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Wheel traffic compaction intensified with orchard age while hydraulic responses were partially decoupled in the top 30 cm 随着果园树龄的增加,轮式交通压实加剧,而在果园顶部30 cm处,水力响应部分解耦
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-12 DOI: 10.1016/j.geoderma.2026.117725
Siyu Wang , Wei Hu , Heather Jenkins , Dougal Stalker , Craig Tregurtha , Rogerio Cichota , Henry Wai Chau , Jim Moir , Karin Müller , Brendon Malcolm
Soil compaction from frequent wheel traffic is a concern in orchards. The potential impacts of soil compaction, particularly over orchard age, on soil physical properties, remain unclear. This study aimed to investigate the impacts of wheel traffic on soil physical properties, both mechanical and hydraulic, at various depths (0–10, 10–20, and 20–30 cm) across different plantation ages in two commercial apple orchards located in Canterbury (3, 12, and 40 years) and Tasman (12, 17, and 28 years), New Zealand. Soil samples and field measurements were taken at three positions: tree rows, wheel tracks, and inter-track areas. Penetration resistance, a mechanical property, was measured in situ as an indicator of compaction, while hydraulic properties, including total porosity, macroporosity, available water capacity, saturated hydraulic conductivity, and relative field capacity were measured in the laboratory using intact soil cores to assess water- and aeration-related functions. Results showed that wheel traffic significantly increased soil compaction, reducing available water capacity and saturated hydraulic conductivity and impairing aeration. Notably, these declines were also observed beyond the visibly compacted wheel tracks, suggesting more widespread functional impairment across orchard soils. Older plantations generally exhibited higher penetration resistance, and significant interactions between plantation age and sampling position were observed for penetration resistance. However, older plantations did not necessarily exhibit worse hydraulic conditions (e.g., available water capacity, saturated hydraulic conductivity), and no interactions between plantation age and sampling position were detected for soil hydraulic properties. These findings suggest that while wheel traffic-induced compaction impaired soil hydraulic functions, compaction intensity and hydraulic responses became less consistent with increasing plantation age. This study highlights the importance and potential of mitigating soil compaction to improve soil physical properties and environmental sustainability through targeted management interventions. Future research should focus on understanding the broader impacts of soil compaction on soil functions (e.g., water and aeration storage and transport) and ecosystem services in orchards.
频繁的车轮交通造成的土壤压实是果园的一个问题。土壤压实对土壤物理性质的潜在影响,特别是超过果园年龄的土壤压实,仍不清楚。本研究以新西兰坎特伯雷(3年、12年和40年)和塔斯曼(12年、17年和28年)两个商业苹果园为研究对象,研究不同种植年限下不同深度(0-10厘米、10-20厘米和20-30厘米)车轮交通对土壤物理性质(机械和水力)的影响。土壤样本和实地测量在三个位置进行:树行、车轮轨迹和轨道间区域。渗透阻力是一种机械性能,作为压实度的指标,在现场进行了测量,而水力性能,包括总孔隙度、宏观孔隙度、有效水容量、饱和水力传导率和相对现场容量,在实验室使用完整的土芯进行了测量,以评估与水和通气相关的功能。结果表明,车轮通行显著增加了土壤压实,降低了有效水量和饱和导水率,并影响了透气性。值得注意的是,在明显压实的车轮痕迹之外也观察到这些下降,这表明果园土壤中更广泛的功能损害。年龄较大的人工林总体表现出较高的穿透阻力,人工林年龄与采样位置之间存在显著的交互作用。然而,较老的人工林并不一定表现出更差的水力条件(例如,可用水量、饱和水力传导率),并且没有发现人工林年龄和采样位置之间的相互作用。这些结果表明,虽然车轮交通引起的压实损害了土壤的水力功能,但随着人工林年龄的增加,压实强度和水力响应变得不一致。本研究强调了通过有针对性的管理干预措施减轻土壤压实对改善土壤物理性质和环境可持续性的重要性和潜力。未来的研究应侧重于了解土壤压实对果园土壤功能(如水分和空气的储存和运输)和生态系统服务的更广泛影响。
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引用次数: 0
Amorphous aluminum hydroxide and rice-husk biochar enhance new organic carbon stabilization via different mechanisms 无定形氢氧化铝和稻壳生物炭通过不同的机制增强了新型有机碳的稳定性
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-12 DOI: 10.1016/j.geoderma.2026.117721
Han Lyu , Arisa Nishiki , Ruohan Zhong , Ryosuke Kusumi , Mayuko Seki , Soh Sugihara , Randy A. Dahlgren , Shinya Funakawa , Tetsuhiro Watanabe
Increasing soil organic carbon (SOC) levels is essential for sustainable agricultural productivity and climate change mitigation, particularly in alkaline soils with inherently low SOC. While amorphous Al hydroxide (Am-Al) significantly influences SOC stabilization in volcanic and humid-region soils, and biochar enhances SOC in temperate and tropical regions, their effectiveness and stabilization mechanisms in alkaline soils require further exploration. We conducted a 1-year incubation of low SOC alkaline soils (5.2 g kg−1) amended with 13C-labeled maize residue (1 g kg−1), with or without Am-Al or rice-husk biochar (each 10 g kg−1); residue mineralization/retention was quantified and molecular composition profiled by solid-state 13C NMR and Py-GC/MS. Rapid decomposition of plant residue ceased around 12 weeks, while plant residue-derived C and native SOC decomposition continued throughout the incubation period. Am-Al significantly reduced maize mineralization within the initial two weeks and retained a higher proportion of residue-derived C than the control soil with maize addition after one year (Am-Al: 36% vs. Control: 28%). 13C NMR and pyrolysis–GC/MS showed smaller decreases in carbohydrate-C and saccharides and a higher carbon preference index and odd–even predominance of alkanes, indicating that Am-Al better preserved carbohydrate- and cuticular-wax-derived components, proxies for less-degraded residues. Respiration dynamics and molecular fingerprints indicate Am-Al rapidly stabilizes labile plant compounds, possibly through non-electrostatic sorption and ligand-exchange. Biochar also retained more residue-derived C (33%) than the control, but its effects on mineralization emerged later in the incubation (>6 months). We attribute this lag to surface degradation/activation of the biochar, which may stabilize residue-derived C more efficiently. Overall, adding Am-Al or biochar with plant residues significantly increased residue-derived C retention through immediate and delayed mechanisms, respectively. Treatments combining Am-Al or biochar with plant residue yielded a net positive C balance over the incubation, whereas residue alone was negative. Thus, the application of Am-Al and biochar with plant residues represents a promising strategy for sustained C stabilization, thereby improving SOC in degraded alkaline soils.
