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Deposition of CuInSe/sub 2/ by the hybrid sputtering-and-evaporation method 溅射-蒸发法沉积CuInSe/ sub2 /
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105961
A. Rockett, T. Lommasson, L. Yang, H. Talieh, P. Campos, J. Thornton
The initial results of experiments characterizing CuInSe/sub 2/ deposition by a hybrid sputtering-and-evaporation technique are presented. The method yields films with compositions and structural properties comparable with those commonly accepted for polycrystalline CuInSe/sub 2/ over a large composition range at growth temperatures up to 450 degrees C. Film compositions are uniform to within +or-1 atomic percent, and nonuniformities can be directly related to the deposition geometry. The Se flux is shown to play a major role in determining both the Se and the In contents of the films at elevated temperatures. The substrate properties strongly affect the film composition. Layers deposited on sputtered Mo surfaces exhibit a lower In content than films on glass at all temperatures examined. Cu, In, and Se diffusion into the column boundaries of the Mo substrates is observed at all growth temperatures.<>
介绍了用溅射和蒸发混合技术表征CuInSe/ sub2 /沉积的初步实验结果。在高达450摄氏度的生长温度下,该方法产生的薄膜的成分和结构性能与多晶CuInSe/sub 2/在很大的成分范围内被普遍接受的薄膜相当。薄膜的成分均匀到+或1个原子百分比,而不均匀性可以直接与沉积几何形状有关。在高温下,硒通量对薄膜中硒和铟含量的测定起着重要作用。衬底性质强烈地影响薄膜的组成。在所有温度下,沉积在溅射Mo表面上的层显示出比玻璃膜更低的In含量。在所有生长温度下都观察到Cu、In和Se向Mo衬底柱边界的扩散。
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引用次数: 8
Material quality and design optimization for high efficiency GaAs solar cells 高效砷化镓太阳能电池的材料质量和设计优化
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105787
S. Ringel, A. Rohatgi
A methodology is developed to determine minority carrier lifetime and recombination velocity in high-efficiency GaAs p/n heteroface solar cells. A combination of measurements and modeling is used to demonstrate that a base lifetime of 8 ns and a heteroface recombination velocity of 1.25*10/sup 5/ cm/s are necessary to simulate the spectral response, cell data, and leakage current in a 21.2% efficient GaAs cell. Optimization of the p/n heteroface structure shows that AM1.5 one-sun efficiencies of approximately 25% are achievable from a thin base/buffer design with a base lifetime of only 15 ns and a well-passivated back surface. In addition, it is shown that the doping dependence of the Shockley-Read-Hall lifetime is an important consideration in GaAs device modeling, especially if a shallow level ( approximately E/sub t/=0.2 eV) limits the bulk lifetime.<>
提出了一种确定高效砷化镓p/n异质面太阳能电池中少数载流子寿命和复合速度的方法。测量和建模的结合表明,在21.2%效率的GaAs电池中,需要8 ns的基寿命和1.25 × 10/sup 5/ cm/s的异质面复合速度来模拟光谱响应、电池数据和泄漏电流。p/n异质面结构优化表明,AM1.5单太阳效率约为25%,采用薄基底/缓冲设计,基底寿命仅为15 ns,背面钝化良好。此外,研究表明,掺杂对肖克利-里德-霍尔寿命的依赖性是GaAs器件建模中的一个重要考虑因素,特别是当浅电平(约E/sub /=0.2 eV)限制了体寿命时。
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引用次数: 6
A new light trapping structure for very-thin, high-efficiency silicon solar cells 一种用于超薄高效硅太阳能电池的新型光捕获结构
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105813
T. Uematsu, M. Ida, K. Hane, Y. Hayashi, T. Saitoh
A novel cell structure with aligned V-grooves on each side is proposed to realize very thin silicon solar cells. The thickness can be less than 50 mu m without reduction of mechanical strength. This structure provides a very high light-trapping effect. The light-generated current in this structure is calculated as 40.58 mA/cm/sup 2/ under AM1.5 100 mW/cm/sup 2/ sunlight. This structure is expected to realize high efficiency, close to the limiting efficiency of around 29% and to yield fruitful results in concentrator cells.<>
为了实现超薄硅太阳能电池,提出了一种新的电池结构,每侧都有对齐的v型槽。厚度可小于50 μ m而不降低机械强度。这种结构提供了非常高的光捕获效果。在AM1.5 100 mW/cm/sup 2/阳光下,该结构产生的光电流计算为40.58 mA/cm/sup 2/。这种结构有望实现高效率,接近29%左右的极限效率,并在聚光电池中产生丰硕的成果。
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引用次数: 8
Phosphorous and boron doping of a-Si-Ge:H alloys and its effect on p-i-n solar cells a-Si-Ge:H合金的磷硼掺杂及其对p-i-n太阳能电池的影响
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105660
R. Arya, J. Newton, B. Fieselmann
