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Enhanced thermal and mechanical properties of flame-retardant expandable graphite modified silk fibroin-based rigid polyurethane foam 增强阻燃性可膨胀石墨改性丝纤维基硬质聚氨酯泡沫的热性能和机械性能
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-05 DOI: 10.1016/j.csite.2024.105418
Xu Zhang , Qihong Guan , Qikai Xiao , Zhi Wang , Hua Xie
At present, in order to reduce the environmental pollution caused by the use of petrochemical products, the preparation of flame-retardant polyurethane foam (PUF) using green raw materials is increasingly attracting widespread attention. A biomass protein-based green flame-retardant rigid PUF (RPUF) with expandable graphite (EG) and silk fibroin (SF) was prepared in a one-step process. Thermal stability, combustion characteristics and compression properties of modified RPUFs were investigated by thermogravimetric analysis, cone test, limiting oxygen index (LOI) test, UL-94 vertical burning test and mechanical compression test. The RPUF with 10 wt% EG (RPUF-SF/EG10) exhibited superior heat resistance, with the highest initial decomposition temperature (Ti), integral programmed decomposition temperatures (IPDT) and activation energy (E). And RPUF-SF/EG10 had the lowest peak heat release rate (PHRR) and total heat release (THR), and it also showed the highest LOI and had a flammability rating of V-0. In Addition, the apparent density and compressive strength of RPUF-SF/EG10 were the largest among the four EG-added materials. The results indicated that RPUF-SF/EG10 had excellent thermal stability, flame retardancy and compression resistance, which was attributed to the synergistic effect of SF and EG in the system. This provided a valuable reference for the development of new, environmentally friendly and high-performance RPUFs.
目前,为了减少使用石化产品造成的环境污染,使用绿色原料制备阻燃聚氨酯泡沫(PUF)正日益受到广泛关注。本研究采用一步法制备了一种基于生物质蛋白的绿色阻燃硬质聚氨酯泡沫(RPUF),其中含有可膨胀石墨(EG)和丝纤维素(SF)。通过热重分析、锥体试验、极限氧指数(LOI)试验、UL-94 垂直燃烧试验和机械压缩试验研究了改性 RPUF 的热稳定性、燃烧特性和压缩性能。含有 10 wt% EG 的 RPUF(RPUF-SF/EG10)表现出优异的耐热性,其初始分解温度(Ti)、积分程序分解温度(IPDT)和活化能(E)均最高。此外,RPUF-SF/EG10 的峰值放热率(PHRR)和总放热率(THR)最低,LOI 最高,可燃性等级为 V-0。此外,在四种添加 EG 的材料中,RPUF-SF/EG10 的表观密度和抗压强度最大。结果表明,RPUF-SF/EG10 具有优异的热稳定性、阻燃性和抗压性,这归功于体系中 SF 和 EG 的协同作用。这为开发新型、环保和高性能的 RPUF 提供了宝贵的参考。
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引用次数: 0
A solving new method for the urea-selective catalytic reduction (SCR) system in a diesel engine using coupled hyperbolic-parabolic partial differential equations (PDEs) 利用双曲-抛物线耦合偏微分方程 (PDE) 解决柴油发动机中尿素选择性催化还原 (SCR) 系统的新方法
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-05 DOI: 10.1016/j.csite.2024.105434
Wenlong Liu , Ying Gao , Yuelin You , Changwen Jiang , Taoyi Hua , Bocong Xia
To control the diesel engine urea SCR system with high accuracy, firstly, the partial differential equations of the SCR system are simplified through variable substitution and the method of characteristic lines to eliminate the partial derivative terms of the hyperbolic partial differential equations in the flow direction. The backward difference method is used to solve the problem, and the adaptive time step is adjusted to improve computational efficiency. Secondly, the Levenberg-Marquardt algorithm is applied to identify the model parameters per second based on the 1800-s test bench data. By combining the experimental data with the parameter identification results, this paper calculated the downstream NOx concentration with 99.5 % accuracy. Finally, the 1800s transient test data was applied to a commonly used single-state SCR control model, and cell numbers 1–4 of the cases were numerically simulated. It was found that the reduced-order model had a computation time of 1 s but was less accurate. When the test data was applied to the model presented in this study, the calculation time was 27s, and the model's calculation results show that the average error of the downstream NOx concentration is 16.95 ppm, which is 14.3 ppm lower than that of the two-cell one-state model.