提高土壤有机碳(SOC)水平对于可持续农业生产力和减缓气候变化至关重要,特别是在固有低SOC的碱性土壤中。无定形氢氧化铝(Am-Al)对火山和湿润地区土壤有机碳稳定有显著影响,生物炭对温带和热带地区土壤有机碳稳定有显著影响,但其在碱性土壤中的有效性和稳定机制有待进一步探索。我们对低有机碳碱性土壤(5.2 g kg - 1)进行了为期1年的培养,用13c标记的玉米渣(1 g kg - 1)进行了改性,添加或不添加Am-Al或稻壳生物炭(各10 g kg - 1);通过固态13C NMR和Py-GC/MS对残渣的矿化/保留进行了定量分析,并对其分子组成进行了分析。植物残渣的快速分解在12周左右停止,而植物残渣衍生的碳和天然有机碳分解在整个孵化期内继续进行。在最初的两周内,Am-Al显著降低了玉米矿化,并且在一年后,与添加玉米的对照土壤相比,Am-Al保留了更高比例的残留物来源C (Am-Al: 36%,对照:28%)。13C NMR和热解- gc /MS显示碳水化合物c和糖类的减少幅度较小,碳偏好指数和烷烃的奇偶优势较高,表明Am-Al较好地保存了碳水化合物和角质蜡衍生成分,代表了较少降解的残留物。呼吸动力学和分子指纹图谱表明,Am-Al可能通过非静电吸附和配体交换快速稳定不稳定的植物化合物。生物炭也比对照保留了更多的残渣衍生的碳(33%),但其对矿化的影响在孵育后期(6个月)才显现出来。我们将这种滞后归因于生物炭的表面降解/活化,这可能更有效地稳定残渣衍生的C。总的来说,在植物残基中添加Am-Al或生物炭分别通过即时和延迟机制显著增加残基碳保留。Am-Al或生物炭与植物残渣混合处理在孵育期间产生净正碳平衡,而残渣单独处理产生负碳平衡。因此,在退化的碱性土壤中施用Am-Al和生物炭是一种很有前景的持续碳稳定策略,从而改善有机碳。
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引用次数: 0
Spectroscopic analysis shows crandallite can be a major component of soil phosphorus 光谱分析表明,辉钼矿可能是土壤磷的主要成分
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-11 DOI: 10.1016/j.geoderma.2026.117712
Christian Vogel , Julian Helfenstein , Michael Massey , Ruben Kretzschmar , Ulrich Schade , René Verel , Oliver Chadwick , Emmanuel Frossard
Phosphorus (P) bioavailability is crucial for the productivity of natural and agricultural ecosystems, and soil P speciation plays a major role therein. Better understanding of P forms present in soil is thus essential to predict bioavailability. However, P speciation studies are only as powerful as the reference spectra used to interpret them, and most studies rely on a limited set of reference spectra. Most studies on soil P forms differentiate between Ca-bound P (e.g. apatite), organic P, Fe-bound P, and Al-bound P. In our analysis of a Ca, Al, and P rich soil from the Kohala region of Hawaii, we identified the mineral crandallite, CaAl3(PO4)2(OH)5·H2O, a mineral previously not considered to play a significant role in soils. Crandallite was first identified with powder X-ray diffraction. Subsequently reference spectra were collected, and the presence of crandallite was confirmed using micro-focused P K-edge X-ray absorption near edge structure (XANES) spectroscopy, micro-infrared spectroscopy, and solid-state 31P nuclear magnetic resonance (NMR) spectroscopy. Crandallite XANES spectra were distinct from other common XANES spectra due to the presence of features in the post-edge region of the spectrum. Linear combination fitting of bulk P K-edge XANES spectra allowed the determination of the proportion of crandallite to the total P content, indicating that crandallite comprises up to half, possibly even more of the soil P in the samples. Crandallite is therefore an important and potentially overlooked component of soil P, which pedogenically forms in soils with high P, Al, and Ca contents, where it could play an important role in P bioavailability.
