Pub Date : 2024-09-11DOI: 10.1016/j.cclet.2024.110444
Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang
Propane dehydrogenation (PDH) is a vital industrial process for producing propene, utilizing primarily Cr-based or Pt-based catalysts. These catalysts often suffer from challenges such as the toxicity of Cr, the high costs of noble metals like Pt, and deactivation issues due to sintering or coke formation at elevated temperatures. We introduce an exceptional Ru-based catalyst, Ru nanoparticles anchored on a nitrogen-doped carbon matrix (Ru@NC), which achieves a propane conversion rate of 32.2 % and a propene selectivity of 93.1 % at 550 °C, with minimal coke deposition and a low deactivation rate of 0.0065 h−1. Characterizations using techniques like TEM and XPS, along with carefully-designed controlled experiments, reveal that the notable performance of Ru@NC stems from the modified electronic state of Ru by nitrogen dopant and the microporous nature of the matrix, positioning it as a top contender among state-of-the-art PDH catalysts.
{"title":"Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix","authors":"Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang","doi":"10.1016/j.cclet.2024.110444","DOIUrl":"10.1016/j.cclet.2024.110444","url":null,"abstract":"<div><div>Propane dehydrogenation (PDH) is a vital industrial process for producing propene, utilizing primarily Cr-based or Pt-based catalysts. These catalysts often suffer from challenges such as the toxicity of Cr, the high costs of noble metals like Pt, and deactivation issues due to sintering or coke formation at elevated temperatures. We introduce an exceptional Ru-based catalyst, Ru nanoparticles anchored on a nitrogen-doped carbon matrix (Ru@NC), which achieves a propane conversion rate of 32.2 % and a propene selectivity of 93.1 % at 550 °C, with minimal coke deposition and a low deactivation rate of 0.0065 h<sup>−1</sup>. Characterizations using techniques like TEM and XPS, along with carefully-designed controlled experiments, reveal that the notable performance of Ru@NC stems from the modified electronic state of Ru by nitrogen dopant and the microporous nature of the matrix, positioning it as a top contender among state-of-the-art PDH catalysts.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 2","pages":"Article 110444"},"PeriodicalIF":9.4,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142699174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-11DOI: 10.1016/j.cclet.2024.110014
Xi Tang , Chunlei Zhu , Yulu Yang , Shihan Qi , Mengqiu Cai , Abdullah N. Alodhayb , Jianmin Ma
The battery energy density can be improved by raising the operating voltage, however, which may lead to rapid capacity decay due to the continuous electrolyte decomposition and the thickening of electrode electrolyte interphases. To address these challenges, we proposed tripropyl phosphate (TPP) as an additive−regulating Li+ solvation structure to construct a stable LiF–rich electrode carbonate−based electrolyte interphases for sustaining 4.6 V Li||LiCoO2 batteries. This optimized interphases could help reduce the resistance and achieve better rate performance and cycling stability. As expected, the Li||LiCoO2 battery retained 79.4 % capacity after 100 cycles at 0.5 C, while the Li||Li symmetric cell also kept a stable plating/stripping process over 450 h at the current density of 1.0 mA/cm2 with a deposited amount of 0.5 mAh/cm2.
{"title":"Additive regulating Li+ solvation structure to construct dual LiF−rich electrode electrolyte interphases for sustaining 4.6 V Li||LiCoO2 batteries","authors":"Xi Tang , Chunlei Zhu , Yulu Yang , Shihan Qi , Mengqiu Cai , Abdullah N. Alodhayb , Jianmin Ma","doi":"10.1016/j.cclet.2024.110014","DOIUrl":"10.1016/j.cclet.2024.110014","url":null,"abstract":"<div><p>The battery energy density can be improved by raising the operating voltage, however, which may lead to rapid capacity decay due to the continuous electrolyte decomposition and the thickening of electrode electrolyte interphases. To address these challenges, we proposed tripropyl phosphate (TPP) as an additive−regulating Li<sup>+</sup> solvation structure to construct a stable LiF–rich electrode carbonate−based electrolyte interphases for sustaining 4.6 V Li||LiCoO<sub>2</sub> batteries. This optimized interphases could help reduce the resistance and achieve better rate performance and cycling stability. As expected, the Li||LiCoO<sub>2</sub> battery retained 79.4 % capacity after 100 cycles at 0.5 C, while the Li||Li symmetric cell also kept a stable plating/stripping process over 450 h at the current density of 1.0 mA/cm<sup>2</sup> with a deposited amount of 0.5 mAh/cm<sup>2</sup>.</p></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"35 12","pages":"Article 110014"},"PeriodicalIF":9.4,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142168021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-10DOI: 10.1016/j.cclet.2024.110439
Yan Wang , Jiaqi Zhang , Xiaofeng Wu , Sibo Wang , Masakazu Anpo , Yuanxing Fang
Solar-induced water oxidation reaction (WOR) for oxygen evolution is a critical step in the transformation of Earth's atmosphere from a reducing to an oxidation one during its primordial stages. WOR is also associated with important reduction reactions, such as oxygen reduction reaction (ORR), which leads to the production of hydrogen peroxide (H2O2). These transitions are instrumental in the emergence and evolution of life. In this study, transition metals were loaded onto nitrogen-doped carbon (NDC) prepared under the primitive Earth's atmospheric conditions. These metal-loaded NDC samples were found to catalyze both WOR and ORR under light illumination. The chemical pathways initiated by the pristine and metal-loaded NDC were investigated. This study provides valuable insights into potential mechanisms relevant to the early evolution of our planet.
