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Numerical study on dispersed fuel injection strategies for thermal performance enhancement in a self-flue-recirculating radiant tube 自烟道再循环辐射管提高热性能分散喷油策略的数值研究
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-06 DOI: 10.1016/j.energy.2026.140356
Huanbao Fan , Mengxiang Jiang , Lu Dang , Junxiao Feng
This study proposes and evaluates a dual-stage dispersed fuel injection strategy for a novel U-type radiant tube with internal/external flue gas self-recirculation. A comparative analysis was conducted on the flow structure, flame position, heat transfer characteristics, and overall performance of single-stage and dual-stage dispersed fuel injection modes utilizing a validated three-dimensional CFD combustion model. The influence mechanism of the secondary dispersed fuel fraction (χsec-disp, 5%–30%) on tube wall temperature uniformity and NOx emissions was specifically investigated. Results demonstrate that dual-stage dispersed combustion effectively compensates for the axial heat loss along the flow path, significantly elevating the temperature and expanding the high-temperature zone in the second straight tube, despite causing a slight increase in NOx. Increasing the χsec-disp from 5% to 30%, markedly enhanced tube wall temperature uniformity (maximum temperature difference reduced by 21.6%) and suppressed NOx generation and emission (outlet concentration as low as 49.6 mg/m3 @ 8% O2). These improvements stem primarily from the increased proportion of dispersed fuel, which promotes global fuel dispersion, mitigates localized flame concentration, and fosters more uniform combustion within the tube. Therefore, a moderate increase in χsec-disp proves effective in enhancing heating uniformity and reducing NOx emissions, offering pivotal guidance for the design optimization of next-generation radiant tubes.
本研究提出并评估了一种新型内/外烟气自循环u型辐射管的双级分散喷油策略。利用经过验证的三维CFD燃烧模型,对单级和双级分散燃油喷射方式的流动结构、火焰位置、传热特性和整体性能进行了对比分析。重点研究了二次分散燃料馏分(χsec-disp, 5% ~ 30%)对管壁温度均匀性和NOx排放的影响机理。结果表明,两级分散燃烧有效地补偿了沿流道轴向热损失,显著提高了第二直管内的温度,扩大了高温区域,但导致NOx含量略有增加。将χsec-disp值从5%提高到30%,显著提高了管壁温度均匀性(最大温差降低了21.6%),抑制了NOx的生成和排放(出口浓度低至49.6 mg/m3 @ 8% O2)。这些改进主要源于分散燃料比例的增加,这促进了燃料的全球分散,减轻了局部火焰浓度,并促进了管内更均匀的燃烧。因此,适当增加χsec-disp可以有效提高加热均匀性,减少NOx排放,为下一代辐射管的设计优化提供关键指导。
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引用次数: 0
Multi-objective evolutionary algorithm with two-tier fully-connected weight network for day-ahead scheduling of integrated cooling, heating and power energy systems 基于二层全连接权网络的冷、热、电一体化系统日前调度多目标进化算法
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-06 DOI: 10.1016/j.energy.2026.140147
Nanjiang Dong , Tao Zhang , Rui Wang
The day-ahead scheduling of an integrated energy system, which combines cooling, heating, and power generation alongside wind and photovoltaic energy sources, presents several challenges. These challenges stem from the presence of semi-continuous variables, multiple optimization objectives, nonlinearities, and various constraints. Existing multi-objective evolutionary algorithms, however, are not sufficiently efficient in solving the day-ahead scheduling model, particularly when dealing with semi-continuous variables. To address these issues, this paper proposed a novel multi-objective evolutionary algorithm based on a two-tier fully connected weight network. The model leverages a fully connected network to effectively address the semi-continuous variable problem, offering a unique solution to the complexities of day-ahead operation scheduling. The upper layer of the network employs multi-space dimensionality reduction to enhance global search capabilities, while the lower layer focuses on local search for more targeted solutions. Furthermore, the design of constraint repair operators is influenced by the structure of the algorithm, aiming to satisfy the constraints inherent in day-ahead scheduling and improve the efficiency of the search process. In experimental simulations, the proposed algorithm’s performance was compared with that of the latest constrained multi-objective optimization algorithms. The results demonstrate that the proposed algorithm significantly improves both optimization efficiency and the quality of the scheduling solutions. These findings highlight the effectiveness and superiority of the proposed algorithm in optimizing day-ahead scheduling for integrated energy systems.
