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Thermally conductive alumina/organic composites for photovoltaic concentrator cell isolation 光伏聚光器电池隔离用导热氧化铝/有机复合材料
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105923
L.C. Beavis, J. Panitz, D. J. Sharp
Styrene-acrylate copolymer coatings were deposited onto anodized aluminum substrates and the processing characteristics correlated with coating properties. The aluminum (5005-H34) alloy trough or housing module was anodized in a chilled (0-5 degrees C) 18% aqueous sulfuric acid bath. The entire housing was anodized to 50 V at a current density of 1.4 A/dm/sup 2/. A styrene-acrylate copolymer electrophoretic bath was prepared, and the bottom of the inside of the module was electrocoated at 0.5 mA/cm/sup 2/ for 120 s. Breakdown measurements were obtained by placing a probe on the coating composite and gradually increasing the voltage until a current in excess of 10 mA occurred. The results indicate that thin, relatively high thermal conductivity, high-voltage breakdown dielectrics can be formed using this economical process.<>
在阳极氧化铝基体上沉积了苯乙烯-丙烯酸酯共聚物涂层,其工艺特性与涂层性能有关。铝(5005-H34)合金槽或外壳模块在冷冻(0-5℃)18%硫酸水溶液浴中阳极氧化。整个外壳在1.4 a /dm/sup 2/的电流密度下阳极氧化至50 V。制备苯乙烯-丙烯酸酯共聚物电泳液,模块内部底部以0.5 mA/cm/sup 2/的速度电泳120 s。击穿测量是通过在涂层复合材料上放置探针并逐渐增加电压直到电流超过10ma来获得的。结果表明,使用这种经济的方法可以形成薄的、导热系数相对较高的高压击穿电介质。
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引用次数: 5
Electron and proton radiation effects on GaAs and CuInSe/sub 2/ thin film solar cells 电子和质子辐射对GaAs和CuInSe/sub 2/薄膜太阳能电池的影响
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105835
R. Burgess, W.S. Chen, W. Devaney, D. H. Doyle, N. Kim, B. Stanbery
The effects of proton and electron radiation on the performances of GaAs and CuInSe/sub 2//CdZnS (CIS) thin-film solar cells are evaluated. Bare cells (i.e. with no coverglass) were exposed to several energies of electron and proton radiation, and their performances were monitored by illuminated I-V curves, dark I-V curves, and spectral response measurements at different fluence levels. These experiments reconfirm that no measurable damage occurs to CIS solar cells when exposed to 1 and 2 MeV electrons to a total fluence of 5.0*10/sup 15/ cm/sup -2/. For proton irradiations, the results indicate that CIS cells are more radiation resistant than GaAs cells, by a factor of ten, when compared at the same energy levels. Comparison of the electron and proton irradiation results to those reported in the literature shows that the thin-film GaAs solar cells are as radiation resistant as other GaAs bulk cells at 1.0 MeV protons and are more radiation resistant at both the 1.0 MeV electron and 200 keV proton energies.<>
研究了质子和电子辐射对GaAs和CuInSe/ sub2 //CdZnS (CIS)薄膜太阳能电池性能的影响。将裸电池(即没有覆盖玻璃)暴露在几种能量的电子和质子辐射下,并通过照明I-V曲线、暗I-V曲线和不同影响水平下的光谱响应测量来监测其性能。这些实验再次证实,当暴露在1和2 MeV的电子中,总影响为5.0*10/sup 15/ cm/sup -2/时,CIS太阳能电池没有可测量的损伤。对于质子辐照,结果表明,在相同的能量水平下,CIS细胞比GaAs细胞具有更强的抗辐射性,其抗辐射性是GaAs细胞的十倍。将电子和质子辐照结果与文献报道的结果进行比较,表明薄膜GaAs太阳电池在1.0 MeV质子辐照下的抗辐射性能与其他GaAs体电池相当,在1.0 MeV电子和200 keV质子辐照下的抗辐射性能更强
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引用次数: 22
Design of hybrid PV systems 混合光伏系统的设计
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105889
H. Saha, R. Sathpathy, D. Mukherjee
A generalized design methodology based on a basic need criterion was developed for a hybrid PV power system. Application of this methodology to a nonelectrified Indian village in Orissa yielded acceptable values of the optimum mixing ratio of the PV and wind energies. It is shown how PV and wind complement each other to provide year-long dependable energy economically.<>
提出了一种基于基本需求准则的混合光伏发电系统通用设计方法。将这种方法应用于奥里萨邦一个未通电的印度村庄,得出了光伏和风能的最佳混合比例的可接受值。它展示了光伏和风能如何相互补充,经济地提供全年可靠的能源。