为了高精度控制柴油机尿素 SCR 系统,首先通过变量代换和特征线法简化了 SCR 系统的偏微分方程,消除了双曲偏微分方程在流动方向上的偏导数项。采用后向差分法求解,并调整自适应时间步长以提高计算效率。其次,应用 Levenberg-Marquardt 算法,根据 1800 秒的试验台数据确定每秒的模型参数。通过将实验数据与参数识别结果相结合,本文计算下游氮氧化物浓度的准确率达到 99.5%。最后,将 1800 秒瞬态测试数据应用于常用的单态可控硅控制模型,并对 1-4 单元的情况进行了数值模拟。结果发现,降阶模型的计算时间为 1 秒,但精确度较低。将测试数据应用于本研究提出的模型时,计算时间为 27 秒,模型的计算结果显示,下游氮氧化物浓度的平均误差为 16.95 ppm,比两单元单态模型低 14.3 ppm。
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引用次数: 0
Integration of the beam-down technology into SOLATOM's linear Fresnel solar field: Design and experimental results 将束下技术集成到 SOLATOM 的线性菲涅尔太阳能场中:设计和实验结果
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-05 DOI: 10.1016/j.csite.2024.105424
Sebastián Taramona , Jesús Gómez-Hernández , Javier Villa Briongos , Agustín Mingot , Miguel Frasquet
The beam-down linear Fresnel solar field (BDLFR) is a concentrating solar technology that can irradiate linearly a heat flux on a ground receiver. This technology is developed for thermally processing high-density materials up to temperatures of 150–300 °C, such as asphalt aggregates. Here, the linear beam-down technology has been scaled-up and tested. SOLATOM's commercial linear Fresnel reflector has been re-adapted to a BDLFR. This demonstrator loop is located in Universitat Politècnica de València (39.47° N, 0.37° W) and consists of ten linear mirrors 50 cm wide, curved along the transversal axis, and oriented clockwise 18° from the East-West axis. Different beam-down configurations were studied for the design conditions, and once the design was established, it was built using ten flat 15 cm wide mirrors and coupled to a SOLATOM XL module. The modified solar field was tested on day 269 and the obtained heat flux was measured, achieving a peak of 4100 W/m2 for a direct irradiance of 640 W/m2, in two adjacent normal distributions due to misalignments and errors in the installation of beam-down. This was contrasted with Monte Carlo ray-tracing simulations, and with proper mirror alignment it is expected to achieve 7750 W/m2 under similar conditions.
