Pub Date : 2024-03-19DOI: 10.1016/j.coelec.2024.101488
Jeong Eun Yoo, Jiyoung Kim, Rin Jung, Kiyoung Lee
This review focuses on the extraction of lithium-ions (Li+) from the cathode of spent lithium-ion batteries (SLIB) and application of the delithiated cathode in catalytic reactions. Li+ has been extracted from SLIB through electrochemical and chemical leaching methods. Despite challenges for extraction of Li+, delithiated cathode materials demonstrate substantial catalytic efficiency in water electrolysis, dye photodegradation, and photoelectrochemical applications. This enhanced catalytic performance is attributable to the favorable catalytic properties of the transition metal oxide components and numerous catalytically active defects and oxygen vacancies formed by delithiation. The findings underscore the potential of recycling SLIBs into valuable catalysts for environmental and energy-related applications, emphasizing the transformation of waste into resource through efficient material reutilization.
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{"title":"Sustainable catalysts from battery waste: Extraction and catalytic potentials of delithiated cathodes in energy and environmental applications","authors":"Jeong Eun Yoo, Jiyoung Kim, Rin Jung, Kiyoung Lee","doi":"10.1016/j.coelec.2024.101488","DOIUrl":"10.1016/j.coelec.2024.101488","url":null,"abstract":"<div><p>This review focuses on the extraction of lithium-ions (Li<sup>+</sup>) from the cathode of spent lithium-ion batteries (SLIB) and application of the delithiated cathode in catalytic reactions. Li<sup>+</sup> has been extracted from SLIB through electrochemical and chemical leaching methods. Despite challenges for extraction of Li<sup>+</sup>, delithiated cathode materials demonstrate substantial catalytic efficiency in water electrolysis, dye photodegradation, and photoelectrochemical applications. This enhanced catalytic performance is attributable to the favorable catalytic properties of the transition metal oxide components and numerous catalytically active defects and oxygen vacancies formed by delithiation. The findings underscore the potential of recycling SLIBs into valuable catalysts for environmental and energy-related applications, emphasizing the transformation of waste into resource through efficient material reutilization.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"45 ","pages":"Article 101488"},"PeriodicalIF":8.5,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140205259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-15DOI: 10.1016/j.coelec.2024.101487
Muhammad Yasir , Zhiliang Zhao , Min Zeng , Sangaraju Shanmugam , Xinyi Zhang
Ammonia production, mostly for use in fertilizers, currently consumes up to 2% of the world's energy production and accounts for more than 1.6% of global CO2 emissions. Hence, it is essential to develop a sustainable and eco-friendly process for NH3 synthesis. To date, various synthetic techniques have been developed under mild operation conditions. Among them, electrochemical nitrogen reduction reaction (ENRR) allows the direct conversion of atmospheric N2 into NH3 from renewables, offering various advantages, So far, most ENRR have been carried out in aqueous electrolytes. However the faradaic efficiency is usually low in such electrolytes, because water or proton reduction to hydrogen competes with nitrogen reduction. Compared to aqueous electrolytes, non-aqueous electrolytes show high electrochemical stability, increased solubility of N2, high selectivity, promoting the ENRR over hydrogen evolution-reactions, hence improving Faradaic efficiency. However, a comprehensive understanding of ENRR in non-aqueous electrolytes remains inadequate, and challenges such as poor selectivity, low current density, and low energy efficiency still remain in practical implementation. In this review, we summarize the recent progress of ENRR in non-aqueous electrolytes. Some technical challenges arising in this field are highlighted and assessed. In the final part, the perspectives are proposed for future research and commercial practice.
