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Experimental proof-of-concept of bubble column evaporative cooling for PEMFC heavy-duty vehicle thermal management 用于PEMFC重型车辆热管理的泡柱蒸发冷却概念的实验验证
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-03-04 DOI: 10.1016/j.csite.2026.107876
Christian Boßer , David Sedarsky
Challenging heat rejection caused by small temperature differences between ambient air and low-temperature proton exchange membrane fuel cells (PEMFC) lead to significantly increased radiator dimension and fan power requirements, increasing the need for alternative cooling solutions. To overcome these limitations, the high latent heat of water that is produced in the hydrogen PEMFC can be utilized to enhance the overall system heat rejection.
A novel bubble column evaporator concept for fuel cell (FC) thermal management has been developed. High heat and mass transfer rates make bubble columns a promising alternative to evaporate the product water. It consists of a semi-closed loop in which heat is transferred from the FC coolant to a secondary water circuit that is evaporatively cooled by injecting the FC exhaust air into a bubble column. This solution utilizes only air and water for cooling, provides additional heat storage, improves with increasing altitude and does not increase the vehicle's drag.
We present the novel counterflow bubble column evaporator concept together with proof-of-concept measurements to demonstrate its viability by validating theoretically predicted heat rejection rates. Higher superficial gas velocities than previously reported have been investigated to reduce system size, reaching up to 1.22 m/s. Based on the presented measurements and a verified heavy-duty PEMFC truck model, this approach could complement the conventional truck cooling system with 153 kW additional heat rejection for 23 min with 50 kg of water storage. At 20 °C, this corresponds to an increase of over 40% compared to the conventional cooling system alone.
由于环境空气和低温质子交换膜燃料电池(PEMFC)之间的温差很小,导致散热器尺寸和风扇功率要求显著增加,从而增加了对替代冷却解决方案的需求。为了克服这些限制,氢PEMFC中产生的水的高潜热可以用来提高整个系统的散热能力。提出了一种用于燃料电池(FC)热管理的新型泡柱蒸发器概念。高传热传质率使气泡柱成为蒸发产物水的一种很有前途的替代方法。它由一个半闭环组成,其中热量从FC冷却剂传递到二次水路,通过将FC排出的空气注入气泡柱来蒸发冷却。这种解决方案仅利用空气和水进行冷却,提供额外的热量储存,随着高度的增加而改善,并且不会增加车辆的阻力。我们提出了新的逆流泡柱蒸发器概念和概念验证测量,以证明其可行性,通过验证理论预测的散热率。为了减小系统尺寸,研究人员研究了比之前报道的更高的表面气速,达到1.22 m/s。根据所提供的测量结果和经过验证的重型PEMFC卡车模型,该方法可以补充传统卡车冷却系统,在23分钟内提供153千瓦的额外散热,并储存50公斤的水。在20°C时,与传统冷却系统相比,这相当于增加了40%以上。
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引用次数: 0
Enhance the performance of the thermal barrier coated diesel engine with application of novelly extracted and optimization of aquatic plant-based biofuel blend 应用新提取和优化的水生植物基生物燃料混合物,提高热障涂层柴油机的性能
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-03-07 DOI: 10.1016/j.csite.2026.107915
Ramakrishnan Sambasivam, Annamalai Kandasamy
Global energy crisis and environmental issues also have encouraged the quest for renewable and sustainable solutions to the traditional fossil fuels. Alternative biofuels based on water plants offer great potential as they are fast growing, do not compete with food crops and produce high biomass. In the present work, an aquatic weed Hydrilla verticillata was examined as a likely feedstock for biodiesel production. Solvent extracted oil by using n-hexane solvent helps in increasing the yield efficiency and fuel quality from Hydrilla plant feedstocks. The thus obtained oil was mixed with diesel in different ratios and experiments were carried out in a compression ignition engine. Prior to the use of this process analysis work done on zirconia material coated (0.5 mm) that is piston for checking the heat transfer of the piston from top to down with help of ANSYS software and also compared without coated engine. Further to enhance combustion and robustness across the blend range, A zirconia-based thermal barrier coated material was applied to the piston crown to increase in-cylinder heat and pressure to retention and minimize heat losses to the bottom of the piston. The zirconia coating promoted the higher Hydrilla–diesel fulcrum blend ratio and enhanced virility as could be observed in the experiments. The engine with coated piston showed better BTE, less specific fuel consumption and lesser dependency on conventional diesel. Analysis of exhaust emissions further showed that CO reduced, CO2 increased, and unburned HC had decreased but NOx was also increased but kept within permissible limits. The results demonstrate the two-fold advantage of employing Hydrilla biofuel and thermal barrier coating as a collective technique for minimizing fossil fuel dependence and engaging with sustainable engine technologies.
