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An Unusual Defect in a Superheater Tube 过热器管异常缺陷
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001456
An unusual type of defect was discovered during hydraulic testing of a water-tube boiler after repairs to the superheater tubes following erosion from soot-blowers. When the pressure reached 700 psi, slight leakage was found to be taking place from one of the superheater tubes in a region where there appeared to be a split, approximately 8 in. long. What was thought to be a split was actually a pronounced fold. Microscopic examination showed that a corrosion-fatigue fissure had developed from one of the inside corners of the fold, presumably as a result of the fluctuating bending stresses to which this portion of the tube would be subjected because of the discontinuity in the tube wall. It was from this fissure that the leakage occurred. It was evident that the defect developed during the manufacture of the tube, probably in the course of a drawing or rolling operation without an internal plug. The diam of this portion of the tube was reduced by local collapse and folding of the section rather than by longitudinal extension of the tube itself.
在对水管锅炉进行水力测试时,发现了一种不寻常的缺陷,这是在对吹灰器侵蚀后过热器管进行维修后发现的。当压力达到700 psi时,发现过热器管中的一个区域出现了轻微的泄漏,该区域大约有8英寸的裂缝。长。被认为是分裂的东西实际上是一个明显的折叠。显微镜检查表明,从褶皱的一个内角开始出现了腐蚀疲劳裂纹,这可能是由于管壁的不连续导致这部分管子受到波动弯曲应力的结果。泄漏就是从这个裂缝发生的。很明显,这个缺陷是在管子的制造过程中产生的,可能是在没有内塞的拉伸或轧制操作过程中产生的。管的这一部分的直径是由局部坍塌和折叠的部分,而不是由管本身的纵向延伸减少。
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引用次数: 0
Cracking in Gas Turbine Blades 燃气轮机叶片开裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0090181
Cracking in gas turbine blades was found to initiate from a mechanism of low-cycle fatigue (LCF). LCF is induced during thermal loading cycles in gas turbines. However, metallography of two cracked blades revealed a change in microstructure at as-cast surfaces for depths up to 0.41 mm (0.016 in.). Evaluation by SEM confirmed the difference in structure was associated with a lack of formation of coarse gamma prime structure in the matrix. Microhardness and miniature tensile test results indicated lower strength consistent with the absence of the coarse gamma prime constituent. The blade vendor found that the lot of hot isostatically pressed (HIP) blade castings had been exposed to an improper atmosphere during the HIP process, resulting in the weakened structure. Because subsequent failures were found in blades that did not come from the suspect HIP lot, the scope of the problem was considered generic, and the conclusion was that the primary failure mechanism was LCF. Material imperfections were a secondary deficiency that had the effect of causing the blades from the bad HIP lot to crack first.
发现燃气轮机叶片开裂是由低周疲劳机制引起的。LCF是在燃气轮机热负荷循环过程中产生的。然而,在深度达0.41 mm (0.016 in.)的铸态表面,两个裂纹叶片的金相分析显示微观结构发生了变化。扫描电镜分析证实,这种结构差异与基体中未形成粗γ prime结构有关。显微硬度和微观拉伸试验结果表明,强度较低,与缺乏粗γ基本成分一致。叶片供应商发现,许多热等静压(HIP)叶片铸件在HIP过程中暴露在不适当的气氛中,导致结构减弱。由于后续故障发生在并非来自可疑HIP批次的叶片中,因此该问题的范围被认为是通用的,结论是主要故障机制是LCF。材料缺陷是次要缺陷,它会导致来自不良HIP批次的叶片首先开裂。
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引用次数: 0
Failure of a Turbine Vane 涡轮叶片失效
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0046966
A turbine vane made of cast cobalt-base alloy AMS 5382 (Stellite 31; composition: Co-25.5Cr-10.5Ni-7.5W) was returned from service after an undetermined number of service hours because of crack indications on the airfoil sections. This alloy is cast by the precision investment method. Analysis (visual inspection, 100x/500x metallographic examination of sections etched with a mixture of ferric chloride, hydrochloric acid, and methanol, and bend tests) supported the conclusions that cracking of the airfoil sections was caused by thermal fatigue and was contributed to by low ductility due to age hardening, subsurface oxidation related to intragranular carbides, and high residual tensile macrostresses. No further conclusions could be drawn because of the lack of detailed service history, and no recommendations were made.