磷(P)的生物有效性对自然和农业生态系统的生产力至关重要,而土壤磷的形态在其中起着重要作用。因此,更好地了解土壤中存在的磷形态对预测生物可利用性至关重要。然而,磷物种形成的研究仅与用于解释它们的参考光谱一样强大,并且大多数研究依赖于一组有限的参考光谱。大多数关于土壤磷形态的研究区分了钙结合磷(如磷灰石),有机磷,铁结合磷和铝结合磷。在我们对夏威夷Kohala地区富含Ca, Al和P的土壤的分析中,我们发现了矿物辉石矿,CaAl3(PO4)2(OH)5·H2O,一种以前未被认为在土壤中起重要作用的矿物。粉末状x射线衍射首次鉴定了辉长石。随后收集参考光谱,利用微聚焦P - k边缘x射线吸收近边缘结构(XANES)光谱、微红外光谱和固态31P核磁共振(NMR)光谱证实了辉石石的存在。花岗岩XANES光谱与其他常见的XANES光谱不同,主要是由于光谱的后边缘区域存在特征。体磷k边XANES光谱的线性组合拟合可以确定辉橄榄石占总磷含量的比例,表明辉橄榄石占样品中土壤磷的一半以上,甚至更多。在磷、铝、钙含量高的土壤中,辉钼矿是磷的重要组成部分,对磷的生物有效性起着重要作用。
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引用次数: 0
Regional patterns of soil magnetic susceptibility and color in the Itacaiúnas River Watershed: Geological influences and practical applications Itacaiúnas河流流域土壤磁化率和颜色的区域格局:地质影响和实际应用
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-11 DOI: 10.1016/j.geoderma.2026.117722
Paula Godinho Ribeiro , Gabriel Negreiros Salomão , Sérgio Henrique Godinho Silva , Gabriel Caixeta Martins , Luiz Roberto Guimarães Guilherme , Marcio Sousa da Silva , Silvio Junio Ramos , Roberto Dall’Agnol
Magnetic susceptibility (MS) is directly related to magnetic minerals in soils, primarily magnetite and maghemite. Determining MS and soil color is easy and cost-effective using sensors. They have great potential in agriculture, mining, and pedometrics, as they provide numerical characterization of these properties and can be correlated with other soil attributes. This study aimed to determine MS and color of surface (SS) and subsurface (SP) soil samples from a regional geochemical survey of the Itacaiúnas River Watershed, Carajás Mineral Province, and deduce relationships between these properties and soil chemical element contents and geological features. A total of 1204 composite samples from 602 locations at depths of 0–20 cm (SS) and 30–50 cm (SP) were selected for study. For MS determination, samples were analyzed at low frequency (0.47 kHz) and color numerical determination was quantified using a portable colorimeter sensor. The MS variations were strongly associated with local geology. Higher MS values were found along two east–west-oriented zones corresponding to northern and southern hydrothermal copper belts. These belts host iron oxide–copper–gold (IOCG) mineralization, where magnetite is systematically present among hydrothermal minerals. Reddish soils exhibit a spatial distribution similar to samples with higher MS values, indicating soil color indirectly reflects magnetic mineral content. MS and soil redness (a* International Commission on Illumination parameter) were positively correlated with Cu, Fe, Ni, and other elements, highlighting their potential for soil monitoring, although correlation strength varied among geological domains. These findings contribute to a soil MS database for the Amazon and may refine existing geological maps, while also indicating MS as an indicator of IOCG mineralization potential to guide new prospecting efforts.
磁化率(MS)与土壤中的磁性矿物直接相关,主要是磁铁矿和磁铁矿。使用传感器测定质谱和土壤颜色既简单又经济。它们在农业、采矿和计步法方面具有巨大的潜力,因为它们提供了这些属性的数值表征,并可以与其他土壤属性相关联。研究了Carajás矿产省Itacaiúnas河流域区域地球化学测量中表层(SS)和地下(SP)土壤样品的质谱和颜色,并推导了这些性质与土壤化学元素含量和地质特征之间的关系。选取深度为0 ~ 20 cm (SS)和30 ~ 50 cm (SP)的602个地点的1204份复合样品进行研究。质谱测定时,样品采用低频(0.47 kHz)分析,颜色定量测定采用便携式比色计传感器。质谱变化与当地地质密切相关。沿北、南热液铜带的两个东西向带MS值较高。这些带具有氧化铁-铜-金(IOCG)成矿作用,其中磁铁矿系统地存在于热液矿物中。红色土壤的空间分布与MS值较高的样品相似,表明土壤颜色间接反映了磁性矿物含量。MS和土壤红度(a* International Commission on Illumination parameter)与Cu、Fe、Ni等元素呈正相关,凸显了它们在土壤监测中的潜力,尽管相关强度因地质域而异。这些发现有助于建立亚马逊地区的土壤质谱数据库,可以完善现有的地质图,同时也表明质谱是IOCG矿化潜力的指标,可以指导新的找矿工作。
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引用次数: 0
The impact of grazing and fertilization intensity on functional trait diversity and assembly processes of soil mesofauna in grasslands 放牧和施肥强度对草地土壤中系动物功能性状多样性和组合过程的影响
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-11 DOI: 10.1016/j.geoderma.2026.117715
Dennis Baulechner , Katharina John , Andrey Zaitsev , Ruslan Saifutdinov , Volkmar Wolters
Assessing the impact of land-use intensification on soil communities is important for developing conservation strategies to maintain grassland ecosystem functioning. We aimed to establish a trait-based mechanistic understanding of how soil community composition responds to varying grazing and fertilization intensity, and whether this alters assembly processes of soil microarthropod metacommunities (Collembola and Oribatida). Microarthropods were sampled at 150 grassland plots of the German DFG Biodiversity Exploratories, covering gradients in three regions (north, centre, south).
