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The role of the carapace in the uptake and storage of newly accumulated metals was investigated in the green crab exposed to environmentally relevant concentrations of calcium ([Ca] = 389 mg L^-1 or 9.7 mmol L^-1), zinc ([Zn] = 82 μg L^-1 or 1.25 μmol L^-1), and nickel ([Ni] = 8.2 μg L^-1 or 0.14 μmol L^-1) in 12 °C seawater, using radio-tracers (⁴⁵Ca, ⁶⁵Zn, ⁶³Ni). After 24-h exposure, carapace exhibited the highest concentration of newly accumulated Ca, whereas carapace and gills exhibited the highest concentrations of both newly accumulated Zn and Ni relative to other tissues. For all three metals, the carapace accounted for >85 % of the total body burden. Acute temperature changes (to 2 °C and 22 °C) revealed the highest overall temperature coefficient Q₁₀ (2.15) for Ca uptake into the carapace, intermediate Q₁₀ for Ni (1.87) and lowest Q₁₀ (1.45) for Zn. New Ca uptake into the carapace continued linearly with time for 24 h, new Zn uptake gradually deviated from linearity, whereas Ni uptake reached a plateau by 6 h. Attachment of a rubber membrane to the dorsal carapace, thereby shielding about 20 % of the total crab surface area from the external water, eliminated both new Zn and Ni incorporation into the shielded carapace, whereas 36 % of new Ca incorporation persisted. When recently euthanized crabs were exposed, new Zn uptake into the carapace remained unchanged, whereas Ca and Ni uptake were reduced by 89 % and 71 %, respectively. We conclude that the carapace is a very important uptake and storage site for all three metals. All of the uptake of new Zn and new Ni, and most of the uptake of new Ca into this tissue comes directly from the external water. For Zn, the mechanism involves only physicochemical processes, whereas for Ca and Ni, life-dependent processes make the major contribution.

Tropical forests are global biodiversity hotspots and are crucial in the global carbon (C) cycle. Understanding the drivers of aboveground carbon stock (AGC) in a heterogeneous and biodiverse system can shed light on the processes underlying the relationship between biodiversity and carbon accumulation. Here, we investigate how biodiversity, environment, and landscape structure affect AGC. We examined such associations in 349 plots comprising over 95,346 km² the Atlantic Forest of southern Brazil, encompassing three forest types: Dense Ombrophylous Forest (DF), Mixed Ombrophylous Forest (MF), and Seasonal Deciduous Forest (SF). Each plot was described by environmental variables, landscape metrics, and biodiversity (species richness and functional diversity). We used diversity, environmental, and landscape variables to build generalized linear mixed models and understand which can affect the forest AGC. We found that species richness is associated positively with AGC in all forest types, combined and separately. Seasonal temperature and isothermality affect AGC in all forest types; additionally, stocks are positively influenced by annual precipitation in SF and isothermality in MF. Among landscape metrics, total fragment edge negatively affects carbon stocks in MF. Our results show the importance of species diversity for carbon stocks in subtropical forests. The climate effect was also relevant, showing the importance of these factors, especially in a world where climate change tends to affect forest stock capacity negatively.

As the spectre of climate change looms large, there is an increasing imperative to develop comprehensive risk assessment tools. The purpose of this work is to evaluate the evolution and current state of research on multi-hazard indices associated with climate-related hazards, highlighting their crucial role in effective risk assessment amidst the growing challenges of climate change. A notable gap in cross-regional comparative studies persists, presenting an opportunity for future research to enhance global understanding and foster universal resilience strategies. However, a significant surge in research output is apparent, following key global milestones related to climate change action. The research landscape is shown to be highly responsive to international policy developments, increasingly adopting interdisciplinary approaches that integrate physical, social, and technological dimensions. Findings reveal a robust emphasis on geospatial analysis and the development of various indices that transform abstract climate risks into actionable data, underscoring a trend towards localized, context-specific vulnerability assessments. Based on dataset systematically curated under the PRISMA guidelines, the review explores how prevailing research themes are reflected in influential journals and author networks, mapping out a dynamic and expanding academic community. Moreover, this work provides critical insights into the underlying literature by conducting a thematic analysis on the typology of studies, the focus on coastal areas, the inclusion of climate change scenarios, the geographical coverage, and the types of climate-related hazards. The practical implications of this review are profound, providing policymakers and practitioners with meaningful insights to enhance climate change mitigation and adaptation efforts through the application of index-based methodologies. By charting a course for future scholarly endeavours, this article aims to strengthen the scientific foundations supporting resilient and adaptive strategies for regions worldwide facing the multifaceted impacts of climate change.