The performance of single-junction a-SiGe:H p-i-n solar cells has been optimized by addressing the alloy composition of the n-layer, the importance of the i(a-SiGe:H)/n interface, and the modification of hole transport in the intrinsic layer by low-level boron doping. The dark conductivity of an a-SiGe:H n-layer was about one order of magnitude lower than that of an a-Si:H n-layer, with a difference of 0.092 eV in the activation energy. Devices with an a-Si:H n-layer have superior performance with higher short-circuit current and FF (fill factor). An inverse graded layer at the i/n interface further improves the FF. Low-level boron doping of the i-layer shifts the Fermi level and changes the charge state of the recombination centers, resulting in an improvement in the long-wavelength response of devices. This optimization has led to an a-SiGe:H solar cell with a conversion efficiency of 10.1% for a short-circuit current density of 20.1 mA/cm/sup 2/.<>
通过解决n层的合金组成、i(a-SiGe:H)/n界面的重要性以及低水平硼掺杂对本征层空穴输运的修饰,优化了单结a-SiGe:H -i-n太阳能电池的性能。a- sige:H - n层的暗电导率比a- si:H - n层低约一个数量级,活化能相差0.092 eV。具有a-Si:H - n层的器件具有更高的短路电流和FF(填充因子),性能优越。在i/n接口处的反向渐变层进一步改善了FF。在i层中掺杂低水平硼,使费米能级发生位移,改变了复合中心的电荷状态,从而提高了器件的长波响应。这种优化导致a- sige:H太阳能电池在短路电流密度为20.1 mA/cm/sup 2/.>时转换效率为10.1%
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引用次数: 0
Predicted performance of near-optimally designed indium phosphide space solar cells at high intensities and temperatures 预测了在高强度和高温度下近乎优化设计的磷化铟空间太阳能电池的性能
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105792
C. Goradia, W. Thesling, M. Ghalla-Goradia, I. Weinberg, C. K. Swartz
The authors calculated the expected performance dependence of near-optimally designed shallow homojunction n/sup +/pp/sup +/ InP solar cells on incident intensities up to 200 AMO and temperatures up to 100 degrees C (373 K). Both circular and rectangular cells were considered, the former for use in a Cassegrainian concentrator array at 100 AM0, 80-100 degrees C and the latter for use in a Slats concentrator array at 20 AM0, 80-100 degrees C. With efficiencies near 22% at 80 degrees C, both the circular and rectangular InP shallow homojunction solar cells compare very favorably to GaAs cells of the same design and may be preferable to the GaAs cells for space applications because of the superior radiation tolerance of the InP cells.<>
作者计算的预期性能依赖算法设计浅同质结n /一口+ / pp /一口+ /可使太阳能电池200 AMO事件强度和温度高达100摄氏度(373 K),圆形和矩形细胞被认为是,前者用于Cassegrainian集中器阵列AM0 100号80 - 100摄氏度,后者用于20 AM0板条集中器阵列,80 - 100度C与效率接近22%在80摄氏度,圆形和矩形InP浅同结太阳能电池与相同设计的GaAs电池相比都非常有利,并且由于InP电池具有优越的辐射耐受性,因此可能比GaAs电池更适合用于空间应用。
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引用次数: 4
Life-cycle comparison of different battery types for use with photovoltaic systems 光伏系统中不同类型电池的寿命周期比较
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105885
S. Lancashire
A summary of results from an extensive study of batteries for PV power systems is presented. The significant characteristics of high-quality lead-acid and nickel-cadmium batteries with respect to their use in PV power systems are compared and the results of a survey of user experiences are presented. For typical PV systems, comparative system sizings and life-cycle costs are presented for several types of battery. The conditions under which different battery types are most appropriate are identified. It is shown that nickel cadmium batteries are often a more cost-effective option than lead-acid batteries for PV systems. This applies in cold, temperature, and hot climates.<>
对光伏发电系统电池的广泛研究结果进行了总结。本文比较了优质铅酸电池和镍镉电池在光伏发电系统中使用的显著特点,并介绍了用户体验调查的结果。对于典型的光伏系统,比较了几种类型的电池的系统尺寸和生命周期成本。确定了不同类型的电池最适合的条件。研究表明,对于光伏系统而言,镍镉电池通常比铅酸电池更具成本效益。这适用于寒冷、高温和炎热的气候
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引用次数: 13
Hybrid renewable energy systems for off-shore naval installations 用于近海海军设施的混合可再生能源系统
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105890
G. Barlowe, R. Day, D. Kilfoyle, R. Roberts, G. Smith
An overview of the design and testing of a hybrid system consisting of two North Wind 12 kW wind generators, a 5 kW Solarex photovoltaic array, and a 138 kWh GNB battery bank to provide power for an offshore tactical aircrew combat training system is presented. Test data were collected via a data acquisition system which provided data collection and reduction into hourly averages, system operational status information, current data, and a user system control. During the prototype testing, the system compiled a 100% availability record. The installation of eight offshore platform power systems is discussed.<>
