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A novel design for amorphous silicon alloy solar cells 非晶硅合金太阳能电池的新设计
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105659
S. Guha, J. Yang, A. Pawlikiewicz, T. Glatfelter, R. Ross, S. Ovshinsky
The authors have developed an amorphous silicon alloy-based solar cell with a novel structure. Computer simulation studies show that for a given short-circuit current, it is possible to obtain a higher open-circuit voltage and fill factor than in a conventional cell design. For a nominal 1.5 eV a-SiGe alloy, the fill factor under red illumination can be improved from 0.55 to 0.64 for the same short-circuit current. Experimental cell structures confirm the theoretical prediction. The novel cell design shows a considerable improvement in efficiency. Dynamic internal collection efficiency measurements show reduced recombination in these cells, which gives rise to the observed higher fill factors. Incorporation of this structure in the bottom cell of a triple device has resulted in the achievement of 13.7% efficiency under global AM1.5 illumination.<>
作者开发了一种结构新颖的非晶硅基太阳能电池。计算机仿真研究表明,对于给定的短路电流,可以获得比传统电池设计更高的开路电压和填充因子。对于标称1.5 eV的a- sige合金,在相同的短路电流下,红色照明下的填充因子可以从0.55提高到0.64。实验细胞结构证实了理论预测。这种新颖的电池设计在效率上有了相当大的提高。动态内部收集效率测量表明,这些细胞中的重组减少了,这导致了观察到的更高的填充因子。将这种结构结合到三联器件的底部电池中,在全局AM1.5照明下,效率达到13.7%
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引用次数: 15
Characterization and modeling of InP solar cells InP太阳能电池的表征与建模
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105834
G. Augustine, A.W. Smith, A. Rohatgi, C. Keavney
InP solar cells were modeled before and after proton irradiation using a PC-1D computer model. It was necessary to include bandgap narrowing in the n/sup +/ emitter to match the calculated and measured quantum efficiency, leakage current, and cell data simultaneously. A high-efficiency ( approximately=18.2%, AM0) InP solar cell was fabricated and modeled successfully. Guidelines are provided for achieving greater than 22% efficiency for InP cells. A 10 MeV proton irradiation with a dose of 2*10/sup 13/ cm/sup -2/ reduces the cell performance of a 16.3% cell to 11% by introducing the deep levels at an E/sub v/ of +0.29 eV and an E/sub v/ of +0.52 eV. Modeling showed that this performance degradation is associated with a decrease in bulk lifetime from 0.75 to 0.028 ns with no appreciable change in front surface recombination velocity.<>
利用PC-1D计算机模型对质子辐照前后的InP太阳能电池进行建模。有必要在n/sup +/发射器中包括带隙缩小,以同时匹配计算和测量的量子效率,泄漏电流和电池数据。制备了一种高效(约=18.2%,AM0)的InP太阳能电池,并成功地建立了模型。为实现大于22%的InP电池效率提供了指南。以2*10/sup 13/ cm/sup -2/的剂量进行10 MeV质子辐照,通过引入E/sub v/ +0.29 eV和E/sub v/ +0.52 eV的深层能级,将16.3%的电池性能降低到11%。建模表明,这种性能下降与整体寿命从0.75 ns减少到0.028 ns有关,而前表面复合速度没有明显变化。
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引用次数: 6
High-efficiency GaAs solar cells from a multiwafer OMVPE reactor 基于多晶片OMVPE反应器的高效砷化镓太阳能电池
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105807
K. Bertness, M. Ristow, H. C. Hamaker
A p/n GaAs solar cell with 24.0% efficiency under 1-sun global illumination (AM1.5, 1000 W/m/sup 2/) has been grown in a multiwafer organometallic vapor-phase epitaxy (OMVPE) reactor. This reactor has demonstrated good uniformity both from run to run and within a single run as part of a pilot line for the batch production of high-efficiency GaAs cells. The 24% efficiency value represents the highest efficiency reported to date for any solar cell under these conditions. The improved performance of these cells is believed to be mostly due to careful control of the emitter doping.<>
在多晶片有机金属气相外延(OMVPE)反应器中,在1太阳全局光照(AM1.5, 1000 W/m/sup 2/)下,生长出了效率为24.0%的p/n GaAs太阳能电池。作为批量生产高效砷化镓电池的中试生产线的一部分,该反应器在每次运行和单次运行中都表现出良好的均匀性。24%的效率值代表了迄今为止报道的在这些条件下任何太阳能电池的最高效率。这些电池性能的提高被认为主要是由于对发射极掺杂的仔细控制
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引用次数: 5
Development in silicon sheet technologies 硅片技术的发展
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105932
A. Goetzberger, A. Rauber