{"title":"Recent progress and prospects in electroreduction of nitrogen to ammonia in non-aqueous electrolytes","authors":"Muhammad Yasir , Zhiliang Zhao , Min Zeng , Sangaraju Shanmugam , Xinyi Zhang","doi":"10.1016/j.coelec.2024.101487","DOIUrl":"10.1016/j.coelec.2024.101487","url":null,"abstract":"<div><p>Ammonia production, mostly for use in fertilizers, currently consumes up to 2% of the world's energy production and accounts for more than 1.6% of global CO<sub>2</sub> emissions. Hence, it is essential to develop a sustainable and eco-friendly process for NH<sub>3</sub> synthesis. To date, various synthetic techniques have been developed under mild operation conditions. Among them, electrochemical nitrogen reduction reaction (ENRR) allows the direct conversion of atmospheric N<sub>2</sub> into NH<sub>3</sub> from renewables, offering various advantages, So far, most ENRR have been carried out in aqueous electrolytes. However the faradaic efficiency is usually low in such electrolytes, because water or proton reduction to hydrogen competes with nitrogen reduction. Compared to aqueous electrolytes, non-aqueous electrolytes show high electrochemical stability, increased solubility of N<sub>2</sub>, high selectivity, promoting the ENRR over hydrogen evolution-reactions, hence improving Faradaic efficiency. However, a comprehensive understanding of ENRR in non-aqueous electrolytes remains inadequate, and challenges such as poor selectivity, low current density, and low energy efficiency still remain in practical implementation. In this review, we summarize the recent progress of ENRR in non-aqueous electrolytes. Some technical challenges arising in this field are highlighted and assessed. In the final part, the perspectives are proposed for future research and commercial practice.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"45 ","pages":"Article 101487"},"PeriodicalIF":8.5,"publicationDate":"2024-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-14DOI: 10.1016/j.coelec.2024.101486
Niloofar Haghighian, Ritu Kataky
Bacterial biofilms are structured communities of microorganisms that play a critical role in various industries and healthcare settings, contributing to chronic infections and biofouling issues. Understanding the metabolites produced by bacterial biofilms is of paramount importance to detect their growth patterns, virulence, and responses to treatment strategies. Electrochemical detection has emerged as a powerful and versatile tool for real-time, label-free, and sensitive analysis of bacterial biofilm metabolites. This review paper investigates recent breakthroughs in the field of electrochemical detection, focusing on the principles, methodologies, and applications of this cutting-edge technology. It includes a comprehensive examination of electrochemical sensors and their various modifications, designed to enhance sensitivity and specificity. Finally, the paper emphasisesing the potential for novel electrochemical techniques and their integration into clinical and industrial settings.
{"title":"Advances in electrochemical detection of bacterial biofilm metabolites","authors":"Niloofar Haghighian, Ritu Kataky","doi":"10.1016/j.coelec.2024.101486","DOIUrl":"10.1016/j.coelec.2024.101486","url":null,"abstract":"<div><p>Bacterial biofilms are structured communities of microorganisms that play a critical role in various industries and healthcare settings, contributing to chronic infections and biofouling issues. Understanding the metabolites produced by bacterial biofilms is of paramount importance to detect their growth patterns, virulence, and responses to treatment strategies. Electrochemical detection has emerged as a powerful and versatile tool for real-time, label-free, and sensitive analysis of bacterial biofilm metabolites. This review paper investigates recent breakthroughs in the field of electrochemical detection, focusing on the principles, methodologies, and applications of this cutting-edge technology. It includes a comprehensive examination of electrochemical sensors and their various modifications, designed to enhance sensitivity and specificity. Finally, the paper emphasisesing the potential for novel electrochemical techniques and their integration into clinical and industrial settings.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"46 ","pages":"Article 101486"},"PeriodicalIF":8.5,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2451910324000474/pdfft?md5=ec47f5cb8abc5c13dcf3429eda77f63b&pid=1-s2.0-S2451910324000474-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-14DOI: 10.1016/j.coelec.2024.101485
Dabin Han, Sangaraju Shanmugam
Rechargeable metal-bromine batteries have emerged as promising candidates to develop competitive, cost-effective, high-energy-density energy storage systems. The general configuration of a metal-bromine battery includes a metal anode and a bromine cathode. The emergence of zinc-bromine redox batteries (ZBRBs) is attributed to the earth's abundance of zinc, the cost-effectiveness of the active materials, and the high theoretical energy density. Recent advancements have highlighted using bromides (Br−, Br2, and Brn− (n = 3, 5, 7 …)) entrapping materials for the cathode to enhance the Br−/Br2 redox reaction and inhibit the Br2 diffusion in the ZBRBs. This review aims to explore the various arrangements and insights into bromides-entrapping-based cathodes recently reported. Finally, we share perspectives on the remaining challenges and prospects for the ZBRBs.