综合能源系统结合了制冷、供暖、发电以及风能和光伏能源,其日前调度面临着一些挑战。这些挑战源于半连续变量、多个优化目标、非线性和各种约束的存在。然而,现有的多目标进化算法在求解日前调度模型时效率不高,特别是在处理半连续变量时。针对这些问题,本文提出了一种基于二层全连接权网络的多目标进化算法。该模型利用全连接网络有效地解决了半连续变量问题,为复杂的日前作业调度提供了独特的解决方案。网络的上层采用多空间降维来增强全局搜索能力,而下层则侧重于局部搜索,以获得更有针对性的解决方案。此外,约束修复算子的设计受算法结构的影响,旨在满足日前调度固有的约束条件,提高搜索过程的效率。在实验仿真中,将该算法的性能与最新的约束多目标优化算法进行了比较。结果表明,该算法显著提高了优化效率和调度解的质量。这些结果突出了该算法在综合能源系统日前调度优化中的有效性和优越性。
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引用次数: 0
Experiment on composition-adjustable combined cooling and power cycle with CO2-based zeotropic mixture: An off-design performance investigation co2基共沸混合气组合可调联合冷却和动力循环试验:非设计性能研究
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-06 DOI: 10.1016/j.energy.2026.140352
Xiaocun Sun , Lingfeng Shi , Wei Lu , Hua Tian , Gequn Shu
CO2 is a promising natural working fluid for the combined cooling and power cycle (CCP) due to its great physical properties. Composition adjustment based on CO2-based zeotropic mixtures can further enhance the performance of CCP in changing external conditions (off-design performance). However, the enhancing effect of composition adjustment on CCP has only been proven effective in theoretical studies. Systematic experimental tests are lacking, and the operating feasibility of composition adjustment remains unrevealed. In this study, the off-design performance of composition-adjustable CCP is investigated. The performance comparison between composition-adjustable CCP and composition-fixed CCP is developed, and the dynamic characteristics of composition-adjustable CCP in off-design conditions are obtained. Experimental results show that composition adjustment can enhance the off-design performance of CCP, and the maximum relative increase can reach 13.7%. During the off-design conditions, the elapsed time of composition balance is significantly smaller than thermal balance, and the consuming time of composition adjustment can be ignored as long as the liquid level in separator is maintained steady. To accelerate the balancing speed of system, a fast regulation strategy based on flow reverse adjustment is proposed, and the elapsed time can be shortened by around half on the premise of maintaining the stabilization of system performance.
由于其良好的物理性质,CO2是一种很有前途的用于冷却和动力联合循环(CCP)的天然工质。基于co2基共沸混合物的成分调整可以进一步提高CCP在变化的外部条件下的性能(非设计性能)。然而,成分调整对CCP的增强作用仅在理论研究中被证明是有效的。缺乏系统的实验测试,成分调整的操作可行性尚未揭示。本文研究了可调成分CCP的非设计性能。对组合可调CCP与组合固定CCP的性能进行了比较,得到了组合可调CCP在非设计工况下的动态特性。实验结果表明,成分调整可以提高CCP的非设计性能,最大相对提高可达13.7%。在非设计工况下,组分平衡运行时间明显小于热平衡,只要保持分离器液位稳定,组分调整耗费的时间可以忽略不计。为了加快系统的平衡速度,提出了一种基于流量反向调节的快速调节策略,在保持系统性能稳定的前提下,可将运行时间缩短一半左右。
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引用次数: 0
Numerical investigation of combustion system design for knock mitigation and thermal efficiency enhancement in a carbon-neutral methanol engine 碳中性甲醇发动机减震增效燃烧系统设计数值研究
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.energy.2026.140333
Zhi Zhang , Chao Jin , Guofeng Yang , Haifeng Liu , Weide Chang , Zanqiao Shu , Zhiqin Jia , Hui Wang , Tiejian Lin , Hua Zhao , Mingfa Yao
