This research conducts a comprehensive experimental study of a solar distillation configuration enhanced with phase change material and internal electric fans, in a single-slope solar stills. Despite their operational simplicity, conventional single-slope solar stills are fundamentally limited by low distillate yields due to significant thermal losses and the formation of a stagnant vapor boundary layer that impedes efficient mass transfer. An experimental arrangement was constructed and tested at Faculty of Engineering, Sinai University, Egypt, and analyzed using 11-E framework, which encompasses assessments of energetic, exergetic, economic, environmental, and sustainability aspects. Four operating scenarios were examined: (i) conventional solar still (CSS), (ii) Enhanced solar still with fans only (ESSF), (iii) Enhanced solar still with paraffin wax only (ESSP), and (iv) Enhanced solar still with both paraffin wax and fans (ESSPF). The results indicated that integrating PCM beneath the absorber plate extended operation into post-sunset hours by providing latent heat storage. At the same time, fans improved internal convection, accelerated vapor transport, and enhanced condensation. The combined configuration (ESSPF) yielded the highest performance, with a supreme daily freshwater productivity of 5.26 ± 0.01 kg/m2, representing an 87.90 ± 0.01% increase compared with the conventional one. Energy and exergy productivity rates for ESSPF reached 49 ± 0.05% and 2.0 ± 0.05%, respectively, while the water production cost decreased to 0.00772 $/L, resulting in a reduced payback period of 5.25 months. An environmental analysis confirmed a substantial decrease in CO2 emissions resulting from a decrease in dependence on traditional fuel-based water production. Furthermore, sustainability and improvement potential indices indicated that the enhanced stills provide a more viable long-term solution. Overall, the integration of paraffin wax and internal fans provides a cost-effective, reliable, and scalable modification to conventional solar stills, supporting global strategies for sustainable and environmentally friendly water desalination.
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