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Well log prediction of total organic carbon: A comprehensive review 测井仪预测总有机碳:全面回顾
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-03 DOI: 10.1016/j.earscirev.2024.104913
Source rocks are fundamental elements for petroleum systems, and Total Organic Carbon (TOC) is one of the most important geochemical parameters in source rock property evaluation. The TOC determination methods using laboratory tests are expensive and limited, therefore prediction of TOC using geophysical well logs are vital for source rock characterization. Though there are various proposed TOC quantitation method, however, there still remains large uncertainty in delineation and quantitation of TOC using well log data due to the complex non-linear relationships between TOC and well log information, as well as the inherent limitations of various methods for TOC prediction. To fill the gaps between TOC and well logs, and eliminate uncertainties existing in empirical methods such as ΔlgR method, the geological, geophysical and geochemical data are integrated. History of source rock evaluation using well logs is reviewed, and sensitive well log parameters for source rocks are selected. The TOC content is correlated with well log series to unravel the well log responses of source rock intervals, and the organic matter rich intervals have high Uranium (U) concentrations and gamma ray (GR) readings, high sonic transit time (AC) and compensated neutron log (CNL), high resistivity, but low density readings. Then the various methods used for TOC quantitation are summarized in terms of their principles, interpretation process, and advantage and limitations. The Schmoker method is not applicable in shales, and borehole regularity will affect the linear regression relationship between TOC and bulk density. The Passey's ΔlgR method is widely used, however, the baseline selection will reduce the accuracy, and ΔlgR method is not applicable in highly mature or deep burial source rocks. The multiple regression analysis is hard to extend in other source rocks. The spectral GR method can hardly be used for lacustrine source rock analysis. The high acquisition costs of Nuclear Magnetic Resonance (NMR) and spectral mineral composition log (Schlumberger's Litho-Scanner logs) limit their extension in source rock evaluation. Artificial intelligence methods such as Back propagation (BP) neural network, Extreme Gradient Boosting (XGBOOST) can be used to predict TOC content via conventional logs, and the results are compared with the geochemical-measured TOC and ΔlgR method. The optimization of various methods for TOC prediction should fully consider their advantage and limitations. Additionally, comprehensive assessment of source rock should determine TOC, quality, and maturity of source rocks. This comprehensive review provides systematic and novel insights in applications of well logs in source rock evaluation, and has potential to fill gaps between geologists, geochemists and petrophysicists.
源岩是石油系统的基本要素,而总有机碳(TOC)是源岩性质评价中最重要的地球化学参数之一。实验室测试的 TOC 测定方法既昂贵又有限,因此利用地球物理测井记录预测 TOC 对源岩特征描述至关重要。虽然目前已经提出了多种 TOC 定量方法,但由于 TOC 与测井资料之间存在复杂的非线性关系,以及各种 TOC 预测方法的固有局限性,使用测井资料对 TOC 进行划分和定量仍然存在很大的不确定性。为了填补 TOC 与测井记录之间的空白,消除经验方法(如 ΔlgR 方法)中存在的不确定性,需要对地质、地球物理和地球化学数据进行整合。回顾了使用测井仪评价源岩的历史,并选择了源岩的敏感测井仪参数。将 TOC 含量与测井系列相关联,以揭示源岩层段的测井反应。富含有机质的岩层段具有较高的铀(U)浓度和伽马射线(GR)读数、较高的声波穿越时间(AC)和补偿中子测井(CNL)、较高的电阻率,但密度读数较低。然后,从原理、解释过程、优势和局限性等方面总结了用于 TOC 定量的各种方法。Schmoker 方法不适用于页岩,钻孔的规则性会影响 TOC 与体积密度之间的线性回归关系。Passey的ΔlgR方法应用广泛,但基线选择会降低精度,且ΔlgR方法不适用于高成熟度或深埋源岩。多元回归分析法很难在其他源岩中推广。光谱 GR 法很难用于湖泊源岩分析。核磁共振(NMR)和光谱矿物成分测井(斯伦贝谢公司的 Litho-Scanner 测井)的采集成本较高,限制了其在源岩评价中的应用。反向传播(BP)神经网络、极端梯度提升(XGBOOST)等人工智能方法可用于通过常规测井预测 TOC 含量,并将结果与地球化学测量的 TOC 和 ΔlgR 方法进行比较。各种 TOC 预测方法的优化应充分考虑其优势和局限性。此外,源岩的综合评估应确定源岩的总有机碳、质量和成熟度。本综述为测井仪在源岩评价中的应用提供了系统而新颖的见解,有望填补地质学家、地球化学家和岩石物理学家之间的空白。
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引用次数: 0
The Ediacaran paleontological record in South America 南美洲埃迪卡拉古生物记录
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-09-03 DOI: 10.1016/j.earscirev.2024.104915

South America figures as one of the most fruitful continents for paleontological research on the Ediacaran-Cambrian transition, with almost 100 years of studies on organisms preserved in carbonates and siliciclastic successions deposited during the birth of the Gondwana supercontinent. However, this scientific record is often scattered among local publications which is part of the reason for the unfamiliarity of geoscientists with the Ediacaran paleontology of this continent. To address this issue, this paper provides a comprehensive overview of Ediacaran paleontology in South America. It achieves this by conducting a thorough assessment of existing research alongside presenting ample new data concerning fossil discoveries. Following current efforts to add new pieces to the complex puzzle on metazoan evolution, this contribution resumes our understanding of the variety and diversity of Ediacaran assemblages in this part of the planet. Positioning South American successions in space and time and comparing them with occurrences worldwide helps us understand the different pulses of extinctions, and their forcings and consequences for life diversification during the Ediacaran. Lastly, by definitively adding the paleontological record of SW Gondwana to the global picture, we seek to contribute to current discussions on the subdivision of the Ediacaran, perhaps the most emblematic period in the geological record.