光束向下线性菲涅尔太阳场(BDLFR)是一种聚光太阳能技术,可在地面接收器上线性照射热通量。这项技术是为热处理温度高达 150-300 °C 的高密度材料(如沥青集料)而开发的。在这里,线性光束向下技术已经进行了放大和测试。SOLATOM 的商用线性菲涅尔反射器已被重新改装为 BDLFR。该示范环路位于瓦伦西亚理工大学(北纬 39.47°,西经 0.37°),由 10 个 50 厘米宽的线性反射镜组成,沿横向轴弯曲,与东西轴成顺时针方向 18°。针对设计条件研究了不同的光束下射配置,设计方案确定后,使用十面 15 厘米宽的平面镜构建了光束下射系统,并与 SOLATOM XL 模块耦合。在第 269 天对修改后的太阳场进行了测试,并测量了所获得的热通量,在直接辐照度为 640 瓦/平方米的情况下,热通量峰值为 4100 瓦/平方米,在两个相邻的正态分布中,由于光束下射安装的错位和误差,热通量峰值为 4100 瓦/平方米。这与蒙特卡洛射线追踪模拟进行了对比,如果镜面对准正确,预计在类似条件下可达到 7750 瓦/平方米。
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引用次数: 0
Optimisation studies on performance enhancement of spray cooling - Machine learning approach 喷雾冷却性能优化研究--机器学习方法
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-05 DOI: 10.1016/j.csite.2024.105422
Umesh B. Deshannavar , Saee H. Thakur , Amith H. Gadagi , Santosh A. Kadapure , Santhosh Paramasivam , Natarajan Rajamohan , Raffaello Possidente , Gianluca Gatto
The performance optimisation of spray cooling heat transfer systems has been identified as a significant step in improving process efficiency, and the application of machine learning tools is a recent development that has enhanced this. This study aims to maximise the heat transfer coefficient for spray cooling at low heat flux levels. The effects of nozzle inclination angle, water pressure, and spray height on heat transfer coefficient were studied. Taguchi L27 orthogonal array technique was used to perform the experiments. A maximum heat transfer coefficient of 181.4 kW/m2K was obtained at a nozzle inclination angle of 60°, spray height of 4 cm, and water pressure of 15 psi. Analysis of variance was performed to find the significance of each variable and its interactions. The results show that for the maximum heat transfer coefficient (181.4 kW/m2K), the optimum levels of the independent variables were A3H1P3, i.e., the highest level of nozzle inclination angle (60°), the lowest level of spray height (4 cm), and the highest level of water pressure (15 psi). The support vector machine outperformed the Random Forest algorithm and Multiple Regression analysis regarding prediction accuracy with a maximum error of 0.15 % and root mean squared error of 0.01.
喷淋冷却传热系统的性能优化已被确定为提高工艺效率的重要步骤,而机器学习工具的应用是最近的一项发展,它提高了这一效率。本研究旨在最大限度地提高低热通量水平下喷雾冷却的传热系数。研究了喷嘴倾角、水压和喷雾高度对传热系数的影响。实验采用了田口 L27 正交阵列技术。在喷嘴倾角为 60°、喷射高度为 4 厘米、水压为 15 磅/平方英寸时,获得的最大传热系数为 181.4 kW/m2K。进行了方差分析,以找出每个变量及其交互作用的显著性。结果表明,对于最大传热系数(181.4 kW/m2K)而言,自变量的最佳水平为 A3H1P3,即最高水平的喷嘴倾斜角(60°)、最低水平的喷射高度(4 厘米)和最高水平的水压(15 psi)。在预测精度方面,支持向量机优于随机森林算法和多元回归分析,最大误差为 0.15%,均方根误差为 0.01。
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引用次数: 0
Experimental study on fire extinguishing efficiency of polymer hydrogel fire extinguishing agent in pine-fir mixed coniferous forest fires 高分子水凝胶灭火剂在松杉针叶混交林火灾中的灭火效率试验研究
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-05 DOI: 10.1016/j.csite.2024.105413
Zhangyin Dai, Congbao Huang, Youcheng Chen, Manyin Zhong, Wenwu He
Pine and fir wood is commonly used in furniture, gardening and construction industries, and has high economic value. It is in great demand in the timber industry. Therefore, pine and fir trees are now widely planted in China. However, pine and fir trees belong to flammable species, with a high content of oil and grease, and the ignition point of pine and fir leaf litter is extremely low. Once burning occurs, it spreads rapidly and can easily turn into a major forest fire. Therefore, the use of extinguishing agents to mitigate and prevent the spread of forest fires is of great importance. In this paper, fire and extinguishing tests were investigated using mixed wood stack burning of pine and fir and mixed fuel from leaf litter. The suppression effects of three different extinguishing agents, AFFF, CAF and hydrogel, on wood fires and leaf litter combustion were compared. And the suppression supply strength of different extinguishing agents to suppress pine and fir trees was determined. The results show that both hydrogel and CAF can effectively extinguish wood stack fires, and AFFF shows re-ignition phenomenon after extinguishing wood stack fires; Comparison of extinguishing time, cooling rate and heat dissipation capacity revealed that hydrogel was superior to CAF; Hydrogel has a highly efficient fire extinguishing properties. It is calculated that the amount of hydrogel used to extinguish pine and cedar fires is only 54 % of the water required, about 87 % of the amount of Class A foam required under the same circumstances, and about 79 % of the amount of aqueous film-forming foam required; Compared with the foam extinguishing agent, the hydrogel extinguishing agent showed better cooling effect, less extinguishing agent dosage, and shorter extinguishing time of 11 s when extinguishing fires in leaf litter; For the rapid spread of leaf litter combustion and easy to re-ignite characteristics, hydrogel has a significant anti-reignition effect.
