This study investigated trends in psychological distress and mental health service use in Japan before and after the COVID-19 pandemic using nationally representative data from the Comprehensive Survey of Living Conditions (2013-2022). Psychological distress was assessed using the Japanese version of the Kessler 6 Scale, with scores of 5-12 indicating moderate distress and scores of ≥13 indicating high distress. Mental health service use was defined as regular visits to hospitals or clinics for depression or other psychological disorders. Analysis of data from 1,765,102 participants revealed that while the prevalence of moderate distress decreased from 24.9 % in 2019 to 21.8 % in 2022, the prevalence of high distress increased from 4.7 % to 5.0 % over the same period. Notably, increases in high distress were most prominent among aged 35-49 population. Cross-sectionally, women aged 26-34 showed highest prevalence of high distress (7.6 %). Additionally, mental health service use rose markedly, especially among young adults with high distress, with women consistently reporting higher distress and service utilization than men. These findings suggest a polarization in psychological distress in Japan, with a decline in moderate symptoms concurrent with a rise in severe distress, highlighting emerging gaps in mental health care. The results underscore the need for targeted interventions and the expansion of accessible, diverse mental health services to address unmet needs, particularly among vulnerable subgroups including young women and middle-aged population.
{"title":"Psychological distress and mental health service use trends in Japan (2013-2022): Focusing on the change before and after the COVID-19 pandemic.","authors":"Natsu Sasaki, Asuka Takae, Hiroki Asaoka, Naoaki Kuroda, Hiroshi Yatsuya, Nanami Nishio, Takahiro Tabuchi, Daisuke Nishi","doi":"10.1016/j.jad.2025.120398","DOIUrl":"10.1016/j.jad.2025.120398","url":null,"abstract":"<p><p>This study investigated trends in psychological distress and mental health service use in Japan before and after the COVID-19 pandemic using nationally representative data from the Comprehensive Survey of Living Conditions (2013-2022). Psychological distress was assessed using the Japanese version of the Kessler 6 Scale, with scores of 5-12 indicating moderate distress and scores of ≥13 indicating high distress. Mental health service use was defined as regular visits to hospitals or clinics for depression or other psychological disorders. Analysis of data from 1,765,102 participants revealed that while the prevalence of moderate distress decreased from 24.9 % in 2019 to 21.8 % in 2022, the prevalence of high distress increased from 4.7 % to 5.0 % over the same period. Notably, increases in high distress were most prominent among aged 35-49 population. Cross-sectionally, women aged 26-34 showed highest prevalence of high distress (7.6 %). Additionally, mental health service use rose markedly, especially among young adults with high distress, with women consistently reporting higher distress and service utilization than men. These findings suggest a polarization in psychological distress in Japan, with a decline in moderate symptoms concurrent with a rise in severe distress, highlighting emerging gaps in mental health care. The results underscore the need for targeted interventions and the expansion of accessible, diverse mental health services to address unmet needs, particularly among vulnerable subgroups including young women and middle-aged population.</p>","PeriodicalId":14963,"journal":{"name":"Journal of affective disorders","volume":" ","pages":"120398"},"PeriodicalIF":4.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145258443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-15Epub Date: 2025-10-08DOI: 10.1016/j.jad.2025.120410
Patricia González-Palacios, Viviana Ramírez, José Joaquín Muros, Pablo José González-Domenech, Miguel Ángel Baca, Celia Monteagudo, Ana Rivas
Background: Obesity, considered a worldwide epidemic, generate great interest to the scientific community due to its impact on public health. Particularly in children because of their vulnerability. In view of the bidirectional relationship between obesity and neurodevelopmental aspects, this study aims to evaluate the effect of excess weight on cognitive and behavioural development.
Methods: A total of 130 Spanish children (3 to 12 years) were included. Cognitive function and behaviour were assessed using the validated Wechsler Intelligence Scale for Children-V (WISC-V) and Behaviour Assessment System for Children-3 (BASC-3) tests, respectively. Individuals were classified into groups according to body mass index (BMI) (normal weight and overweight/obesity). Multivariable logistic regression models were performed to address the influence of excess weight on cognitive-behavioural functioning.