全球能源危机和环境问题也促使人们寻求替代传统化石燃料的可再生和可持续解决方案。基于水生植物的替代生物燃料提供了巨大的潜力,因为它们生长迅速,不与粮食作物竞争,并且产生高生物量。在本工作中,研究了水草水蛭作为生物柴油生产的可能原料。采用正己烷溶剂萃取油有助于提高水螅装置原料的收率和燃料质量。将所得油与柴油按不同比例混合,并在压燃式发动机上进行了实验。在使用此工艺分析工作之前,在ANSYS软件的帮助下,对氧化锆材料涂层(0.5 mm)的活塞进行了从上到下的传热检查,并对未涂层的发动机进行了比较。为了进一步提高混合燃料的燃烧性能和坚固性,活塞顶部采用了锆基热障涂层材料,以增加气缸内的热量和压力,以保持活塞底部的热量损失,并将热量损失降到最低。实验结果表明,氧化锆涂层提高了水合柴油支点混合比,提高了动力性能。采用涂层活塞的发动机表现出更好的BTE、更低的油耗和对传统柴油的依赖性。尾气排放进一步分析表明,CO减少,CO2增加,未燃烧HC减少,NOx也增加,但保持在允许范围内。结果表明,采用Hydrilla生物燃料和热障涂层作为一种集体技术,可以最大限度地减少对化石燃料的依赖,并参与可持续发动机技术,具有双重优势。
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引用次数: 0
Coupled thermophoretic and thermocapillary effects on the motion of a particle near an immiscible fluid interface 耦合热泳和热毛细效应对靠近非混相流体界面的粒子运动的影响
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-02-23 DOI: 10.1016/j.csite.2026.107852
M.S. Faltas , E.A. Ashmawy , M.G. Nashwan , Baraa A. Ahmed , M. El-Sayed
Thermophoretic transport near fluid interfaces governs a wide array of natural and technological processes, yet a unified theoretical framework that simultaneously captures particle-surface slip phenomena and interfacial thermocapillarity has remained absent from the literature. This study bridges that critical gap by developing a semi-analytical framework, solved via the boundary collocation method, to investigate the motion of a spherical particle in a viscous fluid near an immiscible fluid–fluid interface. The model’s novelty lies in its comprehensive integration of thermal creep, mechanical slip, and thermal stress slip at the particle surface with the transformative influence of thermocapillary (Marangoni) flow. Following rigorous validation against established rigid-wall limits, our analysis reveals physical phenomena that fundamentally diverge from classical predictions for solid boundaries. Most notably, strong interfacial thermocapillary flow is shown to counteract the expected hydrodynamic retardation of an insulating particle, even inverting its motion into a regime of net acceleration. Furthermore, our results challenge the traditional view of mechanical slip as a simple drag-reducer, uncovering a non-monotonic dual role where slip initially weakens the thermophoretic drive before its drag-reducing effect becomes dominant. We also demonstrate for the first time that the impact of thermal stress slip can reverse from enhancing to hindering at higher Knudsen numbers, a complex behavior contingent upon the thermal properties of the secondary fluid. These findings establish a more complete physical picture of thermophoresis in multiphase systems, providing a powerful predictive toolset with direct implications for designing advanced thermal precipitators, engineering “smart fluids” with tunable transport properties, and fabricating novel composite materials through the controlled deposition of particles at interfaces.