{"title":"Recent advances in the hybrid cathode for rechargeable zinc-bromine redox batteries","authors":"Dabin Han, Sangaraju Shanmugam","doi":"10.1016/j.coelec.2024.101485","DOIUrl":"10.1016/j.coelec.2024.101485","url":null,"abstract":"<div><p>Rechargeable metal-bromine batteries have emerged as promising candidates to develop competitive, cost-effective, high-energy-density energy storage systems. The general configuration of a metal-bromine battery includes a metal anode and a bromine cathode. The emergence of zinc-bromine redox batteries (ZBRBs) is attributed to the earth's abundance of zinc, the cost-effectiveness of the active materials, and the high theoretical energy density. Recent advancements have highlighted using bromides (Br<sup>−</sup>, Br<sub>2,</sub> and Br<sub>n</sub><sup>−</sup> (n = 3, 5, 7 …)) entrapping materials for the cathode to enhance the Br<sup>−</sup>/Br<sub>2</sub> redox reaction and inhibit the Br<sub>2</sub> diffusion in the ZBRBs. This review aims to explore the various arrangements and insights into bromides-entrapping-based cathodes recently reported. Finally, we share perspectives on the remaining challenges and prospects for the ZBRBs.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"45 ","pages":"Article 101485"},"PeriodicalIF":8.5,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-14DOI: 10.1016/j.coelec.2024.101482
K. Karuppasamy , Jining Lin , Dhanasekaran Vikraman , Vishwanath Hiremath , P. Santhoshkumar , Hyun-Seok Kim , Akram Alfantazi , T. Maiyalagan , Jan G. Korvink , Bharat Sharma
The safety issues and lack of availability of lithium metal have led to the ever-increasing demand for research on new battery technologies, driven by the need for high-performance electrochemical energy storage (EES) systems. In this regard, sodium-ion batteries (SIBs) are plausible substitutes for commercial lithium-ion batteries (LIBs). However, the growth of SIBs is primarily hampered by insufficient electrochemical characteristics caused by the sluggish diffusion kinetics of sodium ions. Many solutions have been proposed to overcome such shortcuts, including employing innovative fabrication strategies and development in battery technology, such as the advances in 3D-printed electrodes to improve the overall SIBs’ performance. This brief review explores the recent advancements in SIB technology, directed explicitly at using 3D-printed anodes for improved sodium storage. This new additive process can substantially enhance the efficiency, electrochemical performance, and scalability of SIBs.
{"title":"Towards greener energy storage: Brief insights into 3D-printed anode materials for sodium-ion batteries","authors":"K. Karuppasamy , Jining Lin , Dhanasekaran Vikraman , Vishwanath Hiremath , P. Santhoshkumar , Hyun-Seok Kim , Akram Alfantazi , T. Maiyalagan , Jan G. Korvink , Bharat Sharma","doi":"10.1016/j.coelec.2024.101482","DOIUrl":"10.1016/j.coelec.2024.101482","url":null,"abstract":"<div><p>The safety issues and lack of availability of lithium metal have led to the ever-increasing demand for research on new battery technologies, driven by the need for high-performance electrochemical energy storage (EES) systems. In this regard, sodium-ion batteries (SIBs) are plausible substitutes for commercial lithium-ion batteries (LIBs). However, the growth of SIBs is primarily hampered by insufficient electrochemical characteristics caused by the sluggish diffusion kinetics of sodium ions. Many solutions have been proposed to overcome such shortcuts, including employing innovative fabrication strategies and development in battery technology, such as the advances in 3D-printed electrodes to improve the overall SIBs’ performance. This brief review explores the recent advancements in SIB technology, directed explicitly at using 3D-printed anodes for improved sodium storage. This new additive process can substantially enhance the efficiency, electrochemical performance, and scalability of SIBs.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"45 ","pages":"Article 101482"},"PeriodicalIF":8.5,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-14DOI: 10.1016/j.coelec.2024.101483
Zeshen Deng, Liuzhang Ouyang, Longtao Ma, Lichun Yang, Min Zhu
Aqueous zinc-ion batteries (AZIBs) hold tremendous potential as next-generation large-scale energy storage devices, yet they face significant challenges. The reversibility of AZIBs is hindered by the unstable electrode/electrolyte interface caused by dendrite formation and parasitic side reactions. Electrolyte additives present a promising and straightforward approach to enhance the reversibility of AZIBs while maintaining overall energy density. In this short review, we systematically summarize the impacts of electrolyte additives based on the functional mechanisms. We provide a comprehensive analysis of the effects of additives on the bulk electrolyte and the electrode/electrolyte interface, as well as highlight the significance of multifunctional additives for achieving durable anodes and cathodes. To address the current research limitations, we offer perspectives on future research directions, guiding the exploration of novel additives and the realization of high-performance AZIBs.
