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PC-1D version 2: enhanced numerical solar cell modelling PC-1D版本2:增强数值太阳能电池建模
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105730
P. Basore, D. Rover, A. Smith
PC-1D is a finite-element program for modeling semiconductor devices in one dimension on personal computers. It has the ability to address complex issues associated with heavy doping, high-level injection, and transients. Significant improvements have been made to the program, resulting in a new version. The authors describe the enhancements and their application to modern crystalline cells, including new provisions for heterostructures, antireflection coatings and light trapping, an upgraded user interface, and unattended operation for optimization studies.<>
PC-1D是一个用于在个人计算机上对半导体器件进行一维建模的有限元程序。它有能力解决与重掺杂、高水平注射和瞬态相关的复杂问题。该程序已进行了重大改进,产生了一个新版本。作者描述了这些改进及其在现代晶体电池中的应用,包括异质结构的新规定、抗反射涂层和光捕获、升级的用户界面以及用于优化研究的无人值守操作。
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引用次数: 81
Preparation and properties of CuInSe/sub 2/ solar cells with a ZnSe intermediate layer ZnSe中间层CuInSe/ sub2 /太阳能电池的制备及性能研究
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105946
Ji-Beom Yoo, A. Fahrenbruch, R. Bube
CuInSe/sub 2/-based solar cells were prepared by thermal evaporation using CdS and In/sub 2/O/sub 3/ as window layers, with a thin ZnSe layer between the window layer and the CuInSe/sub 2/. The effects of ZnSe with thicknesses between 200 AA and 2000 AA and ZnSe deposition temperatures between 100 degrees C and 200 degrees C were investigated. For the CdS:In/CdS/ZnSe/CuInSe/sub 2/ cells, as the ZnSe thickness increases, J/sub 0/ decreases and/or the diode factor A increases. For the In/sub 2/O/sub 3//ZnSe/CuInSe/sub 2/ cells the change of J/sub 0/ is much less and there is an increase in the diode factor for increasing ZnSe thickness. Under illumination, the V/sub oc/ of the cell is the same with and without ZnSe and the cells with ZnSe layers thicker than 400 AA show strong photosuppression.<>
以CdS和In/sub 2/O/sub 3/作为窗口层,采用热蒸发法制备了CuInSe/sub 2/基太阳能电池,窗口层与CuInSe/sub 2/之间有一层薄薄的ZnSe层。研究了ZnSe厚度在200aa ~ 2000aa之间,ZnSe沉积温度在100℃~ 200℃之间的影响。对于CdS:In/CdS/ZnSe/CuInSe/sub 2/电池,随着ZnSe厚度的增加,J/sub 0/减小和/或二极管因子A增加。对于In/sub 2/O/sub 3//ZnSe/CuInSe/sub 2/电池,J/sub 0/的变化要小得多,而随着ZnSe厚度的增加,二极管系数也有所增加。光照下,添加ZnSe和不添加ZnSe时,电池的V/sub / oc值相同,且ZnSe层厚度大于400 AA的电池表现出较强的光抑制作用。
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引用次数: 2
Energy-resolved defect kinetics in a-Si:H investigated by modulated photocurrents 用调制光电流研究a-Si:H中能量分解缺陷动力学
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105678
G. Schumm, G. H. Bauer
The gap state distribution in a-Si:H for solar cells was investigated by phase shift analysis of modulated photocurrents. Two peaks in the density of states at 0.6 and 0.38 eV below E/sub c/ were detected. Upon light soaking the peaks of shallow states were quenched and the peaks of deep states were enhanced; the original distribution was restored by annealing above 120 degrees C. The formation and annealing kinetics of the deep states were studied. A power law was obtained for the formation. Activation energies for annealing were centered around 1.1 eV, and a correlation of the activation energies with the energetic position of defects in the gap was obtained. To explain the results, a model of the defect structure involving charged and neutral Si defects in different hybridization states is discussed.<>
利用调制光电流的相移分析研究了太阳能电池中硅硅氢离子的隙态分布。在E/sub / c/以下的0.6和0.38 eV处检测到两个态密度峰。光浸泡后,浅态峰被淬灭,深态峰被增强;在120℃以上退火后恢复了原始分布,研究了深态的形成和退火动力学。得到了该构造的幂律。退火过程的活化能以1.1 eV为中心,得到了活化能与间隙中缺陷的能量值之间的关系。为了解释这一结果,讨论了不同杂化态下带电和中性硅缺陷的缺陷结构模型。
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引用次数: 0
High efficiency GaAs/CuInSe/sub 2/ tandem junction solar cells 高效GaAs/CuInSe/ sub2 /串联结太阳能电池
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105743
N. Kim, R. Burgess, B. Stanbery, R. Mickelsen, J. Avery, R. McClelland, B. King, M. Boden, R. Gale
