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Phenotypic measurements of broadleaf tree seedlings based on improved UNet and Pix2PixHD 基于改进的 UNet 和 Pix2PixHD 对阔叶树苗进行表型测量
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-21 DOI: 10.1016/j.indcrop.2024.119880
The nondestructive, high-precision measurement of the phenotypic parameters of broadleaf tree seedlings is critical for seedling growth monitoring. In this paper, we take broadleaf tree seedlings as the research object and design a complete set of equipment, models, and methods ranging from automatic tree seedling image acquisition to seedling image segmentation, branch and leaf separation, image restoration of occluded branches, and final plant phenotype measurement. The experimental results show that the mean intersection over union (mIoU) of the proposed segmentation model for tree seedling branches and leaves reaches 87.95 and 98.37 %, respectively, and that the mean pixel accuracy (mPA) reaches 93.16 and 99.24 %, respectively. The structural similarity index (SSIM) and peak signal-to-noise ratio (PSNR) of branch restoration reach 98.5 % and 41.48 dB, respectively. By calculating the phenotypic parameters of tree seedling, we can keep the mean average precision error (MAPE) of the tree seedling height, ground diameter, canopy width, and canopy layer within 6 %. The results indicate that the proposed methods can more accurately extract the branch and leaf regions of a tree seedling and recover the missing parts of branches and trunks, providing a new nondestructive method of plant phenotypic measurement for broadleaf tree seedling cultivation and growth monitoring.
无损、高精度测量阔叶树幼苗的表型参数对于幼苗生长监测至关重要。本文以阔叶树苗为研究对象,设计了一套完整的设备、模型和方法,从自动树苗图像采集到树苗图像分割、枝叶分离、遮挡枝条的图像复原以及最终的植物表型测量。实验结果表明,所提出的树苗枝叶分割模型的平均交集大于结合率(mIoU)分别达到 87.95 % 和 98.37 %,平均像素精度(mPA)分别达到 93.16 % 和 99.24 %。树枝复原的结构相似性指数(SSIM)和峰值信噪比(PSNR)分别达到 98.5 % 和 41.48 dB。通过计算树苗的表型参数,我们可以将树苗高度、地径、冠幅和冠层的平均精度误差(MAPE)控制在 6% 以内。结果表明,所提出的方法能更准确地提取树苗的枝叶区域,恢复缺失的枝干部分,为阔叶树苗培育和生长监测提供了一种新的无损植物表型测量方法。
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引用次数: 0
Genome-wide identification of isopentenyl transferase genes in cotton and their roles in regulating vegetative branching after topping 棉花中异戊烯基转移酶基因的全基因组鉴定及其在调控打顶后无性系分枝中的作用
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-21 DOI: 10.1016/j.indcrop.2024.119853
The promotion of vegetative branching in plants after topping has been observed without a clear understanding of the underlying mechanism. This study aimed to investigate the role of isopentenyl transferase (IPT) and cytokinins in the regulation of vegetative branching in cotton (Gossypium hirsutum L.), hypothesizing that they play key roles in this process. Plant topping was implemented at peak flowering stage in field-grown cotton, and seedcotton yield, yield components, vegetative branching, fruiting, and cytokinin levels were examined over two consecutive years. The results showed that plant topping significantly enhanced the growth and development of vegetative branches, as evidenced by increased biomass, leaf area, and fruiting of vegetative branches, along with an accumulation of cytokinin accumulation at the tips of vegetative branches. This led to a 10.3 % rise in boll density and an 11.4 % increase in seedcotton yield compared with the non-topped control. The analysis of RNA-seq and qRT-PCR data revealed significant differences in the expression patterns of IPT genes, suggesting their importance in regulating the growth and development of vegetative branches. Furthermore, examing the IPT gene families in diploid and tetraploid cotton species identified a total of 8, 8, 16, and 16 IPT genes, categorized into 6 groups. Prediction of cis-acting elements of GhIPT gene family promoters and analysis of their expression profiles demonstrated the involvement of GhIPT genes in multiple plant growth pathways with specific spatio-temporal expression. The findings underline that plant topping enhances cytokinins accumulation at vegetative branch tips by up-regulating IPT genes, leading to increased vegetative branching, fruiting, and ultimately, seedcotton yield. This study provides valuable insights into enhancing cotton yield formation through the regulation of growth and development of vegetative branches by GhIPTs and offers a crucial reference for further investigations into the functions of IPT genes.