南美洲是埃迪卡拉纪-寒武纪过渡时期古生物学研究成果最丰富的大陆之一,对冈瓦纳超级大陆诞生期间沉积在碳酸盐岩和硅质岩层中的生物进行了近 100 年的研究。然而,这些科学记录往往散见于当地出版物中,这也是地球科学家不熟悉该大陆埃迪卡拉古生物学的部分原因。针对这一问题,本文对南美洲埃迪卡拉古生物学进行了全面概述。为此,本文在对现有研究进行全面评估的同时,还提供了有关化石发现的大量新数据。目前,我们正在努力为元古动物进化的复杂拼图增添新的碎片,这篇论文将重新唤起我们对地球上这一地区埃迪卡拉生物群的多样性的认识。对南美洲的演替进行空间和时间定位,并将其与世界各地的演替进行比较,有助于我们了解埃迪卡拉纪期间不同的灭绝浪潮及其对生命多样化的影响和后果。最后,通过明确地将冈瓦纳西南部的古生物记录添加到全球图景中,我们试图为当前关于埃迪卡拉纪细分的讨论做出贡献,埃迪卡拉纪可能是地质记录中最具代表性的时期。
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引用次数: 0
Review of the missing link between field and modeled submarine debris flows: Scale effects of physical modeling 审查实地与模型海底泥石流之间缺失的联系:物理建模的规模效应
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-30 DOI: 10.1016/j.earscirev.2024.104911

Submarine debris flows occur under the cloak of the sea and are giants among other types of landslides on planet Earth. They pose a significant threat to sustainable offshore development and marine ecosystems. Existing research on these flows mainly rely on back-analyzing field events and conducting miniaturized experiments. However, it is unclear whether the dynamics of miniaturized flows are similar to field ones. In this review, dimensional analysis is used to evaluate laboratory and field data collated from the literature to compare the dynamics of submarine debris flows at different scales. Miniaturized flows are demonstrated to have disproportionately low yield stress and viscosity compared to field flows. The low yield stress is caused by the need to reduce the clay content of a model debris mixture so that it can flow under substantially reduced gravitational driving stresses in laboratory conditions. Consequently, some proposed scaling relationships in the literature derived from laboratory experiments need to be used with caution. Specifically, both the Reynolds and Bingham numbers cannot independently provide a scale-invariant criterion for distinguishing between laminar and turbulent flows. Instead, the Hampton number, with a threshold >0.001, is proposed for the design of the yield stress and clay contents of laboratory flows. Moreover, reduced model viscous stress drastically reduces erosion potential, which limits the existing understanding of the excess fluid pressures generated at the flow-bed interface, and thus flow mobility. The mobility of field flows is generally attributed to hydroplaning. However, this conjecture mainly stems from experiments with impervious boundaries. Such an idealization exaggerates the effects of excess fluid pressures that develop during hydroplaning. An enhanced understanding of the differences in dynamics between field and modeled flows can improve the design of future experiments to model submarine debris flows.

海底泥石流发生在海的隐蔽处,是地球上其他类型滑坡中的巨型滑坡。它们对近海可持续发展和海洋生态系统构成重大威胁。现有的研究主要依赖于对现场事件的反向分析和微型实验。然而,目前还不清楚小型化流体的动态是否与野外流体相似。本综述采用维度分析法评估从文献中整理的实验室和实地数据,以比较不同尺度的海底碎屑流动力学。研究表明,与野外流动相比,小型化流动的屈服应力和粘度过低。产生低屈服应力的原因是需要降低模型碎片混合物的粘土含量,使其能够在实验室条件下在重力驱动应力大幅降低的情况下流动。因此,需要谨慎使用文献中提出的一些源自实验室实验的比例关系。具体来说,雷诺数和宾厄姆数都不能独立提供区分层流和湍流的尺度不变标准。取而代之的是汉普顿数,其临界值为 0.001,用于设计实验室流动的屈服应力和粘土含量。此外,模型粘性应力的降低大大降低了侵蚀潜力,这限制了对流床界面产生的过大流体压力的现有理解,从而限制了流动的流动性。野外流动的流动性一般归因于水力平移。然而,这种猜测主要源于不透水边界的实验。这种理想化的方法夸大了水漂过程中产生的过大流体压力的影响。加强对现场流与模型流之间动力学差异的了解,可以改进未来模拟海底碎屑流的实验设计。
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引用次数: 0
A review of abyssal serpentinite geochemistry and geodynamics 深海蛇绿岩地球化学和地球动力学综述
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-30 DOI: 10.1016/j.earscirev.2024.104910
<div><p>The formation of abyssal serpentinites leads to deep changes of the oceanic lithosphere rheology and geochemistry, hence playing a key role on geodynamic and geochemical cycles. Here we review and discuss the geochemical diversity of serpentinites collected on abyssal floors (i.e., abyssal serpentinites) from different geodynamical settings, namely passive margin, forearc and oceanic spreading ridges. We further divided abyssal serpentinites from spreading ridges according to the tectonic contexts in which they were exhumed, differentiating slow-spreading centres (exhumed within the axial valleys and at oceanic detachments), ultra-slow spreading centres (from amagmatic axial valleys and smooth seafloor), fast spreading axis (mostly from deeps) and large transform faults (all spreading rates).