High-efficiency, mechanically stacked tandem junction solar cells based on a double-heterostructure GaAs single-crystal thin-film top cell and a polycrystalline CuInSe/sub 2/ (CIS) thin-film bottom cell were developed to meet the power needs projected for future spacecraft. The best performance of these tandem cells achieved so far is 21.3% AM0, one sun, for a 1 cm/sup 2/ four-terminal device at 28 degrees C. A GaAs subcell efficiency of 18.8% and a CuInSe/sub 2/ subcell efficiency of 2.5% were measured for this device. Top cell efficiency up to 19.5% and lower cell efficiency up to 2.83% were measured for other tandem cells. A 3.0% CIS cell was achieved using a GaAs filter with a glycerol optical matching medium. This demonstrated efficiency provides for specific powers up to 620 W/kg when 50 mu m thick substrate and cover glasses are incorporated. Favorable results were obtained from thermal cycling experiments conducted to evaluate survivability of thin GaAs films in adhesive/glass sandwich structures.<>
基于双异质结构GaAs单晶薄膜顶电池和多晶CuInSe/sub 2/ (CIS)薄膜底电池,研制了高效、机械堆叠的串联结太阳能电池,以满足未来航天器的电力需求。到目前为止,这些串联电池的最佳性能是21.3%的AM0,一个太阳,1 cm/sup 2/四端器件,在28℃下,该器件的GaAs亚电池效率为18.8%,CuInSe/sub 2/亚电池效率为2.5%。其他串联电池的最高效率可达19.5%,较低效率可达2.83%。使用GaAs滤光片和甘油光学匹配介质获得3.0%的CIS细胞。当结合50 μ m厚的基板和覆盖玻璃时,该效率可提供高达620 W/kg的比功率。通过热循环实验来评估GaAs薄膜在胶粘剂/玻璃夹层结构中的生存能力,获得了良好的结果。
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引用次数: 8
Lightweight GaAs/Ge solar cells 轻质砷化镓/锗太阳能电池
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105774
Rushikesh M. Patel, S. W. Gersten, D. Perrachione, Y. Yeh, D. K. Wagner, R. Morris
Rugged, thin (<4 mil thick) GaAs-on-germanium 4 cm*4 cm solar cells with an AM0 conversion efficiency of up to 16.9% have been demonstrated. A processing technique suitable for high-volume production of large-area, thin cells has been established. The thinning technique developed here can also be used in the fabrication of high-efficiency lightweight GaAs/Ge and AlGaAs/Ge monolithic tandem cells.<>
坚固,薄(>
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引用次数: 6
7.3% efficient CuInSe/sub 2/ solar cell 7.3%高效CuInSe/ sub2 /太阳能电池
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105967
K. Mitchell, G. Pollock, A. Mason
A 7.3%, 3.3 cm/sup 2/ active area efficient ZnO/thin CdS/CuInS/sub 2/ solar cell is demonstrated with 22.7 mA/cm/sup 2/ J/sub sc/, 592 mV V/sub oc/, and 0.546 fill factor. X-ray diffraction shows that the CuInS/sub 2/ films with are predominantly randomly oriented chalcopyrite CuInS/sub 2/ with additional minor phases such as In/sub 2/S/sub 3/ and Cu/sub 2-x/S present. Optical transmission and reflection data for CuInS/sub 2/ films on glass are also shown. Optical transmission implies a 1.4-eV bandgap, less than the 1.55-eV bandgap for single-crystal CuInS/sub 2/, but consistent with other reported thin-film results. It is concluded that the resolution of several materials, device, and fabrication issues will result in efficiencies of greater than 15%.<>
该电池具有7.3%、3.3 cm/sup 2/有源面积效率、22.7 mA/cm/sup 2/ J/sub sc/、592 mV /sub oc/和0.546填充系数。x射线衍射表明,CuInS/sub - 2/薄膜以随机取向的黄铜矿CuInS/sub - 2/为主,还存在In/sub - 2/S/sub - 3/和Cu/sub - 2-x/S等少量相。给出了玻璃上CuInS/ sub2 /薄膜的光传输和反射数据。光传输意味着1.4 ev的带隙,小于单晶CuInS/sub 2/的1.55 ev带隙,但与其他报道的薄膜结果一致。结论是,解决几个材料、器件和制造问题将导致效率大于15%。
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引用次数: 8
InP homojunction solar cell performance on the LPS III flight experiment InP同质结太阳能电池在LPS III飞行实验中的性能
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105818
D. Brinker, R. E. Hart, I. Weinberg, B.S. Smith
Performance data are presented for indium phosphide n/sup +/p homojunction solar cell modules on the LIPS III flight experiment. The objective of the experiment is to measure the performance of InP cells in the natural radiation environment of the 1100 km altitude, 60+ degrees inclination orbit. Analysis of flight data indicates that the performance of the four cells throughout the first year is near expected values. No degradation in short-circuit current was seen, as was expected from radiation tolerance studies of similar cells. Details of the cell structure and flight module design are discussed. The results of the temperature dependency and radiation tolerance studies necessary for normalization and analysis of the data are included.<>
