,提高了短期WDF的准确性,优化了城市农业的水管理,增强了可持续灌溉,并解决了能源关系,实现了资源的有效利用。
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引用次数: 0
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Energy nexus
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