涡轮叶片由铸造钴基合金AMS 5382 (Stellite 31;成分:Co-25.5Cr-10.5Ni-7.5W)由于翼型部分出现裂纹迹象,在服役数小时后被退回。这种合金是用精密熔模法铸造的。分析(目视检查、用氯化铁、盐酸和甲醇的混合物腐蚀的部分的100倍/500倍金相检查和弯曲试验)支持这样的结论,即翼型部分的开裂是由热疲劳引起的,是由时效硬化导致的低延展性、与晶内碳化物有关的地下氧化和高残余拉伸宏观应力造成的。由于缺乏详细的服务历史,无法得出进一步的结论,也没有提出任何建议。
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引用次数: 0
Failure of Copper Alloy 443 Heat-Exchanger Tubes 443铜合金换热器管的失效
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0048714
Tubes in heat exchangers, made of copper alloy C44300 and used for cooling air failed after 5 to six years of service. Air passed over the shell-side surface of the tubes and was cooled by water flowing through the tubes. Water vapor in the air was condensed (pH 4.5) on the tube surfaces during the cooling process. Air flow over the tubes reversed direction every 585 mm as a result of baffling placed in the heat exchangers. An uneven ridgelike thinning and perforation of the tube wall on the leeward side of the tube was revealed by visual examination. Undercut pits on the outer surface of the tube were revealed by metallographic examination of a cross section of the failed area. Impingement attack which led to perforation was revealed by both the ridgelike appearance of the damaged area and the undercut pitting. The heat exchanger was retubed with tubes made of aluminum bronze (copper alloy C61400).
用于冷却空气的C44300铜合金热交换器管在使用5到6年后失效。空气通过管道的壳面,并被流经管道的水冷却。在冷却过程中,空气中的水蒸气(pH值为4.5)在管表面冷凝。由于放置在热交换器中的挡板,管道上的气流每隔585毫米反转一次方向。目视检查发现导管背风侧管壁有不均匀的脊状变薄和穿孔。通过对失效区域横截面的金相检查,发现了管外表面的凹坑。损伤区呈脊状,凹痕凹陷,可见撞击作用导致穿孔。热交换器用铝青铜(铜合金C61400)制成的管子进行了更换。
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引用次数: 0
Dezincification of Brass Tubes in a Steam Turbine Condenser 汽轮机凝汽器黄铜管的脱锌
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001409
Dezincification is a particular form of corrosive attack which may occur in a variety of environments and to which some brasses are susceptible. It is favored by waters having a high oxygen, carbon dioxide, or chloride content, and is accelerated by elevated temperatures and low water velocities. In the present study, steam turbine condenser tubes had to be renewed after 25 years of service. The tubes were nominally of 70:30 brass. The appearance of a typically corroded one showed uniform dezincification attack on the bore, extending from one-half to two-thirds through the tube wall thickness.
脱锌是一种特殊形式的腐蚀,可能发生在各种环境中,有些黄铜易受其影响。它在含氧量、二氧化碳或氯化物含量高的水中更受欢迎,并因温度升高和水流速度减慢而加速。在本研究中,汽轮机凝汽器管在服役25年后必须进行更新。管名义上是70:30黄铜。典型腐蚀的外观显示,在管壁厚度的1 / 2到2 / 3处,孔内出现均匀的脱锌攻击。
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引用次数: 0
Creep Failure Analysis of Steel Tubes 钢管蠕变失效分析
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001711
J. A. Pero-Sanz, D. Plaza, M. Ruiz, J. Asensio, J. Verdeja
Failures of 10Cr-Mo9-10 and X 20Cr-Mo-V12-1 superheated pipes during service in steam power generation plants are described. Through micrographic and fractographic analysis, creep and overheating were identified as the cause of failure. The Larson-Miller parameter is computed, as a function of oxidation thickness, temperature and time, confirming the creep failure diagnostic.