The status of techniques for the production of sheets, ribbons, and foils of silicon for solar cells is reviewed. Technical problems and economic constraints are analyzed. The horizontal support web technique relies on a wedge-shaped growth interface which decouples the pulling velocity and the growth velocity which are nearly perpendicular to each other. The growing ribbon floats on a silicon melt that is contained in a long silicon crucible and is withdrawn to one side. In the ramp assistant foil technique, the silicon melt is contained in a relatively flat crucible that is open on one side. A preheated substrate is moved across this opening, and some of the melt solidifies on the surface. The silicon-sheets-from-powder technique starts from Si powder or granular silicon (grain size: 50-500 mu m). Three steps are needed to obtain the final ribbon. It is concluded that although the basic ideas as well as the results of these three methods are very distinct, evaluation of their respective merits is difficult.<>
综述了太阳能电池用硅片、硅带和硅箔的生产技术现状。分析了技术问题和经济制约因素。水平支撑腹板技术依赖于一个楔形生长界面,该界面解耦了几乎相互垂直的拉拔速度和生长速度。生长的条带漂浮在硅熔体上,硅熔体包含在一个长硅坩埚中,并向一侧收缩。在斜坡辅助箔技术中,硅熔体被包含在一个相对平坦的坩埚中,坩埚在一侧打开。预热过的基材穿过这个开口,一些熔体在表面凝固。硅片制粉技术从硅粉或颗粒硅(粒度50-500 μ m)开始,需要三步才能得到最终的硅带。结果表明,虽然这三种方法的基本思想和结果非常不同,但很难对它们各自的优点进行评价。
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引用次数: 3
Phosphorous and boron doping of a-Si-Ge:H alloys and its effect on p-i-n solar cells a-Si-Ge:H合金的磷硼掺杂及其对p-i-n太阳能电池的影响
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105660
R. Arya, J. Newton, B. Fieselmann
The performance of single-junction a-SiGe:H p-i-n solar cells has been optimized by addressing the alloy composition of the n-layer, the importance of the i(a-SiGe:H)/n interface, and the modification of hole transport in the intrinsic layer by low-level boron doping. The dark conductivity of an a-SiGe:H n-layer was about one order of magnitude lower than that of an a-Si:H n-layer, with a difference of 0.092 eV in the activation energy. Devices with an a-Si:H n-layer have superior performance with higher short-circuit current and FF (fill factor). An inverse graded layer at the i/n interface further improves the FF. Low-level boron doping of the i-layer shifts the Fermi level and changes the charge state of the recombination centers, resulting in an improvement in the long-wavelength response of devices. This optimization has led to an a-SiGe:H solar cell with a conversion efficiency of 10.1% for a short-circuit current density of 20.1 mA/cm/sup 2/.<>
通过解决n层的合金组成、i(a-SiGe:H)/n界面的重要性以及低水平硼掺杂对本征层空穴输运的修饰,优化了单结a-SiGe:H -i-n太阳能电池的性能。a- sige:H - n层的暗电导率比a- si:H - n层低约一个数量级,活化能相差0.092 eV。具有a-Si:H - n层的器件具有更高的短路电流和FF(填充因子),性能优越。在i/n接口处的反向渐变层进一步改善了FF。在i层中掺杂低水平硼,使费米能级发生位移,改变了复合中心的电荷状态,从而提高了器件的长波响应。这种优化导致a- sige:H太阳能电池在短路电流密度为20.1 mA/cm/sup 2/.>时转换效率为10.1%
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引用次数: 0
Recent results on ion-beam hydrogenation of amorphous silicon 离子束加氢非晶硅的研究进展
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105670
Y. Tsuo, Y. Xu, A. Mascarenhas, S. Deb, A. K. Barua
The ion-beam hydrogenation of undoped amorphous silicon for solar cells obtained by dehydrogenation of glow-discharge-deposited a-Si:H, by glow-discharge deposition at 480 degrees C, and by RF magnetron-sputter deposition was investigated. A Kaufman ion source was used to introduce hydrogen atoms into the a-Si:H. Highly photosensitive a-Si:H films with up to 20 at.% hydrogen bonded predominantly as monohydrides were obtained. The authors report results of Raman Scattering measurements of magnetron-sputtering-deposited amorphous silicon before and after hydrogenation, comparisons of ion-beam and RF posthydrogenation techniques, and a possible application of the ion-beam hydrogenation technique.<>
研究了用发光放电沉积的a-Si:H脱氢、480℃下发光放电沉积和射频磁控溅射沉积制备的太阳能电池用未掺杂非晶硅的离子束加氢。采用Kaufman离子源将氢原子引入到A - si:H中。高度感光的a-Si:H薄膜,高达20 at。得到了以一氢化物为主的氢键。作者报告了磁控溅射沉积非晶硅加氢前后的拉曼散射测量结果,离子束和射频加氢后技术的比较,以及离子束加氢技术的可能应用。
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引用次数: 0
Weldability of GaAs solar cells on either GaAs or Ge substrates GaAs太阳能电池在GaAs或Ge衬底上的可焊性
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105849
C. Chu
A three-dimensional, time-dependent model is developed for parallel gap welding of GaAs/GaAs and GaAs/Ge solar cells. Both GaAs/GaAs and GaAs/Ge solar cells have been welded successfully. However, variations in welding conditions can lead to defects that affect the electrical performance or the reliability of cells interconnected into arrays. In many cases, the main defects are small cracks. The results of the modeling show that cracks can be caused by insufficient dissipation of the heat generated by the welding current. The model also shows that welding cracks can be reduced by changing the welding parameters (reducing weld energy, decreasing the size of the welded region between the probe contact areas). When the calculated welding procedures were implemented, acceptable welds were obtained.<>