First, functional community responses (functional richness, functional dispersion) to grazing and fertilization gradients were analysed using a trait-based approach. Hierarchical assembly models then estimated contributions of stochastic (dispersal-driven) vs. niche-based (environmental filtering, limiting similarity) processes. We compared low- vs. high-intensity plots to test whether trait-based responses shifted assembly processes. Trait–environment relationships were assessed using RLQ analyses.
Increased grazing reduced functional diversity and increased similarity in collembolan communities. Environmental filtering dominated Collembola assembly in intensively grazed grasslands in north and central Germany, but not in the south. Grazing had no effect on oribatid assembly processes. The strength of environmental filtering was region-specific. Fertilizer input was positively correlated with functional richness in Collembola but not Oribatida. Environmental filtering contributed less to Collembola assembly in intensively fertilized than unfertilized sites, suggesting low nutrient availability limits community structure.
Oribatida appeared more resistant to land-use change than Collembola. We conclude that grazing intensification reduces soil microarthropod functional diversity. Under high-intensity use, this promotes environmental filtering (especially for Collembola), altering assembly processes. Medium-intensity grazing reduced some functional groups but communities remained more resilient than at high-intensity sites, where filtering excluded entire groups. We recommend reducing high-intensity grazing to conserve soil biodiversity and ecosystem functioning.
评估土地利用集约化对土壤群落的影响对于制定保护策略以维持草地生态系统功能具有重要意义。我们的目的是建立基于性状的机制理解土壤群落组成如何响应不同的放牧和施肥强度,以及这是否改变了土壤微节肢动物元群落(弹虫和甲虫)的组装过程。在德国DFG生物多样性探测站的150个草地样地取样了小节肢动物,覆盖了北、中、南三个梯度区域。首先,利用基于性状的方法分析了功能群落对放牧和施肥梯度的响应(功能丰富度、功能分散度)。然后,分层装配模型估计了随机(分散驱动)与基于小生境(环境过滤,限制相似性)过程的贡献。我们比较了低强度和高强度的图,以测试基于特征的反应是否改变了组装过程。性状-环境关系采用RLQ分析进行评估。增加放牧减少了collbolan群落的功能多样性,增加了相似性。在德国北部和中部密集放牧的草原上,环境过滤是线虫聚集的主要因素,而在南部则不是。放牧对甲壳虫的组装过程没有影响。环境过滤的强度因地区而异。肥料投入与弹虫的功能丰富度呈显著正相关,与鳞虫的功能丰富度无显著正相关。环境过滤对密集施肥地区弹线虫聚集的贡献小于未施肥地区,表明低养分有效性限制了群落结构。甲虫对土地利用变化的抵抗力强于弹线虫。放牧强度降低了土壤微节肢动物的功能多样性。在高强度使用下,这促进了环境过滤(特别是对于弹珠),改变了装配过程。中等强度的放牧减少了一些功能群落,但与过滤排除了整个群落的高强度放牧相比,群落的恢复能力更强。我们建议减少高强度放牧,以保护土壤生物多样性和生态系统功能。
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引用次数: 0
Intensive smooth cordgrass removal strengthens tidal and temperature impacts on methane emission 密集的平滑清除网草加强了潮汐和温度对甲烷排放的影响
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-10 DOI: 10.1016/j.geoderma.2026.117719
Yueting Deng , Ruichen Lin , Han Yang , Hui Luo , Lulu Song , Xudong Zhu
The world’s largest ecosystem restoration via intensive removals of invasive smooth cordgrass (Spartina alterniflora) is being implemented in coastal China, potentially exerting a large impact on soil biogeochemical cycles of greenhouse gases including methane (CH4). However, the degree to which CH4 emission and its environmental controls change with such anthropogenic disturbances has been rarely assessed with direct empirical evidence. To quantify these disturbance effects, we utilized the eddy covariance (EC) approach to continuously measure net CH4 exchange from Jul. 2022 to Oct. 2023, covering both pre- and post-removal periods, in a disturbed coastal wetland of Southeast China experiencing an intensive cordgrass removal in late Oct. 2022. Our analyses, based on this unique EC dataset of high-frequency (30-min) time series CH4 fluxes, revealed that (a) the removal caused a pulse of CH4 emission peaking one month later up to 0.76 g CH4 m−2 d-1, with the mean post-removal emission over ten times that of the pre-removal level (0.03 g CH4 m−2 d-1); (b) the removal intensified the controls of tidal inundation and pumping on CH4 fluxes, showing much stronger pumping effects within two months following the disturbances; (c) the removal also enlarged the temperature sensitivity of CH4 emission, leading to larger daytime emission especially at afternoon hours; (d) the combination of enhanced tidal impacts and temperature dependence thus promoted the diel variability of CH4 fluxes during the post-removal period. These results suggest that coastal restoration via intensive cordgrass removals boosts both the magnitude and the diel variability of CH4 emission, highlighting the necessity of better understanding the climate impact of restoration activities. Future longer flux data with extended years are needed to further assess potential regime shift in soil CH4 biogeochemistry and long-term evolution of such unintended environmental costs of the restoration.