流体界面附近的热电泳传输控制着广泛的自然和技术过程,然而,同时捕获颗粒表面滑移现象和界面热毛细现象的统一理论框架仍然缺乏文献。本研究通过开发一种半解析框架,通过边界配置方法求解,来研究非混相流体-流体界面附近粘性流体中球形颗粒的运动,从而弥合了这一关键差距。该模型的新颖之处在于它综合考虑了热蠕变、机械滑移和颗粒表面的热应力滑移以及热毛细(Marangoni)流动的转化影响。在对已建立的刚性壁极限进行严格验证后,我们的分析揭示了与固体边界的经典预测根本不同的物理现象。最值得注意的是,强烈的界面热毛细流动被证明可以抵消预期的绝缘粒子的流体动力延迟,甚至将其运动转化为净加速度。此外,我们的研究结果挑战了机械滑移作为简单减阻剂的传统观点,揭示了滑移在其减阻作用成为主导作用之前首先削弱热泳驱动的非单调双重作用。我们还首次证明,在较高的Knudsen数下,热应力滑移的影响可以从增强变为阻碍,这是一种复杂的行为,取决于二次流体的热性质。这些发现建立了多相系统中更完整的热电泳物理图谱,为设计先进的热沉淀器、设计具有可调输运特性的“智能流体”以及通过控制界面颗粒沉积制造新型复合材料提供了强大的预测工具集。
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引用次数: 0
Sustainable separation system for pulsating and multiphase turbulent flow in gas-liquid cylindrical cyclone 气液圆柱旋流器脉动多相湍流可持续分离系统
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-02-27 DOI: 10.1016/j.csite.2026.107871
Pouya Nikpendar, Omid Jahanian, Davood Domiri Ganji, Mohammad Mohsen Peiravi
As oil fields and steam power plants develop further, the separation of gas particles and liquid droplets presents significant challenges. Cyclone separators, as a type of high-efficiency and low-volume separators, are widely used in the separation of gas-liquid flows. In this study, the steady-state performance of the cyclone separator under pulsed and turbulent flow conditions at the outlet of two-phase gas-liquid cylindrical cyclones was simulated using three-dimensional discrete phase model and validated with experimental results from the cyclone constructed. The effect of pulsating output and turbulent flow fluctuations on the separation efficiency and the reduction of unwanted phenomena of gas transport from the lower outlet and liquid transport from the upper outlet were investigated. The innovation in the geometry of these separators were experimentally evaluated and the effect of various geometric parameters including the length of the cyclone below the inlet, the length of the cyclone above the inlet, the diameter of the cyclone and the frequency of the outlet valve were analyzed. Through systematic experimentation and numerical analysis, in addition to reducing the gas carry-under value to zero, the best upper and lower pipe heights of 400 and 1300 mm, respectively, and the best upper outlet diameter of 40 mm were achieved. Also, in addition to reducing the gas carry-under value to zero and controlling the liquid carry-over value through the separation process under the pulse pressure range at an optimal frequency, the best closing and opening times of the pulse outlet valve were 3 and 1 s, respectively.