Results: The results showed that infants who had overweight/obesity were more likely to have lower scores on the full-scale intelligence quotient (FSIQ: OR adjusted = 3.81, p = 0.006), verbal comprehension (VCI: OR adjusted = 2.57, p = 0.045), fluid reasoning (FRI: OR adjusted = 2.79, p value = 0.030) and working memory index (WMI: OR adjusted = 3.59, p = 0.008). No statistically significant results were found between excess weight and behavioural outcomes after adjustment for confounding factors. Secondly, Spearman's correlation analyses revealed a set of inverse correlations between cognitive ability and various behavioural and emotional problems, especially in cases group.
Conclusions: In conclusion, excess weight may be negatively associated with a worse cognitive performance. Further, poorer cognitive function may lead to greater vulnerability to neurobehavioral disturbances in children with excess weight. These results underscore the need of further investigation.
{"title":"Influence of childhood excess weight on cognitive, behavioural and emotional outcomes.","authors":"Patricia González-Palacios, Viviana Ramírez, José Joaquín Muros, Pablo José González-Domenech, Miguel Ángel Baca, Celia Monteagudo, Ana Rivas","doi":"10.1016/j.jad.2025.120410","DOIUrl":"10.1016/j.jad.2025.120410","url":null,"abstract":"<p><strong>Background: </strong>Obesity, considered a worldwide epidemic, generate great interest to the scientific community due to its impact on public health. Particularly in children because of their vulnerability. In view of the bidirectional relationship between obesity and neurodevelopmental aspects, this study aims to evaluate the effect of excess weight on cognitive and behavioural development.</p><p><strong>Methods: </strong>A total of 130 Spanish children (3 to 12 years) were included. Cognitive function and behaviour were assessed using the validated Wechsler Intelligence Scale for Children-V (WISC-V) and Behaviour Assessment System for Children-3 (BASC-3) tests, respectively. Individuals were classified into groups according to body mass index (BMI) (normal weight and overweight/obesity). Multivariable logistic regression models were performed to address the influence of excess weight on cognitive-behavioural functioning.</p><p><strong>Results: </strong>The results showed that infants who had overweight/obesity were more likely to have lower scores on the full-scale intelligence quotient (FSIQ: OR adjusted = 3.81, p = 0.006), verbal comprehension (VCI: OR adjusted = 2.57, p = 0.045), fluid reasoning (FRI: OR adjusted = 2.79, p value = 0.030) and working memory index (WMI: OR adjusted = 3.59, p = 0.008). No statistically significant results were found between excess weight and behavioural outcomes after adjustment for confounding factors. Secondly, Spearman's correlation analyses revealed a set of inverse correlations between cognitive ability and various behavioural and emotional problems, especially in cases group.</p><p><strong>Conclusions: </strong>In conclusion, excess weight may be negatively associated with a worse cognitive performance. Further, poorer cognitive function may lead to greater vulnerability to neurobehavioral disturbances in children with excess weight. These results underscore the need of further investigation.</p>","PeriodicalId":14963,"journal":{"name":"Journal of affective disorders","volume":"393 Pt A","pages":"120410"},"PeriodicalIF":4.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145274615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-15Epub Date: 2025-09-08DOI: 10.1016/j.jcis.2025.138982
Yang Zhang, Xiaoqian Xu, Yi Yang, Xi Luo, Kai Yang, Momo Safari, Haitao Huang, Jinli Qiao
Directly integrating solar energy into zinc-air batteries (ZABs) systems represents an eco-friendly, efficient and low-cost strategy, yet the rational design of photo-enhanced ZABs for high-performance solar energy utilization continues to pose a significant scientific challenge. Herein, the FeNC-C3N4 photo-electrocatalyst with Schottky heterojunction is fabricated through a facile "ball-milling and spray-coating" approach, which effectively integrates FeNC with graphitic carbon nitride (g-C3N4). Among them, g-C3N4 functions as a photoactive catalytic material, whereas FeNC serves as an efficient electroactive layer that promotes interfacial electron transfer from g-C3N4 under illumination, thereby improving the spatial separation of photogenerated carriers and extending their lifetime. Remarkably, in comparison with FeNC-based ZABs (370.53 mWcm-2 and 228 h), FeNC-C3N4-based ZABs demonstrate a record-high power density of 540.58 mW cm-2 under illumination, along with stable charge-discharge cycling over 1028 h at 10 mA cm-2, representing the highest performance reported to date for photo-enhanced ZABs (PZABs). More importantly, when operated at 10 mA cm-2 under illumination, the g-C3N4-modified FeNC-C3N4-based PZABs achieve a significantly reduced charging voltage of ∼1.94 V, in stark contrast to the conventional FeNC-based ZABs (∼2.09 V), corresponding to a notable voltage reduction of ∼0.15 V. This work offers a straightforward strategy for developing photo-enhanced ZABs that efficiently harness solar energy to reduce the charging voltage of conventional ZABs.
