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Effect of Buffer Charge Redistribution on RF Losses and Harmonic Distortion in GaN-on-Si Substrates 缓冲电荷再分布对硅基氮化镓衬底射频损耗和谐波失真的影响
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-04-08 DOI: 10.1109/JEDS.2024.3386170
Pieter Cardinael;Sachin Yadav;Bertrand Parvais;Jean-Pierre Raskin
Understanding and mitigation of substrate RF losses and signal distortion are critical to enable high-performance GaN-on-Si front-end-modules. While the origin of RF losses and consequently a decreased effective substrate resistivity $({rho }_{eff})$ in GaN-on-Si substrates is now understood to be diffusion of Al and Ga atoms into the silicon substrate during III-N growth, the effect of upper III-N buffer layers on the ${rho }_{eff}$ degradation under stressed conditions remains unclear. In this paper, we show that up to 50% variation in ${rho }_{eff}$ at 2 GHz can take place over more than 1,000 s when the substrate is stressed at 50 V. Additionally, Coplanar Wave Guide (CPW) large-signal measurements under the same experimental conditions show a variation of $2^{mathrm{ nd}}$ harmonic power of up to 5dB. A thermally activated stress and relaxation behavior shows the signature of traps which are present in the C-doped layers. With the help of a simplified TCAD model of the GaN-on-Si stack, we link this behavior to slow charge redistribution in the C-doped buffer continuously modifying the flat-band voltage ( $text{V}_{text {FB}}$ ) of the Metal-Insulator-Semiconductor (MIS) structure. Free carrier transport across the buffer is shown to have the greatest contribution on the large time constants, highlighting the importance of vertical transport paths in GaN-on-Si stacks.
要实现高性能硅基氮化镓前端模块,了解并减少基底射频损耗和信号失真至关重要。虽然硅基氮化镓衬底的射频损耗以及由此导致的有效衬底电阻率$({rho }_{eff})$下降的原因现在已被理解为在III-N生长过程中铝和镓原子向硅衬底的扩散,但上层III-N缓冲层对受压条件下${rho }_{eff}$退化的影响仍不清楚。本文表明,当衬底在 50 V 下受压时,2 GHz 频率下的 ${rho }_{eff}$ 在 1,000 秒内会发生高达 50%的变化。此外,在相同实验条件下进行的共面波导 (CPW) 大信号测量显示,2^{mathrm{nd}}$谐波功率的变化高达 5dB。热激活应力和弛豫行为显示了掺杂 C 的层中存在陷阱的特征。借助简化的硅基氮化镓(GaN-on-Si)堆栈 TCAD 模型,我们将这种行为与掺杂 C 的缓冲器中缓慢的电荷再分布联系起来,这种再分布会持续改变金属-绝缘体-半导体(MIS)结构的平带电压(${V}_{text {FB}}$)。跨缓冲器的自由载流子传输对大时间常数的贡献最大,这突出了硅基氮化镓叠层中垂直传输路径的重要性。
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引用次数: 0
Machine Learning-Based Compact Model Design for Reconfigurable FETs 基于机器学习的可重构 FET 紧凑型模型设计
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-04-08 DOI: 10.1109/JEDS.2024.3386113
Maximilian Reuter;Johannes Wilm;Andreas Kramer;Niladri Bhattacharjee;Christoph Beyer;Jens Trommer;Thomas Mikolajick;Klaus Hofmann
In integrated circuit design compact models are the abstraction layer which connects semiconductor physics and circuit simulation. Established compact models like BSIM provide a powerful platform for many kinds of conventional MOSFETs. However, novel device concepts like reconfigurable FETs (RFETs) come with a higher expressiveness. Due to their altered transport physics as compared to classical inversion mode MOSFETs those devices are hard to describe in a closed form expression by classical compact models. Table models bridge this gap for devices with novel features or materials, but circuit simulation becomes slow and inaccurate due to interpolation and convergence difficulties. Table model data can, however, be translated to closed form expressions, providing equation based models without the need for interpolation during simulation time. This work shows data driven approaches to generate compact models from biasing tables without physical analysis of the device behavior. Two automated modeling techniques are applied to a recently emerged RFET, forming a Verilog-A compact model for DC and transient simulation in Cadence Virtuoso. Drive current is implemented as a neural network, large enough to accurately predict behavior of a multi-gate device. The high dynamic range from $mA$ to $pA$ is covered by combining a linear model for high currents and a logarithmic model for low currents. For transient simulation precise models for electrode charges are essential. Here, symbolic regression provides human-readable closed form expressions which allow direct implementation in Verilog-A. The compact model approach is demonstrated with device data generated from a structural technology model (TCAD). However, the entire modeling flow can directly be used on real device measurements, if a technology model is unavailable or unpractical. We show that the presented machine learning based compact models show better convergence, more accurate predictions and faster simulation $(82$ to 308 times) in Cadence SPECTRE than simple table models generated from the same device.
