Advanced Materials最新文献

The increasing demand for energy supply in sensing units and the computational efficiency of computation units has prompted researchers to explore novel, integrated technology that offers high efficiency and low energy consumption. Self-powered sensing technology enables environmental perception without external energy sources, while neuromorphic computation provides energy-efficient and high-performance computing capabilities. The integration of self-powered sensing technology and neuromorphic computation presents a promising solution for an all-in-one system. This review examines recent developments and advancements in self-powered artificial neuron devices based on triboelectric, piezoelectric, and photoelectric effects, focusing on their structures, mechanisms, and functions. Furthermore, it compares the electrical characteristics of various types of self-powered artificial neuron devices and discusses effective methods for enhancing their performance. Additionally, this review provides a comprehensive summary of self-powered perception systems, encompassing tactile, visual, and auditory perception systems. Moreover, it elucidates recently integrated systems that combine perception, computing, and actuation units into all-in-one configurations, aspiring to realize closed-loop control. The seamless integration of self-powered sensing and neuromorphic computation holds significant potential for shaping a more intelligent future for humanity.

The advancement of photo-assisted rechargeable sodium-metal batteries with high energy efficiency, lightweight structure, and simplified design is crucial for the growing demand in portable electronics. However, addressing the intrinsic safety concerns of liquid electrolytes and the sluggish reaction kinetics in existing photoelectrochemical storage cathodes (PSCs) remains a significant challenge. In this work, functionalized light-driven composite solid electrolyte (CSE) fillers are systematically screened, and optimized PSC materials are employed to construct advanced photo-assisted solid-state sodium-metal battery (PSSMB). To further enhance the mechanical properties and poly(ethylene oxide) compatibility of the CSE, natural lignocellulose is incorporated, enabling the fabrication of flexible PSSMBs. In situ tests and density functional theory calculations reveal that the light-driven electric field facilitated sodium salt dissociation, reduced interfacial resistance, and improved ionic conductivity (0.1 mS cm^-1). Meanwhile, energy-level matching of the PSC maximized the utilization of photogenerated carriers, accelerating reaction kinetics and enhancing interface compatibility between the electrolyte and cathode. The resulting flexible pouch-type PSSMB demonstrates a remarkable discharge capacity of 117 mAh g^-1 and outstanding long-term cycling stability, retaining 89.1% of its capacity and achieving an energy storage efficiency of 96.8% after 300 cycles at 1 C. This study highlights a versatile strategy for advancing safe, high-performance solid-state batteries.

Inspired by nature's ability to master materials for performance and sustainability, biomimicry has enabled the creation of bioinspired materials for structural color, superadhesion, hydrophobicity and hydrophilicity, among many others. This review summarizes the emerging trends in novel sustainable fluorocarbon-free bioinspired designs for creating superhydrophobic and superoleophobic surfaces. It discusses methods, challenges, and future directions, alongside the impact of computational modeling and artificial intelligence in accelerating the experimental development of more sustainable surface materials. While significant progress is made in superhydrophobic materials, sustainable superoleophobic surfaces remain a challenge. However, bioinspiration and experimental techniques supported by computational platforms are paving the way to new renewable and biodegradable repellent surfaces that meet environmental standards without sacrificing performance. Nevertheless, despite environmental concerns, and policies, several bioinspired designs still continue to apply fluorination and other environmentally harmful techniques to achieve the required standard of repellency. As discussed in this critical review, a new paradigm that integrates advanced materials characterization, nanotechnology, additive manufacturing, computational modeling, and artificial intelligence is coming, to generate bioinspired materials with tailored superhydrophobicity and superoleophobicity while adhering to environmental standards.

Harnessing cross-species regenerative cues to direct human regenerative potential is increasingly recognized as an excellent strategy in regenerative medicine, particularly for addressing the challenges of impaired wound healing in aging populations. The skin mucus of Andrias davidianus plays a critical role in self-protection and tissue repair, yet the fundamental regenerative factors and mechanisms involved remain elusive. Here, this work presents evidence that glycosaminoglycans (GAGs) derived from the skin secretion of Andrias davidianus (SAGs) serve as potent mediators of angiogenesis and inflammatory remodeling, facilitating efficient healing of diabetic wounds. Mechanistic studies reveal that SAGs promote macrophage polarization toward an anti-inflammatory and pro-regenerative phenotype (CD206⁺/Arg1⁺) via glucolipid metabolic reprogramming. This process suppresses excessive inflammation and enhances the expression of VEGF and IL-10 to create a facilitative microenvironment for tissue regeneration. Additionally, this work develops SAGs-GelMA composite microspheres that address multiple stages of wound healing, including rapid hemostasis, exudate control, and activation of endogenous regenerative processes. This engineered approach significantly improves the scarless healing of diabetic wounds by facilitating the recruitment and activation of reparative macrophages. The findings offer new insights into the regenerative mechanisms of Andrias davidianus and highlight the potential therapeutic application of SAGs in tissue repair.

The dry battery electrode (DBE) process offers significant advantages over conventional wet-coating methods for electrode fabrication. Unlike traditional processes that rely on toxic solvents such as N-methyl-2-pyrrolidone (NMP), the DBE technique uses solvent-free methods, reducing environmental impact and production costs while enhancing compatibility and performance. However, polytetrafluoroethylene (PTFE), the only binder currently used for large-scale DBE fabrication (binder fibrillation), faces potential regulatory restrictions under Polyfluoroalkyl Substances (PFAS) guidelines and limits Li-ion conductivity, elastomeric properties, and particle adhesion. This study explores a novel dual-binder system, termed the "bollard hitch" model, designed to overcome these limitations as the first PTFE-less binder for binder fibrillation. Poly(acrylic acid)-grafted sodium carboxymethyl cellulose (PC) acts as the "bollard," strongly attaching to the PTFE "anchor." This binder system reduces PTFE usage by over 70% and enables the fabrication of high-mass loading cathodes (up to 90 mg cm^{- 2}, 15.6 mAh cm^{- 2}) with superior performance. It enhances ionic conductivity and mechanical strength, making it suitable for high-voltage applications and offering great potential to revolutionize the manufacturing of high-performance, durable energy storage systems.