松木和杉木常用于家具、园艺和建筑行业,具有很高的经济价值。木材行业对其需求量很大。因此,中国目前广泛种植松树和杉树。然而,松杉木属于易燃树种,油脂含量高,松杉木落叶的燃点极低。一旦发生燃烧,蔓延速度快,很容易演变成大面积森林火灾。因此,使用灭火剂来减轻和防止森林火灾的蔓延具有十分重要的意义。本文使用松木和杉木的混合木材堆垛燃烧以及落叶混合燃料对火灾和灭火试验进行了研究。比较了 AFFF、CAF 和水凝胶三种不同灭火剂对木材火灾和落叶燃烧的抑制效果。并确定了不同灭火剂对松树和杉树的抑制供应强度。结果表明,水凝胶和 CAF 都能有效扑灭木材堆垛火灾,而 AFFF 在扑灭木材堆垛火灾后会出现复燃现象;在灭火时间、冷却速度和散热能力方面的比较表明,水凝胶优于 CAF;水凝胶具有高效灭火性能。据计算,用于扑灭松树和杉木火灾的水凝胶量仅为所需水量的 54%,约为相同情况下所需 A 级泡沫量的 87%,约为所需水成膜泡沫量的 79%;与泡沫灭火剂相比,水凝胶灭火剂的冷却效果更好,灭火剂用量更少,扑灭落叶林火灾的时间更短,仅为 11 秒;针对落叶林燃烧蔓延快、易复燃的特点,水凝胶具有显著的防复燃效果。
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引用次数: 0
Damage power enhancement of fuel air explosive with typical metal hydrides additions 添加典型金属氢化物增强燃料空气炸药的破坏力
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-05 DOI: 10.1016/j.csite.2024.105440
Bei-bei Zhang , Yang-fan Cheng , Xiao-wen Ma , Hong-hao Ma
To study the damage power enhancement of fuel air explosive (FAE) with metal hydrides, the effects of metal hydrides (TiH2, MgH2, ZrH2) powders on shock wave and thermal damage of pure propylene oxide (PO) were explored using a 20 L spherical explosion test system combined with colorimetric thermometry technology. The experimental results showed that compared with the base metal powders, the explosion overpressures, maximum pressure rise rates and maximum average temperatures of the solid-liquid mixed fuel with the metal hydrides (TiH2, MgH2, ZrH2) powders increased by 11.04 %, 22.61 %, 4.80 % and 26.68 %, 38.18 %, 13.91 % as well as 6.85 %, 8.57 %, 1.34 %, respectively. Furthermore, the effects of metal hydride powders on the cloud explosion fuel were better than those of Al powders, and MgH2 powders had the most significant effects on the damage power enhancement of pure PO. Metal hydride powders as high-energy additives could improve the energy release characteristics of FAE.