{"title":"Photo-responsive Fe single-atom dispersed FeNC-C<sub>3</sub>N<sub>4</sub> electrocatalysts with Schottky heterojunction for photo-enhanced zinc-air batteries.","authors":"Yang Zhang, Xiaoqian Xu, Yi Yang, Xi Luo, Kai Yang, Momo Safari, Haitao Huang, Jinli Qiao","doi":"10.1016/j.jcis.2025.138982","DOIUrl":"10.1016/j.jcis.2025.138982","url":null,"abstract":"<p><p>Directly integrating solar energy into zinc-air batteries (ZABs) systems represents an eco-friendly, efficient and low-cost strategy, yet the rational design of photo-enhanced ZABs for high-performance solar energy utilization continues to pose a significant scientific challenge. Herein, the FeNC-C<sub>3</sub>N<sub>4</sub> photo-electrocatalyst with Schottky heterojunction is fabricated through a facile \"ball-milling and spray-coating\" approach, which effectively integrates FeNC with graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>). Among them, g-C<sub>3</sub>N<sub>4</sub> functions as a photoactive catalytic material, whereas FeNC serves as an efficient electroactive layer that promotes interfacial electron transfer from g-C<sub>3</sub>N<sub>4</sub> under illumination, thereby improving the spatial separation of photogenerated carriers and extending their lifetime. Remarkably, in comparison with FeNC-based ZABs (370.53 mWcm<sup>-2</sup> and 228 h), FeNC-C<sub>3</sub>N<sub>4</sub>-based ZABs demonstrate a record-high power density of 540.58 mW cm<sup>-2</sup> under illumination, along with stable charge-discharge cycling over 1028 h at 10 mA cm<sup>-2</sup>, representing the highest performance reported to date for photo-enhanced ZABs (PZABs). More importantly, when operated at 10 mA cm<sup>-2</sup> under illumination, the g-C<sub>3</sub>N<sub>4</sub>-modified FeNC-C<sub>3</sub>N<sub>4</sub>-based PZABs achieve a significantly reduced charging voltage of ∼1.94 V, in stark contrast to the conventional FeNC-based ZABs (∼2.09 V), corresponding to a notable voltage reduction of ∼0.15 V. This work offers a straightforward strategy for developing photo-enhanced ZABs that efficiently harness solar energy to reduce the charging voltage of conventional ZABs.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"702 Pt 2","pages":"138982"},"PeriodicalIF":9.7,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145084511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-15Epub Date: 2025-07-21DOI: 10.1016/j.jad.2025.119963
Juan Manuel Marquez-Romero
{"title":"Concerns regarding scope and methodological framing in \"Mining the risk factors for stroke occurrence and dietary protective factors based on the NHANES database: Analysis using SHAP\".","authors":"Juan Manuel Marquez-Romero","doi":"10.1016/j.jad.2025.119963","DOIUrl":"10.1016/j.jad.2025.119963","url":null,"abstract":"","PeriodicalId":14963,"journal":{"name":"Journal of affective disorders","volume":" ","pages":"119963"},"PeriodicalIF":4.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144698646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-15Epub Date: 2025-10-08DOI: 10.1016/j.jad.2025.120397
Xiaoyun Zhou, Frank Jia, Matthew Bambling, Sisira Edirippulige, Harvey Whiteford, Jialing Lin
Objective: This study investigated the association between multiple NDDs and the prevalence and severity of current depression and anxiety among children aged 3-17 years.
Methods: We analyzed parent- or caregiver-reported data from 2016 to 2023 US National Survey of Children's Health. Children aged 3-17 years were included. We considered a broader spectrum of NDDs by including behavioral problems and grouped children based on the number of NDDs (out of ten): no multiple NDDs (none or one NDD), two NDDs, three NDDs, four NDDs, and five or more NDDs. Four mental health outcomes were measured: depression (yes/no), anxiety (yes/no), depression severity (mild/moderate/severe), and anxiety severity (mild/moderate/severe). Multinomial logistic regression models were used.