</p><p>The major and trace element composition of abyssal serpentinites is first controlled by melt extraction and melt/rock interaction processes occurring prior to serpentinization. Slow-, fast- spreading ridges and forearc serpentinites are distinguished by low Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> ratios and depleted REE signatures when compared to abyssal serpentinites recovered from ultra-slow spreading ridges, transform faults and passive margins, where magmatic extraction is likely more limited or/and melt/rock reaction prominent. Ultra-slow spreading ridge serpentinites have high Fe<sup>3+</sup>/∑Fe when compared to passive margin and forearc serpentinites, while slow spreading ridge and transform fault serpentinites have intermediate Fe<sup>3+</sup>/∑Fe, close to that of magnetite. This distribution is correlated with MgO/SiO<sub>2</sub> ratios, suggesting that high MgO contents could thwart Fe oxidation, and thus H<sub>2</sub> production, in abyssal environments.</p><p>The presence of mafic units at depth affects the chemical properties (e.g., sulfur activity [<em>a</em>H<sub>2</sub>S], oxygen fugacity (<em>f</em>O<sub>2</sub>)) of the serpentinizing fluids leading to contrasting enrichments of redox sensitive elements (S, U, Eu, Ce, As, Sb) and metals (Zn, Cu) in abyssal serpentinites. At slow-spreading ridges, the circulation of high <em>a</em>H<sub>2</sub>S and low <em>f</em>O<sub>2</sub> fluids, equilibrated with gabbroic rocks, leads to the formation of serpentinites with pronounced Eu anomalies, enrichments of LREE over M-HREE and of As over Sb, and to the storage of metal (Zn, Cu) and sulfide in serpentinites. In contrast, at ultra-slow spreading ridges and at transform faults, the absence of an active magmatic system limits changes in seawater composition prior to serpentinization. The oxidizing conditions favours Ce(IV) (Ce anomalies on REE patterns), and the preferential mobility of Sb(V) over Sb(III) (coupled behaviour between Sb and As), as well as the storage of sulfate over sulfides in rocks. Fast spreading ridge serpentinites present both features with samples having negative Ce anomaly (Ce (IV)) and others with positiv
深海蛇绿岩的形成导致了海洋岩石圈流变学和地球化学的深层变化,因此对地球动力和地球化学循环起着关键作用。在此,我们回顾并讨论了从被动边缘、前弧和大洋扩张脊等不同地球动力学环境中采集的深海海底蛇绿岩(即深海蛇绿岩)的地球化学多样性。我们根据深海蛇绿岩出露的构造背景,进一步划分了扩张脊的深海蛇绿岩,将其分为慢扩张中心(在轴谷内和大洋脱离处出露)、超慢扩张中心(来自变形轴谷和光滑海底)、快速扩张轴(主要来自深海)和大型转换断层(所有扩张速率)。深海蛇绿岩的主要元素和微量元素组成首先受蛇绿岩化之前发生的熔体萃取和熔体/岩石相互作用过程的控制。与从超慢速扩张海脊、转换断层和被动边缘回收的深海蛇绿岩相比,慢速、快速扩张海脊和前弧蛇绿岩的Al2O3/SiO2比率较低,REE特征贫乏,而在超慢速扩张海脊、转换断层和被动边缘,岩浆萃取可能更为有限,或/和熔体/岩石反应更为突出。与被动边缘和前弧蛇纹岩相比,超慢速扩张海脊蛇纹岩具有较高的 Fe3+/∑Fe,而慢速扩张海脊和转换断层蛇纹岩具有中等的 Fe3+/∑Fe,接近磁铁矿的 Fe3+/∑Fe。这种分布与 MgO/SiO2 比率相关,表明在深海环境中,高 MgO 含量可能会阻碍铁的氧化,从而阻碍 H2 的产生、在深海蛇绿岩中,氧化还原敏感元素(S、U、Eu、Ce、As、Sb)和金属(Zn、Cu)的富集形成了鲜明对比。在缓慢扩张的海脊,高 aH2S 和低 fO2 流体与辉长岩平衡循环,形成了具有明显 Eu 异常的蛇绿岩,LREE 元素富集于 M-HREE 元素,As 元素富集于 Sb 元素,金属(Zn、Cu)和硫化物储存在蛇绿岩中。相反,在超慢速扩张海脊和转换断层,由于缺乏活跃的岩浆系统,限制了蛇纹岩化之前海水成分的变化。氧化条件有利于Ce(IV)(REE图案上的Ce异常),有利于Sb(V)而不是Sb(III)的移动(Sb和As之间的耦合行为),以及有利于硫酸盐而不是硫化物在岩石中的储存。快速扩张脊蛇纹岩具有这两种特征,其中一些样品具有负的铈异常(铈(IV)),而另一些样品则具有正的Eu*(Eu(II))。在大洋扩张脊,深海蛇绿岩中的流体移动元素(FME)和非氧化还原敏感元素(如 Cs、Ba、Rb、B 或 Li)是均匀的。被动边缘和弧前蛇绿岩均无 Ce 异常,只有少数弧前样品显示 Eu 异常和中等程度的 LREE 富集。前弧蛇绿岩是地球化学的终成体。在那里,板块衍生流体的影响增强了富含 FME 的蛇绿岩的形成,这些蛇绿岩与富含 CO2 的沉积物衍生流体有很强的亲缘关系(即相对于 Rb 和 Sb,Cs 和 As 分别富集)。
{"title":"A review of abyssal serpentinite geochemistry and geodynamics","authors":"","doi":"10.1016/j.earscirev.2024.104910","DOIUrl":"10.1016/j.earscirev.2024.104910","url":null,"abstract":"&lt;div&gt;&lt;p&gt;The formation of abyssal serpentinites leads to deep changes of the oceanic lithosphere rheology and geochemistry, hence playing a key role on geodynamic and geochemical cycles. Here we review and discuss the geochemical diversity of serpentinites collected on abyssal floors (i.e., abyssal serpentinites) from different geodynamical settings, namely passive margin, forearc and oceanic spreading ridges. We further divided abyssal serpentinites from spreading ridges according to the tectonic contexts in which they were exhumed, differentiating slow-spreading centres (exhumed within the axial valleys and at oceanic detachments), ultra-slow spreading centres (from amagmatic axial valleys and smooth seafloor), fast spreading axis (mostly from deeps) and large transform faults (all spreading rates).