在集成电路设计中,紧凑型模型是连接半导体物理和电路仿真的抽象层。BSIM 等成熟的紧凑模型为多种传统 MOSFET 提供了强大的平台。然而,可重构场效应晶体管(RFET)等新型器件概念需要更高的表现力。与经典反转模式 MOSFET 相比,这些器件的传输物理特性发生了改变,因此很难用经典紧凑模型的封闭式表达来描述。表模型为具有新特征或新材料的器件弥补了这一缺陷,但由于插值和收敛困难,电路仿真变得缓慢和不准确。然而,表模型数据可以转化为封闭式表达式,提供基于方程的模型,而无需在仿真过程中进行插值。这项工作展示了无需对器件行为进行物理分析就能从偏置表生成紧凑模型的数据驱动方法。两种自动建模技术被应用于最近出现的射频晶体管,在 Cadence Virtuoso 中形成了用于直流和瞬态仿真的 Verilog-A 紧凑模型。驱动电流以神经网络的形式实现,其规模足以准确预测多栅极器件的行为。通过结合大电流的线性模型和小电流的对数模型,可以覆盖从 $mA$ 到 $pA$ 的高动态范围。对于瞬态模拟,精确的电极电荷模型至关重要。在这里,符号回归提供了人类可读的封闭式表达式,可以直接在 Verilog-A 中实现。通过结构技术模型 (TCAD) 生成的器件数据,演示了紧凑模型方法。不过,如果没有技术模型或技术模型不实用,整个建模流程也可直接用于真实设备测量。我们的研究表明,在 Cadence SPECTRE 中,与从相同器件生成的简单表格模型相比,所介绍的基于机器学习的紧凑模型具有更好的收敛性、更准确的预测和更快的仿真速度(82 到 308 倍)。
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引用次数: 0
Small-Signal and Large-Signal RF Characterization and Modeling of Low and High Voltage FinFETs for 14/16 nm Technology Node SoCs 用于 14/16 纳米技术节点 SoC 的低压和高压 FinFET 的小信号和大信号射频特性分析与建模
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-04-01 DOI: 10.1109/JEDS.2024.3384008
Anirban Kar;Shivendra Singh Parihar;Jun Z. Huang;Huilong Zhang;Weike Wang;Kimihiko Imura;Yogesh Singh Chauhan
Modern System-on-Chip (SoC) architectures necessitate low-voltage (LV) core transistors featuring excellent digital, analog, and radio frequency (RF) properties, as well as thick oxide transistors serving as robust I/O buffers and high-voltage (HV) transistors essential for efficient power management. This study presents a comprehensive DC to RF characterization, a detailed modeling strategy, and subsequent model parameter extraction for commercially produced LV and HV Fin Field Effect Transistors (FinFETs) at 14/16 nm technology. The industry-standard BSIM-CMG compact model is modified to accurately capture the characteristics of the HV FinFET devices integrated with the digital LV FinFETs for SoC applications. A detailed analysis of the DC, analog, and RF performance of LV, I/O, and HV FinFETs compared to the contemporary planar CMOS technology is performed. The large-signal performance of the device is evaluated using the developed model and validated with the measured data. Finally, a concise overview of the performance indicators associated with the modeled device is also presented.