Methanol, a promising carbon-neutral fuel, enables engines operating stoichiometrically with a three-way catalytic converter (TWCC) to achieve high power output while maintaining low emissions. However, engine performance under high-load conditions is limited by knock and maximum in-cylinder pressure (Pmax). Combustion system plays a crucial role, yet research in this field remains scarce. This study performs a numerical investigation of a port-fuel-injection (PFI) heavy-duty spark-ignition (SI) methanol engine, with the objective of guiding combustion system design through enhanced in-cylinder flow, knock mitigation, and thermal efficiency improvement. The results indicate that designing chamber geometry for tumble ratio (TR) enhances turbulent kinetic energy (TKE) more effectively than adjusting swirl or squish flows. The tumble-optimized cylindrical chamber improves indicated thermal efficiency (ITE) by 0.5% over the original chamber. The diameter-depth ratio critically influences flow patterns—larger ratios increase TR during compression but reduce swirl ratio (SR). The high-TR (D86) and high-SR (D70) chambers, featuring large and small diameter-depth ratios respectively, significantly enhance combustion performance, while the medium diameter-depth ratio design (D78) exhibits intermediate performance. Compared to the D78 chamber, the D70 and D86 chambers achieve 0.3% and 0.5% higher ITE, representing improvements of 0.8% and 1.0% over the original chamber, respectively. Furthermore, the diameter-depth ratio significantly affects engine knock characteristics. The knock intensity (KI) initially decreases and then increases with increasing diameter-depth ratio. The D78 chamber exhibits the lowest knock tendency, indicating an optimal diameter-depth ratio near 2.5. This design achieves the highest ITE under both Pmax and knock-limited conditions, reaching 46.92% and 47.21%, respectively.
甲醇是一种很有前途的碳中性燃料,它可以使发动机通过三元催化转化器(TWCC)进行化学计量操作,在保持低排放的同时实现高功率输出。然而,发动机在高负荷条件下的性能受到爆震和最大缸内压力(Pmax)的限制。燃烧系统起着至关重要的作用,但在这方面的研究仍然很少。本研究对一种燃气喷射(PFI)重型火花点火(SI)甲醇发动机进行了数值研究,目的是通过增强缸内流动、减少爆震和提高热效率来指导燃烧系统的设计。结果表明,与调整旋流或压流相比,设计适合转捩比的腔室结构能更有效地提高湍流动能。经过翻滚优化的圆柱形燃烧室比原始燃烧室的指示热效率(ITE)提高0.5%。径深比对流动型有重要影响,较大的径深比增加压缩时的TR,但降低旋流比(SR)。高tr (D86)和高sr (D70)燃烧室分别采用大径深比和小径深比设计,显著提高了燃烧性能,而中径深比设计(D78)表现出中等性能。与D78试验箱相比,D70和D86试验箱的ITE分别提高了0.3%和0.5%,分别比原试验箱提高了0.8%和1.0%。此外,径深比对发动机爆震特性有显著影响。随着径深比的增大,爆震强度先减小后增大。D78型燃烧室爆震趋势最小,表明其最佳径深比在2.5附近。该设计在Pmax和敲限条件下的ITE均达到最高,分别达到46.92%和47.21%。
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引用次数: 0
Manipulating bubble departure by varying helix structure heights to enhance pool boiling heat transfer 通过改变螺旋结构的高度来控制气泡的偏离,以增强池沸腾传热
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.energy.2026.140322
Ching-Wen Lo , Po-Yao Syu , Chen-Kuang Wang , Ya-Yu Chiang
This study investigates the influence of helix structure arrays on saturated pool boiling performance through a systematic parametric evaluation of helix height and density. A total of seven copper-based surfaces, including one flat baseline and six helix-structured configurations, were tested in distilled water under atmospheric pressure. The results demonstrate that appropriately designed helix structures can simultaneously enhance the critical heat flux (CHF) and the heat transfer coefficient (HTC) by up to 78% and 164%, respectively. These enhancements are attributed to the combined effects of shortened bubble residence time, increased bubble departure height, and intensified local convective flow fields. High-speed imaging revealed that taller helix arrays facilitate vapor column detachment and reduce vapor accumulation above the heated surface, while particle image velocimetry (PIV) confirmed the presence of accelerated upward fluid motion induced by vapor ejection and capillary-driven liquid return. These findings underscore the critical role of helix geometry in manipulating interfacial bubble dynamics and promoting liquid–vapor separation, offering promising insights for the thermal design of advanced boiling surfaces.