{"title":"From electrolyte to electrode interface: Understanding impacts of electrolyte additives for aqueous zinc-ion batteries","authors":"Zeshen Deng, Liuzhang Ouyang, Longtao Ma, Lichun Yang, Min Zhu","doi":"10.1016/j.coelec.2024.101483","DOIUrl":"10.1016/j.coelec.2024.101483","url":null,"abstract":"<div><p>Aqueous zinc-ion batteries (AZIBs) hold tremendous potential as next-generation large-scale energy storage devices, yet they face significant challenges. The reversibility of AZIBs is hindered by the unstable electrode/electrolyte interface caused by dendrite formation and parasitic side reactions. Electrolyte additives present a promising and straightforward approach to enhance the reversibility of AZIBs while maintaining overall energy density. In this short review, we systematically summarize the impacts of electrolyte additives based on the functional mechanisms. We provide a comprehensive analysis of the effects of additives on the bulk electrolyte and the electrode/electrolyte interface, as well as highlight the significance of multifunctional additives for achieving durable anodes and cathodes. To address the current research limitations, we offer perspectives on future research directions, guiding the exploration of novel additives and the realization of high-performance AZIBs.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"45 ","pages":"Article 101483"},"PeriodicalIF":8.5,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149107","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-14DOI: 10.1016/j.coelec.2024.101481
Ulises A. Zitare , Jonathan Szuster , Daniel H. Murgida
This short review describes recent work on the use of SAM-coated electrodes for studying redox proteins and enzymes. These platforms, in conjunction with electrochemical and in situ spectroelectrochemical techniques, provide a wealth of information on the structure, dynamics and reactivity of the immobilized proteins. New experimental evidence and theoretical developments, which suppose a major breakthrough in the fundamental understanding of interfacial electron transfer reactions of proteins immobilized on SAM-coated electrodes, are presented. Selected examples of mechanistic insights into redox and redox-coupled processes of the immobilized proteins, as well as the development of alternative SAM coatings for improved protein adsorption, stability and current densities are also discussed.
这篇简短的综述介绍了利用 SAM 涂层电极研究氧化还原蛋白和酶的最新研究成果。这些平台与电化学和原位光谱电化学技术相结合,提供了有关固定蛋白质的结构、动力学和反应性的大量信息。新的实验证据和理论发展为从根本上理解固定在 SAM 涂层电极上的蛋白质的界面电子转移反应提供了重大突破。此外,还讨论了对固定化蛋白质的氧化还原和氧化还原耦合过程的机理认识的部分实例,以及为改善蛋白质吸附、稳定性和电流密度而开发的替代性 SAM 涂层。
{"title":"SAM-modified electrodes for understanding and harnessing the properties of redox proteins","authors":"Ulises A. Zitare , Jonathan Szuster , Daniel H. Murgida","doi":"10.1016/j.coelec.2024.101481","DOIUrl":"10.1016/j.coelec.2024.101481","url":null,"abstract":"<div><p>This short review describes recent work on the use of SAM-coated electrodes for studying redox proteins and enzymes. These platforms, in conjunction with electrochemical and in situ spectroelectrochemical techniques, provide a wealth of information on the structure, dynamics and reactivity of the immobilized proteins. New experimental evidence and theoretical developments, which suppose a major breakthrough in the fundamental understanding of interfacial electron transfer reactions of proteins immobilized on SAM-coated electrodes, are presented. Selected examples of mechanistic insights into redox and redox-coupled processes of the immobilized proteins, as well as the development of alternative SAM coatings for improved protein adsorption, stability and current densities are also discussed.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"46 ","pages":"Article 101481"},"PeriodicalIF":8.5,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-14DOI: 10.1016/j.coelec.2024.101484
Nathanael C. Ramos , Adam Holewinski
Electrooxidation of aldehydes to carboxylates has been observed to yield H2 at small anodic potentials on Group IB metal electrodes (mainly Cu, Ag, and Au) in alkaline media. When paired with hydrogen evolution at the cathode, only one mole of electrons is transferred to generate a mole each of hydrogen and carboxylate product. Recently, this phenomenon of electrochemical oxidative dehydrogenation (EOD) has gained renewed interest as it has been demonstrated with biomass-derived substrates at industrially relevant current densities. The high electron efficiency, low cell voltage, and valuable anode products of EOD all give cause for further investigation into its prospects for co-producing renewable hydrogen and organic chemicals. Currently, the underlying mechanism of EOD remains unclear. This contribution reviews the present understanding of the reaction mechanism and highlights notable performance benchmarks to date, emphasizing the role of catalyst material and reaction conditions.