Results: Among 267,044 children (mean age = 10.2 years; male = 51.8 %), 10.6 % had multiple NDDs. The increasing number of co-occurring NDDs was associated with higher odds of prevalence and severity of depression and anxiety. Children with multiple NDDs were 4.7-5.3 times more likely to have depression and 5.8-12.9 times more likely to have anxiety compared with those without multiple NDDs. These positive associations remained consistent for mild or moderate depression (adjusted odds ratios [ORs]: 5.0-5.6) and for mild or moderate anxiety (adjusted ORs: 5.6-8.9). The associations were more pronounced for severe mental health conditions, with children being 7.8-16.9 times more likely to experience severe depression and 8.1-34.9 times more likely to experience severe anxiety.
Conclusions: The cumulative mental health burden associated with multiple NDDs emphasizes the need for integrated screening and tailored interventions to support this population.
{"title":"Associations between multiple neurodevelopmental disorders and mental health in children.","authors":"Xiaoyun Zhou, Frank Jia, Matthew Bambling, Sisira Edirippulige, Harvey Whiteford, Jialing Lin","doi":"10.1016/j.jad.2025.120397","DOIUrl":"10.1016/j.jad.2025.120397","url":null,"abstract":"<p><strong>Objective: </strong>This study investigated the association between multiple NDDs and the prevalence and severity of current depression and anxiety among children aged 3-17 years.</p><p><strong>Methods: </strong>We analyzed parent- or caregiver-reported data from 2016 to 2023 US National Survey of Children's Health. Children aged 3-17 years were included. We considered a broader spectrum of NDDs by including behavioral problems and grouped children based on the number of NDDs (out of ten): no multiple NDDs (none or one NDD), two NDDs, three NDDs, four NDDs, and five or more NDDs. Four mental health outcomes were measured: depression (yes/no), anxiety (yes/no), depression severity (mild/moderate/severe), and anxiety severity (mild/moderate/severe). Multinomial logistic regression models were used.</p><p><strong>Results: </strong>Among 267,044 children (mean age = 10.2 years; male = 51.8 %), 10.6 % had multiple NDDs. The increasing number of co-occurring NDDs was associated with higher odds of prevalence and severity of depression and anxiety. Children with multiple NDDs were 4.7-5.3 times more likely to have depression and 5.8-12.9 times more likely to have anxiety compared with those without multiple NDDs. These positive associations remained consistent for mild or moderate depression (adjusted odds ratios [ORs]: 5.0-5.6) and for mild or moderate anxiety (adjusted ORs: 5.6-8.9). The associations were more pronounced for severe mental health conditions, with children being 7.8-16.9 times more likely to experience severe depression and 8.1-34.9 times more likely to experience severe anxiety.</p><p><strong>Conclusions: </strong>The cumulative mental health burden associated with multiple NDDs emphasizes the need for integrated screening and tailored interventions to support this population.</p>","PeriodicalId":14963,"journal":{"name":"Journal of affective disorders","volume":"393 Pt A","pages":"120397"},"PeriodicalIF":4.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145274623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-15Epub Date: 2025-09-03DOI: 10.1016/j.jcis.2025.138912
Xuyuan Fan, Shuimiao Xia, Lihao Yang, Guanfei Liu, Jie Huang, Yao Liu, Zhicheng Shi
Polymer dielectrics have attracted substantial attention for their extensive applications in advanced electronic power systems. However, their practical implementation is substantially hindered by the drastic deterioration in breakdown strength and energy storage capabilities at elevated temperatures. Herein, corrugated alumina (Al2O3) nanosheets anchored with uniformly dispersed silver nanoparticles (AgNPs) are fabricated via a sequential bimetallic ion exchange method using polyimide (PI) film as the sacrificing template. The AgNPs and Al2O3 nanosheets (AONSs) are in-situ formed on the molecular chain of PI in one step, which not only avoids the aggregation of AgNPs but also ensures the high purity of the AgNPs@AONSs. Benefiting from the excellent high-temperature insulating properties of Al2O3 and the Coulomb blockade effect of AgNPs, when the AgNPs@AONSs are incorporated into polymer dielectrics, they can act as powerful charge transport buffer strips and improve the breakdown strength. The polyetherimide film filled with merely 0.1 wt% AgNPs@AONSs shows ultra-high energy densities of 10.22 J cm-3 at 150 °C with 90 % efficiency and 7.49 J cm-3 at 200 °C with 80 % efficiency, which are 542 % and 226 % that of the pristine polyetherimide, respectively. The excellent high-temperature performances of the composite films make them promising candidates for high-temperature pulsed power systems.