介绍了蒸汽发电厂10Cr-Mo9-10和x20cr - mo - v12 -1过热管在使用过程中的故障。通过显微和断口分析,确定蠕变和过热是失效的原因。计算了拉尔森-米勒参数作为氧化厚度、温度和时间的函数,确定了蠕变失效诊断。
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引用次数: 0
Stress-Corrosion Cracking of a Brass Tube in a Generator Air Cooler Unit 发电机空冷机组黄铜管应力腐蚀开裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0091703
An arsenical admiralty brass (UNS C44300) finned tube in a generator air cooler unit at a hydroelectric power station failed. The unit had been in operation for approximately 49,000 h. The cooling medium for the tubes was water from a river. Air flowed over the finned exterior of the tubes, while water circulated through the tubes. Investigation (visual inspection, leak testing, history review, 100X micrographs etched in potassium dichromate, chemical analysis, and EDS and XRD analysis of internal tube deposits) supported the conclusion that the cause of the tube leaks was ammonia-induced SCC. Because the cracks initiated on the inside surfaces of the tubes and because the river water was not treated before it entered the coolers, the ammonia was likely present in the river water and probably concentrated under the internal deposits. Recommendations included either eliminating the ammonia (prohibitively expensive in cost and time) or using an alternate material (such as a 70Cu-30Ni alloy or a more expensive titanium alloy) that is resistant to ammonia corrosion as well as to chlorides and sulfur species.
某水电站发电机空气冷却器单元中的含砷海军黄铜(UNS C44300)翅片管发生故障。该装置已经运行了大约49,000小时。管道的冷却介质是河水。空气流过管道的鳍状外部,而水在管道中循环。调查(目视检查、泄漏测试、历史回顾、重铬酸钾蚀刻的100X显微照片、化学分析、内部管沉积物的EDS和XRD分析)支持了管泄漏原因是氨诱导的SCC的结论。因为裂缝是从管道的内表面开始的,而且河水在进入冷却器之前没有经过处理,所以氨很可能存在于河水中,并可能集中在内部沉积物下。建议包括消除氨(在成本和时间上都非常昂贵)或使用替代材料(如70Cu-30Ni合金或更昂贵的钛合金),这些材料既耐氨腐蚀,也耐氯化物和硫。
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引用次数: 0
Recovery of a Type 304 Stainless Steel Piping System Contaminated with Chlorides 被氯化物污染的304型不锈钢管道系统的回收
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001559
A. A. Stein, V. Zilberstein, W. S. Clancy, G. J. Davis
One inch diam Type 304 stainless steel piping was designed to carry containment atmosphere samples to an analyzer to monitor hydrogen and oxygen levels during operational and the design basis accident conditions that are postulated to occur in a boiling water reactor. Only one of six lines in the system had thru-wall cracks. Shallow incipient cracks were detected at the lowest elevations of one other line. The balance of the system had no signs of SCC attack. Chlorides and corrosion deposits in varying amounts were found throughout the system. The failure mechanism was transgranular, chloride, stress-corrosion cracking. Replacement decisions were based on the presence of SCC attack or heavy corrosion deposits indicative of extended exposure time to chloride-contaminated water. The existing uncracked pipe, about 75 percent of the piping in the system, was retained despite the presence of low level surface chlorides. Controls were implemented to insure that temperatures are kept below 150 deg F, or, walls of the pipe are moisture-free or the cumulative wetted period will never exceed 30 h.
设计一英寸直径的304型不锈钢管道,用于将安全壳大气样品输送到分析仪,以监测运行期间的氢和氧水平,以及在沸水反应堆中假定发生的设计基础事故条件。该系统的六条线路中只有一条有穿墙裂缝。在另一条线路的最低海拔处检测到浅的初期裂缝。系统平衡无SCC攻击迹象。在整个系统中发现了不同数量的氯化物和腐蚀沉积物。破坏机制为穿晶、氯化物、应力腐蚀开裂。更换决定是基于SCC攻击或重度腐蚀沉积物的存在,这表明在氯化物污染的水中暴露时间延长。尽管存在低水平的表面氯化物,但仍保留了现有的未破裂管道,约占系统中管道的75%。控制措施的实施是为了确保温度保持在150华氏度以下,或者确保管壁不受潮,或者累计受潮时间不超过30小时。
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引用次数: 0
Aging of Boiler Rivets 锅炉铆钉老化
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c9001448
Rivets from the longitudinal seam of the terminal shell ring of a 12 year old Lancashire boiler broke off easily during examination. Cleavage fractures indicated a brittle material. Microstructure of a sectioned rivet head was typical of a normal rimming steel except the ferrite crystals contained numerous nitride needles. Their existence indicated an abnormally high nitrogen content. If such a steel is heated for a lengthy period to a temperature of that prevailing in a boiler, precipitation of the nitrides may be expected, with consequent embrittlement. In this case, embrittlement of this type was the primary cause of the breaking off of the type rivet heads. Nothing was observed in the course of the examination that suggested caustic cracking.