现代片上系统 (SoC) 架构需要具有出色数字、模拟和射频 (RF) 特性的低压 (LV) 核心晶体管,以及用作稳健 I/O 缓冲器的厚氧化物晶体管和对高效电源管理至关重要的高压 (HV) 晶体管。本研究针对采用 14/16 纳米技术的商用低压和高压鳍式场效应晶体管 (FinFET) 介绍了全面的直流到射频特性分析、详细的建模策略以及随后的模型参数提取。对行业标准 BSIM-CMG 紧凑型模型进行了修改,以准确捕捉与数字 LV FinFET 集成在 SoC 应用中的 HV FinFET 器件的特性。与当代平面 CMOS 技术相比,对 LV、I/O 和 HV FinFET 的直流、模拟和射频性能进行了详细分析。使用开发的模型评估了器件的大信号性能,并通过测量数据进行了验证。最后,还简要概述了与建模器件相关的性能指标。
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引用次数: 0
Mechanism of Threshold Voltage Instability in Double Gate α-IGZO Nanosheet TFT Under Bias and Temperature Stress 偏置和温度应力下双栅α-IGZO 纳米片 TFT 的阈值电压不稳定性机理
IF 2 3区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-03-29 DOI: 10.1109/JEDS.2024.3406676
Muhammad Aslam;Shu-Wei Chang;Yi-Ho Chen;Yao-Jen Lee;Yiming Li;Wen-Hsi Lee
ABSTRACT Amorphous indium gallium zinc oxide (a-IGZO)-based thin film transistors (TFTs) are increasingly becoming popular because of their potential in futuristic applications, including CMOS technology. Given the demand for CMOS-compatible, ultra-scaled, reliable, and high-performing devices, we fabricate and analyze scaled-channel a-IGZO-TFTs with an optimal double-gate structure, a thin nanosheet-based channel, and an effective high- $kappa$ dielectric namely HfO2. The reliably reported double gate IGZO nanosheet TFTs (DG-IGZO-NS-TFTs) are tested under positive and negative bias stress at variant temperatures, and the resulting modulations are analyzed critically. The reported DG-IGZO-NSTFTs exhibit a negative side threshold voltage shift ( $Delta$ Vth) accompanied by an increase in Ion/Ion(0) under negative bias temperature stress (NBTS) at elevated temperatures, which indicates the presence of additional charges. An anomalous negative side shifting of the Vth is observed under positive bias temperature stress (PBTS), where diffused hydrogen atoms are identified as introducing excess n-type carriers into the channel and causing the observed $Delta$ Vth. The spectroscopic analysis is performed to establish evidence for the assumed mechanisms, and the role of individual gates is investigated in the context of performance variance under temperature-bias stress. Moreover, the partial reversibility of the stress-induced degradation is experimentally established and methodically discussed. Overall, the reported results offer a comprehensive understanding of scaled-channel DG-NS-IGZO-TFTs, which help shape performance-enhancement strategies, control degradation mechanisms, and define appropriate application scenarios.
摘要 基于非晶铟镓锌氧化物(a-IGZO)的薄膜晶体管(TFT)因其在未来应用(包括 CMOS 技术)中的潜力而越来越受欢迎。鉴于对 CMOS 兼容型、超大规模、可靠和高性能器件的需求,我们制造并分析了具有最佳双栅结构、基于纳米薄片的薄沟道和有效的高 $/kappa$ 介质(即 HfO2)的超大规模沟道 a-IGZO-TFT 。在不同温度下的正负偏压应力条件下测试了可靠报道的双栅极 IGZO 纳米片 TFT(DG-IGZO-NS-TFT),并对由此产生的调制进行了批判性分析。所报告的 DG-IGZO-NSTFT 在高温负偏压温度应力 (NBTS) 下表现出负侧阈值电压偏移($Delta$ Vth),同时伴随着 Ion/Ion(0) 的增加,这表明存在额外的电荷。在正偏压温度应力(PBTS)下,Vth 出现异常的负侧移,扩散的氢原子被认为是将过量的 n 型载流子引入沟道并导致观察到的 $Delta$ Vth。光谱分析为假定机制提供了证据,并结合温度偏置应力下的性能差异研究了单个栅极的作用。此外,还通过实验确定并讨论了应力诱导退化的部分可逆性。总之,所报告的结果提供了对缩放沟道 DG-NS-IGZO-TFT 的全面理解,有助于制定性能增强策略、控制退化机制和定义适当的应用场景。
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引用次数: 0
Efficient Quantum Dot Light-Emitting Diodes With DAA Doped Electron Transport Layer 具有 DAA 掺杂电子传输层的高效量子点发光二极管
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-03-28 DOI: 10.1109/JEDS.2024.3382874
Haomin Chen;Qunying Zeng;Yangbin Zhu;Tuo Wu;Yijie Fan;Tailiang Guo;Hailong Hu;Fushan Li
Zinc oxidenanoparticles (ZnO NPs) is widely used as electron transport layer material in quantum dot light-emitting diodes (QLED) due to its high carrier mobility, unique photoelectric properties and good stability. However, because ZnO has higher electron mobility than organic hole transport materials, the carrier transport is unbalanced. In addition, ZnO NPs has many surface defects, which is easy to capture electrons or holes, increasing the probability of non-radiative recombination. To solve these problems, we carefully selected an organic compound diallylamine (DAA) doping method to modify the surface of ZnO. DAA is found to not only reduce the quenching at the interface between ZnO and QD, but also regulate the energy level position to promote the carrier injection balance of QLED devices. Compared with control ZnO QLED, the external quantum efficiency (EQE) of the red QLED with DAA-modified ZnO NPs is significantly improved, the peakEQE of the devices increased by 21% from 18.8% to 23.6%. respectively. It is a simple and economical solution for manufacturing high-performance QLED.