本文通过对螺旋高度和密度的系统参数评价,探讨了螺旋结构阵列对饱和池沸腾性能的影响。共有七个铜基表面,包括一个平坦的基线和六个螺旋结构的配置,在常压蒸馏水中进行了测试。结果表明,合理设计螺旋结构可同时提高临界热流密度(CHF)和换热系数(HTC),分别可提高78%和164%。这些增强是由于气泡停留时间缩短、气泡离开高度增加和局部对流流场增强的综合作用。高速成像显示,较高的螺旋阵列有助于蒸汽柱脱离,减少受热表面上方的蒸汽积聚,而粒子图像测速(PIV)证实了蒸汽喷射和毛细管驱动的液体回流导致的加速向上流体运动的存在。这些发现强调了螺旋几何结构在操纵界面气泡动力学和促进液汽分离方面的关键作用,为高级沸腾表面的热设计提供了有希望的见解。
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引用次数: 0
Study on the hydrodynamic characteristics of a six-nozzle ultra-large capacity Pelton turbine during the switching of the operating nozzles 六喷嘴超大容量水轮机工作喷嘴切换时的水动力特性研究
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.energy.2026.140328
Xiao-Dong Wang , Xuan Wang , Shao-Dang Hu, Wen-Quan Wang, Yan Yan
The evolving demands of modern power systems impose stricter requirements on the load-following capabilities of hydropower units. Pelton turbines, in response to load adjustments, typically switch the operating nozzles to maintain high hydraulic efficiency. However, the hydrodynamic characteristics during this transitional process remain poorly understood. To address this gap, this study employs a coupled one-dimensional method of characteristics (MOC) and three-dimensional computational fluid dynamics (CFD) method to investigate the transient process during switching of the operating nozzles of Pelton turbine. Specifically, this study investigates the influence of nozzle opening control schemes on flow field, pressure distribution, and external characteristics. The results reveal that, at small nozzle openings, pressure fluctuations in the water supply system become more intense, with a maximum peak-to-peak Cp of 0.065. These fluctuations further induce fluctuations in the torque and radial force of runner, their maximum values are 3.8 and 2.7 times those under steady operating conditions, respectively. Moreover, the dominant frequency of pressure fluctuations on the bucket is 6fn under six-nozzle and four-nozzle operating, whereas with four nozzles, the characteristic frequencies is also including 2fn, and 4fn. Notably, when nozzles are actuated simultaneously in on/off operations, the resulting pressure fluctuations are significantly mitigated, and both the flow rate and torque exhibit a more linear response, which is a recommended nozzle switching mode.