兰开夏郡一台12年旧锅炉的终端壳环纵缝铆钉在检查时容易断裂。解理断裂表明是一种脆性材料。铆钉头切片的显微组织除了铁素体晶体中含有大量的氮化针状物外,其余的都是典型的普通镶边钢。它们的存在表明氮含量异常高。如果将这种钢长时间加热到锅炉中普遍存在的温度,则氮化物可能会析出,从而产生脆化。在这种情况下,这种类型的脆化是类型铆钉头断裂的主要原因。在检查过程中没有观察到任何表明腐蚀性开裂的迹象。
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引用次数: 0
Stress-Corrosion Cracking of Inconel X-750 Springs Inconel X-750弹簧的应力腐蚀开裂
Pub Date : 2019-06-01 DOI: 10.31399/asm.fach.power.c0048158
Several of the springs, made of 1.1 mm diam Inconel X-750 wire and used for tightening the interstage packing ring in a high-pressure turbine, were found broken after approximately seven years of operation. Intergranular cracks about 1.3 mm in depth and oriented at an angle of 45 deg to the axis of the wire were revealed by metallographic examination. A light-gray phase, which had the appearance of liquid-metal corrosion, was observed to have penetrated the grains on the fracture surfaces. The spring wires were found to fracture in a brittle manner characteristic of fracture from torsional loading (along a plane 45 deg to the wire axis). Liquid-metal embrittlement was expected to have been caused by metals (Sn, Zn, Pb) which melt much below maximum service temperature of the turbine. The springs were concluded to have fractured by intergranular stress-corrosion cracking promoted by the action of liquid zinc and tin in combination with static and torsional stresses on the spring wire. As a corrective measure, Na, Sn, and Zn which were present in pigmented oil used as a lubricant during spring winding was cleaned thoroughly by the spring manufacturer before shipment to remove all contaminants.
其中几个弹簧由直径1.1毫米的英科耐尔X-750钢丝制成,用于拧紧高压涡轮的级间填料环,在大约7年的运行后被发现断裂。金相检查发现,晶粒间裂纹深度约为1.3 mm,与线材轴线呈45度角。在断口表面观察到一种浅灰色相渗透到晶粒中,具有液态金属腐蚀的特征。弹簧钢丝断裂呈脆性断裂,具有扭转载荷断裂的特征(沿与钢丝轴线45度的平面)。液态金属脆化预计是由于金属(Sn, Zn, Pb)在远低于涡轮机最高使用温度的情况下熔化造成的。结果表明,弹簧断裂是由锌液和锡液的共同作用以及弹簧丝上的静应力和扭转应力共同引起的晶间应力腐蚀开裂。作为一项纠正措施,在弹簧缠绕过程中作为润滑剂的颜料油中存在的Na, Sn和Zn在装运前由弹簧制造商彻底清洗以去除所有污染物。
{"title":"Stress-Corrosion Cracking of Inconel X-750 Springs","authors":"","doi":"10.31399/asm.fach.power.c0048158","DOIUrl":"https://doi.org/10.31399/asm.fach.power.c0048158","url":null,"abstract":"\u0000 Several of the springs, made of 1.1 mm diam Inconel X-750 wire and used for tightening the interstage packing ring in a high-pressure turbine, were found broken after approximately seven years of operation. Intergranular cracks about 1.3 mm in depth and oriented at an angle of 45 deg to the axis of the wire were revealed by metallographic examination. A light-gray phase, which had the appearance of liquid-metal corrosion, was observed to have penetrated the grains on the fracture surfaces. The spring wires were found to fracture in a brittle manner characteristic of fracture from torsional loading (along a plane 45 deg to the wire axis). Liquid-metal embrittlement was expected to have been caused by metals (Sn, Zn, Pb) which melt much below maximum service temperature of the turbine. The springs were concluded to have fractured by intergranular stress-corrosion cracking promoted by the action of liquid zinc and tin in combination with static and torsional stresses on the spring wire. As a corrective measure, Na, Sn, and Zn which were present in pigmented oil used as a lubricant during spring winding was cleaned thoroughly by the spring manufacturer before shipment to remove all contaminants.","PeriodicalId":107406,"journal":{"name":"ASM Failure Analysis Case Histories: Power Generating Equipment","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133724555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
ASM Failure Analysis Case Histories: Power Generating Equipment
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