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Hydrogen and Oxygen Permeability through PEFC Membrane and Membrane Electrode Assembly 通过PEFC膜和膜电极组件的氢和氧渗透性
Pub Date : 2023-09-29 DOI: 10.1149/11204.0291ecst
Miho Kageyama, Beste Balci, Shotaro Danjo, Kimiyo Nakamichi, Motoaki Kawase
A proton exchange membrane (PEM) is an important component of a polymer electrolyte fuel cell (PEFC) from the viewpoint of proton transport. Only protons are desired to be transported through a membrane, but the feed gases also permeate. The permeation of the feed gas through a membrane affects the PEFC performance. Temperature and relative humidity dependencies of the hydrogen and oxygen permeability through a perfluorosulfonic acid (PFSA) membrane were measured. By considering that a membrane consists of three layers, i.e. a bulk layer sandwiched between skin layers, the transport properties of each layer were separated. The bulk layer effective diffusion coefficients of hydrogen and oxygen through both a PEM and an MEA were formulated as a function of temperature and RH. The oxygen transfer coefficient in the skin layer increased with RH, whereas the hydrogen transfer coefficient was almost constant regardless of RH.
从质子传输的角度来看,质子交换膜(PEM)是聚合物电解质燃料电池(PEFC)的重要组成部分。只有质子需要通过膜传输,但原料气体也会渗透。原料气通过膜的渗透影响PEFC的性能。测量了氢和氧通过全氟磺酸(PFSA)膜的温度和相对湿度的依赖关系。考虑到膜由三层组成,即在表皮层之间夹着一大块层,因此将每一层的传输特性分开。通过PEM和MEA的体积层有效扩散系数是温度和相对湿度的函数。皮肤层的氧传递系数随相对湿度增大而增大,而氢传递系数与相对湿度无关。
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引用次数: 0
Molecular analysis of hydrogen-bond structures in polymer electrolyte membrane in polymer electrolyte fuel cells below freezing temperatures 低温聚合物电解质燃料电池中聚合物电解质膜中氢键结构的分子分析
Pub Date : 2023-09-29 DOI: 10.1149/11204.0285ecst
Hiroki Nishizawa, Takuya Mabuchi, Naoya Uene, Takashi Tokumasu
The PEFC has been attracted to achieve carbon neutralization with using of cars and so on. Unclearness of the internal state of the polymer electrolyte membrane (PEM) below freezing temperature is one of the biggest problems toward expansion of operating temperature. Our final objective is to reveal the internal state of PEM and transport mechanism in such environment. We performed the reactive force field molecular dynamics to analyze the internal structure of PEM because under such environment chemical reaction is the key transport mechanisms. A radial distribution function (RDF) was performed to analyze the structure in PEM. Our RDF was in good agreement with other simulation results. We found the increase of water molecules in the overlapped solvation area with the decrease in temperature. The water molecules hardly move in the overlapped area, indicating that proton diffusivity decreases.
PEFC已被吸引来实现碳中和使用汽车等。聚合物电解质膜(PEM)在冷冻温度下的内部状态不清楚是影响工作温度膨胀的最大问题之一。我们的最终目标是揭示质子交换膜的内部状态和在这种环境下的传输机制。由于在这种环境下,化学反应是PEM的主要传输机制,因此我们采用反应力场分子动力学方法来分析PEM的内部结构。采用径向分布函数(RDF)对PEM结构进行了分析。我们的RDF与其他仿真结果吻合较好。我们发现,随着温度的降低,重叠溶剂化区的水分子增多。水分子在重叠区域几乎不移动,表明质子扩散率降低。
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引用次数: 0
Nanosecond Laser Irradiation for Interface Bonding Characterization 纳秒激光辐照用于界面键合表征
Pub Date : 2023-09-29 DOI: 10.1149/11203.0039ecst
Vincent Larrey, Arthur Arribehaute, Brendon Caulfield, Pablo Acosta Alba, Christophe Morales, Paul Noël, Mathieu Opprecht, Frank Fournel, Didier Landru, Francois Rieutord
In this study, we propose a novel method to quantify the interfacial water trapped at the direct bonding interface. The concept is to intentionally create bonding defects with controlled size and shape, and use them as sensors for the gases generated through the oxidation of a material (in our case, Silicon) by water adsorbed on the surfaces prior to bonding. The evolution of the sensor sizes provides valuable insights into the amount of gas they have trapped, allowing us to analyze the imbibition effect. Analyzing sensors arrays also enables us to quantify the amount of water that was initially present at the bonding interface. Moreover, it opens up the possibility of proposing a novel bonding energy measurement method.