中国沿海地区正在实施世界上最大规模的生态系统修复,通过大量清除入侵的互花米草(Spartina interniflora),可能对包括甲烷(CH4)在内的温室气体的土壤生物地球化学循环产生重大影响。然而,很少有直接的经验证据评估CH4排放及其环境控制随这种人为干扰而变化的程度。为了量化这些干扰效应,我们利用涡动相关(EC)方法连续测量了2022年7月至2023年10月期间中国东南部沿海受干扰湿地的净CH4交换,涵盖了去除前和去除后的时期,该湿地在2022年10月下旬经历了一次密集的网茅去除。基于这一独特的EC高频(30分钟)时间序列CH4通量数据集,我们的分析表明:(a)去除导致CH4排放脉冲在一个月后达到峰值0.76 g CH4 m−2 d-1,去除后的平均排放量是去除前水平(0.03 g CH4 m−2 d-1)的十倍以上;(b)清除加强了潮汐淹没和抽吸对CH4通量的控制,在扰动发生后的两个月内,抽吸效果明显增强;(c) CH4排放的温度敏感性增大,导致白天特别是下午CH4排放增大;(d)增强的潮汐影响和温度依赖性共同促进了CH4通量在去除后时期的日变率。这些结果表明,通过密集清除网茅进行的海岸恢复增加了CH4排放的幅度和日变率,突出了更好地了解恢复活动对气候影响的必要性。未来需要更长时间的通量数据,以进一步评估土壤CH4生物地球化学的潜在状态变化以及恢复过程中这种意外环境成本的长期演变。
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引用次数: 0
Differential responses of prokaryotic and fungal communities in soil microenvironments to drying and wetting as affected by soil aggregate isolation method 土壤团聚体分离方法对土壤微环境中原核生物和真菌群落干湿响应的差异影响
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-10 DOI: 10.1016/j.geoderma.2026.117723
Jonathan Y. Lin , Daoyuan Wang , Cameron K. McMillan , King C. Law , Kate M. Scow , Jorge L. Mazza Rodrigues
Microorganisms live in communities within and on the surface of soil aggregates of varying sizes. A growing body of evidence suggests that different size fractions of aggregates are habitats for distinct microbial communities, but comparisons have been difficult owing to different aggregate separation methods. Two aggregate isolation methods, dry and wet sieving, originating from field moist and dried soils were used to investigate their effects on the prokaryotic and fungal communities in four aggregate size fractions (large macroaggregates (>2000 μm), small macroaggregates (250–2000 μm), microaggregates (53–250 μm), and silt & clay (<53 μm)) using metabarcoding of the 16S rRNA gene and internal transcribed spacer. While prokaryotic community composition among treatments in each of the four size fractions was different, the composition and alpha diversity for fungi were more resistant to change in large and small macroaggregates than in the microaggregate and silt & clay fractions. The average prokaryotic ribosomal RNA copy number and genome size increased in all aggregate size fractions when soils were dried before sieving. Decisions on which aggregate separation method to use depend heavily on the questions one is interested in, but soil storage conditions between sample collection and sieving are highlighted as driving the biggest differences in microbial community composition.