为了研究金属氢化物对燃料空气炸药(FAE)破坏力的增强,使用 20 L 球形爆炸试验系统并结合比色测温技术,探讨了金属氢化物(TiH2、MgH2、ZrH2)粉末对纯环氧丙烷(PO)冲击波和热破坏的影响。实验结果表明,与基本金属粉末相比,含有金属氢化物(TiH2、MgH2、ZrH2)粉末的固液混合燃料的爆炸超压、最大压力上升率和最大平均温度分别增加了 11.04%、22.61%、4.80% 和 26.68%、38.18%、13.91%,以及 6.85%、8.57%、1.34%。此外,金属氢化物粉末对云爆燃料的影响优于铝粉,而 MgH2 粉末对纯 PO 的破坏力增强效果最为显著。金属氢化物粉末作为高能添加剂可改善 FAE 的能量释放特性。
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引用次数: 0
Significance of heat transfer in a reversible esterification of Arrhenius activation energy with partial slip 部分滑移的阿伦尼乌斯活化能可逆酯化过程中热量传递的意义
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-05 DOI: 10.1016/j.csite.2024.105316
R. Umadevi , D. Arivukkodi , Sultan Alshehery , Ilyas Khan
The significance of heat transfer during a reversible esterification process in a magnetohydrodynamic boundary layer Casson fluid flow along a vertical stretching plate is examined. The multi-slip conditions are considered in a porous medium. The presence of chemical process requiring an activation energy is considered in the analysis. The study also investigates the hydromagnetic boundary layer Casson fluid flow alongwith partial slip conditions across a vertical stretching plate. The incorporation of multi-slip constraints in a porous medium, alongside magnetic fields and other parameters, highlights its relevance in diverse engineering fields such as thermal engineering, polymerization, and biodiesel industries. Understanding the characteristics of such fluids under complex conditions is vital for optimizing heat and mass transfer in industrial applications, making this investigation timely and valuable. The nonlinear differential set of equations are solved numerically involving Runge-Kutta based shooting approach of fourth order and the results are verified with the bvp4c tool and the findings are explored using graphical plots. The predominance of significant factors on flow configurations are analyzed and presented in graphs and tables. A comprehensive analysis is provided on the effects on velocity, concentration, and temperature of diverse parameters such as reaction rate constant, magnetic parameter, suction parameter, mass Grashof number, Prandtl number, Casson parameter, thermal radiation parameter and slip parameters. The tabular representation of the adverse effects of drag coefficient, rate of mass transfer and Nusselt number on flow configurations for various significant parameters is presented. It is inferred that for the case of reversible and irreversible flows, the shear stress rate escalates by 29% when the magnetic parameter elevates from 0.5 to 1.5 and about 35% when the Casson parameter elevates from 0.5 to 1.5. For the suction parameter, the coefficient of drag increased by 27% and 26% for irreversible and reversible flows respectively. When the reaction rate increases from 0.5 to 1.5, the rate of shear stress elevates by 0.5% and 0.02% for irreversible and reversible flows in order. The Nusselt number decreased about 7% and 8% when the magnetic parameter and Casson parameter rises from 0.5 to 1.5 respectively, for irreversible and reversible flows. It is noteworthy that the previous studies are in precise agreement with the present investigation.