人们一直在观察打顶后植物无性分枝的促进作用,但对其内在机理并不清楚。本研究旨在探讨异戊烯基转移酶(IPT)和细胞分裂素在棉花(Gossypium hirsutum L.)无性分枝调控过程中的作用,假设它们在这一过程中发挥关键作用。在大田种植的棉花盛花期进行打顶,连续两年对籽棉产量、产量成分、无性系分枝、结实和细胞分裂素水平进行了研究。结果表明,植株打顶能显著促进无性系枝条的生长发育,表现在无性系枝条的生物量、叶面积和结果量增加,以及无性系枝条顶端的细胞分裂素积累。与不打顶的对照组相比,棉铃密度增加了 10.3%,籽棉产量增加了 11.4%。对 RNA-seq 和 qRT-PCR 数据的分析表明,IPT 基因的表达模式存在显著差异,这表明它们在调控无性系枝条的生长和发育方面具有重要作用。此外,通过研究二倍体和四倍体棉花的 IPT 基因家族,共发现了 8、8、16 和 16 个 IPT 基因,分为 6 组。对 GhIPT 基因家族启动子顺式作用元件的预测及其表达谱的分析表明,GhIPT 基因参与了多种植物生长途径,并具有特定的时空表达。研究结果强调,植株顶端通过上调 IPT 基因来增强细胞分裂素在无性系枝梢的积累,从而提高无性系分枝、结实率,并最终提高籽棉产量。这项研究为通过 GhIPTs 调控无性系枝条的生长发育来提高棉花产量提供了宝贵的见解,并为进一步研究 IPT 基因的功能提供了重要参考。
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引用次数: 0
Nanostructured cotton fabrics for personal passive cooling with enhanced thermal conduction and energy saving 用于个人被动冷却的纳米结构棉织物,可增强热传导并节约能源
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-20 DOI: 10.1016/j.indcrop.2024.119884
Textiles with passive cooling capabilities offer an efficient way to optimize personal thermal regulation. However, the simultaneous achievement of passive cooling, durability, and comfort in a single fabric poses a significant challenge. Herein, an ingenious cotton fabric that can be fabricated through a facile dip-dry technique is proposed. Carboxylated cellulose nanocrystals are grafted onto the fiber surfaces, and then covalently linked with hydroxylated boron nitride nanosheets to form a nanostructured coating. The resulting fabric demonstrates a remarkable enhancement of 69 % in its thermal conductivity and an impressive 56 % rise in in-plane thermal diffusivity, when compared to the pristine cotton fabric. This has the potential to raise the comfort setpoint temperature of indoor cooling equipment by 2.1 °C, thereby reducing cooling energy consumption by 22.2 %, while significantly enhancing the perceived cooling effect on the skin. Under the direct sunlight, the nanostructured fabric cools the skin by 1.21 °C below ambient temperature, preventing an excessive increase of 8.2 °C in skin temperature. Moreover, the resulting fabric maintains comparable levels of comfort and wearability as that of the original cotton fabric. This study presents an innovative strategy towards the development of passive cooling textiles.