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引用次数: 0
A critical analysis of the determination of the density of defects in a-Si/sub 1-x/Ge/sub x/ alloys with the PDS technique PDS技术测定A - si /sub - 1-x/Ge/sub -x/合金缺陷密度的关键分析
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105690
D. Della Sala, C. Reita, G. Conte, F. Galluzzi, G. Grillo
The application of PDS (photothermal deflection spectroscopy) to the counting of defect states is complicated in a-Ge/sub x/Si/sub 1-x/ by the coexistence of two types of dangling bonds and their unknown energetic position in the forbidden energy gap. Using a model density of states, the authors conclude that it is intrinsically impossible to distinguish between Si and Ge dangling bonds. In addition, despite the fact that the density of bulk defects can be evaluated successfully, it is suggested that there is always a spurious absorption due to surface states. The measured density of dangling bonds keeps increasing from pure a-Si:H (N/sub d/ equivalent to 2*10/sup 16/ cm/sup -3/) to pure a-Ge:H (N/sub d/ equivalent to 5*10/sup 17/ cm/sup -3/), and this is shown to be a material property.<>
在a-Ge/sub x/Si/sub 1-x/中,由于两种悬空键的共存以及它们在禁能隙中的未知能量位置,使得PDS(光热偏转光谱)在缺陷态计数中的应用变得复杂。使用模型态密度,作者得出结论,从本质上讲,不可能区分Si和Ge悬空键。此外,尽管可以成功地评估体缺陷的密度,但由于表面状态的原因,总是存在虚假吸收。悬空键的测量密度从纯a- si:H (N/sub d/相当于2*10/sup 16/ cm/sup -3/)到纯a- ge:H (N/sub d/相当于5*10/sup 17/ cm/sup -3/)不断增加,这是一种材料性质。
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引用次数: 0
Electrochemical and galvanic corrosion effects in thin-film photovoltaic modules 薄膜光伏组件中的电化学和电偶腐蚀效应
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105667
G. Mon, L. Wen, J. Meyer, R. Ross, A. Nelson
The electrochemical and galvanic corrosion properties of thin-film photovoltaic (TF-PV) modules (solar cells) and module subcomponents are determined and interpreted in the light of established corrosion science. Results of a detailed study of thin-film aluminum metallization corrosion are presented. Bar-graph corrosion, observed in fielded modules, has been induced experimentally and found to be electrochemical in nature. Corrosion rates and passivation techniques for TF-PV modules are discussed.<>
薄膜光伏(TF-PV)组件(太阳能电池)和组件子组件的电化学和电腐蚀特性根据已建立的腐蚀科学进行了确定和解释。介绍了薄膜铝金属化腐蚀的详细研究结果。在现场模块中观察到的条形图腐蚀已经在实验中引起,并且发现本质上是电化学的。讨论了TF-PV组件的腐蚀速率和钝化技术。
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引用次数: 26
Test and study of utility interface and control problems for residential PV systems in Rokko Island 200 kW test facility 住宅光伏系统在六甲岛200kw试验台的效用接口及控制问题的测试与研究
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105868
Y. Takeda, K. Takigawa, H. Kobayashi, K. Nakahara, T. Morishita, A. Kitamura, A. Miyoshi, H. Matsuda, S. Komatsu
A 200 kW test facility comprising one hundred 2 kWp PV systems and a simulated utility grid was constructed to establish an adequate utility interface and control technology for small-scale dispersed PV systems. Experimental results are described. Demonstration experiments were performed, and the results show that the harmonic distortion in the distribution line was little influenced, and the problem of harmonics has been almost solved. It is confirmed that appropriate measures must be established for prevention of voltage variation in the low-voltage distribution line and for prevention of islanding during power outages. Solutions to these problems were also investigated using this facility.<>
建立了一个200千瓦的测试设施,包括100个2千瓦的光伏系统和一个模拟的公用事业电网,以建立一个适当的小型分散光伏系统的公用事业接口和控制技术。描述了实验结果。实验结果表明,该方法对配电网谐波畸变影响不大,基本解决了配电网谐波问题。确认必须制定适当的措施防止低压配电线路的电压变化和防止停电时的孤岛。这些问题的解决方案也研究了使用该设施
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引用次数: 2