{"title":"Recent advances in anodic hydrogen production: Electrochemical oxidative dehydrogenation of aldehydes to carboxylates","authors":"Nathanael C. Ramos , Adam Holewinski","doi":"10.1016/j.coelec.2024.101484","DOIUrl":"10.1016/j.coelec.2024.101484","url":null,"abstract":"<div><p>Electrooxidation of aldehydes to carboxylates has been observed to yield H<sub>2</sub> at small anodic potentials on Group IB metal electrodes (mainly Cu, Ag, and Au) in alkaline media. When paired with hydrogen evolution at the cathode, only one mole of electrons is transferred to generate a mole each of hydrogen and carboxylate product. Recently, this phenomenon of electrochemical oxidative dehydrogenation (EOD) has gained renewed interest as it has been demonstrated with biomass-derived substrates at industrially relevant current densities. The high electron efficiency, low cell voltage, and valuable anode products of EOD all give cause for further investigation into its prospects for co-producing renewable hydrogen and organic chemicals. Currently, the underlying mechanism of EOD remains unclear. This contribution reviews the present understanding of the reaction mechanism and highlights notable performance benchmarks to date, emphasizing the role of catalyst material and reaction conditions.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"45 ","pages":"Article 101484"},"PeriodicalIF":8.5,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-13DOI: 10.1016/j.coelec.2024.101479
Qinglan Zhao , Yan Zhang , Dapeng Cao , Minhua Shao
Electrochemical co-reduction of CO2 and nitrates presents a promising alternative for urea production. However, the current electrochemical synthesis of urea faces challenges related to low selectivity and production rates. The development of high-efficiency electrocatalysts is the key to performance improvement of urea electrosynthesis. This minireview primarily focuses on the rational design of catalysts, starting with a mechanistic overview. In addition, the advancement of electrolyzers for urea electrochemical synthesis is also discussed aiming to articulate guiding principles of achieving high-rate production reaching industrial relevant level in the future.
{"title":"The prospects of urea manufacturing via electrochemical co-reduction of CO2 and nitrates","authors":"Qinglan Zhao , Yan Zhang , Dapeng Cao , Minhua Shao","doi":"10.1016/j.coelec.2024.101479","DOIUrl":"10.1016/j.coelec.2024.101479","url":null,"abstract":"<div><p>Electrochemical co-reduction of CO<sub>2</sub> and nitrates presents a promising alternative for urea production. However, the current electrochemical synthesis of urea faces challenges related to low selectivity and production rates. The development of high-efficiency electrocatalysts is the key to performance improvement of urea electrosynthesis. This minireview primarily focuses on the rational design of catalysts, starting with a mechanistic overview. In addition, the advancement of electrolyzers for urea electrochemical synthesis is also discussed aiming to articulate guiding principles of achieving high-rate production reaching industrial relevant level in the future.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"45 ","pages":"Article 101479"},"PeriodicalIF":8.5,"publicationDate":"2024-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140149212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-11DOI: 10.1016/j.coelec.2024.101478
Xinglei He, Hong Yan, Ke-Yin Ye
Porous materials are emerging recyclable electrocatalysts that exhibit many advantages such as rich pore environments, tunable structures and functionalities, and large specific surface areas. However, the research of these materials in organic electrocatalysis is promising but only emerged recently. In this review, we summarized the latest research progress of porous carbon materials, metal-organic frameworks (MOFs), and covalent-organic frameworks (COFs) in organic electrocatalysis, focusing on their structural optimization, electrochemical performance, and reaction mechanisms. In addition, the main challenges and future directions in this field were also discussed. We hope that this review can inspire more research interest of synthetic organic chemists in the development of porous electrocatalysts in organic electrocatalysis.
{"title":"Porous electrocatalysts modified electrodes in organic electrocatalysis","authors":"Xinglei He, Hong Yan, Ke-Yin Ye","doi":"10.1016/j.coelec.2024.101478","DOIUrl":"10.1016/j.coelec.2024.101478","url":null,"abstract":"<div><p>Porous materials are emerging recyclable electrocatalysts that exhibit many advantages such as rich pore environments, tunable structures and functionalities, and large specific surface areas. However, the research of these materials in organic electrocatalysis is promising but only emerged recently. In this review, we summarized the latest research progress of porous carbon materials, metal-organic frameworks (MOFs), and covalent-organic frameworks (COFs) in organic electrocatalysis, focusing on their structural optimization, electrochemical performance, and reaction mechanisms. In addition, the main challenges and future directions in this field were also discussed. We hope that this review can inspire more research interest of synthetic organic chemists in the development of porous electrocatalysts in organic electrocatalysis.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"45 ","pages":"Article 101478"},"PeriodicalIF":8.5,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140205328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}