具有被动冷却功能的纺织品为优化个人热调节提供了有效途径。然而,如何在单一织物中同时实现被动降温、耐用性和舒适性是一项重大挑战。本文提出了一种巧妙的棉织物,可通过简单的浸干技术制成。羧基化纤维素纳米晶体被接枝到纤维表面,然后与羟基化氮化硼纳米片共价连接,形成纳米结构涂层。与原始棉织物相比,这种织物的导热率显著提高了 69%,平面内热扩散率提高了 56%,令人印象深刻。这有可能将室内制冷设备的舒适设定温度提高 2.1 °C,从而将制冷能耗降低 22.2%,同时显著增强皮肤的冷却效果。在阳光直射下,纳米结构织物能使皮肤温度比环境温度低 1.21 °C,防止皮肤温度过度升高 8.2 °C。此外,纳米结构织物还能保持与原棉织物相当的舒适度和耐磨性。这项研究为被动冷却纺织品的开发提供了一种创新战略。
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引用次数: 0
Spent mushroom substrate of Ganoderma lucidum developed nanocatalyst (CSA/BaO@K2CO3) for efficient biodiesel synthesis from blended oil feedstock 灵芝废菌基质开发的纳米催化剂(CSA/BaO@K2CO3)用于从混合油原料中高效合成生物柴油
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-20 DOI: 10.1016/j.indcrop.2024.119871
The dietary and biological advantages of mushrooms are driving a global boom in the mushroom industry. The widespread production of mushrooms corresponds to disposal challenge, generating a significant volume of biowaste known as spent mushroom substrate. Their use as a catalyst can assist in lowering the expense of producing catalyst and the issue related to their disposal. Hence, the current study focused on developing a nanocatalyst for biodiesel synthesis from a blend of eight different types of oil. The catalyst was synthesized by using spent mushroom substrate (sawdust) of Ganoderma lucidum as the foundation of the catalyst, which was impregnated by BaO and K2CO3 via the wet-impregnation method followed by calcination. The developed nanocatalyst CSA/BaO@K2CO3 (CSA, calcined spent substrate ash) was characterized via various sophisticated methods like XRD (X-ray Diffraction), BET (Brunauer-Emmett-Teller), FT-IR (Fourier Transform Infrared Spectroscopy), FESEM (Field Emission Scanning Electron Microscopy) - EDX (Energy Dispersive Spectroscopy), XPS (X-ray photoelectron spectroscopy), HRTEM (High Resolution Transmission Electron Microscopy), and SAED (Selected Area Electron Diffraction). The HRTEM data showed that the average particle size of CSA/BaO@K2CO3 was 14.368 ± 0.262 nm, which confirmed it as a nanocatalyst. The synthesized catalyst’s catalytic activity was investigated for the transesterification of the blended oil (BO), where the influence of different optimum parameters was investigated. The catalyst consisted of a BET surface area of 16.441 m2 g−1 and resulted in the highest biodiesel yield of 94.36 ± 0.29 % under the optimized reaction conditions of 10 wt% of catalyst load, 9:1 of methanol to oil molar ratio (MTOMR), 65 ℃ of reaction temperature, and 34.67 ± 0.58 min of reaction duration. The biodiesel conversion under the optimized condition was also determined and found to be 95.85 %. The conversion of biodiesel was confirmed using spectroscopic techniques. The reusability test was carried out and found that the catalyst was reusable for up to three cycles. The energy of activation for transesterification using the synthesized catalyst was evaluated to be 83.55 kJ/mol.
蘑菇在饮食和生物方面的优势推动了全球蘑菇产业的蓬勃发展。蘑菇的广泛生产带来了处理难题,产生了大量生物垃圾,即废蘑菇基质。将蘑菇用作催化剂有助于降低生产催化剂的成本,并减少与处置蘑菇相关的问题。因此,目前的研究重点是开发一种纳米催化剂,用于从八种不同类型的油混合中合成生物柴油。催化剂的合成是以灵芝的废蘑菇基质(锯末)为基础,通过湿浸渍法浸渍 BaO 和 K2CO3,然后进行煅烧。所开发的纳米催化剂 CSA/BaO@K2CO3(CSA,煅烧过的废基质灰)通过各种复杂的方法进行了表征,如 XRD(X 射线衍射)、BET(布鲁诺-艾美特-泰勒)、FT-IR(傅立叶变换红外光谱)、FESEM(场发射扫描电子显微镜)、EDX(能量色散光谱)、XPS(X 射线光电子能谱)、HRTEM(高分辨率透射电子显微镜)和 SAED(选区电子衍射)。HRTEM 数据显示 CSA/BaO@K2CO3 的平均粒径为 14.368 ± 0.262 nm,这证实了它是一种纳米催化剂。研究了合成催化剂在混合油(BO)酯交换反应中的催化活性,并考察了不同最佳参数的影响。该催化剂的 BET 表面积为 16.441 m2 g-1,在催化剂载量为 10 wt%、甲醇与油的摩尔比为 9:1、反应温度为 65 ℃、反应时间为 34.67 ± 0.58 min 的优化反应条件下,生物柴油产率最高,为 94.36 ± 0.29 %。在优化条件下测定的生物柴油转化率为 95.85%。生物柴油的转化率通过光谱技术得到了确认。进行了可重复使用性测试,发现催化剂可重复使用三个循环。经评估,使用合成催化剂进行酯交换反应的活化能为 83.55 kJ/mol。
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引用次数: 0
Deciphering the stability of Eryngium foetidum L. through AMMI and Eberhart and Russell model for herbage and essential oil yield 通过 AMMI 以及艾伯哈特和拉塞尔草本植物和精油产量模型,解读白前胡的稳定性
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-19 DOI: 10.1016/j.indcrop.2024.119848