随着油田和蒸汽电厂的进一步发展,气体颗粒和液滴的分离提出了重大挑战。旋风分离器作为一种高效、小体积的分离器,广泛应用于气液流的分离。本研究采用三维离散相模型对气液两相圆柱旋风分离器在脉冲和湍流两种工况下的稳态性能进行了模拟,并用所构建旋风分离器的实验结果进行了验证。研究了脉动输出和湍流波动对分离效率和减少下出口输气和上出口输液不良现象的影响。实验评价了这些分离器在几何结构上的创新,并分析了各种几何参数的影响,包括入口下方的旋风器长度、入口上方的旋风器长度、旋风器直径和出口阀频率。通过系统的实验和数值分析,在将气体携气量降至零的同时,实现了最佳上、下管高分别为400 mm和1300 mm,最佳上出口直径为40 mm。脉冲出口阀的最佳关闭时间为3 s,最佳开启时间为1 s,除了在脉冲压力范围内以最佳频率通过分离过程将气体携带值降至零和控制液体携带值外。
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引用次数: 0
Effect of droplet size evolution and distribution of water mist on the thermal radiation attenuation 水雾雾滴粒径演变及分布对热辐射衰减的影响
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-02-26 DOI: 10.1016/j.csite.2026.107868
Hassan Raza Shah , Shangqing Tao , Jun Fang , Jingwu Wang , Xuqing Lang , Zhi Jian Tian
Water mist systems for fire protection are widely recognized for their ability to attenuate thermal radiation and suppress fires. This study used high-precision shadow imaging with a non-luminous radiant panel to investigate the water mist droplet evolution and distribution under varying nozzle pressures and radiant panel temperatures (i.e., ambient thermal conditions), and their effects on thermal radiation attenuation (TRA). Under non-thermal conditions, droplet growth with distance was dominated by coalescence, while under thermal exposure, both evaporation and coalescence were observed, with pressure governing the dominant mechanism: at low pressure, droplets transitioned from evaporation-dominant to a combination of evaporation and coalescence, whereas at high pressure, the mechanism sequence was reversed. A radiation-driven critical distance based on characteristic droplet size (CDS) and size variance distribution parameter (σ) was identified, beyond which the dominant mechanism changed. A simplified theoretical equation, validated against experiments, reproduced droplet size and velocity evolution, revealing the coupled mechanism arising from size variation with distance. Furthermore, the water mist radiation protection was significantly influenced by radiant panel temperature, thereby altering TRA. These findings provide theoretical and experimental insights for advancements of efficient water-mist technologies for thermal radiation protection and fire suppression.
消防用水雾系统因其衰减热辐射和扑灭火灾的能力而得到广泛认可。本研究采用非发光辐射板的高精度阴影成像技术,研究了不同喷嘴压力和辐射板温度(即环境热条件)下水雾滴的演化和分布,以及它们对热辐射衰减(TRA)的影响。在非热条件下,液滴随距离的生长以聚并为主,而在热条件下,液滴的生长同时存在蒸发和聚并,以压力为主导机制:低压条件下,液滴由蒸发为主过渡到蒸发和聚并相结合,而高压条件下,机制顺序相反。确定了基于特征液滴尺寸(CDS)和尺寸方差分布参数(σ)的辐射驱动临界距离,在此基础上,主导机理发生了变化。简化的理论方程与实验结果相吻合,再现了液滴尺寸和速度的变化规律,揭示了液滴尺寸随距离变化的耦合机理。此外,水雾辐射防护受辐射板温度的显著影响,从而改变TRA。这些发现为热辐射防护和灭火的高效水雾技术的发展提供了理论和实验见解。
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引用次数: 0
Robust virtual sensing of turbine exit temperature for aero-engines using a truncated generalized correntropy-based extreme learning machine 基于截断广义熵的极限学习机的航空发动机涡轮出口温度鲁棒虚拟感知
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-03-04 DOI: 10.1016/j.csite.2026.107895
Maojun Xu , Yao Qin , Tingyi Ouyang , Bei Liu , Jinxin Liu , Jia Geng , Huihui Miao , Minglong Du , Zhiping Song
Turbine exit total temperature (Tt6) is a critical yet challenging parameter to measure directly in aero-engines due to extreme thermal conditions that often lead to sensor faults like drift, threatening engine safety and efficiency. Virtual sensing provides a viable alternative, but prevailing data-driven methods, typically reliant on the mean squared error (MSE) loss, suffer from performance degradation under non-Gaussian noise and sensor anomalies. To overcome this limitation, this paper introduces a robust virtual sensing framework based on a novel Truncated Generalized Correntropy loss. By integrating the generalized maximum correntropy criterion with an adaptive truncation mechanism, the proposed loss function effectively suppresses the influence of outliers and faulty measurements. Embedded into an Extreme Learning Machine (ELM), this yields the Robust Truncated Generalized Correntropy ELM (RTGC-ELM) algorithm. The framework was rigorously validated using high-fidelity component-level model data under realistic flight profiles and further tested on the public NASA C-MAPSS dataset. Evaluations covered both normal operations and severe sensor fault scenarios (step-type and ramp-type drift). The results demonstrate that RTGC-ELM maintains high accuracy under normal conditions (MAE ∼1.21%) while exhibiting exceptional robustness under faults. For instance, under a step-type fault, RTGC-ELM limited performance degradation to only 0.01% (MAE increase from 1.21% to 1.22%), significantly outperforming conventional ELM (MAE increase from 1.28% to 1.75%) and other algorithms. This superior robustness was consistent across fault types and severity levels, confirmed through statistical significance tests and cross-dataset validation. The proposed RTGC-ELM provides a robust, efficient, and practical solution for analytical redundancy in aero-engine health management systems.