&lt;/p&gt;&lt;p&gt;The major and trace element composition of abyssal serpentinites is first controlled by melt extraction and melt/rock interaction processes occurring prior to serpentinization. Slow-, fast- spreading ridges and forearc serpentinites are distinguished by low Al&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;/SiO&lt;sub&gt;2&lt;/sub&gt; ratios and depleted REE signatures when compared to abyssal serpentinites recovered from ultra-slow spreading ridges, transform faults and passive margins, where magmatic extraction is likely more limited or/and melt/rock reaction prominent. Ultra-slow spreading ridge serpentinites have high Fe&lt;sup&gt;3+&lt;/sup&gt;/∑Fe when compared to passive margin and forearc serpentinites, while slow spreading ridge and transform fault serpentinites have intermediate Fe&lt;sup&gt;3+&lt;/sup&gt;/∑Fe, close to that of magnetite. This distribution is correlated with MgO/SiO&lt;sub&gt;2&lt;/sub&gt; ratios, suggesting that high MgO contents could thwart Fe oxidation, and thus H&lt;sub&gt;2&lt;/sub&gt; production, in abyssal environments.&lt;/p&gt;&lt;p&gt;The presence of mafic units at depth affects the chemical properties (e.g., sulfur activity [&lt;em&gt;a&lt;/em&gt;H&lt;sub&gt;2&lt;/sub&gt;S], oxygen fugacity (&lt;em&gt;f&lt;/em&gt;O&lt;sub&gt;2&lt;/sub&gt;)) of the serpentinizing fluids leading to contrasting enrichments of redox sensitive elements (S, U, Eu, Ce, As, Sb) and metals (Zn, Cu) in abyssal serpentinites. At slow-spreading ridges, the circulation of high &lt;em&gt;a&lt;/em&gt;H&lt;sub&gt;2&lt;/sub&gt;S and low &lt;em&gt;f&lt;/em&gt;O&lt;sub&gt;2&lt;/sub&gt; fluids, equilibrated with gabbroic rocks, leads to the formation of serpentinites with pronounced Eu anomalies, enrichments of LREE over M-HREE and of As over Sb, and to the storage of metal (Zn, Cu) and sulfide in serpentinites. In contrast, at ultra-slow spreading ridges and at transform faults, the absence of an active magmatic system limits changes in seawater composition prior to serpentinization. The oxidizing conditions favours Ce(IV) (Ce anomalies on REE patterns), and the preferential mobility of Sb(V) over Sb(III) (coupled behaviour between Sb and As), as well as the storage of sulfate over sulfides in rocks. Fast spreading ridge serpentinites present both features with samples having negative Ce anomaly (Ce (IV)) and others with positiv","PeriodicalId":11483,"journal":{"name":"Earth-Science Reviews","volume":null,"pages":null},"PeriodicalIF":10.8,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S001282522400237X/pdfft?md5=2510cc0120060dbc7fb50ca53ba321ae&pid=1-s2.0-S001282522400237X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142229442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
How many oceans closed during the Brasiliano Cycle in northeastern Brazil? Implications for the amalgamation of western Gondwana 巴西东北部的巴西利亚诺周期期间有多少海洋关闭?对冈瓦纳西部合并的影响
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-28 DOI: 10.1016/j.earscirev.2024.104909
<div><p>In a pre-Mesozoic drift reconstitution, the Borborema Province in northeastern Brazil connects with the Central African Fold belt to the East and with the Nigerian and Tuareg shields to the North. Therefore, the Borborema Province is an important component to consider in the context of the amalgamation of western Gondwana. The tectonic setting of the Borborema Province has been debated, with some workers advocating for the accretion of allochthonous terranes and others arguing for the decratonization of a large continental landmass followed by the re-accretion of the fragments, either involving or not involving formation of large oceanic domains between them. Resolving the tectonic setting of the Borborema Province has implications for correlations with other Brasiliano-Pan-African belts and supercontinent reconstructions. This paper discusses proposed evidence for oceanic subduction, arc magmatism, and oceanic basin closure based on a comprehensive literature review. This information is integrated with data from the African counterparts of the Borborema Province to provide a geodynamic model for the Neoproterozoic evolution of this portion of western Gondwana. The main evidence for subduction is provided by ultra-high-pressure rocks and c. 660–640 Ma-old intermediate metaigneous rocks with relatively young (1.4–1.0 Ga) whole-rock Sm<img>Nd and zircon Hf model ages in the northwestern part of the Borborema Province. However, a key aspect of the Brasiliano Orogeny in most of the Borborema Province is its synchronous nature. Deposition of predominantly siliciclastic sediments throughout the province ended slightly before or partly coeval with c. 640–610 Ma tectonothermal activity and early orogenic magmatism. Plutons and batholiths emplaced during this age interval comprise predominantly alkali-calcic monzogranites and syenogranites with a large contribution of Paleoproterozoic sources. Together