在这项研究中,我们提出了一种新的方法来量化在直接键合界面上捕获的界面水。这个概念是有意制造出尺寸和形状可控的键合缺陷,并将它们用作传感器,用于在键合之前被吸附在表面的水氧化的材料(在我们的例子中是硅)所产生的气体。传感器尺寸的变化提供了有价值的信息来了解它们所捕获的气体量,使我们能够分析吸胀效应。分析传感器阵列也使我们能够量化最初出现在键合界面上的水量。此外,它开辟了提出一种新的键能测量方法的可能性。
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引用次数: 0
Probing the Catalyst-Ionomer Interface in Catalyst Layers with Sulfo-Phenylated Polyphenylene Ionomers Using CO-Displacement and Stripping Techniques 用co置换和汽提技术探测亚苯基聚苯离聚物在催化剂层中的催化剂-离聚物界面
Pub Date : 2023-09-29 DOI: 10.1149/11204.0069ecst
Robert James Anton, Shikai Sun, Karen Swider-Lyons, Cortney Mittelsteadt, Michael Adamski, Benjamin Britton, Yu Morimoto, Iryna Zenyuk
An investigation of ionomer-catalyst interfaces for electrodes containing sulfo-phenylated polyphenylene (sPPP) ionomers is conducted with CO displacement and stripping experiments. We find that at fully humidified conditions, catalyst layers containing sPPP ionomers show a CO displacement peak that is almost entirely suppressed. This suppression corresponds to adsorption of sulfonic acid group adsorption on only 2% of the available Pt surface. We also observe that at 100% RH, the double-layer capacitance of the catalyst layer is higher when poisoned by CO. This is inverse of the behavior observed with PFSA electrodes, indicating that there might be different ionomer-catalyst interactions present with an sPPP ionomer. We hypothesize that differences between sPPP and perfluorinated sulfonic acid (PFSA) ionomer backbones may account for this difference due to the presence of phenyl rings, which could adsorb to Pt surfaces preferentially at high humidification.
采用CO置换和汽提实验研究了含硫苯基化聚苯(sPPP)离聚体电极的离聚体-催化剂界面。我们发现在完全加湿的条件下,含有sPPP离聚体的催化剂层显示出几乎完全抑制的CO置换峰。这种抑制对应于仅在2%的铂表面吸附磺酸基团。我们还观察到,在100% RH下,当CO中毒时,催化剂层的双层电容更高。这与PFSA电极观察到的行为相反,表明sPPP离聚体可能存在不同的离聚体-催化剂相互作用。我们假设sPPP和全氟磺酸(PFSA)离子单体骨架之间的差异可能是由于苯环的存在造成的,苯环在高湿度下可以优先吸附到Pt表面。
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引用次数: 0
Water Transport Modeling in a Microporous Layer for a Polymer Electrolyte Membrane Water Electrolyzer Having a Gas-Liquid Separating Interdigitated Flow Field 具有气液分离交叉流场的聚合物电解质膜式电解槽微孔层中水输运模型
Pub Date : 2023-09-29 DOI: 10.1149/11204.0273ecst
Hironori Nakajima, Henrik Ekström, Asuka Shima, Yoshitsugu Sone, Göran Lindbergh
A new interdigitated flow field design for polymer electrolyte membrane electrolyzers has been developed for ground and space applications. It internally separates oxygen and liquid water, eliminating the water circulators to remove the bubbles and external gas-liquid separators with buoyancy. The capillary pressure in the hydrophobic microporous layer(MPL) of the anode porous transport layer enables the internal separation of oxygen gas and pressurized liquid water. A finite element model (COM-SOL Multiphysics) simulates water transport in the MPL. Electrochemical impedance spectra determine the electrochemical kinetic parameters for the model. The model accounts for the oxygen bubble coverage of the CL, liquid water saturation in the MPL, and the current ratio between liquid water and water vapor at the MPL-CL interface. The vapor from liquid water in the MPL mixes with oxygen for diffusion. The water evaporation rate based on liquid water saturation in the MPL is introduced.
本文提出了一种用于地面和空间应用的聚合物电解质膜式电解槽的新型交叉流场设计。它内部分离氧气和液态水,消除水循环器去除气泡,外部气液分离器具有浮力。阳极多孔输运层疏水微孔层(MPL)中的毛细压力使氧气和加压液态水在内部分离。一个有限元模型(COM-SOL Multiphysics)模拟了MPL中的水输送。电化学阻抗谱决定了模型的电化学动力学参数。该模型考虑了CL的氧泡覆盖率、MPL中的液态水饱和度以及MPL-CL界面上液态水与水蒸气的电流比。MPL中来自液态水的蒸汽与氧气混合以进行扩散。介绍了MPL中基于液态水饱和度的水分蒸发速率。
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引用次数: 0
Atomic Structures and Chemical states of active and inactive dopants in GaN 氮化镓中活性和非活性掺杂剂的原子结构和化学状态
Pub Date : 2023-09-29 DOI: 10.1149/11202.0067ecst
Yoshiyuki Yamashita, Jingmin Tang, Yusuke Hashimote, Tomohiro Matsushita
We investigated atomic structures and chemical states of active and inactive dopant sites for Mg- and Si- doped in GaN using photoelectron holography and X-ray absorption near edge structure. In the case of Mg-doped GaN, we found that a Mg atom substituting a Ga atom (Mg Ga ) is an active dopant site in GaN whereas Mg Ga with two H atoms is an inactive dopant site in GaN. We found that a Si atom substituting a Ga atom is an active dopant site in Si-doped GaN whereas Si 3 N 4 is an inactive dopant site in GaN.