介绍了一个混合系统的设计和测试概况,该系统由两台12千瓦的北风风力发电机、一个5千瓦的Solarex光伏阵列和一个138千瓦时的GNB电池组组成,为海上战术机组战斗训练系统提供动力。测试数据通过数据采集系统收集,该系统将数据收集并还原为小时平均值、系统运行状态信息、当前数据和用户系统控制。在原型测试期间,系统编制了100%的可用性记录。讨论了八个海上平台电力系统的安装。
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引用次数: 2
Status of LIPS-II GaAs after five years in orbit LIPS-II GaAs在轨5年后的状态
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105859
J.D. Scorfield
Updated and reduced data through day 1995 as well as conclusions about the performance and behavior of the GaAs panel are presented. The performance of the GaAs panel, after initial severe degradation, is encouraging. The results support other data indicating that GaAs solar cells are a viable space power system component. Taking into account recent advances such as Ge substrate use, multibandgap efforts, and significant performance gains, the author concludes that GaAs cells are ready to become the next generation of photovoltaic cells supplying space power for military and commercial missions.<>
提出了截至1995年第一天的最新和减少的数据以及关于GaAs面板的性能和行为的结论。经过最初的严重退化,GaAs面板的性能是令人鼓舞的。结果支持了其他数据,表明砷化镓太阳能电池是一种可行的空间电力系统组件。考虑到最近的进展,如Ge衬底的使用,多带隙的努力,以及显著的性能提升,作者得出结论,GaAs电池已经准备好成为下一代光伏电池,为军事和商业任务提供空间电力
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引用次数: 0
Exact calculation of back surface recombination velocity and its influence on quantum efficiency of n/sup +/-p-p/sup +/ structure based silicon solar cells n/sup +/-p-p/sup +/结构硅太阳电池背面复合速度的精确计算及其对量子效率的影响
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105988
S.N. Singh, P.K. Singh
An exact theory of spectral response of thin-film epitaxial solar cells is developed, and a new expression for the effective back surface recombination velocity is derived. On the basis of this theory, the spectral response as a function of relevant cell parameters, such as dopings, diffusion lengths, and thicknesses of the substrate and epitaxial layer regions and the dead layer, is calculated. It was found that two effects mainly control the spectral response of epitaxial solar cells: (i) the doping ratio of substrate to epitaxial layer and (ii) the dead layer thickness. The former markedly influences the long wavelength region spectral response, while the latter has a profound effect on the short wavelength response. The theory also predicts a significant contribution from the substrate to the quantum efficiency.<>
建立了薄膜外延太阳能电池光谱响应的精确理论,导出了有效后表面复合速度的新表达式。在此理论的基础上,计算了光谱响应作为相关电池参数的函数,如掺杂、扩散长度、衬底和外延层区域以及死层的厚度。研究发现,控制外延太阳能电池光谱响应的主要因素有两个:(1)衬底与外延层的掺杂比和(2)死层厚度。前者对长波区光谱响应有显著影响,而后者对短波区光谱响应有深远影响。该理论还预测了衬底对量子效率的重要贡献。
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引用次数: 2
Improved prediction and analysis of cell performance at elevated temperatures 改进了高温下电池性能的预测和分析
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105769
G. Garlick, B.S. Smith
Improved modeling and analysis have been applied to data on Si solar cells made for the Magellan satellite (Venus orbits) at temperatures from -50 to 100 degrees C. Derived saturation currents for the cells have been used to calculate base minority carrier lifetimes. These rise with temperature, showing some saturation near 100 degrees C. Data are quantitatively explained by an energy band model with divacancy levels at 0.25 eV and impurity levels at 0.6 eV above the valance band. Close fits to experimental results are found for concentrations of 6*10/sup 12//cm/sup 3/ and 1.5-2*10/sup 11//cm/sup 3/ for the 0.25 and 0.6 eV levels, respectively. At 100 degrees C the saturation is controlled by the latter, while divacancies affect the lifetimes at lower temperatures. It is concluded that this analysis of quite usual test data for cells, coupled with temperature variation, provides a powerful insight into basic parameters which determine the cell operational performance.<>
改进的建模和分析已经应用于麦哲伦卫星(金星轨道)在-50到100摄氏度温度下制造的硅太阳能电池的数据,该电池的导出饱和电流已用于计算基本少数载流子寿命。这些随温度升高,在100℃附近显示出一些饱和。数据可以用一个能带模型来定量解释,该能带上的价差能级为0.25 eV,杂质能级为0.6 eV。0.25和0.6 eV浓度分别为6*10/sup 12//cm/sup 3/和1.5-2*10/sup 11//cm/sup 3/,与实验结果非常接近。在100℃时,饱和由后者控制,而在较低温度下,空位影响寿命。结论是,这种对电池相当常见的测试数据的分析,加上温度变化,提供了对决定电池工作性能的基本参数的有力洞察
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引用次数: 0
期刊
Conference Record of the Twentieth IEEE Photovoltaic Specialists Conference
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