现代电力系统不断发展的需求对水电机组的负荷跟随能力提出了更严格的要求。Pelton涡轮机,在响应负荷调整,通常切换操作喷嘴,以保持高的水力效率。然而,在这一过渡过程中的水动力特性仍然知之甚少。为了解决这一空白,本研究采用一维特性法(MOC)和三维计算流体动力学(CFD)方法耦合研究了水轮机工作喷嘴切换过程中的瞬态过程。具体而言,本文研究了喷嘴开度控制方案对流场、压力分布和外部特性的影响。结果表明,当喷嘴开口较小时,供水系统的压力波动更为剧烈,峰间Cp最大值为0.065;这些波动进一步引起转轮转矩和径向力的波动,其最大值分别是稳定工况下的3.8倍和2.7倍。此外,在六喷嘴和四喷嘴工况下,铲斗压力波动的主导频率为6fn,而在四喷嘴工况下,特征频率也包括2fn和4fn。值得注意的是,当喷嘴在开/关操作中同时启动时,由此产生的压力波动明显减轻,流量和扭矩都表现出更线性的响应,这是推荐的喷嘴开关模式。
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引用次数: 0
Experimental and simulation analysis of the optical, electrical, and daylighting performance of the asymmetric concentrating photovoltaic/daylighting system 非对称聚光光伏/采光系统光学、电学和采光性能的实验与仿真分析
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-05 DOI: 10.1016/j.energy.2026.140263
Qingdong Xuan , Ziyi Chen , Bin Jiang , Bin Zhao , Guiqiang Li , Gang Pei
With the rapid growth of the construction industry, energy consumption and environmental pollution have become critical challenges. Reducing building energy use and advancing renewable energy adoption are key solutions to these problems. To address this issue, a novel asymmetric lens-walled concentrating photovoltaic/daylighting control (LACPC-PV/D) system is proposed in this study, designed for south-facing building walls. The LACPC-PV/D system is mainly derived from the truncation of its core component, i.e., the asymmetric lens-walled compound parabolic concentrator (LACPC) with a truncation length of 20.2 mm, achieving a final geometric concentration ratio of 2.22 × . This system optimizes daylighting performance while maintaining high optical efficiency and electrical output. Ray-tracing simulations and indoor experiments were conducted to investigate the optical, electrical, and daylighting performance of the LACPC-PV/D system. Prototypes of the LACPC-PV/D module (with daylighting) and a reference LACPC-PV module (without daylighting) were fabricated and tested under standard conditions using a solar simulator. Results showed that the LACPC-PV/D module enhanced the short-circuit current, open-circuit voltage, and maximum power by 1.59 × , 4.7%, and 1.78 × , respectively, while the reference LACPC-PV module achieved improvements of 1.66 × , 3.8%, and 1.82 × , respectively. These findings indicate minimal impact on optical concentration performance while achieving a daylighting efficiency of 10% within incidence angles of 0–60°. Additionally, the daylighting performance of the LACPC-PV/D system was compared with conventional semi-transparent PV windows. Ray-tracing simulations demonstrated that, within incidence angles of 15°–85°, the LACPC-PV/D system delivered superior daylighting uniformity, reducing the average coefficient of variation (CV) for illuminance distribution from 4.06 to 2.02. To further evaluate economic performance, the Levelized Cost of Electricity (LCOE) and Simple Payback Period (SPB) were compared between the conventional flat PV system and the LACPC-PV/D system. The LACPC-PV/D system achieves an LCOE of 0.04342 USD/kWh and an SPB of 5.3511 years, compared to 0.04376 USD/kWh and 5.3928 years for the conventional system. Furthermore, its module cost per watt-peak (Wp) is approximately 9.33% lower, demonstrating a comprehensive economic benefit.
随着建筑业的快速发展,能源消耗和环境污染已成为严峻的挑战。减少建筑能源使用和推进可再生能源的采用是解决这些问题的关键。为了解决这个问题,本研究提出了一种新的非对称透镜壁聚光光伏/采光控制系统(LACPC-PV/D),设计用于朝南的建筑墙壁。LACPC- pv /D系统主要来源于其核心组件的截断,即截断长度为20.2 mm的非对称透镜壁复合抛物聚光器(LACPC),最终的几何浓缩比为2.22 ×。该系统优化了采光性能,同时保持了高光效和电输出。通过光线追踪模拟和室内实验研究了LACPC-PV/D系统的光学、电学和采光性能。制作了LACPC-PV/D模块(带采光)和参考LACPC-PV模块(不带采光)的原型,并使用太阳能模拟器在标准条件下进行了测试。结果表明,LACPC-PV/D模块的短路电流、开路电压和最大功率分别提高了1.59倍、4.7%和1.78倍,而参考LACPC-PV模块的短路电流、开路电压和最大功率分别提高了1.66倍、3.8%和1.82倍。这些发现表明,在0-60°入射角范围内实现10%的采光效率时,对光学集中性能的影响最小。此外,还将LACPC-PV/D系统的采光性能与传统的半透明PV窗进行了比较。光线追踪模拟表明,在15°-85°入射角范围内,LACPC-PV/D系统具有优异的采光均匀性,将照度分布的平均变异系数(CV)从4.06降低到2.02。为了进一步评估经济性能,比较了传统平板光伏系统和LACPC-PV/D系统的平准化电力成本(LCOE)和简单投资回收期(SPB)。传统系统的LCOE为0.04376美元/千瓦时,SPB为5.3928年,而LACPC-PV/D系统的LCOE为0.04342美元/千瓦时,SPB为5.3511年。每瓦峰组件成本(Wp)降低约9.33%,具有较好的综合经济效益。
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引用次数: 0