with the absence of juvenile oceanic crust remnants and calc-alkaline metavolcanic rocks, it is thus concluded that (i) widespread crustal extension was almost immediately followed by contractional deformation and regional metamorphism, and (ii) crustal reworking was the dominant process, with limited formation and consumption of oceanic lithosphere. A similar conclusion applies to the Nigerian Shield and the central and southern parts of the Central African Fold Belt. In contrast, large volumes of juvenile crust are found in the Tuareg Shield and in the northern part of the Central African Fold Belt. The model envisions that no large oceanic domain separated the São Francisco/Congo Craton from the Amazonian/West Africa Craton in the middle Neoproterozoic, which were part of the Atlantica paleocontinent since c. 2.0 Ga. Extensional conditions in the Borborema Province and its African counterparts are attributed to far-field stresses transmitted to the interior of Atlantica by an outwardly, N-dipping subduction system. The onset of the contractional
在前中生代漂移重组过程中,巴西东北部的博博雷马省与东部的中非褶皱带以及北部的尼日利亚和图阿雷格地盾相连。因此,博尔博雷马省是冈瓦纳西部合并背景下需要考虑的一个重要组成部分。关于博尔博雷马省的构造背景一直存在争议,一些学者主张异生地块的增生,而另一些学者则认为是一个大的大陆地块的解克拉化,然后碎片重新增生,在碎片之间形成或不形成大的洋域。解决博博雷马省的构造环境问题对与其他巴西-泛非带和超大陆重建的相关性有影响。本文根据全面的文献综述,讨论了大洋俯冲、弧岩浆作用和大洋盆地封闭的拟议证据。这些信息与博博雷马省非洲对应地区的数据相结合,为冈瓦纳西部这部分地区的新近新生代演化提供了一个地球动力学模型。博博雷马省西北部的超高压岩石和约 660-640 兆年前的中元古代岩石提供了俯冲作用的主要证据,这些岩石具有相对年轻(1.4-1.0 Ga)的全岩 SmNd 和锆石 Hf 模型年龄。然而,在博博雷马省的大部分地区,巴西造山运动的一个重要方面是其同步性。整个博博雷马省以硅质沉积物为主的沉积略早于或部分与约 640-610 Ma 的构造热活动和早期造山岩浆活动同时结束。在这一时代区间内沉积的岩浆岩和浴积岩主要由碱钙质单斜花岗岩和正长花岗岩组成,其中有大量的古新生代岩浆岩。再加上没有幼年大洋地壳残余和钙碱性变质岩,因此得出结论:(i) 广泛的地壳延伸几乎紧随收缩变形和区域变质作用之后;(ii) 地壳再加工是主要过程,大洋岩石圈的形成和消耗有限。尼日利亚地盾和中非褶皱带中部和南部也得出了类似的结论。相反,在图阿雷格地盾和中部非洲褶皱带北部发现了大量幼壳。根据该模型的设想,在新元古代中期,圣弗朗西斯科/刚果克拉通与亚马孙/西非克拉通之间没有大洋域的分隔,自约 2.0 Ga 以来,这两个克拉通一直是亚特兰蒂斯古陆的一部分。博博雷马省及其非洲同类地区的延伸条件归因于一个向外、N倾的俯冲系统向亚特兰蒂斯内部传递的远场应力。收缩阶段的开始是由于图阿雷格地盾的不同组成部分向亚特兰提卡北部(其东西向缝合带现在被撒哈拉沙漠所掩盖)的增生,以及西非和撒哈拉火山口分别向东南方向和向西南方向的联合缩进。
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引用次数: 0
Evidence of a large igneous province at ca. 347–330 Ma along the northern Gondwana margin linked to the assembly of Pangea: Insights from U–Pb zircon geochronology and geochemistry of the South-Western Branch of the Variscan Belt (Morocco) 约 347-330 Ma 时在冈瓦纳大陆北缘形成一个大型火成岩区的证据:与泛大陆的形成有关沿冈瓦纳大陆北缘的 347-330 Ma 大火成岩带与泛大陆的形成有关:从瓦里斯坎带西南分支(摩洛哥)的U-Pb锆石地质年代学和地球化学中获得的启示
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-23 DOI: 10.1016/j.earscirev.2024.104905
<div><p>The migration and composition of magmatism over time can provide important insights into the tectonic evolution of an orogen like the Variscan Belt. To identify Large Igneous Provinces (LIPs), key criteria include large magmatic volume, intraplate-origin volcanic geochemistry, and significant plumbing systems. Based on such criteria, we present evidence of ca. 347–330 Ma LIP “fragments” in the South-Western Branch of the Variscan Belt (Morocco), exemplified by the Variscan Central Jebilet Massif. The interpretations are based on four new zircon U–Pb ages obtained by sensitive high-resolution ion microprobe (SHRIMP), a geochemical database of Carboniferous mafic sills, dykes, and gabbroic intrusions together, with subordinate layered ultramafic intrusions, silicic intrusive and volcanic rocks of Central Jebilet Massif, combined with previously published and unpublished data including Sr–Nd isotope analyses. Geochemistry data indicate that the early Carboniferous magmatism of the Jebilet Massif is plume-related. Furthermore, primary magmas of the mafic rocks were generated in an intraplate setting and derived by partial melting of complex sources involving asthenosphere, lithospheric mantle, and subducting slab components (dead subduction slabs), and were modified by crustal contamination during ascent. Magmatic rocks in the same stratigraphic position also occur in other Carboniferous basins including Western Meseta (Rehamna and Moroccan Central Massif). The newly obtained and compiled zircon U–Pb ages from Western Meseta rocks, encompassing an area of ∼400,000 km<sup>2</sup>, indicate that magmatism occurred between ca. 347–330 Ma, coeval with volcanic activity in the Eastern Meseta in northeastern Morocco. The similar emplacement ages, in combination with the tectonic reconstruction of northwestern Gondwana at ca. 330 Ma, suggest that the igneous subprovinces of the Jebilet, Rehamna, and Moroccan Central Massif in Western Meseta, along with Tazekka, Debdou, and Mekkam in Eastern