Coriander is an important herb with prodigious application as a flavoring agent, including in the food, beverage, and pharmaceutical industries. Considering the short-lived span of commonly found coriander, Eryngium foetidum is a first-rate alternative, considering it is perennial with a higher shelf life. Taking into account the emerging global market demand, a stable, high essential oil-yielding variety of E. foetidum is the need of the hour. Considering this, in the present study, thirty-five germplasm (seeds) of E. foetidum, which were collected from different regions of Northeast India, were planted in Randomized Block Design (RBD) in the experimental farm of CSIR-NEIST, Jorhat. All the agronomical and essential oil data were recorded as per standard protocol for two consecutive years (2018, 2019, and 2020). In the selection trial, one high essential oil-rich line was selected and planted at four different locations in NE India during the rabi season. By considering four environments of the genotypes, stability was checked using AMMI and the Eberhart-Russell model for four check varieties along with the identified strain, which was named Jor Lab LC-1. The identified variety was found to be more stable considering both the genotype and the environment interaction than the other genotypes. GC-FID and GC/MS analysis of Jor Lab LC-1 essential oil showed that trans-2-dodecenal (62.34 %) is the main component. Moreover, to the best of our knowledge, this is the first report on stability studies on E. foetidum. Therefore, Jor Lab LC-1 can be considered an elite genotype that has the potential to open up new doors for industrial uses, ranging from pharmaceuticals to agriculture, and can contribute to both conservation and cultivation efforts, ultimately safeguarding this valuable plant species for future generations.
芫荽是一种重要的草本植物,作为调味剂在食品、饮料和制药等行业有着广泛的应用。考虑到常见的芫荽生长期较短,多年生的白芫荽(Eryngium foetidum)具有更长的保存期,因此是一种理想的替代品。考虑到新兴的全球市场需求,稳定、高产精油的 E. foetidum 品种是当务之急。有鉴于此,本研究在乔哈特 CSIR-NEIST 实验农场采用随机区组设计(RBD)种植了从印度东北部不同地区收集的 35 个 E. foetidum 种质(种子)。所有农艺和精油数据均按标准协议记录,连续两年(2018 年、2019 年和 2020 年)。在选育试验中,选出了一个富含精油的高产品系,并在蕾季期间在印度东北部的四个不同地点进行了种植。通过考虑基因型的四种环境,使用 AMMI 和 Eberhart-Russell 模型检测了四个对照品种和已鉴定品系(命名为 Jor Lab LC-1)的稳定性。结果发现,考虑到基因型与环境的相互作用,所确定的品种比其他基因型更稳定。Jor Lab LC-1 精油的 GC-FID 和 GC/MS 分析表明,主要成分是反式-2-十二烯醛(62.34%)。此外,据我们所知,这是第一份关于 E. foetidum 的稳定性研究报告。因此,Jor Lab LC-1 可以被视为一种精英基因型,它有潜力为工业用途(从制药到农业)打开新的大门,并能为保护和栽培工作做出贡献,最终为子孙后代保护这一珍贵的植物物种。
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引用次数: 0
Research progress in Ramie fiber extraction: Degumming method, working mechanism, and fiber performance 苎麻纤维提取的研究进展:脱胶方法、工作机理和纤维性能
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-19 DOI: 10.1016/j.indcrop.2024.119876
Ramie fiber, recognized as king of natural fibers, is one of the strongest and longest natural fiber. The fabric made of ramie fibers exhibits the compelling features of being crisp and cool, fast moisture absorption and heat dissipation, as well as favorable air permeability and antibacterial. Since cellulose fibers in raw ramie are stuck tightly by gummy substances consisting of pectin, hemicellulose and lignin, a degumming process is necessary to separate these gummy materials prior to the downstream spinning process. High purified ramie cellulose fibers are supposed to be extracted with high degumming efficiency. However, currently most commonly adopted degumming methods show some inevitable defects, such as long degumming process, high operating cost, serious environmental pollution, and uncontrollable fiber quality. These mentioned issues should be properly addressed in future research work to promote the advancement of ramie fiber industry. The development of green, ecological, environmentally friendly, clean and efficient ramie degumming methods has attracted more and more attention. In this review, the methodologies of degumming processing, including mechanical, chemical, biological and combined degumming methods, are summarized systematically and the resultant properties are also covered. In addition, some research conclusions will be drawn by analyzing the latest process in this field, as well as the views on the remaining challenges and some scientific perspectives or outlook will be finally given for potential readers.