Rubber trees emit a range of volatile organic compounds (VOCs), including isoprene, monoterpenes, and sesquiterpenes, as part of their natural metabolism. These VOCs can significantly influence air quality through photochemical reactions that produce ozone and secondary organic aerosols (SOAs). This study examines the impact of VOCs detected in a rubber tree plantation in Northeastern Thailand on air quality, highlighting their role in atmospheric reactions that lead to the formation of ozone and SOAs. VOCs were collected at varying heights and seasons using Tenax-TA tubes paired with an atmospheric sampler pump and identified by gas chromatography-mass spectrometry. In total, 100 VOCs were identified, including alkanes, alkenes, terpenes, aromatics, and oxygenated VOCs. Principal Coordinate Analysis (PCoA) revealed distinct seasonal VOC profiles, with hydrocarbons, peaking in summer and terpenes in the rainy season. The Linear Mixed-Effects (LME) model indicates that VOC concentrations are more influenced by seasonal changes than by sampling heights. Secondary organic aerosol potential (SOAP) and ozone formation potential (OFP) of selected VOC species were also determined. The total SOAP ranged from 67.24 μg/m³ in summer to 17.87 μg/m³ in winter, while the total OFP ranged from 377.87 μg/m³ in summer to 139.39 μg/m³ in winter. Additionally, positive matrix factorization (PMF) analysis identified four main VOC sources: gasoline combustion (18.3 %), microbial activity (38.6 %), monoterpene emissions during latex production (15.0 %), and industrial sources (28.1 %). These findings provide essential information for managing air pollution in rubber tree plantations. By adopting focused air quality management strategies, plantation operators can mitigate the adverse effects of VOCs, promoting a healthier and more sustainable future.

Compared to other organic contaminants, birds are rarely studied for their exposure to polycyclic aromatic hydrocarbons (PAHs), mainly due to their effective metabolization of parent PAHs. However, as some studies suggest, exposure to PAHs may result in adverse health effects including decreased survival, especially following oil spills. In the present study, we analyzed samples from a sea duck, the common eider Somateria mollissima including feathers, preen oil, blood, liver and bile, to evaluate whether non- lethally collected samples could be reliably used for avian biomonitoring strategies. Phenanthrene was the only individual PAH detected across sample types, with the highest concentration found in preen gland and the lowest in blood. Significant differences in concentrations were observed between bile vs preen gland and liver vs preen gland, while for most compounds neither blood nor feathers showed detectable levels of parent PAHs. Therefore, the utility of those sample types for PAH exposure assessment may be limited and should be interpreted with caution, moreover as several physiological factors may affect them. Additionally, we also provide a comparison with the available literature to review current avian PAH exposure assessment and outline future research focused needs.

A mystery has emerged as to why patterns of increasing extreme rainfall have not been accompanied by similar levels of flooding, garnering growing attention given concerns over future flood risks. Antecedent moisture conditions have been proposed as the missing explanatory factor. Yet, reasons for moisture variability prior to flooding remain largely unstudied. Here, we evaluate the potential utility of precipitation intermittency, defined as the dry spell length prior to a flood, to explain the variability of flooding over 108 watersheds from 1950 to 2022. Flood magnitude is shown to be sensitive to intermittency, particularly in arid and semi-arid regions (PET/P > 0.84) and for basins with low soil field capacity (<0.31 m³/m³). Following extended dry spells >20 days, floods are only possible from the most intense storms, whereas a wider range of storms can produce flooding for shorter intermittency. The flood probability decreases by approximately 0.5 % for each additional day of dry spell, with overall flood probabilities being up to 30 % lower following extended dry periods. These results underscore the potential utility of precipitation intermittency for diagnosing current and future flood risks.

Rare earth elements (REEs) have emerged as contaminants in airborne particulate matter (PM); however, their anthropogenic sources remain poorly quantified, and associated health risks are unknown. This study investigates the REE distribution across eight sizes of airborne PM during July and December in Qingdao, a major Chinese port city. Our results reveal a single coarse-mode distribution with REE concentrations. In contrast, fine PM (size: 0.43-2.1 μm) exhibits notable enrichment of La and Ce compared to Al and other REEs. This study traces La and Ce enrichment to fluid catalytic cracking catalysts (FCCC)-related sources, including refinery and ship emissions, by comparing the REE fractionation in samples with potential sources. We quantify the contributions from FCCC-related sources to La (July: 33.6 % ± 3.2 %, Dec.: 46.4 % ± 5.2 %) and Ce (July: 16.5 % ± 14.3 %, Dec.: 30.3 % ± 12.2 %) by comparing measured concentrations with predictions derived from neighboring REEs, a method previously used exclusively in aquatic systems. For the first time, supply ratios of refinery and ship to FCCC-related La are calculated using a two-component mixing model based on the [La]_FCCC/[V]_anth, revealing the dominance of refinery emissions (July: 97.3 % ± 0.6 %, Dec.: 99.6 % ± 0.1 %). Furthermore, a global review of La and Ce anomalies that integrates published REE data with our findings reveals a widespread distribution of positive anomalies. The significantly positive correlation between La and Ce anomalies underscores FCCC-related emissions as a global source in fine PM, contributing 0-92 % (mean: 35 % ± 33 %) for La and 0-72 % (mean: 21 % ± 24 %) for Ce. Although the non-carcinogenic health risks of Ce are generally low globally, concerns should be raised in areas near source emissions, where Ce health risks sharply increased along with its concentrations. There is urgently need to establish a threshold value for La, owing to its global enrichment. This study provides novel insights into the sources and health implications of REEs in airborne PM.