涡轮出口总温度(Tt6)是航空发动机直接测量的一个关键但具有挑战性的参数,因为极端的热条件经常导致传感器故障,如漂移,威胁发动机的安全和效率。虚拟传感提供了一种可行的替代方案,但主流的数据驱动方法通常依赖于均方误差(MSE)损失,在非高斯噪声和传感器异常情况下会导致性能下降。为了克服这一限制,本文引入了一种基于截断广义熵损失的鲁棒虚拟感知框架。通过将广义最大熵准则与自适应截断机制相结合,所提出的损失函数有效地抑制了异常值和错误测量的影响。嵌入到一个极限学习机(ELM),这产生了鲁棒截断广义相关ELM (RTGC-ELM)算法。该框架在真实飞行剖面下使用高保真组件级模型数据进行了严格验证,并在NASA C-MAPSS公共数据集上进行了进一步测试。评估包括正常操作和严重传感器故障场景(阶梯型和斜坡型漂移)。结果表明,RTGC-ELM在正常条件下保持较高的精度(MAE ~ 1.21%),同时在故障下表现出优异的鲁棒性。例如,在阶跃型故障下,RTGC-ELM将性能下降限制在0.01% (MAE从1.21%增加到1.22%),显著优于传统ELM (MAE从1.28%增加到1.75%)等算法。通过统计显著性检验和跨数据集验证,这种优越的稳健性在故障类型和严重程度上是一致的。提出的RTGC-ELM为航空发动机健康管理系统中的分析冗余提供了一种鲁棒、高效和实用的解决方案。
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引用次数: 0
Study on a two-stage desiccant wheel dehumidification deep mine cooling system driven by mine water source heat pump 矿井水源热泵驱动的两级干燥剂轮除湿深部矿井冷却系统研究
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-03-06 DOI: 10.1016/j.csite.2026.107896
Yuliang Sun , Xuehua Li , Yanzi Lei , Hongtao An , Kaipeng Wang , Qiang Yu
Deep mining is the primary direction for future mine development. However, deep mining causes heat damage, which seriously affects work efficiency and worker health. To satisfy the requirements of thermal comfort, a two-stage desiccant wheel dehumidification deep mine cooling system driven by mine water source heat pump (TSDW-DMCS-MWSHP) is proposed. The system consists of a two-stage desiccant wheel, water source heat pump, air cooler, and air heater. A water source heat pump is used to realize the dual supply of cold and heat, which provides cold and heat sources for cooling the mine airflow and heating the regeneration air. A two-stage desiccant wheel is used to achieve deep dehumidification. A heat and mass transfer model of the system is established and simulated. The effects of the main operating parameters on energy, dehumidification, and exergy performances are systematically investigated. The results show that when the inlet temperature of the mine airflow is 32 °C and the relative humidity is 80 %, the system can achieve a temperature difference of 6 °C, a humidity ratio difference of 11.7 g/kg, and an enthalpy difference of 36.1 kJ/kg. When the two-stage desiccant wheel operates at a low regeneration temperature of 60 °C, the TCOP, DCOP, and exergy efficiency reach their peak values of 2.8, 0.9, and 68.9 %, respectively. Compared with the ground centralized refrigeration system, the supply air relative humidity of the TSDW-DMCS-MWSHP is reduced by 13.3 %, and the COP is increased by 16 %. The TSDW-DMCS-MWSHP offers a viable solution for mitigating mine heat damage and advancing the sustainable development in the mining industry.