介绍了LIPS III飞行试验中磷化铟n/sup +/p同质结太阳能电池组件的性能数据。实验目的是测量InP电池在1100千米高度、60+度倾角轨道自然辐射环境下的性能。对飞行数据的分析表明,这四个单元在第一年的性能接近预期值。正如对类似细胞的辐射耐受性研究所期望的那样,在短路电流中没有看到退化。讨论了单元结构和飞行模块的设计细节。包括数据归一化和分析所必需的温度依赖性和辐射耐受性研究的结果。
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引用次数: 4
Dangling-bond states in a SiGe:H,F measured by temperature-dependent mu tau SiGe中的悬垂键态:H,F由温度相关的mu tau测量
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105673
D. Shen, J. Conde, V. Chu, J.Z. Liu, A. Maruyama, S. Aljishi, Z. Smith, S. Wagner
The authors report a novel technique for measuring the density distribution of the D/sup 0/-/ state in a-Si:H before and after light soaking and in a-SiGe:H,F alloys for solar cells. Electron time-of-flight (TOF) measurements as a function of temperature form the basis of this technique. The deep trapping of electrons controls the mobility-lifetime product ( mu tau )/sub n/, which is evaluated from the integrated TOF current. The dominant deep trap is the D/sup 0/-/ level. The authors determine the density of D/sup 0/-/ states in a:SiGe:H,F that peak at SiE/sub c/-(0.40 to 0.45) eV with maxima in the 10/sup 18/ to 10/sup 19/-cm/sup -3/ eV/sup -1/ range. In a-Si:H, the peak lies at E/sub c/-0.45 eV; it is observed to grow with increasing light-soaking time.<>
作者报告了一种测量太阳能电池用a- si:H和a- sige:H,F合金光浸泡前后D/sup 0/-/态密度分布的新技术。电子飞行时间(TOF)测量作为温度的函数构成了该技术的基础。电子的深度捕获控制了迁移寿命积(mu tau)/sub n/,这是由集成TOF电流计算的。主要的深陷阱是D/sup 0/-/水平。作者确定了a:SiGe:H,F中D/sup 0/-/态的密度,峰值在SiE/sub c/-(0.40 ~ 0.45) eV,最大值在10/sup 18/ ~ 10/sup 19/-cm/sup -3/ eV/sup -1/范围内。在a-Si:H中,峰值位于E/sub c/-0.45 eV;随着光浸泡时间的延长,其生长也随之增加。
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引用次数: 0
Photovoltaic power systems for very low power TV transmitters in India 印度超低功率电视发射机的光伏发电系统
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105895
R. Gosain, P. Kumar, M. Murthy
A very-low power TV transmitter is described, and details of its photovoltaic power supply are given. Design, installation, commissioning, and performance experiences are also presented. The total VLPT system consists of a TV receive-only and a very-low-power (10 W) TV transmitter operated in the VHF frequency range of band 3. Results show that only one power source failed and another tripped.<>
介绍了一种极低功率电视发射机,并详细介绍了其光伏电源。还介绍了设计、安装、调试和性能经验。整个VLPT系统由一个电视接收和一个非常低功率(10w)的电视发射机组成,在波段3的甚高频频率范围内工作。结果表明,只有一个电源故障,另一个电源跳闸
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引用次数: 0
A study on the surface reaction in the growth of amorphous silicon by intermittent deposition method 间歇沉积法生长非晶硅的表面反应研究
Pub Date : 1988-01-01 DOI: 10.1109/PVSC.1988.105669
T. Ishimura, Y. Okayasu, H. Yamamoto, K. Fukui
The surface reaction in the glow discharge plasma growth of a-Si:H for solar cells was studied by the intermittent deposition method in which two kinds of gases are exchanged at short intervals; one is used for growing silicon film: the other for modifying the growing surface. It was found that the fluorine elimination process has an activation energy of 7 meV and that fluorine in the region of 8 A below the growing surface is removed by hydrogen radicals at 250 degrees C. The Si:H prepared by this method has a high photoconductivity of 4*10/sup -4/ ( Omega -cm)/sup -1/ under AM1 100-mW/cm/sup 2/ light and a high photosensitivity of 10/sup 6/. This film shows smaller photodegradation than conventional a-Si:H.<>
采用短时间间隔交换两种气体的间歇沉积法,研究了太阳能电池发光放电等离子体生长中a-Si:H的表面反应;一种用于生长硅膜,另一种用于修饰生长表面。发现氟消除过程活化能为7 meV,生长表面以下8 A区域的氟在250℃下被氢自由基去除。该方法制备的Si:H在AM1 100-mW/cm/sup 2/光下具有4*10/sup -4/ (Omega -cm)/sup -1/的高光导率和10/sup 6/的高光敏性。与传统的a-Si: h >相比,该薄膜的光降解效果更小。
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引用次数: 0
期刊
Conference Record of the Twentieth IEEE Photovoltaic Specialists Conference
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