研究了磁流体边界层卡松流体沿垂直拉伸板流动的可逆酯化过程中热量传递的重要性。考虑了多孔介质中的多滑移条件。分析中考虑了需要活化能的化学过程。研究还探讨了带有部分滑移条件的水磁边界层卡松流体在垂直拉伸板上的流动。在多孔介质中加入多滑移约束条件以及磁场和其他参数,突出了其在热能工程、聚合和生物柴油工业等不同工程领域的相关性。了解此类流体在复杂条件下的特性对于优化工业应用中的传热和传质至关重要,因此这项研究既及时又有价值。非线性微分方程组采用基于 Runge-Kutta 的四阶射击法进行数值求解,并使用 bvp4c 工具对结果进行验证,同时使用图表对研究结果进行探讨。对流动配置中的重要因素进行了分析,并以图表形式呈现。全面分析了反应速率常数、磁参数、吸力参数、质量格拉肖夫数、普朗特尔数、卡森参数、热辐射参数和滑移参数等不同参数对速度、浓度和温度的影响。表中列出了阻力系数、传质速率和努塞尔特数对各种重要参数的流动配置的不利影响。据推断,对于可逆和不可逆流动,当磁力参数从 0.5 升至 1.5 时,剪应力率会增加 29%;当卡森参数从 0.5 升至 1.5 时,剪应力率会增加约 35%。在吸力参数方面,不可逆流和可逆流的阻力系数分别增加了 27% 和 26%。当反应速率从 0.5 增加到 1.5 时,不可逆流和可逆流的剪应力速率依次增加了 0.5% 和 0.02%。当磁性参数和卡松参数从 0.5 升至 1.5 时,不可逆流动和可逆流动的努塞尔特数分别下降了约 7% 和 8%。值得注意的是,之前的研究与本次调查完全一致。
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引用次数: 0
Computer-aiding evaluation of north wall effects of a solar greenhouse: Multiphysics modelling of the indoor environment 日光温室北墙效应的计算机辅助评估:室内环境的多物理场建模
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-04 DOI: 10.1016/j.csite.2024.105361
L. Zhao , Z. Shui , X. Liu , T. Yang , G. Duan
The north wall (NW) of a solar greenhouse (SG), oriented away from direct sunlight, plays a crucial role in thermal insulation; however, impacts of the NW internal surface structure (ISS) on the SG indoor environment remains underexplored. Driven by in situ measurements, the temperature (Ti) and relative humidity (RHi) of a SG are evaluated for three typical NW designs: flat wall (FW), striped wall (SW) and alveolate/honeycombed wall (AW). In both sunny and cloudy scenarios, the AW setup ensures a more favourable thermal environment, well aligned with the power spectral analysis indicating enhanced thermal energy capture. The time-lagged cross correlation highlights solar radiation as the primary driver of SG internal thermal variability, with outdoor temperature being of secondary relevance. Additionally, the AW setup consistently maintains the lowest RHi on sunny days, promoting optimal conditions for plant growth, and ensures more stable humidity levels during cloudy nights. The revealed response of SG internal environments to modified NW ISS should offer some insights into SG design, particularly in optimising conditions for plant growth through modifications to the NW structure.
日光温室(SG)的北墙(NW)远离阳光直射,在保温隔热方面起着至关重要的作用;然而,北墙内表面结构(ISS)对日光温室室内环境的影响仍未得到充分探索。通过现场测量,我们评估了三种典型净水器设计(平壁(FW)、条纹壁(SW)和泡孔/蜂窝壁(AW))的净水器温度(Ti)和相对湿度(RHi)。在晴天和阴天两种情况下,AW 设置都能确保更有利的热环境,这与功率谱分析结果一致,表明热能捕获得到了加强。时滞交叉相关性突出表明,太阳辐射是 SG 内部热变化的主要驱动因素,室外温度只是次要因素。此外,AW 设置在晴天始终保持最低相对湿度,促进植物生长的最佳条件,并确保在多云的夜晚湿度水平更加稳定。所揭示的 SG 内部环境对修改后的 NW ISS 的反应应能为 SG 设计提供一些启示,特别是通过修改 NW 结构优化植物生长条件方面。
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引用次数: 0
Research on thermal runaway and gas generation characteristics of NCM811 high energy density lithium-ion batteries under different triggering methods 不同触发方法下 NCM811 高能量密度锂离子电池的热失控和气体生成特性研究
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-04 DOI: 10.1016/j.csite.2024.105417
Chunjing Lin , Hongtao Yan , Chuang Qi , Jingbo Mao , Li Lao , Yazhou Sun , Tianyi Ma , Dinghong Liu
Safety concerns, including thermal runaway and gas generation, present significant challenges for high-energy-density lithium-ion batteries. Thermal abuse, a common trigger for thermal runaway, can be induced by various methods, including heating rods, coils, plates, and lasers. This study compares the impacts of three heating techniques—heating rods, coils, and plates—on thermal runaway and gas generation in a commercially used NCM811 lithium-ion battery, which has a high energy density of 280.24 Wh/kg (the latest cylindrical 46950 model). The study found that the heating coil was the most effective, triggering thermal runaway more quickly and at a higher temperature than the heating plate and rod. Gas production analysis revealed that the heating coil method generated significantly more gas, particularly CO2, than the other methods. The concentrations of gases produced during thermal runaway (CO, CO2, H2, and CH4) varied by heating method, with the heating coil leading to a more complete battery reaction. The safety evaluation highlighted the hazardous nature of the heating rod method, which produced the widest flammable gas concentration range and the highest explosion risk among the tested heating methods. This study provides critical insights into heating techniques in lithium-ion battery thermal runaway scenarios and offers valuable data for improving safety measures in energy storage systems.