深部开采是未来矿山发展的主要方向。然而,深部开采会造成热损伤,严重影响工作效率和工人身体健康。为满足矿井热舒适性的要求,提出了一种由矿井水源热泵驱动的两级干燥剂轮除湿矿井深部冷却系统。该系统由两级干燥剂轮、水源热泵、空气冷却器和空气加热器组成。采用水源热泵实现冷热双供,为矿井气流的冷却和再生风的加热提供冷热源。采用两级除湿轮,实现深度除湿。建立了系统的传热传质模型并进行了仿真。系统地研究了主要运行参数对能量、除湿和火用性能的影响。结果表明,当矿井气流入口温度为32℃,相对湿度为80%时,系统可实现温差6℃,湿比差11.7 g/kg,焓差36.1 kJ/kg。两级干燥剂轮在低再生温度60℃下运行时,TCOP、DCOP和火用效率分别达到峰值2.8、0.9和68.9%。与地面集中制冷系统相比,TSDW-DMCS-MWSHP送风相对湿度降低13.3%,COP提高16%。TSDW-DMCS-MWSHP为减轻矿山热损害,促进矿山可持续发展提供了可行的解决方案。
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引用次数: 0
Research on the mechanism of water lock removal in tight sandstone gas reservoirs under microwave radiation 微波辐射下致密砂岩气藏水锁解除机理研究
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-02-19 DOI: 10.1016/j.csite.2026.107821
Jie Zhang , Wangru Yang , Shusheng Gao , Jinmei Peng , Feifei Fang , Zhenkai Wu , Ye Zhang , Xiaoliang Huang , Zhilin Qi
Water lock in the near-wellbore region severely constrains the productivity of tight sandstone gas reservoirs. Unlike conventional methods limited by high energy costs and secondary pollution, microwave heating offers a high-efficiency alter native capable of simultaneously reducing flow resistance and inducing fracture-enhanced permeability. This study investigates these mechanisms using Sulige sandstone cores through a combination of CT scanning, XRD, physical experiments, and coupled thermo-hydro-mechanical simulations. Key findings include: (1) Microwave radiation induces pore water vaporization and thermal stress fracturing, significantly improving pore connectivity once a temperature threshold of 500 °C is surpassed. (2) Under optimal conditions (800 W, 15min), the stable production period extended by 23–48 times, and ultimate recovery improved by approximately 20–26% across varying water saturations. (3) Numerical modeling, exhibiting high agreement with experimental data, predicts an effective remediation radius of 0.6 m and a total gas production increase of 0.34 × 106 m3. These results confirm the efficacy of microwave heating in alleviating water lock, offering a robust theoretical and technical basis for optimizing field development strategies.