{"title":"Elucidating oxygen evolution and reduction mechanisms in nitrogen-doped carbon-based photocatalysts","authors":"Yan Wang , Jiaqi Zhang , Xiaofeng Wu , Sibo Wang , Masakazu Anpo , Yuanxing Fang","doi":"10.1016/j.cclet.2024.110439","DOIUrl":"10.1016/j.cclet.2024.110439","url":null,"abstract":"<div><div>Solar-induced water oxidation reaction (WOR) for oxygen evolution is a critical step in the transformation of Earth's atmosphere from a reducing to an oxidation one during its primordial stages. WOR is also associated with important reduction reactions, such as oxygen reduction reaction (ORR), which leads to the production of hydrogen peroxide (H2O2). These transitions are instrumental in the emergence and evolution of life. In this study, transition metals were loaded onto nitrogen-doped carbon (NDC) prepared under the primitive Earth's atmospheric conditions. These metal-loaded NDC samples were found to catalyze both WOR and ORR under light illumination. The chemical pathways initiated by the pristine and metal-loaded NDC were investigated. This study provides valuable insights into potential mechanisms relevant to the early evolution of our planet.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 2","pages":"Article 110439"},"PeriodicalIF":9.4,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Efficient and innovative nano-catalytic oxidation technologies offer a breakthrough in removing emerging contaminants (ECs) from water, surpassing the limitations of traditional methods. Environmental functional materials (EFMs), particularly high-end oxidation systems using eco-friendly nanomaterials, show promise for absorbing and degrading ECs. This literature review presents a comprehensive analysis of diverse traditional restoration techniques-biological, physical, and chemical-assessing their respective applications and limitations in pesticide-contaminated water purification. Through meticulous comparison, we unequivocally advocate for the imperative integration of environmentally benign nanomaterials, notably titanium-based variants, in forthcoming methodologies. Our in-depth exploration scrutinizes the catalytic efficacy, underlying mechanisms, and adaptability of pioneering titanium-based nanomaterials across a spectrum of environmental contexts. Additionally, strategic recommendations are furnished to surmount challenges and propel the frontiers of implementing eco-friendly nanomaterials in practical water treatment scenarios.