安全问题,包括热失控和气体产生,给高能量密度锂离子电池带来了重大挑战。热滥用是热失控的常见诱因,可通过各种方法诱发,包括加热棒、线圈、板和激光。本研究比较了三种加热技术(加热棒、线圈和极板)对商用 NCM811 锂离子电池热失控和气体产生的影响,该电池的能量密度高达 280.24 Wh/kg(最新的圆柱形 46950 型)。研究发现,与加热板和加热棒相比,加热线圈最有效,能更快、更高温度地触发热失控。气体产生分析表明,加热线圈法产生的气体,尤其是二氧化碳,明显多于其他方法。热失控期间产生的气体(CO、CO2、H2 和 CH4)的浓度因加热方法而异,加热线圈导致更完全的电池反应。安全评估强调了加热棒方法的危险性,在测试的加热方法中,加热棒方法产生的可燃气体浓度范围最广,爆炸风险最高。这项研究为锂离子电池热失控情况下的加热技术提供了重要见解,并为改进储能系统的安全措施提供了宝贵数据。
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引用次数: 0
Synthesis of short-chain fluorocarbon surfactant: Enhancing surface and foam performance through hydrocarbon surfactants compounding 短链碳氟化合物表面活性剂的合成:通过碳氢化合物表面活性剂复配提高表面和泡沫性能
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2024-11-04 DOI: 10.1016/j.csite.2024.105409
Wenjun Zhao , Zhisheng Xu , Long Yan , Guoqing Niu
The research of short-chain fluorocarbon surfactants is crucial in effectively and environmentally extinguishing petrochemical fires. In this study, a short-chain fluorocarbon surfactant named 2H,2H-perfluorooctanoic acid sodium salt (PFH-CA) was synthesized, and then characterized its chemical structure, thermal stability, surface activity, and foam property. Subsequently, PFH-CA was compounded with hydrocarbon surfactants including sodium dodecyl sulfate (SDS), dodecyl trimethyl ammonium chloride (DTAC), and N,N-dimethyldodecylamine-N-oxid (OB-2) at different molar ratios. The surface tension, interaction parameters, and foam property of the PFH-CA/hydrocarbon surfactant compounding systems were investigated. The analysis indicates that PFH-CA exhibits excellent surface activity and thermal stability concomitant with poor foam property. Introducing SDS, DTAC, and OB-2 enhances the foam performance and reduces the consumption of PFH-CA through synergistic interactions. Especially, PFH-CA/DTAC (1:4) system possesses the strongest interactions and the best performance, with critical micelle concentration (CMC) and surface tension at CMC (γCMC) of 0.11 mmol/L and 20.90 mN/m, respectively. When concentration of PFH-CA exceeds 0.5 mmol/L, the foaming ability and foam stability stabilize at 30 cm and 90 %, respectively. The enhanced performance of PFH-CA/DTAC system is attributed to the electrostatic attraction between anionic and cationic surfactants, which facilitates the formation of micelles, subsequently leading to better surface activity and foam properties.