Deposition of CuInSe/sub 2/ by the hybrid sputtering-and-evaporation method 溅射-蒸发法沉积CuInSe/ sub2 /
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105961
A. Rockett, T. Lommasson, L. Yang, H. Talieh, P. Campos, J. Thornton
The initial results of experiments characterizing CuInSe/sub 2/ deposition by a hybrid sputtering-and-evaporation technique are presented. The method yields films with compositions and structural properties comparable with those commonly accepted for polycrystalline CuInSe/sub 2/ over a large composition range at growth temperatures up to 450 degrees C. Film compositions are uniform to within +or-1 atomic percent, and nonuniformities can be directly related to the deposition geometry. The Se flux is shown to play a major role in determining both the Se and the In contents of the films at elevated temperatures. The substrate properties strongly affect the film composition. Layers deposited on sputtered Mo surfaces exhibit a lower In content than films on glass at all temperatures examined. Cu, In, and Se diffusion into the column boundaries of the Mo substrates is observed at all growth temperatures.<>
介绍了用溅射和蒸发混合技术表征CuInSe/ sub2 /沉积的初步实验结果。在高达450摄氏度的生长温度下,该方法产生的薄膜的成分和结构性能与多晶CuInSe/sub 2/在很大的成分范围内被普遍接受的薄膜相当。薄膜的成分均匀到+或1个原子百分比,而不均匀性可以直接与沉积几何形状有关。在高温下,硒通量对薄膜中硒和铟含量的测定起着重要作用。衬底性质强烈地影响薄膜的组成。在所有温度下,沉积在溅射Mo表面上的层显示出比玻璃膜更低的In含量。在所有生长温度下都观察到Cu、In和Se向Mo衬底柱边界的扩散。
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引用次数: 8
Modelling of the influence of dislocations on effective diffusion length and photocurrent of polycrystalline silicon cells 位错对多晶硅电池有效扩散长度和光电流影响的建模
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105987
H. El Ghitani, S. Martinuzzi
Green's function is used to establish a three-dimensional model to obtain a detailed rigorous analytical expression of the effect of dislocations. The predictions of the model were verified by measuring the photocurrent, the spectral response, and the effective diffusion lengths of minority carriers (L/sub eff/) and by evaluating the dislocation etch pit density. Three materials are considered, POLYX, SILSO, and SEMIX, which differ by the value of the diffusion length (L/sub n/) in the homogeneous regions of the bulk. It is found that the values of J/sub sc/ and L/sub eff/ are dependent on N/sub dis/ and S/sub d/ provided they are greater than 10/sup 4/ cm/sup -2/ and 10/sup 4/ cm-s/sup -1/, respectively. The computed variations also depend on the value of the diffusion length in the homogeneous region of the bulk material. A reasonable agreement is found with experimental results obtained with large-grained polycrystalline materials such as SILSO and POLYX.<>
利用格林函数建立三维模型,得到位错影响的详细严密的解析表达式。通过测量光电流、光谱响应、少数载流子的有效扩散长度(L/sub / eff/)和位错蚀刻坑密度,验证了模型的预测。考虑了三种材料,POLYX, SILSO和SEMIX,它们在块体均匀区域的扩散长度(L/sub n/)的值不同。发现J/sub sc/和L/sub eff/的值取决于N/sub dis/和S/sub d/,只要它们分别大于10/sup 4/ cm/sup -2/和10/sup 4/ cm- S/ sup -1/。计算的变化也取决于扩散长度的值在块材料的均匀区域。与大晶粒多晶材料SILSO和POLYX.>的实验结果一致
{"title":"Modelling of the influence of dislocations on effective diffusion length and photocurrent of polycrystalline silicon cells","authors":"H. El Ghitani, S. Martinuzzi","doi":"10.1109/PVSC.1988.105987","DOIUrl":"https://doi.org/10.1109/PVSC.1988.105987","url":null,"abstract":"Green's function is used to establish a three-dimensional model to obtain a detailed rigorous analytical expression of the effect of dislocations. The predictions of the model were verified by measuring the photocurrent, the spectral response, and the effective diffusion lengths of minority carriers (L/sub eff/) and by evaluating the dislocation etch pit density. Three materials are considered, POLYX, SILSO, and