Christin Mueller, Ronald Krieg, Ralf Merz, Kay Knöller
Especially in the years 2018 to 2020, a severe drought was observed in central Germany. To explore the potential impact of this drought on the catchment-scale nitrogen cycling, we investigated the ground- and surface-water compartments of the Holtemme watershed, a mesoscale river catchment in the Harz Mountains, Germany. Analysis of nitrate concentrations and corresponding isotope signatures for groundwater and surface water samples was conducted throughout the drought period and continued until discharge conditions returned to the long-term mean in early 2021. The study revealed a pronounced decline in nitrate concentrations in both compartments during the drought, with groundwater showing an average reduction of ~60%, and surface water exhibiting a wide range of changes from +32% to −59% (mid- and downstream decreasing from 19.4 to 2.3 mg L−1). In the post-drought period, surface-water nitrate concentrations increased sharply, reaching values up to 18.3 mg L−1. Isotope investigations allowed us to distinguish between different nitrate sources and microbial turnover processes. Time series analysis of δ15N–NO3 showed regular oscillations within the year ranging from 2‰ to 20‰ (AIR), illustrating a periodic organic fertiliser applications. Corresponding δ18O–NO3 signatures showed higher, seasonally independent variations, with a mean of 6‰ (VSMOW), which can be explained by the expected isotope variability of the ambient water during nitrification. However, flow paths for nitrate mobilisation into the surface water appear to be unaffected by the drought, as the contributions of each nitrate source decreased equally during the dry period. Nitrate concentrations increased markedly after the drought, regardless of the recent nitrate supply, reaching values of up to 20 mg L−1 in 2022.
特别是在2018年至2020年,德国中部发生了严重干旱。为了探索干旱对流域尺度氮循环的潜在影响,我们调查了德国哈茨山脉的一个中尺度河流集水区——Holtemme流域的地表水和地表水。在整个干旱期间,对地下水和地表水样品的硝酸盐浓度和相应的同位素特征进行了分析,并持续到2021年初排放条件恢复到长期平均水平。研究表明,在干旱期间,两个区域的硝酸盐浓度显著下降,地下水平均下降约60%,地表水的变化范围从+32%到- 59%(中下游从19.4 mg L - 1下降到2.3 mg L - 1)。干旱后,地表水硝酸盐浓度急剧上升,最高可达18.3 mg L−1。同位素研究使我们能够区分不同的硝酸盐来源和微生物周转过程。δ15N-NO3的时间序列分析显示,δ15N-NO3在2‰~ 20‰(AIR)的年内有规律振荡,说明有机肥的周期性施用。相应的δ18O-NO3特征表现出较大的季节变化,平均为6‰(VSMOW),这可以用硝化过程中环境水的预期同位素变异来解释。然而,进入地表水的硝酸盐流动路径似乎不受干旱的影响,因为在干旱期间,每种硝酸盐来源的贡献都减少了。无论最近的硝酸盐供应如何,干旱后硝酸盐浓度显著增加,在2022年达到20 mg L−1的值。
{"title":"Effects of a Perennial Drought on Nitrate Fate in an Agriculturally Dominated Mesoscale Catchment as Constrained by Stable Isotope Investigations","authors":"Christin Mueller, Ronald Krieg, Ralf Merz, Kay Knöller","doi":"10.1002/hyp.70383","DOIUrl":"10.1002/hyp.70383","url":null,"abstract":"<p>Especially in the years 2018 to 2020, a severe drought was observed in central Germany. To explore the potential impact of this drought on the catchment-scale nitrogen cycling, we investigated the ground- and surface-water compartments of the Holtemme watershed, a mesoscale river catchment in the Harz Mountains, Germany. Analysis of nitrate concentrations and corresponding isotope signatures for groundwater and surface water samples was conducted throughout the drought period and continued until discharge conditions returned to the long-term mean in early 2021. The study revealed a pronounced decline in nitrate concentrations in both compartments during the drought, with groundwater showing an average reduction of ~60%, and surface water exhibiting a wide range of changes from +32% to −59% (mid- and downstream decreasing from 19.4 to 2.3 mg L<sup>−1</sup>). In the post-drought period, surface-water nitrate concentrations increased sharply, reaching values up to 18.3 mg L<sup>−1</sup>. Isotope investigations allowed us to distinguish between different nitrate sources and microbial turnover processes. Time series analysis of δ<sup>15</sup>N–NO<sub>3</sub> showed regular oscillations within the year ranging from 2‰ to 20‰ (AIR), illustrating a periodic organic fertiliser applications. Corresponding δ<sup>18</sup>O–NO<sub>3</sub> signatures showed higher, seasonally independent variations, with a mean of 6‰ (VSMOW), which can be explained by the expected isotope variability of the ambient water during nitrification. However, flow paths for nitrate mobilisation into the surface water appear to be unaffected by the drought, as the contributions of each nitrate source decreased equally during the dry period. Nitrate concentrations increased markedly after the drought, regardless of the recent nitrate supply, reaching values of up to 20 mg L<sup>−1</sup> in 2022.