近井区水锁严重制约了致密砂岩气藏的产能。不像传统的方法受到高能源成本和二次污染的限制,微波加热提供了一种高效的替代方案,能够同时降低流动阻力和提高裂缝的渗透率。本研究利用苏里格砂岩岩心,通过CT扫描、XRD、物理实验和热-水-力学耦合模拟等方法研究了这些机理。主要发现包括:(1)微波辐射诱导孔隙水蒸发和热应力破裂,当温度阈值超过500℃时,孔隙连通性显著改善。(2)在最佳条件下(800w, 15min),不同含水饱和度下的稳产期延长了23 ~ 48倍,最终采收率提高了约20 ~ 26%。(3)数值模拟结果与实验数据吻合较好,预测有效修复半径为0.6 m,总产气量增加0.34 × 106 m3。这些结果证实了微波加热缓解水锁的有效性,为优化油田开发策略提供了坚实的理论和技术基础。
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引用次数: 0
Thermo-bioconvective transport in an oxytactic microorganisms-laden cavity 富氧微生物腔内的热生物对流输送
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-02-28 DOI: 10.1016/j.csite.2026.107850
Muhammad Sabeel Khan , A. Al-Zubaidi , Noor-ul Absar , M. Asif Memon , Amsalu Fenta
This study investigates heat and mass transfer in a square porous cavity containing oxytactic microorganisms using the Cattaneo–Christov heat flux model and Darcy flow. The governing equations, which incorporate the laws of mass, momentum, and energy conservation, are solved numerically using the finite-element method. Strong agreement is found when the Nusselt and Sherwood values are calculated and compared with the data provided in the black literature to validate the results. The results are calculated and thoroughly presented for a range of values of the physical parameters. Using streamlines, isotherms, concentration profiles and tables, the results show how different parameters like the Lewis number, the Peclet number, the Rayleigh number, and the bioconvection Rayleigh number affect heat and mass transfer with oxytactic microorganisms in the cavity. The cavity’s side walls further highlight how these characteristics affect the Nusselt and Sherwood numbers. With an emphasis on the influence of important physical parameters, the study often offers valuable information about the intricate relationships between heat, fluid flow, and microbe concentration within a porous cavity. It is observed that when the Péclet number increases from the baseline case of 0.1 to 13, the maximum value of the stream function increases by approximately 44. 2%, clearly highlighting the sensitivity of the flow field to variations in the advection strength. Similarly, as the Péclet number increases from 1 to 29, the minimum oxygen concentration decreases by almost 16.1%, indicating substantial oxygen depletion at higher Péclet values. An increase in the relaxation parameter from 0 to 2.55 results in a reduction of 41. 3% in the maximum value of the stream function, demonstrating the significant suppressive effect of relaxation on the convective strength of the flow. The presence of microorganisms improves heat transfer, with the Nusselt number increasing by approximately 15%–20% at low Prandtl numbers and exceeding 30% at higher Prandtl numbers, indicating a synergistic interaction between thermal stratification and bioconvection. Furthermore, as the oxygen consumption parameter increases, the minimum oxygen concentration is reduced by almost 12. 9%, indicating the dominant role of consumption over diffusion in shaping oxygen distribution within the cavity. These results are crucial to improve heat transmission and bioconvection processes in porous media, especially biological or ecological systems where microorganisms are important to dynamics.