Meseta, the igneous rocks of the Maritimes (Magdalen) Basin, the St. Jean du Doigt bimodal layered intrusion (Brittany, France), and other equivalents such as the Iberian Pyrite Belt and the Southern Vosges magmatism, may represent the eroded and/or deformed remnants of a Large Igneous Province (LIP), which we name here the North Gondwana–Avalonia (NGA) LIP. We argue that this newly identified LIP was formed by a mantle plume that may have played a role in the breakup along the northwestern margin of the precursor megacontinent Gondwana and the assembly of Pangea. The plume was likely centered under the thick lithosphere of Avalonia. The large-scale sublithospheric plume-flow channeling from the plume head led to the development of widespread tholeiitic/alkaline magmatism in the thinned lithosphere of Western Meseta, interpreted here as a large thin-spot domain, and calc-alkaline/alkaline magmatism in the thickened lithosphere of the Eastern Meseta. The mantle pl
岩浆活动随时间的迁移和组成可以为了解像瓦里肯带这样的造山带的构造演化提供重要信息。要识别大火成岩带(LIPs),关键标准包括岩浆量大、板块内起源的火山地球化学和重要的管道系统。根据这些标准,我们提出了在瓦利斯坎带西南分支(摩洛哥)发现的约 347-330 Ma LIP "碎片 "的证据,瓦利斯坎中央杰比勒特丘陵就是一个例子。解释的依据是通过灵敏高分辨率离子微探针(SHRIMP)获得的四个新的锆石 U-Pb 年龄,石炭纪岩浆岩、岩体和辉长岩侵入体的地球化学数据库,以及中央杰比勒特山丘的附属层状超基性侵入体、硅侵入体和火山岩,并结合以前发表和未发表的数据(包括锶钕同位素分析)。地球化学数据表明,杰比勒特山丘的石炭纪早期岩浆活动与羽岩有关。此外,岩浆岩的原生岩浆是在板内环境中产生的,由涉及星体层、岩石圈地幔和俯冲板块成分(死俯冲板块)的复杂来源部分熔化而成,并在上升过程中受到地壳污染的改变。地层位置相同的岩浆岩也出现在其他石炭纪盆地,包括西梅塞塔(雷哈姆纳和摩洛哥中央丘)。新近从西梅塞塔(Western Meseta)岩石中获得并汇编的锆石 U-Pb 年龄表明,岩浆活动发生在约 347-330 Ma 之间,与摩洛哥东北部东梅塞塔(Eastern Meseta)的火山活动同时发生。类似的火山喷发年龄与冈瓦纳西北部约 330 Ma 的构造重建相结合,表明火成岩活动发生在约 347-330 Ma 之间。330 Ma,表明西梅塞塔的 Jebilet、Rehamna 和摩洛哥中央丘陵的火成岩子产区,以及东梅塞塔的 Tazekka、Debdou 和 Mekkam,Maritimes(马格达林)盆地的火成岩,St.Jean du Doigt双峰层状侵入体(法国布列塔尼),以及伊比利亚黄铁矿带和南孚日山岩浆岩等其他类似岩体,可能代表了一个大型火成岩省(LIP)的侵蚀和/或变形遗迹,我们在此将其命名为北冈瓦纳-阿瓦鲁尼亚(NGA)LIP。我们认为,这个新发现的大火成岩带是由一个地幔羽流形成的,该羽流可能在前巨型大陆冈瓦纳西北边缘的断裂和潘加大陆的形成过程中发挥了作用。该地幔柱可能位于阿瓦鲁尼亚厚岩石圈的中心。来自羽流头部的大尺度岩石圈下羽流通道,导致在西梅塞塔变薄的岩石圈(这里被解释为一个大的薄点域)中形成了广泛的沸石/碱性岩浆活动,并在东梅塞塔变厚的岩石圈中形成了钙碱性/碱性岩浆活动。地幔羽流可能在大约 390-330 Ma(Maritimes 事件)、大约 370-338 Ma(Iberia 事件)、大约 347-330 Ma(Meseta 事件)以及大约 300 Ma、290-275 Ma 和 250 Ma 的欧洲西北非岩浆省(EUNWA 或 EUNWAMP)时期最为活跃,这些时期是这些地区产生大部分瓦利斯坎岩浆岩的时期。
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引用次数: 0
Mechanics of methane bubbles in consolidated aquatic muds 固结水生淤泥中甲烷气泡的力学原理
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-23 DOI: 10.1016/j.earscirev.2024.104908

Methane (CH4) is a potent greenhouse gas that has a major impact on Earth's climate. CH4 is accommodated in discrete bubbles in aquatic muds, whose sizes greatly exceed the pore size of the hosting sediment. This critical review examines the mechanics of CH4 gas in consolidated aquatic muds at the scale of a single bubble and at a macroscale of gassy sediments, obtained from lab experiments, field observations, and numerical and analytical modeling. Linear elastic fracture mechanics (LEFM) theory is shown to control the single bubble shape, size, morphology, and inner pressure evolution over its entire life cycle. Reviewed implications focus on the effects of the inner bubble pressure on its solute exchange with ambient pore waters; on the dynamic water load effect (e.g., waves, tides) on the bubble growth rate and its release from sediment into the water column; and on competitive bubble pair growth in the aquatic muds, the process that presumably shapes the bubble size distribution pattern in muds. Alternatively, gassy sediment effective mechanical and physical characteristics and effective gassy media theories are examined at the macroscale, which makes them suitable for remote sensing acoustic applications. This review indicates, however, that most of the developed macroscale effective medium theories rely on the cumulative sediment gas content. Moreover, no theory for proper upscaling of the entire set of the microscale single bubble descriptors addressed in this review – bubble size distribution, their orientations and spatial locations, and inner bubble pressures – to the effective medium mechanical properties of gassy muds, exists. This review will serve, therefore, as a basis for the improved upscaling, while preserving the basic microscale bubble descriptors, their growth physics, and controls. Laying this foundation will enhance the accuracy of the acoustic applications. Improved assessment of sediment gas retention based on this upscaling will contribute to geohazard prediction and should reduce a long-persisting uncertainty related to CH4 fluxes from the aquatic sediments.

