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Corrigendum to "Rapid molecular diagnostic method for Gardnerella vaginalis based on CRISPR-Cas12a and recombinase-aided amplification (RAA)" [Clin. Chim. Acta 579 (2025) 120625]. “基于CRISPR-Cas12a和重组酶辅助扩增(RAA)的阴道加德纳菌快速分子诊断方法”的勘误表[临床]。詹。学报579(2025)120625]。
IF 2.9 3区 医学 Q2 MEDICAL LABORATORY TECHNOLOGY Pub Date : 2026-01-15 Epub Date: 2025-10-17 DOI: 10.1016/j.cca.2025.120645
Tong Jiang, Chuang Zhang, Daqing Wang, Zijing Guo, Yong Guo, Hua Liu, Zhuo Wang
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引用次数: 0
Psychological distress and mental health service use trends in Japan (2013-2022): Focusing on the change before and after the COVID-19 pandemic. 日本心理困扰和心理健康服务使用趋势(2013-2022年):关注COVID-19大流行前后的变化
IF 4.9 2区 医学 Q1 CLINICAL NEUROLOGY Pub Date : 2026-01-15 Epub Date: 2025-10-20 DOI: 10.1016/j.jad.2025.120398
Natsu Sasaki, Asuka Takae, Hiroki Asaoka, Naoaki Kuroda, Hiroshi Yatsuya, Nanami Nishio, Takahiro Tabuchi, Daisuke Nishi

This study investigated trends in psychological distress and mental health service use in Japan before and after the COVID-19 pandemic using nationally representative data from the Comprehensive Survey of Living Conditions (2013-2022). Psychological distress was assessed using the Japanese version of the Kessler 6 Scale, with scores of 5-12 indicating moderate distress and scores of ≥13 indicating high distress. Mental health service use was defined as regular visits to hospitals or clinics for depression or other psychological disorders. Analysis of data from 1,765,102 participants revealed that while the prevalence of moderate distress decreased from 24.9 % in 2019 to 21.8 % in 2022, the prevalence of high distress increased from 4.7 % to 5.0 % over the same period. Notably, increases in high distress were most prominent among aged 35-49 population. Cross-sectionally, women aged 26-34 showed highest prevalence of high distress (7.6 %). Additionally, mental health service use rose markedly, especially among young adults with high distress, with women consistently reporting higher distress and service utilization than men. These findings suggest a polarization in psychological distress in Japan, with a decline in moderate symptoms concurrent with a rise in severe distress, highlighting emerging gaps in mental health care. The results underscore the need for targeted interventions and the expansion of accessible, diverse mental health services to address unmet needs, particularly among vulnerable subgroups including young women and middle-aged population.

本研究使用生活条件综合调查(2013-2022年)的全国代表性数据,调查了日本在COVID-19大流行前后的心理困扰和心理健康服务使用趋势。使用日本版的Kessler 6量表评估心理困扰,得分5-12表示中度困扰,得分≥13表示高度困扰。心理健康服务的使用被定义为定期去医院或诊所治疗抑郁症或其他心理障碍。对来自1,765,102名参与者的数据的分析显示,虽然中度痛苦的患病率从2019年的24.9% %下降到2022年的21.8% %,但同期高度痛苦的患病率从4.7% %上升到5.0% %。值得注意的是,高度痛苦的增加在35-49岁的人群中最为明显。横断面上,26-34岁的女性表现出最高的患病率(7.6% %)。此外,心理健康服务的使用显著增加,特别是在高度痛苦的年轻人中,女性报告的痛苦和服务使用率始终高于男性。这些研究结果表明,日本的心理困扰存在两极分化,中度症状减少的同时,严重的困扰却在增加,这突显了精神卫生保健方面正在出现的差距。结果强调需要有针对性的干预措施和扩大可获得的多样化心理健康服务,以解决未满足的需求,特别是在包括青年妇女和中年人口在内的弱势亚群体中。
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引用次数: 0
Influence of childhood excess weight on cognitive, behavioural and emotional outcomes. 儿童期超重对认知、行为和情绪结果的影响。
IF 4.9 2区 医学 Q1 CLINICAL NEUROLOGY Pub Date : 2026-01-15 Epub Date: 2025-10-08 DOI: 10.1016/j.jad.2025.120410
Patricia González-Palacios, Viviana Ramírez, José Joaquín Muros, Pablo José González-Domenech, Miguel Ángel Baca, Celia Monteagudo, Ana Rivas

Background: Obesity, considered a worldwide epidemic, generate great interest to the scientific community due to its impact on public health. Particularly in children because of their vulnerability. In view of the bidirectional relationship between obesity and neurodevelopmental aspects, this study aims to evaluate the effect of excess weight on cognitive and behavioural development.