</p>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"40 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2026-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/hyp.70383","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145904777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Giora J. Kidron, Rafael Kronenfeld, Abraham Starinsky, Bo Xiao
Non-rainfall water (NRW), principally dew, was regarded as the main factor responsible for the relatively high productivity of the Negev Desert. Nevertheless, these measurements also included distillation, that is, vapour condensation that stems from the wet ground, which reflect indirect rain water (IRW) and denotes water relocation rather than water addition. Aiming to differentiate between NRW (and dew) and IRW (and distillation), biomarkers were used: the threshold required for microorganism respiration (0.03 mm) and net photosynthesis (0.05 mm) and the threshold of liquid water (0.1 mm). Based on 3 years of measurements, our findings indicate that (a) in comparison to an average number of rainy (> 0.1 mm) events of 22 days, the number of NRW and IRW was 139 days and 42 days, respectively, largely affected by RH and wind speed, (b) average annual amount of NRW ≥ 0.03 mm was 12.8 mm, which was 2.7-fold higher than IRW (4.8 mm), but yet, the amount of dew was only 1.5-fold higher than distillation (6.2 vs. 4.1 mm, respectively), (c) annual duration of ≥ 0.03 mm was by 3.5-fold longer for NRW (328.3 h) than for IRW (93.4 h) but annual dew duration (128.3) was only 1.8-fold higher than that of distillation (72.7 h), (d) out of all the available vapour, 39.8% resulted in distillation which also provided 36.2% of the vapour-driven duration. The findings indicate that even in a dew desert such as the Negev, distillation plays an important role, pointing to its possible role not only for dew deserts but also for non-dewy deserts.
{"title":"Distillation Plays an Important Role Also in A Dew Desert","authors":"Giora J. Kidron, Rafael Kronenfeld, Abraham Starinsky, Bo Xiao","doi":"10.1002/hyp.70366","DOIUrl":"10.1002/hyp.70366","url":null,"abstract":"<p>Non-rainfall water (NRW), principally dew, was regarded as the main factor responsible for the relatively high productivity of the Negev Desert. Nevertheless, these measurements also included distillation, that is, vapour condensation that stems from the wet ground, which reflect indirect rain water (IRW) and denotes water relocation rather than water addition. Aiming to differentiate between NRW (and dew) and IRW (and distillation), biomarkers were used: the threshold required for microorganism respiration (0.03 mm) and net photosynthesis (0.05 mm) and the threshold of liquid water (0.1 mm). Based on 3 years of measurements, our findings indicate that (a) in comparison to an average number of rainy (> 0.1 mm) events of 22 days, the number of NRW and IRW was 139 days and 42 days, respectively, largely affected by RH and wind speed, (b) average annual amount of NRW ≥ 0.03 mm was 12.8 mm, which was 2.7-fold higher than IRW (4.8 mm), but yet, the amount of dew was only 1.5-fold higher than distillation (6.2 vs. 4.1 mm, respectively), (c) annual duration of ≥ 0.03 mm was by 3.5-fold longer for NRW (328.3 h) than for IRW (93.4 h) but annual dew duration (128.3) was only 1.8-fold higher than that of distillation (72.7 h), (d) out of all the available vapour, 39.8% resulted in distillation which also provided 36.2% of the vapour-driven duration. The findings indicate that even in a dew desert such as the Negev, distillation plays an important role, pointing to its possible role not only for dew deserts but also for non-dewy deserts.</p>","PeriodicalId":13189,"journal":{"name":"Hydrological Processes","volume":"40 1","pages":""},"PeriodicalIF":2.9,"publicationDate":"2026-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/hyp.70366","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145904721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}