Selecting an appropriate electron donor to enhance nitrogen removal for treating low C/N wastewater in ecological floating beds (EFBs) is controversy. In this study, a systematic and comprehensive evaluation of sodium acetate (EFB-C), sodium thiosulfate (EFB-S) and iron scraps (EFB-Fe) was performed in a 2-year experiment on long-term viability including nitrogen removal and greenhouse gas emissions associated with key molecular biological mechanisms. The results showed that EFB-C (43-85 %) and EFB-S (40-88 %) exhibited superior total nitrogen (TN) removal. Temperature and hydraulic retention time (HRT) have significant impacts on TN removal of EFB-Fe, however, it could reach 86 % under high temperature (30-35 °C) and a long HRT (3 days), and it has lowest N₂O (0-6.2 mg m^-2 d^-1) and CH₄ (0-5.3 mg m^-2 d^-1) fluxes. Microbial network analysis revealed that the microbes changed from competing to cooperating after adding electron donors. A higher abundance of anammox genera was enriched in EFB-Fe. The Mantel's test and structural equation model provided proof of the differences, which showed that acetate and thiosulfate were similar, whereas Fe⁰ was different in the nitrogen removal mechanism. Molecular biology analyses further verified that heterotrophic, autotrophic, and mixotrophic coupled with anammox were the main TN removal pathways for EFB-C, EFB-S, and EFB-Fe, respectively. These findings provide a better understanding of the biological mechanisms for selecting appropriate electron donors for treating low C/N wastewater.

Despite efforts to reduce dependence on coal-fired power generation due to climate concerns, continued usage for energy stability is anticipated. This study was conducted to address environmental issues associated with coal-fired power generation and promote its persistent utilization. we aimed to establish both eco-friendly and economically sustainable practices by mitigating waste such as fly ash (FA) and bottom ash (BA) emissions while recycling them in circulating fluidized bed combustion (CFBC). Initially, we conducted a literature review to analyze the global and domestic trends in coal-fired power generation. Subsequently, we performed experimental research on CO₂ crystallization as a multifaceted approach for treating exhaust gases and waste materials such as FA and BA simultaneously. Throughout this research, we implemented a simple process to ensure scalability. In the context of carbon capture, utilization, and storage (CCUS) technology, we conducted experimental research on mineralizing CO₂ targeting FA and BA by applying ambient temperature, atmospheric pressure, and simulated exhaust gas. The empirical findings demonstrated that 12.28 kg CO₂/ton and 58.14 kg CO₂/ton of CO₂ were immobilized for BA and FA, respectively. The economic evaluation was measured based on the experimental results obtained from the techno-economic analysis (TEA). The B/C ratio stands at 1.07, with the cost of composite carbonate estimated at USD 159.6 per ton. With an internal rate of return (IRR) of 7.78 % and a net present value (NPV) of USD 7294.59, the economic viability demonstrates considerable promise. Ultimately, this study aims to mitigate the impact of coal-fired power plants on climate change and enhance environmental sustainability through CO₂ removal and waste recycling.

The cosmogenic radionuclide ⁷Be (T_1/2: 53.29 days) and ¹⁰Be (T_1/2: 1.39 My), as unique tracers, play an excellent indicative role in atmospheric environmental changes and Earth surface processes. Currently, their different characteristics and influencing factors in various natural climate environments are still vague. Here, we used a state-of-the-art accelerator mass spectrometry to synchronously measure the ultra-trace ⁷Be and ¹⁰Be in aerosols, obtaining the spatial and temporal variability of daily-resolution atmospheric ⁷Be and ¹⁰Be in different natural climate regions (n = 11) of China. The survey results show that the ¹⁰Be and ⁷Be concentrations in the central/southern regions of China (22-38°N, 85-119°E) in 2020/21 are (0.5-18.7)·10⁴ and (0.4-6.1)·10⁴ atoms·m^-3, respectively, with ¹⁰Be/⁷Be ratios of 0.7-3.3. Except for the Tibetan Plateau, there are differences in the concentration thresholds of ¹⁰Be and ⁷Be in various regions, especially in ¹⁰Be concentration. These ¹⁰Be/⁷Be thresholds are consistent in areas with an altitude range of 4-3420 m a.s.l and reach their highest values throughout the spring of the year. The analysis results indicate that both ⁷Be and ¹⁰Be are influenced by local meteorological conditions such as rainfall and boundary layer disturbances, while also exhibiting different distribution states. This distribution states is due to the re-suspended soil dust ¹⁰Be interference caused by soil wind erosion to varying degrees in different regions, with an average contribution to aerosol ¹⁰Be of 5.0 ± 2.6 %-24.2 % ± 13.3 %, and is controlled by local annual rainfall (r = 0.8, p < 0.01). Furthermore, unlike the characteristics of ¹⁰Be and ⁷Be concentrations influenced by local meteorological conditions, the daily variation of corrected ¹⁰Be/⁷Be exhibits independence from meteorological processes other than stratosphere troposphere transport, and its significant seasonal oscillations indicate changes in atmospheric circulation in the East Asian monsoon region.