Methods: A total of 130 Spanish children (3 to 12 years) were included. Cognitive function and behaviour were assessed using the validated Wechsler Intelligence Scale for Children-V (WISC-V) and Behaviour Assessment System for Children-3 (BASC-3) tests, respectively. Individuals were classified into groups according to body mass index (BMI) (normal weight and overweight/obesity). Multivariable logistic regression models were performed to address the influence of excess weight on cognitive-behavioural functioning.

Results: The results showed that infants who had overweight/obesity were more likely to have lower scores on the full-scale intelligence quotient (FSIQ: OR adjusted = 3.81, p = 0.006), verbal comprehension (VCI: OR adjusted = 2.57, p = 0.045), fluid reasoning (FRI: OR adjusted = 2.79, p value = 0.030) and working memory index (WMI: OR adjusted = 3.59, p = 0.008). No statistically significant results were found between excess weight and behavioural outcomes after adjustment for confounding factors. Secondly, Spearman's correlation analyses revealed a set of inverse correlations between cognitive ability and various behavioural and emotional problems, especially in cases group.

Conclusions: In conclusion, excess weight may be negatively associated with a worse cognitive performance. Further, poorer cognitive function may lead to greater vulnerability to neurobehavioral disturbances in children with excess weight. These results underscore the need of further investigation.

背景:肥胖被认为是一种世界性的流行病,由于它对公众健康的影响,引起了科学界的极大兴趣。尤其是儿童,因为他们很脆弱。鉴于肥胖与神经发育方面的双向关系,本研究旨在评估超重对认知和行为发展的影响。方法:共纳入130名西班牙儿童(3 ~ 12岁)。认知功能和行为分别采用经验证的韦氏儿童智力量表- v (WISC-V)和儿童行为评估系统-3 (BASC-3)测试进行评估。根据身体质量指数(BMI)(正常体重和超重/肥胖)将个体分为几组。采用多变量逻辑回归模型来解决超重对认知行为功能的影响。结果:超重/肥胖婴儿在全面智商(FSIQ: OR调整值= 3.81,p = 0.006)、言语理解(VCI: OR调整值= 2.57,p = 0.045)、流体推理(FRI: OR调整值= 2.79,p值= 0.030)和工作记忆指数(WMI: OR调整值= 3.59,p = 0.008)得分较低。在调整混杂因素后,没有发现超重和行为结果之间有统计学意义的结果。其次,Spearman的相关分析揭示了认知能力与各种行为和情绪问题之间的一系列负相关关系,特别是在个案组中。结论:总之,超重可能与认知能力下降负相关。此外,较差的认知功能可能导致超重儿童更容易受到神经行为障碍的影响。这些结果强调了进一步调查的必要性。
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引用次数: 0
Photo-responsive Fe single-atom dispersed FeNC-C3N4 electrocatalysts with Schottky heterojunction for photo-enhanced zinc-air batteries. 具有Schottky异质结的光响应Fe单原子分散fen - c3n4电催化剂用于光增强锌空气电池。
IF 9.7 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-01-15 Epub Date: 2025-09-08 DOI: 10.1016/j.jcis.2025.138982
Yang Zhang, Xiaoqian Xu, Yi Yang, Xi Luo, Kai Yang, Momo Safari, Haitao Huang, Jinli Qiao