甲烷(CH4)是一种对地球气候有重大影响的强效温室气体。CH4 存在于水生淤泥中的离散气泡中,其大小大大超过了所在沉积物的孔径。本评论通过实验室实验、实地观测以及数值和分析建模,从单个气泡尺度和含气沉积物的宏观尺度研究了CH4气体在固结水生泥浆中的力学作用。研究表明,线性弹性断裂力学(LEFM)理论可以控制单个气泡的形状、大小、形态和整个生命周期的内压演变。研究的意义主要集中在气泡内压对其与周围孔隙水进行溶质交换的影响;动态水负荷(如海浪、潮汐)对气泡生长速度及其从沉积物中释放到水体的影响;以及水生淤泥中气泡成对竞争生长的影响,这一过程可能塑造了淤泥中气泡的大小分布模式。此外,还在宏观尺度上研究了含气沉积物的有效机械和物理特性以及有效含气介质理论,这使它们适合于遥感声学应用。然而,本综述表明,大多数已开发的宏观有效介质理论都依赖于累积沉积物气体含量。此外,本综述中涉及的一整套微观单一气泡描述指标--气泡大小分布、其方向和空间位置以及内部气泡压力--都没有理论可以适当地提升到含气泥浆的有效介质机械特性。因此,本综述将作为改进升级的基础,同时保留基本的微尺度气泡描述符、其生长物理和控制。奠定这一基础将提高声学应用的准确性。在此基础上改进的沉积物气体滞留评估将有助于地质灾害预测,并应减少与水生沉积物 CH4 通量有关的长期存在的不确定性。
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引用次数: 0
Reply to Discussion: “Haiyang Zhang and Muhammad Arif. Residual trapping capacity of subsurface systems for geological storage of CO2: Measurement techniques, meta-analysis of influencing factors, and future outlook. Earth-Science Reviews (2024): 104764.” 对讨论的答复:"张海洋和 Muhammad Arif.用于二氧化碳地质封存的地下系统的剩余捕集能力:测量技术、影响因素元分析及未来展望。地球科学评论》(2024 年):104764."
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-22 DOI: 10.1016/j.earscirev.2024.104907

Geological storage of CO2 is a promising technique to mitigate anthropogenic CO2 emissions. The effectiveness of CO2 storage in the subsurface formations relies on various trapping mechanisms that immobilize the injected CO2. Among these mechanisms, residual trapping has been identified as a critical factor, closely associated with residual CO2 saturation. The extent of residual CO2 saturation is strongly influenced by the petrophysical physicochemical and hydrodynamic properties of CO2/fluid/rock systems and operational conditions, thereby governing the overall residual trapping efficiency.

This article reviews the published experimental datasets on the initial and residual CO2 saturation and analyzes the corresponding trapping efficiency for a range of in-situ CO2/fluid/rock systems. We explore the factors that influence trapping efficiency, including wettability, rock type, rock properties, and flow rate. The gas saturations and trapping efficiencies of different gas types (i.e., CO2, N2, and H2) are also discussed. Finally, we present the knowledge gaps and outline prospects for future research. This review establishes a state-of-art data repository of gas saturations in different conditions, enhancing our understanding of residual trapping in subsurface gas storage.

二氧化碳的地质封存是减少人为二氧化碳排放的一项前景广阔的技术。在地下地层中封存二氧化碳的有效性取决于各种固定注入的二氧化碳的捕集机制。在这些机制中,残余捕集被认为是一个关键因素,与残余二氧化碳饱和度密切相关。残余 CO2 饱和度受 CO2/流体/岩石系统的岩石物理化学和流体力学性质以及作业条件的影响很大,从而制约着整体残余捕集效率。本文回顾了已发表的关于初始和残余 CO2 饱和度的实验数据集,并分析了一系列原位 CO2/流体/岩石系统的相应捕集效率。我们探讨了影响捕集效率的因素,包括润湿性、岩石类型、岩石性质和流速。我们还讨论了不同气体类型(即 CO2、N2 和 H2)的气体饱和度和捕集效率。最后,我们提出了知识差距,并概述了未来研究的前景。本综述建立了不同条件下气体饱和度的最新数据资源库,加深了我们对地下储气库残余气体捕集的理解。
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引用次数: 0
Quantifying the pattern of organic carbon burial through Cretaceous Oceanic Anoxic Event 2 量化白垩纪大洋缺氧事件 2 的有机碳埋藏模式
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-22 DOI: 10.1016/j.earscirev.2024.104903

The Cenomanian-Turonian Oceanic Anoxic Event 2 (OAE 2, ca. 94 Ma) is characterized by a marked positive carbon isotope excursion (CIE) recorded in global marine basins. This CIE results from a global-scale increase in organic matter burial, facilitated by high productivity and seawater deoxygenation. To date, however, the precise pattern of changes in the burial rate of organic matter through the event has not been well constrained. In this work, we present a compilation of data from 42 globally distributed OAE 2 sites, as well as organic carbon isotope (δ13Corg), total organic carbon (TOC), and trace element concentration data from a new OAE 2 interval in southern Tibet, China. In southern Tibet, the absence of redox-sensitive trace element enrichment through OAE 2 indicates prevailing oxic conditions. Organic carbon (OC) mass accumulation rate (MAR) at this site decreased from the lower part of the CIE to the upper part, in contrast to an approximate doubling of organic carbon MAR in the upper part observed globally. This result, coupled with detailed analysis of the compilation, shows that redox was a key factor controlling organic burial rates during OAE 2, with OC MAR scaling positively with increasing deoxygenation. Leveraging a biogeochemical model to simulate these data suggets that 5–20% of the seafloor became anoxic during OAE 2, and that this deoxygenation was accompanied by 100% to 200% increase in global seawater P concentration. Our findings indicate that during OAE 2, elevated nutrient levels may have resulted from enhanced recycling from sediments under reducing conditions, sustaining intensified primary production and subsequent organic carbon export and burial.