Study of power recovery mechanism and system-level thermodynamic optimization of a novel compression high-temperature heat pump 新型压缩高温热泵功率回收机理及系统级热力优化研究
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-04 DOI: 10.1016/j.energy.2026.140216
Zhengyong Li , Youcai Liang , Yan Zhu , Shunchun Yao
High-temperature heat pump technology is promising in the process of electrifying industrial heating. The high temperature characteristics cause limitations of refrigerant, component material, and cycle performance. To this end, this study employs a novel flash tank vapor injection enhanced cycle (NFVI-EEC) to explore the power recovery mechanism of the cycle. It features active dryness regulation, staged expansion, and dual-stage subcooling. In this paper, thermodynamic and economic models of NFVI-EEC are constructed, and the conversion principle and optimization direction of the throttling loss and the heat transfer loss are analyzed in detail. Innovatively, ejector efficiency and vapor injection efficiency, both centered on expansion work recovery capability, are proposed. Under typical operating conditions, using R1224yd(Z)/R1233zd(E) as refrigerant,the vapor injection efficiency of NFVI-EEC is improved by 14.96%-20.73% compared with FVIC; and the ejector efficiency is reduced by 9.99%-18.50% compared with BEEC. R1224yd(Z)/R1233zd(E) achieves the highest COP (3.51) among all refrigerant mixtures evaluated. Therefore, to further enhance the system performance of NFVI-EEC, the ejector efficiency can be used as an optimization target for further improvement. The theoretical framework for expansion process analysis constructed in this study will help guide the optimization of the expansion process in high-temperature heat pumps in the future.
高温热泵技术在工业供热电气化过程中具有广阔的应用前景。高温特性导致制冷剂、部件材料和循环性能的限制。为此,本研究采用一种新型闪蒸罐注汽强化循环(NFVI-EEC),探索该循环的功率回收机制。它具有主动干燥调节,分级膨胀和双级过冷。本文建立了NFVI-EEC的热力学和经济模型,详细分析了节流损失和换热损失的换算原理和优化方向。创新地提出了以膨胀功采收率为中心的喷射器效率和注汽效率。在典型工况下,采用R1224yd(Z)/R1233zd(E)作为制冷剂,NFVI-EEC的注汽效率比FVIC提高14.96% ~ 20.73%;与BEEC相比,喷射器效率降低9.99% ~ 18.50%。R1224yd(Z)/R1233zd(E)在所有制冷剂混合物中COP值最高,为3.51。因此,为了进一步提高NFVI-EEC的系统性能,可以将喷射器效率作为进一步提高的优化目标。本研究构建的膨胀过程分析的理论框架将有助于指导今后高温热泵膨胀过程的优化。
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引用次数: 0
Upgraded utilization of biochar after heavy metal (Ni) adsorption for CO2 capture 重金属(Ni)吸附后生物炭对CO2捕获的升级利用
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-04 DOI: 10.1016/j.energy.2026.140326
Jialiang Dong , Ruikun Wang , Shiteng Tan , Zhenghui Zhao , Qianqian Yin , Jun Cheng , Xuehai Yu , Eric J. Hu , Fuyan Gao
Biochar, with its well-developed pore structure and tunable surface chemistry, has been widely employed for heavy metal adsorption. However, the biochar after adsorption of heavy metals suffers from high risk of secondary pollution and difficulty in resource utilization. This study explores a feasible approach to converting it into an efficient CO2 adsorbent. Heavy metal ions (represented by Ni2+ in this study) are primarily captured via the mesoporous structure of biochar and can be stably anchored to the carbon skeleton after high temperature treatment. This process introduces alkali metal oxide sites on the biochar surface, which were confirmed as chemisorption centers for CO2 by in situ near-ambient pressure X-ray photoelectron spectroscopy (in situ NAP-XPS). Meanwhile, the adsorbed Ni2+ acts as in situ structural template, inducing the evolution of mesopores into narrow micropores, increasing the intermolecular forces between the pore walls and CO2. The synergistic enhancement effect of chemical and physical adsorption significantly improves the CO2 adsorption performance of biochar. The Ni-loaded biochar achieves a CO2 adsorption capacity of 4.49 mmol/g at 25 °C and 1 bar, and a CO2/N2 dynamic separation coefficient of 74.47 in multi-component breakthrough experiments. This study provides a green and sustainable approach that combines heavy metal pollution control with the development of CO2 capture materials, delivering dual energy and environmental benefits.