氧化锌纳米粒子(ZnO NPs)因其高载流子迁移率、独特的光电特性和良好的稳定性,被广泛用作量子点发光二极管(QLED)的电子传输层材料。然而,由于氧化锌的电子迁移率高于有机空穴传输材料,因此载流子传输不平衡。此外,ZnO NPs 表面缺陷多,容易捕获电子或空穴,增加了非辐射重组的概率。为了解决这些问题,我们精心选择了一种有机化合物二烯丙基胺(DAA)掺杂法来修饰氧化锌表面。研究发现,DAA 不仅能减少 ZnO 和 QD 之间界面的淬灭,还能调节能级位置,促进 QLED 器件的载流子注入平衡。与对照 ZnO QLED 相比,使用 DAA 修饰 ZnO NPs 的红色 QLED 的外部量子效率(EQE)显著提高,器件的峰值 EQE 分别从 18.8% 提高到 23.6%,提高了 21%。这是制造高性能 QLED 的一种简单而经济的解决方案。
{"title":"Efficient Quantum Dot Light-Emitting Diodes With DAA Doped Electron Transport Layer","authors":"Haomin Chen;Qunying Zeng;Yangbin Zhu;Tuo Wu;Yijie Fan;Tailiang Guo;Hailong Hu;Fushan Li","doi":"10.1109/JEDS.2024.3382874","DOIUrl":"10.1109/JEDS.2024.3382874","url":null,"abstract":"Zinc oxidenanoparticles (ZnO NPs) is widely used as electron transport layer material in quantum dot light-emitting diodes (QLED) due to its high carrier mobility, unique photoelectric properties and good stability. However, because ZnO has higher electron mobility than organic hole transport materials, the carrier transport is unbalanced. In addition, ZnO NPs has many surface defects, which is easy to capture electrons or holes, increasing the probability of non-radiative recombination. To solve these problems, we carefully selected an organic compound diallylamine (DAA) doping method to modify the surface of ZnO. DAA is found to not only reduce the quenching at the interface between ZnO and QD, but also regulate the energy level position to promote the carrier injection balance of QLED devices. Compared with control ZnO QLED, the external quantum efficiency (EQE) of the red QLED with DAA-modified ZnO NPs is significantly improved, the peakEQE of the devices increased by 21% from 18.8% to 23.6%. respectively. It is a simple and economical solution for manufacturing high-performance QLED.","PeriodicalId":13210,"journal":{"name":"IEEE Journal of the Electron Devices Society","volume":null,"pages":null},"PeriodicalIF":2.3,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ieeexplore.ieee.org/stamp/stamp.jsp?tp=&arnumber=10485228","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140324058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improvement of AlGaN/GaN HEMT Noise Figure Using Thick Cu Metallization for Satellite Communication Applications 利用厚铜金属化技术改善 AlGaN/GaN HEMT 噪声图,用于卫星通信应用
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-03-22 DOI: 10.1109/JEDS.2024.3381030
Howie Tseng;Yueh-Chin Lin;Chieh Cheng;Po-Wei Chen;Heng-Tung Hsu;Yi-Fan Tsao;Edward Yi Chang
In this study, AlGaN/GaN high-electron-mobility-transistor (HEMT) with thick Cu metallization is investigated, and the Radio Frequency (RF) performance and the reliability are analyzed. By applying thick Cu metallization of $6.0 ~mu text{m}$ as interconnect, the cut-off frequency (fT), the maximum oscillation frequency (fmax), and the power performance can be improved. Besides, the thick-Cu-metallized device exhibits reduced minimum noise figure (NFmin) of 0.7, 1.0, 2.2 and 2.8 dB at 12, 14, 28 and 38 GHz, respectively, which can be attributed to the reduction of the source and drain resistance caused by thick Cu metallization. Furthermore, for stress test under high drain-to-source voltage (VDS) and high temperature, the proposed device exhibits good stability. The results show that the thick Cu metallization technology has great potential to be applied in satellite communication system.