建立了GaAs/GaAs和GaAs/Ge太阳能电池平行间隙焊接的三维时效模型。GaAs/GaAs和GaAs/Ge太阳能电池均已成功焊接。然而,焊接条件的变化可能导致影响电气性能或连接成阵列的电池的可靠性的缺陷。在许多情况下,主要缺陷是小裂纹。模拟结果表明,焊接电流产生的热量散失不足会导致裂纹的产生。该模型还表明,通过改变焊接参数(降低焊接能量、减小探头接触区域之间的焊接区域尺寸)可以减小焊接裂纹。当计算的焊接程序被执行时,得到了可接受的焊缝。
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引用次数: 4
The measurement of bulk and surface recombination by means of modulated free carrier absorption 用调制自由载流子吸收法测量体积和表面复合
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105767
F. Sanii, R. J. Schwartz, R.F. Pierret, W. Au
A measurement technique is described which makes it possible to monitor the lifetime and surface recombination velocity of the starting wafer as well as a partially or completely processed wafer in the Si solar-cell fabrication process. This technique uses an infrared laser to monitor the carrier concentration via free carrier absorption while periodically exciting free carriers by means of a visible laser. The excited laser is sinusoidally modulated with an electro-optical modulator at frequencies of 100 Hz to 100 kHz. The free carriers generated by the exciter beam attenuate the probe beam, and the resultant output is detected with a phase-sensitive lock-in amplifier. The quantities measured are the amplitude and the phase of the detected signal relative to the exciter beam. The measured data are then fitted to theoretical expressions, and the bulk lifetime and surface recombination velocities are determined. The amplitude and phase are independent quantities, and the computed values from the two sets of data provide a self-consistency test.<>
本文描述了一种测量技术,该技术可以监测硅太阳能电池制造过程中起始晶片以及部分或完全加工晶片的寿命和表面复合速度。该技术利用红外激光通过自由载流子吸收来监测载流子浓度,同时利用可见光激光周期性地激发自由载流子。被激发的激光用电光调制器在100赫兹到100千赫的频率上进行正弦调制。激发光束产生的自由载流子使探测光束衰减,由此产生的输出由相敏锁相放大器检测。测量的量是相对于激振器光束的被检测信号的幅度和相位。然后将实测数据拟合为理论表达式,确定了体寿命和表面复合速度。振幅和相位是独立的量,两组数据的计算值提供了自一致性检验。
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引用次数: 10
IEEE and IEC photovoltaic standards update IEEE和IEC光伏标准更新
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105907
J. Wohlgemuth, R. Klein
The IEEE Standards Coordinating Committee 21, Photovoltaics (PV) and the International Electrotechnical Commission (IEC) Technical Committee (TC82) on Photovoltaics are developing photovoltaic standards. Documents that have been published, are in press, have been approved for publication, or are in the review process, are described. Work is also continuing on preparation of documents for design qualification of modules, on-site systems measurements, and procedures for various environmental tests.<>
IEEE标准协调委员会21、光伏(PV)和国际电工委员会(IEC)光伏技术委员会(TC82)正在制定光伏标准。描述已出版的、正在出版的、已批准出版的或正在审查过程中的文件。为模块的设计鉴定、现场系统测量和各种环境测试程序准备文件的工作也在继续。
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引用次数: 2
Electron radiation and annealing of MOCVD GaAs and GaAs/Ge solar cells MOCVD GaAs和GaAs/Ge太阳能电池的电子辐射和退火
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105839
M. Chung, D. Meier, J.R. Szedon, J. Bartko
A comparison of the radiation tolerances of MOCVD-grown GaAs/GaAs cells and GaAs/Ge cells was undertaken using 1 MeV electrons. The electron radiation was delivered in doses of 1*10/sup 16/ cm/sup -2/ up to a total dose of 1*10/sup 17/ cm/sup -2/ for GaAs/GaAs and a total dose of 7*10/sup 16/ cm/sup -2/ for GaAs/Ge. Following each dose, the cells were annealed at either 250 degrees C or 300 degrees C for 1 h in nitrogen. It was found that the radiation tolerance of the GaAs/Ge cells was superior to that of the GaAs/GaAs cells. DLTS and EBIC measurements are presented.<>
利用1mev电子对mocvd生长的GaAs/GaAs细胞和GaAs/Ge细胞的辐射耐受性进行了比较。电子辐射剂量为1*10/sup 16/ cm/sup -2/, GaAs/GaAs的总剂量为1*10/sup 17/ cm/sup -2/, GaAs/Ge的总剂量为7*10/sup 16/ cm/sup -2/。每次给药后,细胞在250℃或300℃的氮气中退火1小时。结果表明,GaAs/Ge细胞的耐辐射性能优于GaAs/GaAs细胞。介绍了DLTS和EBIC测量方法。
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引用次数: 3
期刊
Conference Record of the Twentieth IEEE Photovoltaic Specialists Conference
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