SEMIX, which differ by the value of the diffusion length (L/sub n/) in the homogeneous regions of the bulk. It is found that the values of J/sub sc/ and L/sub eff/ are dependent on N/sub dis/ and S/sub d/ provided they are greater than 10/sup 4/ cm/sup -2/ and 10/sup 4/ cm-s/sup -1/, respectively. The computed variations also depend on the value of the diffusion length in the homogeneous region of the bulk material. A reasonable agreement is found with experimental results obtained with large-grained polycrystalline materials such as SILSO and POLYX.<<ETX>>","PeriodicalId":10562,"journal":{"name":"Conference Record of the Twentieth IEEE Photovoltaic Specialists Conference","volume":"10 1","pages":"1624-1628 vol.2"},"PeriodicalIF":0.0,"publicationDate":"1988-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72967522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Photon degradation of AlGaAs/GaAs solar cells AlGaAs/GaAs太阳能电池的光子降解
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105852
B. Anspaugh, R. Kachare, P. Iles
The behavior of GaAs solar cells after photon illumination for a prolonged exposure time is presented. More than 55 OMCVD AlGaAs/GaAs solar cells were exposed for over 400 h to AM0 photons at 29 degrees C in three separate, well-controlled runs. Significant degradation of solar cell efficiency was observed in two out of three runs. Although noticeable losses in the open-circuit voltage, fill factor, and maximum power were observed, no change in the short-circuit current was found. In one of the runs, no change was seen in either the test cells or the control cells. Each cell in this run was protected with a coverglass. The cells in this run had thicker buffer layers and thinner window layers than the cells in the other two runs.<>
研究了砷化镓太阳能电池在长时间曝光后的发光特性。超过55个OMCVD AlGaAs/GaAs太阳能电池在29摄氏度的温度下,在三个独立的、控制良好的运行中暴露在AM0光子下超过400小时。在三次运行中有两次观察到太阳能电池效率显著下降。虽然开路电压、填充系数和最大功率有明显的损失,但短路电流没有变化。在其中一次运行中,在测试细胞或控制细胞中都没有看到变化。这一趟的每个牢房都用玻璃罩保护着。与其他两次运行的细胞相比,这次运行的细胞具有更厚的缓冲层和更薄的窗口层
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引用次数: 4
Photoluminescence quenching by electric fields in hydrogenated amorphous silicon 氢化非晶硅的电场致光猝灭
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105686
T. Muschik, R. Schwarz, H. Curtins, M. Favre
The decrease of photoluminescence (PL) intensity at low temperature was measured as a function of external fields (up to 3*10/sup 5/ V/cm) in hydrogenated amorphous silicon (a-Si:H). The results are discussed within the framework of the recombination of geminate pairs together with basic physical phenomena such as carrier separation during thermalization trapping of photoexcited carriers in band tails, and possible subsequent reemission or tunneling out of traps. It is concluded that separation of carriers during relaxation in extended and flat tail states is the dominant process for the field quenching of PL intensity. But other processes such as Poole-Frenkel emission and tunneling out of traps cannot be ruled out totally. The basic idea of carrier separation is supported by consistent values for the average mobility from both the quenching of PL intensity with electric fields and the concomitant energy shift of the maximum in the PL spectra.<>
测量了氢化非晶硅(a- si:H)在低温下的光致发光(PL)强度随外加电场(高达3*10/sup 5/ V/cm)的变化规律。讨论了这些结果,并结合了一些基本的物理现象,如光激发载流子在带尾的热化捕获过程中的载流子分离,以及随后可能的再发射或隧穿出陷阱。结果表明,在扩展尾和平尾弛豫状态下载流子的分离是导致PL强度场猝灭的主要原因。但也不能完全排除其他过程,如普尔-弗伦克尔发射和隧道出陷阱。载流子分离的基本思想得到了电场对PL强度的猝灭和PL光谱中最大值的伴随能量位移的平均迁移率的一致值的支持。
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引用次数: 2
期刊
Conference Record of the Twentieth IEEE Photovoltaic Specialists Conference
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