本研究对具有厚铜金属化层的 AlGaN/GaN 高电子迁移率晶体管 (HEMT) 进行了研究,并分析了其射频 (RF) 性能和可靠性。通过使用 6.0 ~mu text{m}$的厚铜金属化作为互连,可以提高截止频率(fT)、最大振荡频率(fmax)和功率性能。此外,厚铜金属化器件在 12、14、28 和 38 GHz 频率下的最小噪声系数(NFmin)分别降低了 0.7、1.0、2.2 和 2.8 dB,这可归因于厚铜金属化降低了源电阻和漏电阻。此外,在高漏极至源极电压(VDS)和高温条件下进行应力测试时,所提出的器件表现出良好的稳定性。结果表明,厚铜金属化技术在卫星通信系统中具有巨大的应用潜力。
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引用次数: 0
Bulk Carrier Contaminations and Their Effects on MOSFETs Under Energy Harvesting Systems 散装载体污染及其对能量收集系统下 MOSFET 的影响
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-03-21 DOI: 10.1109/JEDS.2024.3403649
Yuta Watanabe;Takaya Sugiura;Nobuhiko Nakano
Energy harvesters, such as photovoltaic cells, generate carriers in the deep substrate regions; these carriers can affect MOSFETs and deteriorate their performance or even cause malfunctioning. In this study, we discussed the effects of bulk carrier contamination on integrated MOSFETs in the context of energy-harvesting devices. We confirmed that the close integration of MOSFET circuits in a photovoltaic cell causes malfunctioning under strong light illumination. Moreover, numerical simulations revealed that PMOS is highly sensitive to carrier contamination as a forward pn-junction from the bulk-side storage carriers into the NWell region. Furthermore, increasing the distance from the illumination window was not an effective countermeasure, and alternative methods, such as the silicon-on-insulator substrate, n−-substrate, or NMOS logic, should be implemented for such large-scale integration.
能量收集器(如光伏电池)会在深层衬底区域产生载流子;这些载流子会影响 MOSFET,使其性能下降,甚至导致故障。在这项研究中,我们以能量收集器件为背景,讨论了块状载流子污染对集成 MOSFET 的影响。我们证实,光伏电池中 MOSFET 电路的紧密集成会在强光照射下导致故障。此外,数值模拟显示,PMOS 对载流子污染高度敏感,因为它是从体侧存储载流子进入 NWell 区域的正向 pn 结。此外,增大与照明窗口的距离并不是有效的应对措施,在进行此类大规模集成时应采用其他方法,如硅绝缘体衬底、n-衬底或 NMOS 逻辑。
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引用次数: 0
Machine Learning-Based Modeling of Hot Carrier Injection in 40 nm CMOS Transistors 基于机器学习的 40 纳米 CMOS 晶体管热载流子注入建模
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-03-21 DOI: 10.1109/JEDS.2024.3380572
Xhesila Xhafa;Ali Doğuş Güngördü;Mustafa Berke Yelten
This paper presents a machine-learning-based approach for the degradation modeling of hot carrier injection in metal-oxide-semiconductor field-effect transistors (MOSFETs). Stress measurement data have been employed at various stress conditions of both n- and p-MOSFETs with different channel geometries. Gaussian process regression algorithm is preferred to model the post-stress characteristics of the drain-source current, the threshold voltage, and the drain-source conductance. The model outcomes have been compared with the actual measurements, and the accuracy of the generated models has been demonstrated across the test data by providing the appropriate statistics metrics. Finally, case studies of degradation estimation have been considered involving the usage of machine-learning-based models on transistors with different channel geometries or subjected to distinct stress conditions. The outcomes of this analysis reveal that the established models yield high accuracy in such contexts.