Directly integrating solar energy into zinc-air batteries (ZABs) systems represents an eco-friendly, efficient and low-cost strategy, yet the rational design of photo-enhanced ZABs for high-performance solar energy utilization continues to pose a significant scientific challenge. Herein, the FeNC-C3N4 photo-electrocatalyst with Schottky heterojunction is fabricated through a facile "ball-milling and spray-coating" approach, which effectively integrates FeNC with graphitic carbon nitride (g-C3N4). Among them, g-C3N4 functions as a photoactive catalytic material, whereas FeNC serves as an efficient electroactive layer that promotes interfacial electron transfer from g-C3N4 under illumination, thereby improving the spatial separation of photogenerated carriers and extending their lifetime. Remarkably, in comparison with FeNC-based ZABs (370.53 mWcm-2 and 228 h), FeNC-C3N4-based ZABs demonstrate a record-high power density of 540.58 mW cm-2 under illumination, along with stable charge-discharge cycling over 1028 h at 10 mA cm-2, representing the highest performance reported to date for photo-enhanced ZABs (PZABs). More importantly, when operated at 10 mA cm-2 under illumination, the g-C3N4-modified FeNC-C3N4-based PZABs achieve a significantly reduced charging voltage of ∼1.94 V, in stark contrast to the conventional FeNC-based ZABs (∼2.09 V), corresponding to a notable voltage reduction of ∼0.15 V. This work offers a straightforward strategy for developing photo-enhanced ZABs that efficiently harness solar energy to reduce the charging voltage of conventional ZABs.

将太阳能直接集成到锌空气电池(ZABs)系统中是一种环保、高效和低成本的策略,但合理设计用于高性能太阳能利用的光增强ZABs仍然是一个重大的科学挑战。本文通过简单的“球磨和喷涂”方法制备了具有Schottky异质结的fen - c3n4光电催化剂,有效地将fen - c3n4与石墨化氮化碳(g-C3N4)结合在一起。其中,g-C3N4作为光活性催化材料,而FeNC作为高效电活性层,促进g-C3N4在光照下的界面电子转移,从而改善光生载流子的空间分离,延长其寿命。值得注意的是,与基于fencc3n4的ZABs (370.53 mWcm-2和228 h)相比,基于fencc3n4的ZABs在光照下表现出创纪录的高功率密度540.58 mWcm-2,以及在10 mA cm-2下1028 h的稳定充放电循环,代表了迄今为止报道的光增强ZABs (PZABs)的最高性能。更重要的是,当在10 mA cm-2的光照下工作时,g- c3n4修饰的基于fencc3n4的PZABs的充电电压显著降低了~ 1.94 V,与传统的基于fenczabs (~ 2.09 V)形成鲜明对比,相当于显著降低了~ 0.15 V的电压。这项工作为开发光增强ZABs提供了一种直接的策略,该策略可以有效地利用太阳能来降低传统ZABs的充电电压。
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引用次数: 0
Concerns regarding scope and methodological framing in "Mining the risk factors for stroke occurrence and dietary protective factors based on the NHANES database: Analysis using SHAP". 对“基于NHANES数据库挖掘中风发生的危险因素和饮食保护因素:使用SHAP分析”的范围和方法框架的关注。
IF 4.9 2区 医学 Q1 CLINICAL NEUROLOGY Pub Date : 2026-01-15 Epub Date: 2025-07-21 DOI: 10.1016/j.jad.2025.119963
Juan Manuel Marquez-Romero
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引用次数: 0
Associations between multiple neurodevelopmental disorders and mental health in children. 儿童多重神经发育障碍与心理健康的关系
IF 4.9 2区 医学 Q1 CLINICAL NEUROLOGY Pub Date : 2026-01-15 Epub Date: 2025-10-08 DOI: 10.1016/j.jad.2025.120397
Xiaoyun Zhou, Frank Jia, Matthew Bambling, Sisira Edirippulige, Harvey Whiteford, Jialing Lin

Objective: This study investigated the association between multiple NDDs and the prevalence and severity of current depression and anxiety among children aged 3-17 years.

Methods: We analyzed parent- or caregiver-reported data from 2016 to 2023 US National Survey of Children's Health. Children aged 3-17 years were included. We considered a broader spectrum of NDDs by including behavioral problems and grouped children based on the number of NDDs (out of ten): no multiple NDDs (none or one NDD), two NDDs, three NDDs, four NDDs, and five or more NDDs. Four mental health outcomes were measured: depression (yes/no), anxiety (yes/no), depression severity (mild/moderate/severe), and anxiety severity (mild/moderate/severe). Multinomial logistic regression models were used.

Results: Among 267,044 children (mean age = 10.2 years; male = 51.8 %), 10.6 % had multiple NDDs. The increasing number of co-occurring NDDs was associated with higher odds of prevalence and severity of depression and anxiety. Children with multiple NDDs were 4.7-5.3 times more likely to have depression and 5.8-12.9 times more likely to have anxiety compared with those without multiple NDDs. These positive associations remained consistent for mild or moderate depression (adjusted odds ratios [ORs]: 5.0-5.6) and for mild or moderate anxiety (adjusted ORs: 5.6-8.9). The associations were more pronounced for severe mental health conditions, with children being 7.8-16.9 times more likely to experience severe depression and 8.1-34.9 times more likely to experience severe anxiety.