我们利用光电子全息和x射线吸收近边结构研究了氮化镓中镁和硅掺杂活性和非活性位点的原子结构和化学状态。在Mg掺杂GaN的情况下,我们发现一个Mg原子取代一个Ga原子(Mg Ga)在GaN中是一个活性掺杂位点,而两个H原子的Mg Ga在GaN中是一个非活性掺杂位点。我们发现,Si原子取代Ga原子是Si掺杂GaN的活性掺杂位点,而si3n4是GaN的非活性掺杂位点。
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引用次数: 0
(Invited) In-Depth Understanding of the Key Contributors to the Total Flicker Noise in Advanced Logic Devices (特邀)深入了解高级逻辑器件中总闪烁噪声的主要影响因素
Pub Date : 2023-09-29 DOI: 10.1149/11201.0053ecst
Bogdan Cretu, Abderrahim Tahiat, Anabela Veloso, Eddy Simoen
The aim of this work is to perform an in-depth analysis in order to identify the key contributors to the total flicker noise in advanced MOSFET technologies, e.g. UTBOX, Gate-all-around (GAA) nanowire or nanosheet FET devices. For all investigated devices of these technologies an increase of the flat-band noise power spectral density level with the increase of the applied gate voltage was observed. This may be related to the correlated carrier number and mobility fluctuations noise mechanisms and/or with additional access resistances noise contributions. Different existing models have been applied in order to identify the key 1/f noise mechanism. However, a discrepancy in the obtained 1/f noise contributors is highlighted, and leads to some questioning about which employed model is most accurate and gives good indications on the key contributors and estimated parameters of the total flicker noise.
这项工作的目的是进行深入分析,以确定先进MOSFET技术中总闪烁噪声的关键因素,例如UTBOX,栅极全方位(GAA)纳米线或纳米片FET器件。在所研究的器件中,平带噪声功率谱密度随外加栅极电压的增加而增加。这可能与相关的载流子数和迁移率波动噪声机制和/或附加的接入阻力噪声贡献有关。为了确定关键的1/f噪声机制,应用了不同的现有模型。然而,得到的1/f噪声贡献者之间的差异是突出的,这导致了一些问题,即所采用的模型最准确,并能很好地指示总闪烁噪声的关键贡献者和估计参数。
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引用次数: 0
Numerical Reconstruction of Proton Exchange Membrane Fuel Cell Gas Diffusion Layers 质子交换膜燃料电池气体扩散层的数值重建
Pub Date : 2023-09-29 DOI: 10.1149/11204.0049ecst
Danan Yang, Himani Garg, Steven B. Beale, Martin Andersson
Stochastic reconstruction is widely employed for effective and flexible imitation of Gas Diffusion Layers (GDLs), e.g., to facilitate the study of their properties. However, the reconstruction often overlooks crucial factors such as fiber curvature, fiber stack arrangement, and fiber anisotropy. Consequently, the impact of these structural characteristics remains poorly understood. In this study, an in-house reconstruction procedure is developed based on the periodic surface model. This procedure enables the generation of GDLs with either straight or curved fibers, layer-by-layer or random arrangement, and different probabilities of through-plane fiber orientation angles. The porosity, domain size, and fiber diameter are extracted from an experimental image-based GDL and utilized as input data for the reconstruction. Furthermore, the different GDLs are compared in terms of pore size distribution and through-plane porosity distribution. It is concluded that introducing proper selections of these fiber features gives the reconstruction more realistic properties.