短链碳氟化合物表面活性剂的研究对于有效、环保地扑灭石油化工火灾至关重要。本研究合成了一种名为 2H,2H-全氟辛酸钠盐(PFH-CA)的短链碳氟化合物表面活性剂,并对其化学结构、热稳定性、表面活性和泡沫特性进行了表征。随后,以不同摩尔比将 PFH-CA 与十二烷基硫酸钠(SDS)、十二烷基三甲基氯化铵(DTAC)和 N,N-二甲基十二烷基胺-N-氧化物(OB-2)等烃类表面活性剂复配。研究了 PFH-CA 与烃类表面活性剂复配体系的表面张力、相互作用参数和泡沫特性。分析表明,PFH-CA 具有优异的表面活性和热稳定性,但泡沫性能较差。引入 SDS、DTAC 和 OB-2 可通过协同作用提高泡沫性能并减少 PFH-CA 的消耗。其中,PFH-CA/DTAC(1:4)体系的相互作用最强,性能最好,临界胶束浓度(CMC)和 CMC 时的表面张力(γCMC)分别为 0.11 mmol/L 和 20.90 mN/m。当 PFH-CA 的浓度超过 0.5 mmol/L 时,发泡能力和泡沫稳定性分别稳定在 30 cm 和 90 %。PFH-CA/DTAC 系统性能的提高归因于阴离子表面活性剂和阳离子表面活性剂之间的静电吸引作用,这种作用促进了胶束的形成,从而提高了表面活性和泡沫性能。
{"title":"Synthesis of short-chain fluorocarbon surfactant: Enhancing surface and foam performance through hydrocarbon surfactants compounding","authors":"Wenjun Zhao ,&nbsp;Zhisheng Xu ,&nbsp;Long Yan ,&nbsp;Guoqing Niu","doi":"10.1016/j.csite.2024.105409","DOIUrl":"10.1016/j.csite.2024.105409","url":null,"abstract":"<div><div>The research of short-chain fluorocarbon surfactants is crucial in effectively and environmentally extinguishing petrochemical fires. In this study, a short-chain fluorocarbon surfactant named 2<em>H</em>,2<em>H</em>-perfluorooctanoic acid sodium salt (PFH-CA) was synthesized, and then characterized its chemical structure, thermal stability, surface activity, and foam property. Subsequently, PFH-CA was compounded with hydrocarbon surfactants including sodium dodecyl sulfate (SDS), dodecyl trimethyl ammonium chloride (DTAC), and <em>N</em>,<em>N</em>-dimethyldodecylamine-<em>N</em>-oxid (OB-2) at different molar ratios. The surface tension, interaction parameters, and foam property of the PFH-CA/hydrocarbon surfactant compounding systems were investigated. The analysis indicates that PFH-CA exhibits excellent surface activity and thermal stability concomitant with poor foam property. Introducing SDS, DTAC, and OB-2 enhances the foam performance and reduces the consumption of PFH-CA through synergistic interactions. Especially, PFH-CA/DTAC (1:4) system possesses the strongest interactions and the best performance, with critical micelle concentration (<em>CMC</em>) and surface tension at <em>CMC</em> (<em>γ</em><sub><em>CMC</em></sub>) of 0.11 mmol/L and 20.90 mN/m, respectively. When concentration of PFH-CA exceeds 0.5 mmol/L, the foaming ability and foam stability stabilize at 30 cm and 90 %, respectively. The enhanced performance of PFH-CA/DTAC system is attributed to the electrostatic attraction between anionic and cationic surfactants, which facilitates the formation of micelles, subsequently leading to better surface activity and foam properties.</div></div>","PeriodicalId":9658,"journal":{"name":"Case Studies in Thermal Engineering","volume":"64 ","pages":"Article 105409"},"PeriodicalIF":6.4,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142659676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Case Studies in Thermal Engineering
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