生物炭具有发达的孔隙结构和可调的表面化学性质,被广泛应用于重金属吸附。但吸附重金属后的生物炭存在二次污染风险高、资源化利用困难等问题。本研究探索了一种将其转化为高效CO2吸附剂的可行方法。重金属离子(在本研究中以Ni2+为代表)主要通过生物炭的介孔结构被捕获,经过高温处理后可以稳定地锚定在碳骨架上。该工艺在生物炭表面引入碱金属氧化物位点,通过原位近环境压力x射线光电子能谱(in situ NAP-XPS)证实这些位点是CO2的化学吸附中心。同时,吸附的Ni2+作为原位结构模板,诱导介孔演化为狭窄的微孔,增加了孔壁与CO2之间的分子间作用力。化学吸附和物理吸附的协同增强效应显著提高了生物炭对CO2的吸附性能。在多组分突破实验中,负载ni的生物炭在25℃、1 bar条件下的CO2吸附量为4.49 mmol/g, CO2/N2动态分离系数为74.47。本研究提供了一种绿色和可持续的方法,将重金属污染控制与二氧化碳捕获材料的开发相结合,实现了能源和环境的双重效益。
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引用次数: 0
Joint development of tidal current energy in multi-channels surrounding Xiushan Island, China 秀山岛周边多通道潮汐能联合开发
IF 9.4 1区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-04 DOI: 10.1016/j.energy.2026.140327
Zhen Huang , Peng Dai , Jisheng Zhang
Xiushan Island is situated in Zhoushan waters, which harbors abundant tidal current energy resources in China, with complex sub-channels surrounding it. This study employs a high-resolution numerical model of tidal currents in Zhoushan waters to evaluate the tidal energy potential and explore the feasibility of integrated exploration of multi-channels around Xiushan Island. Furthermore, the study investigates the competitive effects of sub-channels and assesses the resulting redistribution of flow rate and velocity. Results show that the theoretical tidal current energy potential in the vicinity of Xiushan Island is approximately 1050 MW. Joint exploration of multiple channels yields an energy increase of 10.11% to 33.92% compared to the independent development of each channel. This phenomenon is induced by the competitive effects of flow dynamics when turbines are installed in the multi - channel zone. Numerical results demonstrate that the flow rate of the parallel channels can be increased by up to 17% during the development of individual channels. This integrated approach enables a more effective and comprehensive extraction of tidal current energy resources within the study area.
秀山岛位于舟山海域,舟山海域蕴藏着中国丰富的潮汐能资源,其周边有复杂的子水道。本研究采用舟山海域高分辨率潮流数值模型,对舟山海域潮汐能潜力进行评价,探讨秀山岛周边多通道综合勘探的可行性。此外,本研究还研究了子通道的竞争效应,并评估了由此产生的流量和速度的再分配。结果表明,秀山岛附近的理论潮流位能约为1050 MW。多通道联合勘探比单通道独立开发能提高10.11% ~ 33.92%。这种现象是由于水轮机安装在多通道区域时,流动动力学的竞争效应所引起的。数值结果表明,在单个通道的发展过程中,平行通道的流速可提高17%。这种综合方法可以更有效、更全面地提取研究区内的潮流能源资源。
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