本文介绍了一种基于机器学习的方法,用于对金属氧化物半导体场效应晶体管(MOSFET)中的热载流子注入进行降解建模。采用了具有不同沟道几何形状的 n 型和 p 型 MOSFET 在各种应力条件下的应力测量数据。采用高斯过程回归算法对漏极-源极电流、阈值电压和漏极-源极电导的应力后特性进行建模。模型结果与实际测量结果进行了比较,并通过提供适当的统计指标证明了所生成模型在整个测试数据中的准确性。最后,还考虑了退化估计的案例研究,包括在具有不同沟道几何结构或处于不同应力条件下的晶体管上使用基于机器学习的模型。分析结果表明,已建立的模型在这种情况下具有很高的准确性。
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引用次数: 0
Effects of Ion Channeling and Co-Implants on Ion Ranges and Damage in Si: Studies With PL, SRP, SIMS and MC Models 离子通道和共植入物对硅中离子范围和损伤的影响:利用 PL、SRP、SIMS 和 MC 模型进行的研究
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-03-19 DOI: 10.1109/JEDS.2024.3379328
Michael I. Current;Takuya Sakaguchi;Yoji Kawasaki;Viktor Samu;Anita Pongracz;Luca Sinko;Árpád Kerekes;Zsolt Durkó
This study uses photoluminescence (PL) and other carrier-recombination sensitive probes in combination with spreading resistance profiling (SRP), SIMS and IMSIL MC-calculations to monitor the ion range and damage levels in highly-channeled and random beam orientation 7.5 MeV B and 10 MeV P and As profiles and various combinations of co-implants with 50 keV Phosphorus implants in Silicon(100). The effects of annealing on the 10 MeV profiles showed the strong shifts in PL data from implant damage in the as-implanted and annealed samples. Curious “intermittencies” were seen in the PL signals from MeV implant defect centers.
本研究使用光致发光(PL)和其他载流子重配敏感探针,结合扩散电阻曲线(SRP)、SIMS 和 IMSIL MC 计算,监测硅(100)中高通道和随机束向 7.5 MeV B 和 10 MeV P 和 As 曲线中的离子范围和损伤程度,以及 50 keV 磷植入物的各种共植入物组合。退火对 10 MeV 曲线的影响表明,在植入和退火样品中,由于植入损伤,PL 数据发生了强烈偏移。在来自 MeV 植入缺陷中心的 PL 信号中出现了奇怪的 "间歇 "现象。
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引用次数: 0
Conductivity Enhancement of PVD-WS2 Films Using Cl2-Plasma Treatment Followed by Sulfur-Vapor Annealing 利用 Cl2 等离子处理和硫气退火增强 PVD-WS2 薄膜的导电性
IF 2.3 3区 工程技术 Q2 Engineering Pub Date : 2024-03-18 DOI: 10.1109/JEDS.2024.3378745
Keita Kurohara;Shinya Imai;Takuya Hamada;Tetsuya Tatsumi;Shigetaka Tomiya;Kuniyuki Kakushima;Kazuo Tsutsui;Hitoshi Wakabayashi
The conductivity of tungsten disulfide (WS2) films using sputtering, which is a physical vapor deposition (PVD), was enhanced using a chlorine (Cl2)-plasma treatment and sulfur-vapor annealing (SVA). For WS2 films to be used in thermoelectric devices, its carrier concentration must be controlled. Therefore, we exposed WS2 films to Cl2-plasma as a doping method. In addition, SVA was performed to improve the crystallinity of the film and potentially introduce activating dopants. Consequently, the conductivity of the Cl2-plasma-treated PVD-WS2 films (0.440 S/m) more than doubled compared with that of an untreated PVD-WS2 film (0.201 S/m). The doping type in this experiment is considered to be n-type on the basis of a positive peak shift observed in the X-ray photoelectron spectra.
二硫化钨(WS2)薄膜是一种物理气相沉积(PVD)技术,采用溅射法(即物理气相沉积),通过氯(Cl2)等离子体处理和硫气退火(SVA)增强了其导电性。要将 WS2 薄膜用于热电设备,必须控制其载流子浓度。因此,我们将 WS2 薄膜暴露在 Cl2-等离子体中,作为一种掺杂方法。此外,还进行了 SVA 处理,以提高薄膜的结晶度,并可能引入活化掺杂剂。结果,经 Cl2- 等离子体处理的 PVD-WS2 薄膜的电导率(0.440 S/m)比未经处理的 PVD-WS2 薄膜的电导率(0.201 S/m)提高了一倍多。根据 X 射线光电子能谱中观察到的正峰值移动,本实验中的掺杂类型被认为是 n 型。
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引用次数: 0
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IEEE Journal of the Electron Devices Society
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