{"title":"Excellent high-temperature breakdown and energy storage performances of polyetherimide dielectric film with silver/alumina nanosheets derived from sequential bimetallic ion exchange.","authors":"Xuyuan Fan, Shuimiao Xia, Lihao Yang, Guanfei Liu, Jie Huang, Yao Liu, Zhicheng Shi","doi":"10.1016/j.jcis.2025.138912","DOIUrl":"10.1016/j.jcis.2025.138912","url":null,"abstract":"<p><p>Polymer dielectrics have attracted substantial attention for their extensive applications in advanced electronic power systems. However, their practical implementation is substantially hindered by the drastic deterioration in breakdown strength and energy storage capabilities at elevated temperatures. Herein, corrugated alumina (Al<sub>2</sub>O<sub>3</sub>) nanosheets anchored with uniformly dispersed silver nanoparticles (AgNPs) are fabricated via a sequential bimetallic ion exchange method using polyimide (PI) film as the sacrificing template. The AgNPs and Al<sub>2</sub>O<sub>3</sub> nanosheets (AONSs) are in-situ formed on the molecular chain of PI in one step, which not only avoids the aggregation of AgNPs but also ensures the high purity of the AgNPs@AONSs. Benefiting from the excellent high-temperature insulating properties of Al<sub>2</sub>O<sub>3</sub> and the Coulomb blockade effect of AgNPs, when the AgNPs@AONSs are incorporated into polymer dielectrics, they can act as powerful charge transport buffer strips and improve the breakdown strength. The polyetherimide film filled with merely 0.1 wt% AgNPs@AONSs shows ultra-high energy densities of 10.22 J cm<sup>-3</sup> at 150 °C with 90 % efficiency and 7.49 J cm<sup>-3</sup> at 200 °C with 80 % efficiency, which are 542 % and 226 % that of the pristine polyetherimide, respectively. The excellent high-temperature performances of the composite films make them promising candidates for high-temperature pulsed power systems.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"702 Pt 1","pages":"138912"},"PeriodicalIF":9.7,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145005762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2026-01-15Epub Date: 2025-09-12DOI: 10.1016/j.cca.2025.120589
Jesiel Francisco de Jesus Fernandes Martins Lima, Thaíse Emilia Moreira da Silva, Ana Cristina Dos Santos Lopes, Victor Antonio Ferreira Freire, Melina Barros-Pinheiro, Patrícia Nessralla Alpoim
{"title":"Corrigendum to \"Soluble thrombomodulin in preeclampsia: A systematic review and meta-analysis\". [Clin. Chimica Acta 549 (2024) 120323].","authors":"Jesiel Francisco de Jesus Fernandes Martins Lima, Thaíse Emilia Moreira da Silva, Ana Cristina Dos Santos Lopes, Victor Antonio Ferreira Freire, Melina Barros-Pinheiro, Patrícia Nessralla Alpoim","doi":"10.1016/j.cca.2025.120589","DOIUrl":"10.1016/j.cca.2025.120589","url":null,"abstract":"","PeriodicalId":10205,"journal":{"name":"Clinica Chimica Acta","volume":" ","pages":"120589"},"PeriodicalIF":2.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145058338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aqueous batteries have become a prospective future energy storage system because of their low coefficient of cost and stability. However, their lower energy density limits their applications. Ammonium ions (NH4+) have a small hydration radius and light molar mass, and aqueous ammonium ion batteries (AAIBs) are anticipated for solving the inherent low-energy density problem of aqueous batteries. Exploring highly performing storage materials for aqueous ammonium ion batteries continues to be a research hotspot in recent years. Here, we propose a strategy to regulate the tunneling vanadium oxide' structure (VOM) based on the electron-mediated orbital-energy level synergistic strategy of the high-spin 3d transition metal (Mn) to assist AAIBs to achieve high energy density. The VOM has a capacity of up to 270 mAh g-1 at a current density of 0.2 A g-1, and the battery system containing poly(ammonium benzene) (PANI) (named VOM//PANI) has an energy density of up to 63.5 Wh kg-1. At the same time, we demonstrate the chemical energy storage mechanism of hydrogen bonding and the kinetics of interfacial chemical reactions in VOM based on a series of ex-situ or in-situ tests. Density-functional theory (DFT) calculations and experiments demonstrate that the introduction of high-spin transition metals can directionally regulate and optimize the electronic structure of V, which helps to achieve efficient NH4+ storage. This work offers novel concepts for the advancement of high-performance AAIBs as energy storage materials, as well as new strategies for the future large-scale grid-level applications of AAIBs.