苎麻纤维是公认的天然纤维之王,是强度最高、长度最长的天然纤维之一。用苎麻纤维制成的织物具有清爽凉快、吸湿散热快、透气性好、抗菌性强等显著特点。由于原料苎麻中的纤维素纤维会被果胶、半纤维素和木质素等胶状物质紧紧粘住,因此在下游纺纱工艺之前,必须采用脱胶工艺将这些胶状物质分离出来。高纯度的苎麻纤维素纤维应该以较高的脱胶效率提取出来。然而,目前普遍采用的脱胶方法存在一些不可避免的缺陷,如脱胶过程长、运行成本高、环境污染严重、纤维质量不可控等。这些问题都需要在今后的研究工作中妥善解决,以促进苎麻纤维产业的发展。开发绿色、生态、环保、清洁、高效的苎麻脱胶方法已引起越来越多的关注。本综述系统地总结了脱胶处理的方法,包括机械脱胶法、化学脱胶法、生物脱胶法和联合脱胶法等,并对脱胶后的性能进行了阐述。此外,还将通过分析该领域的最新进展得出一些研究结论,并对尚存的挑战发表看法,最后为潜在读者提供一些科学观点或展望。
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引用次数: 0
Experimental and kinetic analysis of Bambusa tulda pyrolysis in carbon dioxide and nitrogen atmosphere 二氧化碳和氮气环境下簕杜鹃热解的实验和动力学分析
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-19 DOI: 10.1016/j.indcrop.2024.119806
<div><div>Experiments were conducted using a fixed-bed pyrolysis system and a thermo-gravimetric analyzer to investigate the effect of <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> and <span><math><mrow><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span> atmosphere on thermal degradation, physicochemical, structural, and elemental characteristics of <em>Bambusa tulda</em> and its char. A kinetic study was conducted at four different heating rates to determine the activation energy, pre-exponential factor, and kinetic model. The results indicate significant weight loss during the second stage of pyrolysis, primarily due to the thermal degradation of low molecular weight compounds such as hemicelluloses, cellulose, and a small fraction of lignin. The <span><math><mrow><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span>atmosphere leads to more significant weight loss compared to<span><math><mrow><mspace></mspace><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></mrow></math></span> atmosphere, with an average weight loss of about 80 % under <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn><mspace></mspace></mrow></msub></math></span> and approximately 95 % under <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>. This difference is likely due to specific gas-phase reactions and the consumption of carbon fuel induced by <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>. Iso-conversional methods determined that the average activation energy of <em>Bambusa tulda</em> in the presence of <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> was 160.05 kJ mol<sup>−1</sup>, whereas under<span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>, it was 105.51 kJ mol<sup>−1</sup>. The kinetic mechanism of <em>B. Tulda</em> for both the atmosphere was validated using Cardio’s master plots. The data points for activation energy and pre-exponential factors show a strong linear fit across incremental conversion fractions, indicating the presence of the kinetic compensation effect. Biochar produced in <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> atmosphere (BCC) exhibited larger pores than biochar generated in <span><math><mrow><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span> atmosphere (BCN). BCN has a porous, organized structure, while BCC displays pores with a channel-like structure due to the development of an aromatic structure. The carbon content and calorific value of <em>Bambusa tulda</em> char are noteworthy, with values of 81.23 % and 25.36 MJ kg<sup>−1</sup> for N<sub>2</sub> atmosphere, and 85.16 % and 29.44 MJ kg<sup>−1</sup> for <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn
使用固定床热解系统和热重分析仪进行了实验,以研究 N2 和 CO2 气氛对簕杜鹃及其焦炭的热降解、物理化学、结构和元素特性的影响。在四种不同的加热速率下进行了动力学研究,以确定活化能、预指数和动力学模型。结果表明,在热解的第二阶段,主要由于低分子量化合物(如半纤维素、纤维素和一小部分木质素)的热降解,重量损失明显。与 N2 气氛相比,CO2 气氛导致的重量损失更为显著,N2 气氛下的平均重量损失约为 80%,而 CO2 气氛下的平均重量损失约为 95%。这种差异可能是由于二氧化碳引起的特定气相反应和碳燃料消耗造成的。等转换法确定,在 N2 存在下,图尔达簕竹的平均活化能为 160.05 kJ mol-1,而在 CO2 下,平均活化能为 105.51 kJ mol-1。使用卡迪奥主图验证了两种气氛下簕杜鹃的动力学机制。活化能和前指数因子的数据点在各个增量转化分数上显示出很强的线性拟合,表明存在动力学补偿效应。与在氮气环境中生成的生物炭(BCN)相比,在二氧化碳环境中生成的生物炭(BCC)孔隙更大。BCN 具有多孔、有序的结构,而 BCC 则由于芳香结构的形成而显示出具有通道状结构的孔隙。簕杜鹃炭的含碳量和热值值得注意,在氮气环境下分别为 81.23 % 和 25.36 兆焦耳/千克-1,在二氧化碳环境下分别为 85.16 % 和 29.44 兆焦耳/千克-1,这表明其具有作为气化过程原料或化石燃料替代品的潜力。
{"title":"Experimental and kinetic analysis of Bambusa tulda pyrolysis in carbon dioxide and nitrogen atmosphere","authors":"","doi":"10.1016/j.indcrop.2024.119806","DOIUrl":"10.1016/j.indcrop.2024.119806","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Experiments were conducted using a fixed-bed pyrolysis system and a thermo-gravimetric analyzer to investigate the effect of &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; and &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;CO&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; atmosphere on thermal degradation, physicochemical, structural, and elemental characteristics of &lt;em&gt;Bambusa tulda&lt;/em&gt; and its char. A kinetic study was conducted at four different heating rates to determine the activation energy, pre-exponential factor, and kinetic model. The results indicate significant weight loss during the second stage of pyrolysis, primarily due to the thermal degradation of low molecular weight compounds such as hemicelluloses, cellulose, and a small fraction of lignin. The &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;CO&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;atmosphere leads to more significant weight loss compared to&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; atmosphere, with an average weight loss of about 80 % under &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; and approximately 95 % under &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;CO&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;. This difference is likely due to specific gas-phase reactions and the consumption of carbon fuel induced by &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;CO&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;. Iso-conversional methods determined that the average activation energy of &lt;em&gt;Bambusa tulda&lt;/em&gt; in the presence of &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; was 160.05 kJ mol&lt;sup&gt;−1&lt;/sup&gt;, whereas under&lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;CO&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;, it was 105.51 kJ mol&lt;sup&gt;−1&lt;/sup&gt;. The kinetic mechanism of &lt;em&gt;B. Tulda&lt;/em&gt; for both the atmosphere was validated using Cardio’s master plots. The data points for activation energy and pre-exponential factors show a strong linear fit across incremental conversion fractions, indicating the presence of the kinetic compensation effect. Biochar produced in &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;CO&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; atmosphere (BCC) exhibited larger pores than biochar generated in &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; atmosphere (BCN). BCN has a porous, organized structure, while BCC displays pores with a channel-like structure due to the development of an aromatic structure. The carbon content and calorific value of &lt;em&gt;Bambusa tulda&lt;/em&gt; char are noteworthy, with values of 81.23 % and 25.36 MJ kg&lt;sup&gt;−1&lt;/sup&gt; for N&lt;sub&gt;2&lt;/sub&gt; atmosphere, and 85.16 % and 29.44 MJ kg&lt;sup&gt;−1&lt;/sup&gt; for &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;CO&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142534842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical performance of windmill palm reinforced textile fabrics and their sustainable composite 风车棕榈增强织物及其可持续复合材料的机械性能