随机重建被广泛用于有效和灵活地模拟气体扩散层(gdl),例如便于研究其性质。然而,这种重构往往忽略了光纤曲率、光纤堆叠排列和光纤各向异性等关键因素。因此,这些结构特征的影响仍然知之甚少。在本研究中,开发了一种基于周期曲面模型的内部重建程序。该方法可以生成直线或弯曲光纤,分层或随机排列,以及不同概率的穿过平面的光纤取向角的gdl。从基于实验图像的GDL中提取孔隙度、区域尺寸和纤维直径,并将其作为重建的输入数据。此外,还比较了不同GDLs的孔径分布和通面孔隙度分布。通过对这些纤维特性的适当选择,可以使重建的材料具有更真实的性能。
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引用次数: 0
(Digital Presentation) Facile Fabrication of Nickel and Sc-Doped Zirconia Cermet Electrode Thin Film on YSZ Substrate Via Screen-Printing for Solid Oxide Electrochemical Cells 固体氧化物电化学电池在YSZ衬底上丝网印刷制备掺杂镍和sc的氧化锆陶瓷电极薄膜
Pub Date : 2023-09-29 DOI: 10.1149/11205.0159ecst
Christine Mae Macalisang, Rinlee Cervera
Electrode materials play a key role in the performance of solid oxide electrochemical cells. In this study, screen-printing was used to fabricate a porous nickel – scandia-stabilized zirconia (Ni-ScSZ) cermet electrode on a dense YSZ solid electrolyte substrate. The effect of sintering temperatures, 1200°C and 1300°C, on the structure and morphology of the deposited films were investigated. The screen-printed films were sintered and then reduced under an Ar/5% H 2 gas environment at 700°C for 2h to form porous electrodes. The sintered films exhibited NiO and ScSZ cubic phases from X-ray diffraction (XRD) analysis. A desired porous morphology of NiO-ScSZ film sintered at 1200°C was achieved compared to a denser morphology sintered at 1300°C as revealed by the scanning electron microscopy (SEM) micrographs. XRD patterns of reduced samples suggested a complete reduction of cubic NiO to Ni with an increase in porosity as observed from SEM micrographs.
电极材料对固体氧化物电化学电池的性能起着至关重要的作用。在本研究中,采用丝网印刷技术在致密的YSZ固体电解质衬底上制备了多孔镍钪稳定氧化锆(Ni-ScSZ)金属陶瓷电极。研究了烧结温度1200℃和1300℃对镀层结构和形貌的影响。将丝网印刷薄膜烧结后,在Ar/5% h2气体环境下,在700℃下还原2h,形成多孔电极。通过x射线衍射(XRD)分析,烧结膜表现为NiO和ScSZ立方相。扫描电镜(SEM)显微照片显示,在1200°C下烧结的NiO-ScSZ膜具有理想的多孔形貌,而在1300°C下烧结的NiO-ScSZ膜具有致密的形貌。还原样品的XRD谱图表明,随着孔隙率的增加,立方NiO完全还原为Ni。
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引用次数: 0
A Three-Dimensional, Multiphysics Model of An Alkaline Electrolyzer 碱性电解槽的三维多物理场模型
Pub Date : 2023-09-29 DOI: 10.1149/11204.0433ecst
Diogo Loureiro Martinho, Torsten Berning, Mohammadmahdi Abdollahzadehsangroudi, Anders Rønne Rasmussen, Jakob Hærvig, Samuel Simon Araya
As the most mature technology within the electrolysis field, alkaline electrolyzers are expected to play an important role in the energetic transition. Advantages as their simplicity, modularity and low-cost components make it an interesting technology for the near future. However, the fundamental physics are complex as it includes multicomponent, multiphase flow, porous media, electrochemistry and heat transfer. To have a better understanding of these phenomena, the presented work is devoted to the development of a computational fluid dynamic model to better understand the behavior of all the species that are part of this technology.
碱性电解槽作为电解领域最成熟的技术,有望在能量转换中发挥重要作用。其简单、模块化和低成本组件的优势使其在不久的将来成为一项有趣的技术。然而,基础物理是复杂的,因为它包括多组分、多相流、多孔介质、电化学和传热。为了更好地理解这些现象,本文致力于开发一种计算流体动力学模型,以更好地理解所有物种的行为,这些物种都是这项技术的一部分。
{"title":"A Three-Dimensional, Multiphysics Model of An Alkaline Electrolyzer","authors":"Diogo Loureiro Martinho, Torsten Berning, Mohammadmahdi Abdollahzadehsangroudi, Anders Rønne Rasmussen, Jakob Hærvig, Samuel Simon Araya","doi":"10.1149/11204.0433ecst","DOIUrl":"https://doi.org/10.1149/11204.0433ecst","url":null,"abstract":"As the most mature technology within the electrolysis field, alkaline electrolyzers are expected to play an important role in the energetic transition. Advantages as their simplicity, modularity and low-cost components make it an interesting technology for the near future. However, the fundamental physics are complex as it includes multicomponent, multiphase flow, porous media, electrochemistry and heat transfer. To have a better understanding of these phenomena, the presented work is devoted to the development of a computational fluid dynamic model to better understand the behavior of all the species that are part of this technology.","PeriodicalId":11473,"journal":{"name":"ECS Transactions","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135245711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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