{"title":"Application of titanium-based advanced oxidation processes in pesticide-contaminated water purification: Emerging opportunities and challenges","authors":"Chu Wu , Zhichao Dong , Jinfang Hou , Jian Peng , Shuangyu Wu , Xiaofang Wang , Xiangwei Kong , Yue Jiang","doi":"10.1016/j.cclet.2024.110438","DOIUrl":"10.1016/j.cclet.2024.110438","url":null,"abstract":"<div><div>Efficient and innovative nano-catalytic oxidation technologies offer a breakthrough in removing emerging contaminants (ECs) from water, surpassing the limitations of traditional methods. Environmental functional materials (EFMs), particularly high-end oxidation systems using eco-friendly nanomaterials, show promise for absorbing and degrading ECs. This literature review presents a comprehensive analysis of diverse traditional restoration techniques-biological, physical, and chemical-assessing their respective applications and limitations in pesticide-contaminated water purification. Through meticulous comparison, we unequivocally advocate for the imperative integration of environmentally benign nanomaterials, notably titanium-based variants, in forthcoming methodologies. Our in-depth exploration scrutinizes the catalytic efficacy, underlying mechanisms, and adaptability of pioneering titanium-based nanomaterials across a spectrum of environmental contexts. Additionally, strategic recommendations are furnished to surmount challenges and propel the frontiers of implementing eco-friendly nanomaterials in practical water treatment scenarios.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 3","pages":"Article 110438"},"PeriodicalIF":9.4,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143318381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-07DOI: 10.1016/j.cclet.2024.110428
Yanqiong Wang , Yaqi Hou , Fengwei Huo , Xu Hou
Excessive Fe3+ ion concentrations in wastewater pose a long-standing threat to human health. Achieving low-cost, high-efficiency quantification of Fe3+ ion concentration in unknown solutions can guide environmental management decisions and optimize water treatment processes. In this study, by leveraging the rapid, real-time detection capabilities of nanopores and the specific chemical binding affinity of tannic acid to Fe3+, a linear relationship between the ion current and Fe3+ ion concentration was established. Utilizing this linear relationship, quantification of Fe3+ ion concentration in unknown solutions was achieved. Furthermore, ethylenediaminetetraacetic acid disodium salt was employed to displace Fe3+ from the nanopores, allowing them to be restored to their initial conditions and reused for Fe3+ ion quantification. The reusable bioinspired nanopores remain functional over 330 days of storage. This recycling capability and the long-term stability of the nanopores contribute to a significant reduction in costs. This study provides a strategy for the quantification of unknown Fe3+ concentration using nanopores, with potential applications in environmental assessment, health monitoring, and so forth.
{"title":"Fe3+ ion quantification with reusable bioinspired nanopores","authors":"Yanqiong Wang , Yaqi Hou , Fengwei Huo , Xu Hou","doi":"10.1016/j.cclet.2024.110428","DOIUrl":"10.1016/j.cclet.2024.110428","url":null,"abstract":"<div><div>Excessive Fe<sup>3+</sup> ion concentrations in wastewater pose a long-standing threat to human health. Achieving low-cost, high-efficiency quantification of Fe<sup>3+</sup> ion concentration in unknown solutions can guide environmental management decisions and optimize water treatment processes. In this study, by leveraging the rapid, real-time detection capabilities of nanopores and the specific chemical binding affinity of tannic acid to Fe<sup>3+</sup>, a linear relationship between the ion current and Fe<sup>3+</sup> ion concentration was established. Utilizing this linear relationship, quantification of Fe<sup>3+</sup> ion concentration in unknown solutions was achieved. Furthermore, ethylenediaminetetraacetic acid disodium salt was employed to displace Fe<sup>3+</sup> from the nanopores, allowing them to be restored to their initial conditions and reused for Fe<sup>3+</sup> ion quantification. The reusable bioinspired nanopores remain functional over 330 days of storage. This recycling capability and the long-term stability of the nanopores contribute to a significant reduction in costs. This study provides a strategy for the quantification of unknown Fe<sup>3+</sup> concentration using nanopores, with potential applications in environmental assessment, health monitoring, and so forth.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 2","pages":"Article 110428"},"PeriodicalIF":9.4,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-07DOI: 10.1016/j.cclet.2024.110429
Chenhao Zhang , Qian Zhang , Yezhou Hu , Hanyu Hu , Junhao Yang , Chang Yang , Ye Zhu , Zhengkai Tu , Deli Wang
Developing high performance electrocatalysts for the cathodic oxygen reduction reaction (ORR) is essential for the widespread application of fuel cells. Herein, a promising Pt2NiCo atomic ordered ternary intermetallic compound with N-doped carbon layer coating (o-Pt2NiCo@NC) has been synthesized via a facile method and applied in acidic ORR. The confinement effect provided by the carbon layer not only inhibits the agglomeration and sintering of intermetallic nanoparticles during high temperature process but also provides adequate protection for the nanoparticles, mitigating the aggregation, detachment and poisoning of nanoparticles during the electrochemical process. As a result, the o-Pt2NiCo@NC demonstrates a mass activity (MA) and specific activity (SA) of 0.65 A/mgPt and 1.41 mA/cmPt2 in 0.1 mol/L HClO4, respectively. In addition, after 30,000 potential cycles from 0.6 V to 1.0 V, the MA of o-Pt2NiCo@NC shows much lower decrease than the disordered Pt2NiCo alloy and Pt/C. Even cycling at high potential cycles of 1.5 V for 10,000 cycles, the MA still retains ∼70 %, demonstrating superior long-term durability. Furthermore, the o-Pt2NiCo@NC also exhibits strong tolerance to CO, SOx, and POx molecules in toxicity tolerance tests. The strategy in this work provides a novel insight for the development of ORR catalysts with high catalytic activity, durability and toxicity tolerance.