Conclusions: The cumulative mental health burden associated with multiple NDDs emphasizes the need for integrated screening and tailored interventions to support this population.

目的:探讨3-17岁儿童多重ndd与当前抑郁、焦虑患病率及严重程度的关系。方法:我们分析了2016年至2023年美国全国儿童健康调查中父母或照顾者报告的数据。包括3-17岁的儿童。我们考虑了更广泛的NDD范围,包括行为问题,并根据NDD的数量(十分之十)对儿童进行分组:没有多个NDD(没有或一个NDD),两个NDD,三个NDD,四个NDD,五个或更多NDD。测量了四种心理健康结果:抑郁(是/否)、焦虑(是/否)、抑郁严重程度(轻度/中度/严重)和焦虑严重程度(轻度/中度/严重)。采用多项逻辑回归模型。结果:267044名儿童(平均年龄10.2岁,男性51.8%)中,10.6%患有多发性ndd。同时发生的ndd数量的增加与抑郁和焦虑的患病率和严重程度的增加有关。与没有多种ndd的儿童相比,患有多种ndd的儿童患抑郁症的可能性高出4.7-5.3倍,患焦虑症的可能性高出5.8-12.9倍。这些正相关在轻度或中度抑郁(校正比值比[or]: 5.0-5.6)和轻度或中度焦虑(校正比值比:5.6-8.9)中保持一致。这种关联在严重的精神健康状况中更为明显,儿童患严重抑郁症的可能性是其7.8-16.9倍,患严重焦虑的可能性是其8.1-34.9倍。结论:与多种ndd相关的累积精神健康负担强调需要进行综合筛查和量身定制的干预措施来支持这一人群。
{"title":"Associations between multiple neurodevelopmental disorders and mental health in children.","authors":"Xiaoyun Zhou, Frank Jia, Matthew Bambling, Sisira Edirippulige, Harvey Whiteford, Jialing Lin","doi":"10.1016/j.jad.2025.120397","DOIUrl":"10.1016/j.jad.2025.120397","url":null,"abstract":"<p><strong>Objective: </strong>This study investigated the association between multiple NDDs and the prevalence and severity of current depression and anxiety among children aged 3-17 years.</p><p><strong>Methods: </strong>We analyzed parent- or caregiver-reported data from 2016 to 2023 US National Survey of Children's Health. Children aged 3-17 years were included. We considered a broader spectrum of NDDs by including behavioral problems and grouped children based on the number of NDDs (out of ten): no multiple NDDs (none or one NDD), two NDDs, three NDDs, four NDDs, and five or more NDDs. Four mental health outcomes were measured: depression (yes/no), anxiety (yes/no), depression severity (mild/moderate/severe), and anxiety severity (mild/moderate/severe). Multinomial logistic regression models were used.</p><p><strong>Results: </strong>Among 267,044 children (mean age = 10.2 years; male = 51.8 %), 10.6 % had multiple NDDs. The increasing number of co-occurring NDDs was associated with higher odds of prevalence and severity of depression and anxiety. Children with multiple NDDs were 4.7-5.3 times more likely to have depression and 5.8-12.9 times more likely to have anxiety compared with those without multiple NDDs. These positive associations remained consistent for mild or moderate depression (adjusted odds ratios [ORs]: 5.0-5.6) and for mild or moderate anxiety (adjusted ORs: 5.6-8.9). The associations were more pronounced for severe mental health conditions, with children being 7.8-16.9 times more likely to experience severe depression and 8.1-34.9 times more likely to experience severe anxiety.</p><p><strong>Conclusions: </strong>The cumulative mental health burden associated with multiple NDDs emphasizes the need for integrated screening and tailored interventions to support this population.</p>","PeriodicalId":14963,"journal":{"name":"Journal of affective disorders","volume":"393 Pt A","pages":"120397"},"PeriodicalIF":4.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145274623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Excellent high-temperature breakdown and energy storage performances of polyetherimide dielectric film with silver/alumina nanosheets derived from sequential bimetallic ion exchange. 序贯双金属离子交换制备的银/氧化铝纳米片聚醚酰亚胺介质薄膜具有优异的高温击穿和储能性能。
IF 9.7 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-01-15 Epub Date: 2025-09-03 DOI: 10.1016/j.jcis.2025.138912
Xuyuan Fan, Shuimiao Xia, Lihao Yang, Guanfei Liu, Jie Huang, Yao Liu, Zhicheng Shi