微生物生活在不同大小的土壤团聚体内部和表面的群落中。越来越多的证据表明,不同大小的团聚体部分是不同微生物群落的栖息地,但由于不同的团聚体分离方法,比较一直很困难。利用16S rRNA基因的元编码和内部转录间隔物,研究了干湿两种团聚体分离方法(干湿筛分)对土壤中4个团聚体粒径组分(大团聚体(2000 μm)、小团聚体(250 ~ 2000 μm)、微团聚体(53 ~ 250 μm)和粉土团聚体(53 μm)的影响。虽然4个粒径组分中不同处理的原核生物群落组成不同,但真菌的组成和α多样性在大团聚体和小团聚体中比在微团聚体和粉土组分中更能抵抗变化。土壤在筛前干燥后,原核核糖体RNA拷贝数和基因组大小均增加。使用哪种聚合分离方法的决定在很大程度上取决于一个人感兴趣的问题,但样品收集和筛分之间的土壤储存条件被强调为驱动微生物群落组成的最大差异。
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引用次数: 0
Different mechanisms of phosphorus transformation in calcareous and acid soils affected by ammonium polyphosphate 聚磷酸铵对钙质和酸性土壤磷转化的不同影响机制
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-10 DOI: 10.1016/j.geoderma.2026.117718
Yang Luo, Yaoli Su, Minghui Huang, Yang Li, Dehua Xu, Zhengjuan Yan, Xinlong Wang
The effects of ammonium polyphosphate (APP, (NH4)n+2PnO3n+1, n < 20) on soil phosphorus (P) availability vary depending on polymerization distributions and the soil type, yet the mechanisms driving these differences remain unclear. This study explored the availability and transformation of P affected by APP1 (P species of P1-P2) and APP2 (P species of P1-P7) in two different soils, in comparison with conventional ammonium phosphates (APs). APP application increased Olsen-P by 10.7–24.8% in calcareous soil, but decreased it by 2.6–10.8% in acid soil relative to APs. In calcareous soil, APP significantly increased soluble-P, adsorbed-P, and Fe-associated P, as reflected by CaCl2, NaHCO3, and NaOH extractable Ps, while decreased more stable Ca-associated P and occluded P indicated by NH4Ac and Na3C6H5O7-Na2S2O4-NaOH extractable Ps. The changes in the composition of CaCO3 and Fe/Al oxides together with/without the reduced organic carbon loss mainly contributed to the decrease in P sorption/precipitation and the increase in P desorption/dissolution. In acid soil, APP significantly increased microbial biomass P, leading to reduced labile inorganic P and elevated labile organic P. Meanwhile, APP increased both oxalate-extractable and complex Fe/Al oxides, which affected P adsorption–desorption to a certain extent. Compared to APP1, APP2 resulted in P existing in a more labile adsorbed state, thereby increasing P availability in both calcareous and acid soils. The main processes affecting P availability in the calcareous soils were abiotic transformations, while biotic transformations played the key role in the acid soils.
聚磷酸铵(APP, (NH4)n+2PnO3n+1, n < 20)对土壤磷有效性的影响因聚合分布和土壤类型而异,但导致这些差异的机制尚不清楚。以常规磷酸铵(APs)为对照,探讨了两种不同土壤中APP1 (P1-P2的P种)和APP2 (P1-P7的P种)对磷的有效性和转化的影响。在钙质土壤中,施用APP使Olsen-P含量增加了10.7% ~ 24.8%,而在酸性土壤中则使Olsen-P含量降低了2.6 ~ 10.8%。在钙质土壤中,APP显著增加了CaCl2、NaHCO3和NaOH可提取磷,显著增加了可溶性磷、吸附磷和铁伴生磷,而NH4Ac和Na3C6H5O7-Na2S2O4-NaOH可提取磷,显著降低了较为稳定的钙伴生磷和闭合磷。CaCO3和Fe/Al氧化物组成的变化,以及有机碳损失的减少和不减少,主要是导致磷的吸附/沉淀减少和磷的解吸/溶解增加。在酸性土壤中,APP显著增加了微生物生物量P,导致活性无机P降低,活性有机P升高。同时,APP增加了草酸-可萃取和复合Fe/Al氧化物,在一定程度上影响了磷的吸附-解吸。与APP1相比,APP2使磷以更不稳定的吸附状态存在,从而提高了钙质和酸性土壤中磷的有效性。影响钙质土壤磷有效性的主要过程是非生物转化,而在酸性土壤中,生物转化起关键作用。
{"title":"Different mechanisms of phosphorus transformation in calcareous and acid soils affected by ammonium polyphosphate","authors":"Yang Luo,&nbsp;Yaoli Su,&nbsp;Minghui Huang,&nbsp;Yang Li,&nbsp;Dehua Xu,&nbsp;Zhengjuan Yan,&nbsp;Xinlong Wang","doi":"10.1016/j.geoderma.2026.117718","DOIUrl":"10.1016/j.geoderma.2026.117718","url":null,"abstract":"<div><div>The effects of ammonium polyphosphate (APP, (NH<sub>4</sub>)<sub>n+2</sub>P<sub>n</sub>O<sub>3n+1</sub>, n &lt; 20) on soil phosphorus (P) availability vary depending on polymerization distributions and the soil type, yet the mechanisms driving these differences remain unclear. This study explored the availability and transformation of P affected by APP1 (P species of P<sub>1</sub>-P<sub>2</sub>) and APP2 (P species of P<sub>1</sub>-P<sub>7</sub>) in two different soils, in comparison with conventional ammonium phosphates (APs). APP application increased Olsen-P by 10.7–24.8% in calcareous soil, but decreased it by 2.6–10.8% in acid soil relative to APs. In calcareous soil, APP significantly increased soluble-P, adsorbed-P, and Fe-associated P, as reflected by CaCl<sub>2</sub>, NaHCO<sub>3</sub>, and NaOH extractable Ps, while decreased more stable Ca-associated P and occluded P indicated by NH<sub>4</sub>Ac and Na<sub>3</sub>C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>-Na<sub>2</sub>S<sub>2</sub>O<sub>4</sub>-NaOH extractable Ps. The changes in the composition of CaCO<sub>3</sub> and Fe/Al oxides together with/without the reduced organic carbon loss mainly contributed to the decrease in P sorption/precipitation and the increase in P desorption/dissolution. In acid soil, APP significantly increased microbial biomass P, leading to reduced labile inorganic P and elevated labile organic P. Meanwhile, APP increased both oxalate-extractable and complex Fe/Al oxides, which affected P adsorption–desorption to a certain extent. Compared to APP1, APP2 resulted in P existing in a more labile adsorbed state, thereby increasing P availability in both calcareous and acid soils. The main processes affecting P availability in the calcareous soils were abiotic transformations, while biotic transformations played the key role in the acid soils.</div></div>","PeriodicalId":12511,"journal":{"name":"Geoderma","volume":"467 ","pages":"Article 117718"},"PeriodicalIF":6.6,"publicationDate":"2026-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146146753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Subsoiling reduces N2O emissions by altering the relative gas diffusivity, O2 status and microbial communities in grazed pasture soil 深埋土壤通过改变放牧草地土壤的相对气体扩散系数、O2状态和微生物群落减少N2O排放