{"title":"N-doped carbon confined ternary Pt2NiCo intermetallics for efficient oxygen reduction reaction","authors":"Chenhao Zhang , Qian Zhang , Yezhou Hu , Hanyu Hu , Junhao Yang , Chang Yang , Ye Zhu , Zhengkai Tu , Deli Wang","doi":"10.1016/j.cclet.2024.110429","DOIUrl":"10.1016/j.cclet.2024.110429","url":null,"abstract":"<div><div>Developing high performance electrocatalysts for the cathodic oxygen reduction reaction (ORR) is essential for the widespread application of fuel cells. Herein, a promising Pt<sub>2</sub>NiCo atomic ordered ternary intermetallic compound with N-doped carbon layer coating (<em>o</em>-Pt<sub>2</sub>NiCo@NC) has been synthesized <em>via</em> a facile method and applied in acidic ORR. The confinement effect provided by the carbon layer not only inhibits the agglomeration and sintering of intermetallic nanoparticles during high temperature process but also provides adequate protection for the nanoparticles, mitigating the aggregation, detachment and poisoning of nanoparticles during the electrochemical process. As a result, the <em>o</em>-Pt<sub>2</sub>NiCo@NC demonstrates a mass activity (MA) and specific activity (SA) of 0.65 A/mg<sub>Pt</sub> and 1.41 mA/cm<sub>Pt</sub><sup>2</sup> in 0.1 mol/L HClO<sub>4</sub>, respectively. In addition, after 30,000 potential cycles from 0.6 V to 1.0 V, the MA of <em>o</em>-Pt<sub>2</sub>NiCo@NC shows much lower decrease than the disordered Pt<sub>2</sub>NiCo alloy and Pt/C. Even cycling at high potential cycles of 1.5 V for 10,000 cycles, the MA still retains ∼70 %, demonstrating superior long-term durability. Furthermore, the <em>o</em>-Pt<sub>2</sub>NiCo@NC also exhibits strong tolerance to CO, SO<sub>x</sub>, and PO<sub>x</sub> molecules in toxicity tolerance tests. The strategy in this work provides a novel insight for the development of ORR catalysts with high catalytic activity, durability and toxicity tolerance.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 3","pages":"Article 110429"},"PeriodicalIF":9.4,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143318377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-07DOI: 10.1016/j.cclet.2024.110431
Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan
Core-shell colloidal particles with a polymer layer have broad applications in different areas. Herein, we developed a two-step method combining aqueous surface-initiated photoinduced polymerization-induced self-assembly and photoinduced seeded reversible addition-fragmentation chain transfer (RAFT) polymerization to prepare a diverse set of core-shell colloidal particles with a well-defined polymer layer. Chemical compositions, structures, and thicknesses of polymer layers could be conveniently regulated by using different types of monomers and feed [monomer]/[chain transfer agent] ratios during seeded RAFT polymerization.
{"title":"Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization","authors":"Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan","doi":"10.1016/j.cclet.2024.110431","DOIUrl":"10.1016/j.cclet.2024.110431","url":null,"abstract":"<div><div>Core-shell colloidal particles with a polymer layer have broad applications in different areas. Herein, we developed a two-step method combining aqueous surface-initiated photoinduced polymerization-induced self-assembly and photoinduced seeded reversible addition-fragmentation chain transfer (RAFT) polymerization to prepare a diverse set of core-shell colloidal particles with a well-defined polymer layer. Chemical compositions, structures, and thicknesses of polymer layers could be conveniently regulated by using different types of monomers and feed [monomer]/[chain transfer agent] ratios during seeded RAFT polymerization.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 2","pages":"Article 110431"},"PeriodicalIF":9.4,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-07DOI: 10.1016/j.cclet.2024.110426
Yuan Liu , Boyang Wang , Yaxin Li , Weidong Li , Siyu Lu
Carbon dots (CDs), due to their low cost, high stability, and high luminous efficiency, have emerged as an excellent material for the emissive layer in next-generation electroluminescent light-emitting diodes (ELEDs). However, improving the efficiency of fluorescent CDs-based ELEDs remains challenging, primarily because it is difficult to utilize triplet excitons in the electroluminescence process. Therefore, enhancing the exciton utilization efficiency of CDs during electroluminescence is crucial. Based on this, we exploited the characteristic large exciton binding energy commonly found in CDs to develop exciton-emitting CDs. These CDs facilitate the radiative recombination of excitons during electroluminescence, thereby improving the electroluminescent efficiency. By rationally selecting precursors, we developed high quantum efficiency CDs and subsequently constructed CDs-based ELEDs. The blue-light device exhibited an external quantum efficiency of over 4 %. This study introduces a novel design concept for CDs, providing a new strategy for developing high-performance blue ELEDs based on CDs.