Polymer dielectrics have attracted substantial attention for their extensive applications in advanced electronic power systems. However, their practical implementation is substantially hindered by the drastic deterioration in breakdown strength and energy storage capabilities at elevated temperatures. Herein, corrugated alumina (Al2O3) nanosheets anchored with uniformly dispersed silver nanoparticles (AgNPs) are fabricated via a sequential bimetallic ion exchange method using polyimide (PI) film as the sacrificing template. The AgNPs and Al2O3 nanosheets (AONSs) are in-situ formed on the molecular chain of PI in one step, which not only avoids the aggregation of AgNPs but also ensures the high purity of the AgNPs@AONSs. Benefiting from the excellent high-temperature insulating properties of Al2O3 and the Coulomb blockade effect of AgNPs, when the AgNPs@AONSs are incorporated into polymer dielectrics, they can act as powerful charge transport buffer strips and improve the breakdown strength. The polyetherimide film filled with merely 0.1 wt% AgNPs@AONSs shows ultra-high energy densities of 10.22 J cm-3 at 150 °C with 90 % efficiency and 7.49 J cm-3 at 200 °C with 80 % efficiency, which are 542 % and 226 % that of the pristine polyetherimide, respectively. The excellent high-temperature performances of the composite films make them promising candidates for high-temperature pulsed power systems.