震旦纪-土伦纪大洋缺氧事件 2(OAE 2,约 94 Ma)的特点是在全球海洋盆地记录到明显的碳同位素正偏移(CIE)。这种碳同位素偏移是由于高生产力和海水脱氧导致全球范围内有机物埋藏量增加的结果。然而,迄今为止,有机物埋藏率在这一事件中的确切变化模式还没有得到很好的解释。在这项工作中,我们汇集了全球分布的 42 个 OAE 2 地点的数据,以及中国西藏南部一个新的 OAE 2 区间的有机碳同位素(δ13Corg)、总有机碳(TOC)和微量元素浓度数据。在西藏南部,OAE 2没有出现对氧化还原反应敏感的微量元素富集现象,这表明当时处于缺氧状态。该地点的有机碳(OC)质量累积率(MAR)从CIE下部向上部下降,与全球观测到的上部有机碳质量累积率约翻一番的情况形成鲜明对比。这一结果以及对汇编的详细分析表明,氧化还原是控制 OAE 2 期间有机碳埋藏率的一个关键因素,有机碳埋藏率随脱氧程度的增加而呈正比例增长。利用生物地球化学模型模拟这些数据表明,在 OAE 2 期间,5%-20% 的海底变得缺氧,这种脱氧伴随着全球海水 P 浓度 100%-200%的增加。我们的研究结果表明,在 OAE 2 期间,养分水平的升高可能是由于在还原条件下沉积物的循环增强,从而维持了强化的初级生产以及随后的有机碳输出和埋藏。
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引用次数: 0
The uplift of the East Africa - Arabia swell 东非-阿拉伯涌浪的抬升
IF 10.8 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-18 DOI: 10.1016/j.earscirev.2024.104901

The East Africa - Arabia topographic swell is an anomalously high-elevation region of ∼4000 km long (from southern Ethiopia to Jordan) and ∼ 1500 km wide (from Egypt to Saudi Arabia) extent. The swell is dissected by the Main Ethiopian, Red Sea, and Gulf of Aden rifts, and characterized by widespread basaltic volcanic deposits emplaced from the Eocene to the present. Geochemical and geophysical data confirm the involvement of mantle processes in swell formation; however, they have not been able to fully resolve some issues, e.g., regarding the number and location of plumes and uplift patterns. This study addresses these questions and provides a general evolutionary model of the region by focusing on the present topographic configuration through a quantitative analysis and correlating long and intermediate wavelength features with mantle and rifting processes. Moreover, the isostatic and dynamic components of topography have been evaluated considering a range of seismic tomographic models for the latter. When interpreted jointly with geological data including volcanic deposits, the constraints do imply causation by a single process which shaped the past and present topography of the study area: the upwelling of the Afar superplume. Once hot mantle material reached the base of the lithosphere below the Horn of Africa during the Late Eocene, the plume flowed laterally toward the Levant area guided by pre-existing discontinuities in the Early Miocene. Plume material reached the Anatolian Plateau in the Late Miocene after slab break-off and the consequent formation of a slab window. During plume material advance, buoyancy forces led to the formation of the topographic swell and tilting of the Arabia Peninsula. The persistence of mantle support beneath the study area for tens of million years also affected the formation and evolution of the Nile and Euphrates-Tigris fluvial networks. Subsequently, surface processes, tectonics, and volcanism partly modified the initial topography and shaped the present-day landscape.

东非--阿拉伯地形隆起是一个异常高海拔地区,长约 4000 公里(从埃塞俄比亚南部到约旦),宽约 1500 公里(从埃及到沙特阿拉伯)。该膨胀区被埃塞俄比亚主断裂带、红海断裂带和亚丁湾断裂带所分割,从始新世至今,该膨胀区广泛分布着玄武质火山沉积物。地球化学和地球物理数据证实了地幔过程参与了膨胀的形成;然而,这些数据并不能完全解决一些问题,例如羽流的数量和位置以及隆起模式。本研究针对这些问题,通过定量分析,重点研究了该地区目前的地形构造,并将长波长和中波长特征与地幔和断裂过程联系起来,从而为该地区提供了一个总体演化模型。此外,考虑到后者的一系列地震层析成像模型,还对地形的等静力和动力成分进行了评估。在与包括火山沉积物在内的地质数据共同解释时,这些制约因素确实暗示了一个单一过程的成因,该过程塑造了研究区域过去和现在的地形:阿法尔超大火山口的上涌。在晚始新世,炽热的地幔物质到达非洲之角以下岩石圈的底部后,在早中新世预先存在的断裂带的引导下,羽流向黎凡特地区横向流动。在板块断裂并随之形成板块窗口之后,羽流物质于晚中新世到达安纳托利亚高原。在羽流物质前进的过程中,浮力导致了地形膨胀和阿拉伯半岛的倾斜。在研究区域下方持续数千万年的地幔支撑也影响了尼罗河和幼发拉底河-底格里斯河河流网络的形成和演变。随后,地表过程、构造和火山活动部分改变了最初的地形,形成了今天的地貌。
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引用次数: 0
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Earth-Science Reviews
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