本研究利用Cattaneo-Christov热流模型和Darcy流研究了含氧趋化微生物的方形多孔腔内的传热传质。控制方程包含质量、动量和能量守恒定律,采用有限元方法进行数值求解。当计算Nusselt和Sherwood值并与黑人文献中提供的数据进行比较以验证结果时,发现强烈的一致性。对物理参数的一系列值进行了计算并给出了完整的结果。利用流线、等温线、浓度曲线和表格,研究了Lewis数、Peclet数、瑞利数和生物对流瑞利数等不同参数对腔内氧趋化微生物传热传质的影响。空腔的侧壁进一步突出了这些特征如何影响努塞尔和舍伍德数。由于强调重要物理参数的影响,该研究通常提供有关多孔腔内热量,流体流动和微生物浓度之间复杂关系的有价值的信息。可以观察到,当psamclet数从0.1的基线情况增加到13时,流函数的最大值增加了大约44。2%,明显地突出了流场对平流强度变化的敏感性。同样,当psamclet数从1增加到29时,最低氧浓度下降了近16.1%,表明在较高的psamclet值下存在大量的氧消耗。松弛参数从0增加到2.55,导致减小41。流函数的最大值为3%,表明松弛对流的对流强度有明显的抑制作用。微生物的存在改善了传热,低普朗特数时努塞尔数增加约15%-20%,高普朗特数时超过30%,表明热分层和生物对流之间存在协同作用。此外,随着耗氧量参数的增加,最小氧浓度降低了近12。9%,表明在形成腔内氧气分布方面,消耗比扩散起主导作用。这些结果对于改善多孔介质中的传热和生物对流过程至关重要,特别是在微生物对动力学很重要的生物或生态系统中。
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引用次数: 0
Determination of paclitaxel anticancer drug solubility in supercritical CO2: Thermodynamics modeling and machine learning approach 紫杉醇抗癌药物在超临界CO2中的溶解度测定:热力学建模和机器学习方法
IF 6.4 2区 工程技术 Q1 THERMODYNAMICS Pub Date : 2026-04-01 Epub Date: 2026-02-26 DOI: 10.1016/j.csite.2026.107864
Gholamhossein Sodeifian , Ratna Surya Alwi , Nedasadat Saadati Ardestani , Adel Noubigh , Reza Derakhsheshpour , Amir Elyasi
To facilitate the effective design of supercritical fluid (SCF) processes aimed at micro- or nanosizing solid pharmaceuticals, obtaining solubility data in environmentally friendly solvents such as pressurized carbon dioxide (CO2) is essential. Solubility assessment represents a critical first step in evaluating SCF technologies. This study introduces a statistical methodology to experimentally determine the solubility of paclitaxel (Pac) in supercritical CO2. UV-vis spectrophotometric studies were carried out under pressures ranging from 120 to 270 bar and temperatures ranging from 308 to 338 K. Three distinct modeling approaches were used to predict and correlate the experimentally determined solubility of paclitaxel: (i) a collection of six density-based empirical models; (ii) a hybrid of the Peng-Robinson (PR) equation of state and the van der Waals quadratic mixing rule; and (iii) machine learning procedures, including fifteen non-linear regressions. A solubility range of 0.0017 to 0.077 g/L was observed for paclitaxel. At a steady temperature, the paclitaxel mole fraction increased as the pressure rose, albeit a crossover occurrence was noted. While all methods achieved adequate levels of correlation accuracy, the Méndez-Santiago & Teja (MT) model outperformed the others in terms of predictive power, with an AARD of only 4.06%. For the first time semi-empirical correlations were used to estimate the paclitaxel/Sc-CO2 system enthalpies as ΔHtot = 28.04 kJ/mol, ΔHsol = −19.11 kJ/mol, and, ΔHvap = 47.15 kJ/mol.
为了促进超临界流体(SCF)工艺的有效设计,获得环境友好型溶剂(如加压二氧化碳(CO2))中的溶解度数据是必不可少的。溶解度评估是评估SCF技术的关键第一步。本文介绍了一种统计方法来实验测定紫杉醇(Pac)在超临界CO2中的溶解度。紫外-可见分光光度法研究在120至270巴的压力和308至338 K的温度范围下进行。三种不同的建模方法用于预测和关联实验确定的紫杉醇溶解度:(i)六个基于密度的经验模型的集合;(ii) Peng-Robinson (PR)状态方程与van der Waals二次混合规则的混合;(iii)机器学习程序,包括15个非线性回归。紫杉醇的溶解度为0.0017 ~ 0.077 g/L。在稳定的温度下,紫杉醇摩尔分数随着压力的增加而增加,尽管注意到交叉发生。虽然所有的方法都达到了足够的相关精度水平,但msamudez - santiago &; Teja (MT)模型在预测能力方面优于其他方法,AARD仅为4.06%。本文首次采用半经验相关法估计了紫杉醇/Sc-CO2体系焓分别为ΔHtot = 28.04 kJ/mol, ΔHsol =−19.11 kJ/mol, ΔHvap = 47.15 kJ/mol。
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Case Studies in Thermal Engineering
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