聚合物电介质在先进电子电力系统中的广泛应用引起了人们的广泛关注。然而,它们的实际实施受到高温下击穿强度和能量储存能力急剧恶化的严重阻碍。本文以聚酰亚胺(PI)薄膜为牺牲模板,通过顺序双金属离子交换法制备了以均匀分散的银纳米粒子(AgNPs)为锚定的波纹氧化铝(Al2O3)纳米片。在PI分子链上一步形成AgNPs和Al2O3纳米片(AONSs),既避免了AgNPs的聚集,又保证了AgNPs@AONSs的高纯度。利用Al2O3优异的高温绝缘性能和AgNPs的库仑阻断效应,AgNPs@AONSs加入到聚合物电介质中,可以作为强大的电荷传输缓冲带,提高击穿强度。0.1% wt% AgNPs@AONSs填充的聚醚酰亚胺薄膜在150°C和200°C分别显示出10.22 J cm-3和7.49 J cm-3的超高能量密度,效率分别为90%和80%,分别是原始聚醚酰亚胺的54.2%和226%。复合薄膜优异的高温性能使其成为高温脉冲电源系统的理想候选材料。
{"title":"Excellent high-temperature breakdown and energy storage performances of polyetherimide dielectric film with silver/alumina nanosheets derived from sequential bimetallic ion exchange.","authors":"Xuyuan Fan, Shuimiao Xia, Lihao Yang, Guanfei Liu, Jie Huang, Yao Liu, Zhicheng Shi","doi":"10.1016/j.jcis.2025.138912","DOIUrl":"10.1016/j.jcis.2025.138912","url":null,"abstract":"<p><p>Polymer dielectrics have attracted substantial attention for their extensive applications in advanced electronic power systems. However, their practical implementation is substantially hindered by the drastic deterioration in breakdown strength and energy storage capabilities at elevated temperatures. Herein, corrugated alumina (Al<sub>2</sub>O<sub>3</sub>) nanosheets anchored with uniformly dispersed silver nanoparticles (AgNPs) are fabricated via a sequential bimetallic ion exchange method using polyimide (PI) film as the sacrificing template. The AgNPs and Al<sub>2</sub>O<sub>3</sub> nanosheets (AONSs) are in-situ formed on the molecular chain of PI in one step, which not only avoids the aggregation of AgNPs but also ensures the high purity of the AgNPs@AONSs. Benefiting from the excellent high-temperature insulating properties of Al<sub>2</sub>O<sub>3</sub> and the Coulomb blockade effect of AgNPs, when the AgNPs@AONSs are incorporated into polymer dielectrics, they can act as powerful charge transport buffer strips and improve the breakdown strength. The polyetherimide film filled with merely 0.1 wt% AgNPs@AONSs shows ultra-high energy densities of 10.22 J cm<sup>-3</sup> at 150 °C with 90 % efficiency and 7.49 J cm<sup>-3</sup> at 200 °C with 80 % efficiency, which are 542 % and 226 % that of the pristine polyetherimide, respectively. The excellent high-temperature performances of the composite films make them promising candidates for high-temperature pulsed power systems.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"702 Pt 1","pages":"138912"},"PeriodicalIF":9.7,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145005762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Retraction notice to "Oxygen vacancies enhancing hierarchical NiCo2S4@MnO2 electrode for flexible asymmetric supercapacitors" [J. Colloid Interface Sci. 678(Part B) (2025) 902-914]. “氧空位增强层次化NiCo2S4@MnO2柔性非对称超级电容器电极”的撤回通知[J]。胶体界面科学,678(B部分)(2025)902-914]。
IF 9.7 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-01-15 Epub Date: 2025-09-27 DOI: 10.1016/j.jcis.2025.139114
Qianwen Liu, Chengjingmeng Zhang, Ruidong Li, Jie Li, Bingyue Zheng, Shuxin Song, Lihua Chen, Tingxi Li, Yong Ma
{"title":"Retraction notice to \"Oxygen vacancies enhancing hierarchical NiCo<sub>2</sub>S<sub>4</sub>@MnO<sub>2</sub> electrode for flexible asymmetric supercapacitors\" [J. Colloid Interface Sci. 678(Part B) (2025) 902-914].","authors":"Qianwen Liu, Chengjingmeng Zhang, Ruidong Li, Jie Li, Bingyue Zheng, Shuxin Song, Lihua Chen, Tingxi Li, Yong Ma","doi":"10.1016/j.jcis.2025.139114","DOIUrl":"10.1016/j.jcis.2025.139114","url":null,"abstract":"","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"702 Pt 2","pages":"139114"},"PeriodicalIF":9.7,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145184383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to "Soluble thrombomodulin in preeclampsia: A systematic review and meta-analysis". [Clin. Chimica Acta 549 (2024) 120323]. “可溶性血栓调节素在子痫前期:一项系统综述和荟萃分析”的更正。(中国。化学学报549(2024):120323。
IF 2.9 3区 医学 Q2 MEDICAL LABORATORY TECHNOLOGY Pub Date : 2026-01-15 Epub Date: 2025-09-12 DOI: 10.1016/j.cca.2025.120589
Jesiel Francisco de Jesus Fernandes Martins Lima, Thaíse Emilia Moreira da Silva, Ana Cristina Dos Santos Lopes, Victor Antonio Ferreira Freire, Melina Barros-Pinheiro, Patrícia Nessralla Alpoim
{"title":"Corrigendum to \"Soluble thrombomodulin in preeclampsia: A systematic review and meta-analysis\". [Clin. Chimica Acta 549 (2024) 120323].","authors":"Jesiel Francisco de Jesus Fernandes Martins Lima, Thaíse Emilia Moreira da Silva, Ana Cristina Dos Santos Lopes, Victor Antonio Ferreira Freire, Melina Barros-Pinheiro, Patrícia Nessralla Alpoim","doi":"10.1016/j.cca.2025.120589","DOIUrl":"10.1016/j.cca.2025.120589","url":null,"abstract":"","PeriodicalId":10205,"journal":{"name":"Clinica Chimica Acta","volume":" ","pages":"120589"},"PeriodicalIF":2.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145058338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Orbital energy level engineering: 3d high-spin Mn's d-electron mediating electronic structure of VO2 boosting highly durable aqueous ammonium ion batteries. 轨道能级工程:三维高自旋Mn的d电子介导VO2的电子结构,促进高耐用的水铵离子电池。
IF 9.7 1区 化学 Q1 CHEMISTRY, PHYSICAL Pub Date : 2026-01-15 Epub Date: 2025-08-30 DOI: 10.1016/j.jcis.2025.138826
Zhenhua Zhou, Miao Cui, Tianming Lv, Jian Cao, Ziqi Ren, Yi Zhong, HongXin Zhao, Hongye Zheng, Yifu Zhang, Yang Wang, Changgong Meng