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-07 DOI: 10.1016/j.geoderma.2026.117716
Juan Liu , Timothy Clough , Sam Carrick , Jiafa Luo , Andriy Podolyan , Naomi Wells , Chris Chisholm , Jupei Shen , Peng Li , Lianfeng Du , Hong Pan , Limei Zhang , Hong J. Di
Nitrous oxide (N2O) is a potent greenhouse gas predominantly emitted from grazed pasture through denitrification, driven by soil oxygen (O2) availability and urine-derived nitrogen (N). Pasture soils are vulnerable to compaction from animal treading, restricting gas diffusion and enhancing N2O emissions. Although subsoiling alleviates compaction, its impact on soil O2 status and N2O emissions, particularly under high urine N load, remain poorly understood and rarely investigated. This in-situ field study (March-August 2023) evaluated the effect of subsoiling on soil moisture, O2 content, relative gas diffusivity (Dp/Do), functional gene abundance, N2O emissions, and pasture production. Treatments included non-subsoiling or subsoiling, each with or without synthetic ruminant urine (713 kg N ha−1). Subsoiling improved macroporosity, enhanced O2 availability, increased Dp/Do at 5, 10 and 20 cm depth (P < 0.001), and reduced moisture at 10 cm depth (P < 0.001). Subsoiling significantly reduced N2O emissions by 52% and 81% of non-subsoiled plots for non-urine and urine treatments, respectively (P < 0.05). Dp/Do was strongly correlated with N2O fluxes during the first 15 days following urine application (R2 = 0.590.87), suggesting its utility as a predictive indicator under high substrate availability. Molecular analysis showed reduced nirK gene abundance under subsoiling, with limited response for other denitrification genes. Subsoiling had no significant effect on pasture yield or N uptake. Overall, subsoiling mitigates N2O emissions by improving soil aeration and Dp/Do while maintaining productivity, offering a promising strategy for sustainable N management in grazed pasture soils.
一氧化二氮(N2O)是一种强效温室气体,主要由放牧牧场通过反硝化作用排放,受土壤氧(O2)有效性和尿源性氮(N)的驱动。牧草土壤容易被动物踩踏压实,限制气体扩散,增加N2O排放。虽然沉土缓解了压实,但其对土壤O2状态和N2O排放的影响,特别是在高尿氮负荷下,仍然知之甚少,很少研究。本研究(2023年3月- 8月)评估了深埋对土壤水分、O2含量、相对气体扩散系数(Dp/Do)、功能基因丰度、N2O排放和牧草产量的影响。处理包括不渗土或渗土,分别添加或不添加合成反刍动物尿液(713 kg N ha−1)。沉土改善了宏观孔隙度,增强了O2有效性,增加了5、10和20 cm深度的Dp/Do (P < 0.001),降低了10 cm深度的水分(P < 0.001)。在不排尿和排尿处理中,未排尿地块的N2O排放量分别显著减少52%和81% (P < 0.05)。Dp/Do与尿液应用后15天内N2O通量密切相关(R2 = 0.59-0.87),表明其在高底物利用率下可作为预测指标。分子分析表明,土壤深埋降低了nirK基因的丰度,对其他反硝化基因的响应有限。深耕对牧草产量和氮素吸收无显著影响。总体而言,深埋土壤通过改善土壤通气和Dp/Do来减少N2O排放,同时保持生产力,为放牧草地土壤的可持续氮管理提供了一种有希望的策略。
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引用次数: 0
Selecting the right samples rather than more samples: A new spectral–environmental similarity strategy for local soil spectral modeling 选择正确的样本而不是更多的样本:一种新的光谱-环境相似策略用于局部土壤光谱建模
IF 6.6 1区 农林科学 Q1 SOIL SCIENCE Pub Date : 2026-02-07 DOI: 10.1016/j.geoderma.2026.117710
Liangyi Li , Zipeng Zhang , Minglu Sun , Jianli Ding , Jingzhe Wang , Dong Xu , Yuanyuan Huang
Addressing the dual challenges of limited sample size and high environmental heterogeneity in small-scale soil organic carbon (SOC) spectral modeling, this study proposes a fundamental hypothesis: selecting samples that are similar to the target region in both “spectral features and environmental characteristics” is more effective for improving prediction accuracy and stability. Based on this assumption, we developed a synergistic sample transfer strategy that integrates spectral similarity with environmental similarity under the Third Law of Geography, aiming to systematically screen the most comparable samples from the global soil spectral library to enhance the performance and robustness of local SOC modeling. A spectral-environmental similarity framework was established to identify samples that are simultaneously similar to the target region in spectral properties and environmental settings, and instance-based transfer modeling experiments were conducted in five representative small-sample regions (A-E). Results show that the synergistic strategy significantly improved modeling performance in most regions, with maximum increases in predictive power (as indicated by R2) of up to 18% compared with the baseline global transfer model. Remarkably, even when the number of global samples was reduced from 20,961 to around 200, the proposed strategy still outperformed local modeling and conventional global modeling approaches. In relatively stable environments, higher weights on environmental similarity yielded the best models, whereas in highly heterogeneous regions, spectral similarity played a more dominant role. The synergistic strategy also optimized the distribution of important spectral bands, enhanced SOC-responsive features in the visible region (450–750 nm), suppressed redundant information, and improved modeling efficiency. This study demonstrates that the proposed spectral-environmental synergistic sample transfer modeling method not only challenges the conventional assumption that “more samples guarantee better models” but also provides a novel pathway and theoretical support for the efficient use of global soil spectral libraries in regional SOC modeling.