碳点（CD）因其低成本、高稳定性和高发光效率，已成为下一代电致发光二极管（ELED）发光层的绝佳材料。然而，提高基于荧光光盘的电致发光二极管的效率仍然具有挑战性，这主要是因为在电致发光过程中很难利用三重激子。因此，提高 CD 在电致发光过程中的激子利用效率至关重要。在此基础上，我们利用光盘中常见的大激子结合能特性，开发出了激子发光光盘。这些光盘有助于激子在电致发光过程中进行辐射重组，从而提高电致发光效率。通过合理选择前驱体，我们开发出了高量子效率的光盘，并随后构建了基于光盘的电致发光器件。该蓝光器件的外部量子效率超过 4%。这项研究引入了一种新颖的光盘设计理念，为开发基于光盘的高性能蓝光发光二极管提供了一种新策略。
{"title":"Understanding excitonic behavior and electroluminescence light emitting diode application of carbon dots","authors":"Yuan Liu , Boyang Wang , Yaxin Li , Weidong Li , Siyu Lu","doi":"10.1016/j.cclet.2024.110426","DOIUrl":"10.1016/j.cclet.2024.110426","url":null,"abstract":"<div><div>Carbon dots (CDs), due to their low cost, high stability, and high luminous efficiency, have emerged as an excellent material for the emissive layer in next-generation electroluminescent light-emitting diodes (ELEDs). However, improving the efficiency of fluorescent CDs-based ELEDs remains challenging, primarily because it is difficult to utilize triplet excitons in the electroluminescence process. Therefore, enhancing the exciton utilization efficiency of CDs during electroluminescence is crucial. Based on this, we exploited the characteristic large exciton binding energy commonly found in CDs to develop exciton-emitting CDs. These CDs facilitate the radiative recombination of excitons during electroluminescence, thereby improving the electroluminescent efficiency. By rationally selecting precursors, we developed high quantum efficiency CDs and subsequently constructed CDs-based ELEDs. The blue-light device exhibited an external quantum efficiency of over 4 %. This study introduces a novel design concept for CDs, providing a new strategy for developing high-performance blue ELEDs based on CDs.</div></div>","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 2","pages":"Article 110426"},"PeriodicalIF":9.4,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142699175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-06DOI: 10.1016/j.cclet.2024.110417
Dong Sui, Jiayi Liu
{"title":"Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery","authors":"Dong Sui, Jiayi Liu","doi":"10.1016/j.cclet.2024.110417","DOIUrl":"10.1016/j.cclet.2024.110417","url":null,"abstract":"","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"36 2","pages":"Article 110417"},"PeriodicalIF":9.4,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142699592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-05DOI: 10.1016/j.cclet.2023.108998
Shan Jiang , Lingchen Meng , Wenyue Ma , Qingkai Qi , Wei Zhang , Bin Xu , Leijing Liu , Wenjing Tian
{"title":"Corrigendum to “Morphology controllable conjugated network polymers based on AIE-active building block for TNP detection”","authors":"Shan Jiang , Lingchen Meng , Wenyue Ma , Qingkai Qi , Wei Zhang , Bin Xu , Leijing Liu , Wenjing Tian","doi":"10.1016/j.cclet.2023.108998","DOIUrl":"10.1016/j.cclet.2023.108998","url":null,"abstract":"","PeriodicalId":10088,"journal":{"name":"Chinese Chemical Letters","volume":"35 12","pages":"Article 108998"},"PeriodicalIF":9.4,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S100184172300788X/pdfft?md5=7b2fd6712dfae77b1d0fbf30c42a8345&pid=1-s2.0-S100184172300788X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142149364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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