Aqueous batteries have become a prospective future energy storage system because of their low coefficient of cost and stability. However, their lower energy density limits their applications. Ammonium ions (NH4+) have a small hydration radius and light molar mass, and aqueous ammonium ion batteries (AAIBs) are anticipated for solving the inherent low-energy density problem of aqueous batteries. Exploring highly performing storage materials for aqueous ammonium ion batteries continues to be a research hotspot in recent years. Here, we propose a strategy to regulate the tunneling vanadium oxide' structure (VOM) based on the electron-mediated orbital-energy level synergistic strategy of the high-spin 3d transition metal (Mn) to assist AAIBs to achieve high energy density. The VOM has a capacity of up to 270 mAh g-1 at a current density of 0.2 A g-1, and the battery system containing poly(ammonium benzene) (PANI) (named VOM//PANI) has an energy density of up to 63.5 Wh kg-1. At the same time, we demonstrate the chemical energy storage mechanism of hydrogen bonding and the kinetics of interfacial chemical reactions in VOM based on a series of ex-situ or in-situ tests. Density-functional theory (DFT) calculations and experiments demonstrate that the introduction of high-spin transition metals can directionally regulate and optimize the electronic structure of V, which helps to achieve efficient NH4+ storage. This work offers novel concepts for the advancement of high-performance AAIBs as energy storage materials, as well as new strategies for the future large-scale grid-level applications of AAIBs.

水电池因其低成本系数和稳定性而成为未来很有前景的储能系统。然而,它们较低的能量密度限制了它们的应用。铵离子(NH4+)具有水化半径小、摩尔质量轻的特点,有望解决水电池固有的低能量密度问题。探索高性能的水铵离子电池存储材料一直是近年来的研究热点。本文提出了一种基于高自旋三维过渡金属(Mn)电子介导的轨道-能级协同策略调控氧化钒隧穿结构(VOM)的策略,以帮助AAIBs实现高能量密度。在电流密度为0.2 a g-1时,VOM的容量高达270 mAh g-1,而含有聚苯铵(PANI)(命名为VOM//PANI)的电池系统的能量密度高达63.5 Wh kg-1。同时,通过一系列非原位或原位实验,我们论证了VOM中氢键的化学能储存机理和界面化学反应动力学。密度泛函理论(DFT)计算和实验表明,引入高自旋过渡金属可以定向调节和优化V的电子结构,有助于实现高效的NH4+存储。这项工作为高性能AAIBs作为储能材料的发展提供了新的概念,也为未来AAIBs的大规模电网应用提供了新的策略。
{"title":"Orbital energy level engineering: 3d high-spin Mn's d-electron mediating electronic structure of VO<sub>2</sub> boosting highly durable aqueous ammonium ion batteries.","authors":"Zhenhua Zhou, Miao Cui, Tianming Lv, Jian Cao, Ziqi Ren, Yi Zhong, HongXin Zhao, Hongye Zheng, Yifu Zhang, Yang Wang, Changgong Meng","doi":"10.1016/j.jcis.2025.138826","DOIUrl":"10.1016/j.jcis.2025.138826","url":null,"abstract":"<p><p>Aqueous batteries have become a prospective future energy storage system because of their low coefficient of cost and stability. However, their lower energy density limits their applications. Ammonium ions (NH<sub>4</sub><sup>+</sup>) have a small hydration radius and light molar mass, and aqueous ammonium ion batteries (AAIBs) are anticipated for solving the inherent low-energy density problem of aqueous batteries. Exploring highly performing storage materials for aqueous ammonium ion batteries continues to be a research hotspot in recent years. Here, we propose a strategy to regulate the tunneling vanadium oxide' structure (VOM) based on the electron-mediated orbital-energy level synergistic strategy of the high-spin 3d transition metal (Mn) to assist AAIBs to achieve high energy density. The VOM has a capacity of up to 270 mAh g<sup>-1</sup> at a current density of 0.2 A g<sup>-1</sup>, and the battery system containing poly(ammonium benzene) (PANI) (named VOM//PANI) has an energy density of up to 63.5 Wh kg<sup>-1</sup>. At the same time, we demonstrate the chemical energy storage mechanism of hydrogen bonding and the kinetics of interfacial chemical reactions in VOM based on a series of ex-situ or in-situ tests. Density-functional theory (DFT) calculations and experiments demonstrate that the introduction of high-spin transition metals can directionally regulate and optimize the electronic structure of V, which helps to achieve efficient NH<sub>4</sub><sup>+</sup> storage. This work offers novel concepts for the advancement of high-performance AAIBs as energy storage materials, as well as new strategies for the future large-scale grid-level applications of AAIBs.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"702 Pt 1","pages":"138826"},"PeriodicalIF":9.7,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145028666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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