针对小尺度土壤有机碳(SOC)光谱建模中样本量有限和环境异质性高的双重挑战,本研究提出了一个基本假设:选择在“光谱特征和环境特征”上都与目标区域相似的样本,可以更有效地提高预测精度和稳定性。基于这一假设,我们开发了基于地理第三定律的光谱相似度与环境相似度相结合的协同样本转移策略,旨在系统地筛选全球土壤光谱库中最具可比性的样本,以提高局部土壤有机碳模型的性能和鲁棒性。建立光谱-环境相似性框架,识别与目标区域在光谱特性和环境设置上同时相似的样本,并在5个具有代表性的小样本区域(A- e)进行基于实例的转移建模实验。结果表明,在大多数地区,协同策略显著提高了建模性能,与基线全球转移模型相比,预测能力(如R2所示)的最大增幅高达18%。值得注意的是,即使全局样本数量从20,961减少到200左右,所提出的策略仍然优于局部建模和传统的全局建模方法。在相对稳定的环境中,较高的环境相似度权重可以得到最佳模型,而在高度异质的区域,光谱相似度起更大的作用。该协同策略还优化了重要光谱带的分布,增强了可见光区域(450-750 nm)的soc响应特征,抑制了冗余信息,提高了建模效率。研究表明,本文提出的光谱-环境协同样本迁移建模方法不仅挑战了“样本越多,模型越好”的传统假设,而且为有效利用全球土壤光谱库进行区域土壤有机碳建模提供了新的途径和理论支持。
{"title":"Selecting the right samples rather than more samples: A new spectral–environmental similarity strategy for local soil spectral modeling","authors":"Liangyi Li ,&nbsp;Zipeng Zhang ,&nbsp;Minglu Sun ,&nbsp;Jianli Ding ,&nbsp;Jingzhe Wang ,&nbsp;Dong Xu ,&nbsp;Yuanyuan Huang","doi":"10.1016/j.geoderma.2026.117710","DOIUrl":"10.1016/j.geoderma.2026.117710","url":null,"abstract":"<div><div>Addressing the dual challenges of limited sample size and high environmental heterogeneity in small-scale soil organic carbon (SOC) spectral modeling, this study proposes a fundamental hypothesis: selecting samples that are similar to the target region in both “spectral features and environmental characteristics” is more effective for improving prediction accuracy and stability. Based on this assumption, we developed a synergistic sample transfer strategy that integrates spectral similarity with environmental similarity under the Third Law of Geography, aiming to systematically screen the most comparable samples from the global soil spectral library to enhance the performance and robustness of local SOC modeling. A spectral-environmental similarity framework was established to identify samples that are simultaneously similar to the target region in spectral properties and environmental settings, and instance-based transfer modeling experiments were conducted in five representative small-sample regions (A-E). Results show that the synergistic strategy significantly improved modeling performance in most regions, with maximum increases in predictive power (as indicated by R<sup>2</sup>) of up to 18% compared with the baseline global transfer model. Remarkably, even when the number of global samples was reduced from 20,961 to around 200, the proposed strategy still outperformed local modeling and conventional global modeling approaches. In relatively stable environments, higher weights on environmental similarity yielded the best models, whereas in highly heterogeneous regions, spectral similarity played a more dominant role. The synergistic strategy also optimized the distribution of important spectral bands, enhanced SOC-responsive features in the visible region (450–750 nm), suppressed redundant information, and improved modeling efficiency. This study demonstrates that the proposed spectral-environmental synergistic sample transfer modeling method not only challenges the conventional assumption that “more samples guarantee better models” but also provides a novel pathway and theoretical support for the efficient use of global soil spectral libraries in regional SOC modeling.</div></div>","PeriodicalId":12511,"journal":{"name":"Geoderma","volume":"467 ","pages":"Article 117710"},"PeriodicalIF":6.6,"publicationDate":"2026-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146134155","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Geoderma
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