水电池因其低成本系数和稳定性而成为未来很有前景的储能系统。然而,它们较低的能量密度限制了它们的应用。铵离子(NH4+)具有水化半径小、摩尔质量轻的特点,有望解决水电池固有的低能量密度问题。探索高性能的水铵离子电池存储材料一直是近年来的研究热点。本文提出了一种基于高自旋三维过渡金属(Mn)电子介导的轨道-能级协同策略调控氧化钒隧穿结构(VOM)的策略,以帮助AAIBs实现高能量密度。在电流密度为0.2 a g-1时,VOM的容量高达270 mAh g-1,而含有聚苯铵(PANI)(命名为VOM//PANI)的电池系统的能量密度高达63.5 Wh kg-1。同时,通过一系列非原位或原位实验,我们论证了VOM中氢键的化学能储存机理和界面化学反应动力学。密度泛函理论(DFT)计算和实验表明,引入高自旋过渡金属可以定向调节和优化V的电子结构,有助于实现高效的NH4+存储。这项工作为高性能AAIBs作为储能材料的发展提供了新的概念,也为未来AAIBs的大规模电网应用提供了新的策略。
{"title":"Orbital energy level engineering: 3d high-spin Mn's d-electron mediating electronic structure of VO<sub>2</sub> boosting highly durable aqueous ammonium ion batteries.","authors":"Zhenhua Zhou, Miao Cui, Tianming Lv, Jian Cao, Ziqi Ren, Yi Zhong, HongXin Zhao, Hongye Zheng, Yifu Zhang, Yang Wang, Changgong Meng","doi":"10.1016/j.jcis.2025.138826","DOIUrl":"10.1016/j.jcis.2025.138826","url":null,"abstract":"<p><p>Aqueous batteries have become a prospective future energy storage system because of their low coefficient of cost and stability. However, their lower energy density limits their applications. Ammonium ions (NH<sub>4</sub><sup>+</sup>) have a small hydration radius and light molar mass, and aqueous ammonium ion batteries (AAIBs) are anticipated for solving the inherent low-energy density problem of aqueous batteries. Exploring highly performing storage materials for aqueous ammonium ion batteries continues to be a research hotspot in recent years. Here, we propose a strategy to regulate the tunneling vanadium oxide' structure (VOM) based on the electron-mediated orbital-energy level synergistic strategy of the high-spin 3d transition metal (Mn) to assist AAIBs to achieve high energy density. The VOM has a capacity of up to 270 mAh g<sup>-1</sup> at a current density of 0.2 A g<sup>-1</sup>, and the battery system containing poly(ammonium benzene) (PANI) (named VOM//PANI) has an energy density of up to 63.5 Wh kg<sup>-1</sup>. At the same time, we demonstrate the chemical energy storage mechanism of hydrogen bonding and the kinetics of interfacial chemical reactions in VOM based on a series of ex-situ or in-situ tests. Density-functional theory (DFT) calculations and experiments demonstrate that the introduction of high-spin transition metals can directionally regulate and optimize the electronic structure of V, which helps to achieve efficient NH<sub>4</sub><sup>+</sup> storage. This work offers novel concepts for the advancement of high-performance AAIBs as energy storage materials, as well as new strategies for the future large-scale grid-level applications of AAIBs.</p>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"702 Pt 1","pages":"138826"},"PeriodicalIF":9.7,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145028666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}