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-19 DOI: 10.1016/j.indcrop.2024.119776
Windmill palm fibers, as a new type of cellulose fiber, have several advantages such as being environmentally friendly, lightweight, and having excellent mechanical properties. In this paper, different types of windmill palm fibers were used to prepare fabrics. Then, the fabrics were used to prepare palm fabric reinforced composites. The structure and mechanical properties of the raw, alkalized, as well as bleached windmill palm fibers, fabrics, and composites were characterized. The results showed that the windmill palm fibers with removed hemicellulose had the highest mechanical performance, with tensile strength and Young's modulus being 252.72±60.42 MPa and 1.07±0.32 GPa. At the same time, the palm reinforced composites with alkalized windmill palm fiber were endowed with higher mechanical properties with a tensile strength of 69.89±6.30 MPa. The bleached windmill palm fiber exhibited the highest wear resistance. While the alkalized windmill palm fiber had a well UV resistant property. Both alkali treatment and bleach treatment had a positive effect on enhancing the mechanical properties of the palm reinforced composites. The palm reinforced composites are partially degradable, which plays a positive role in promoting carbon neutrality.
风车棕榈纤维作为一种新型纤维素纤维,具有环保、轻质、机械性能优异等优点。本文使用不同类型的风车棕榈纤维制备织物。然后,用这些织物制备棕榈织物增强复合材料。对未加工、碱化以及漂白的风车棕榈纤维、织物和复合材料的结构和机械性能进行了表征。结果表明,去除半纤维素的风车棕榈纤维具有最高的机械性能,拉伸强度和杨氏模量分别为 252.72±60.42 MPa 和 1.07±0.32 GPa。同时,碱化风车棕榈纤维的棕榈增强复合材料具有更高的力学性能,抗拉强度为 69.89±6.30 兆帕。漂白风车棕榈纤维表现出最高的耐磨性。而碱化风车棕榈纤维具有良好的抗紫外线性能。碱处理和漂白处理对提高棕榈增强复合材料的机械性能都有积极作用。棕榈增强复合材料可部分降解,这对促进碳中和起到了积极作用。
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引用次数: 0
HaVTE1 confers ABA insensitivity by blocking the ABA signaling pathway in sunflowers (Helianthus annuus L.) HaVTE1 通过阻断向日葵(Helianthus annuus L.)中的 ABA 信号通路赋予其 ABA 不敏感性
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-19 DOI: 10.1016/j.indcrop.2024.119850
Sunflower (Helianthus annuus) is the fourth major oilseed crop in the world, with remarkable tolerance in saline-alkali soils. The VTE1 gene encodes tocopherol cyclase (TC), an enzyme pivotal in the biosynthesis of both vitamin E and vitamin K1. Despite its integral role in the synthesis of these crucial vitamins, the functional analysis of VTE1 under abiotic stress in sunflowers remains scant. In the present investigation, a structural analysis of the VTE1 protein across 155 diverse species revealed a highly conserved evolutionary trace. The expression profiling of HaVTE1 depicted that the HaVTE1 was responsive to the ABA pathway. Transgenic results confirmed that overexpression of HaVTE1 in Arabidopsis and sunflower showed decreased sensitivity to ABA while knocking-down in sunflower exhibited the opposite phenotype. Furthermore, biochemical experiments displayed that HaVTE1 decreases ABA sensitivity by scavenging superoxide contents. Concurrently, the transcriptome analysis revealed that HaVTE1 blocked the upstream of the ABA signaling cascade, which was further confirmed by luciferase assay, resulting in reduced sensitivity to ABA of HaVTE1 overexpression plants. The findings shed light on a theoretical basis for the sunflower responses to ABA signaling and abiotic stresses.
向日葵(Helianthus annuus)是世界第四大油料作物,对盐碱土具有显著的耐受性。VTE1 基因编码生育酚环化酶(TC),这是一种在维生素 E 和维生素 K1 的生物合成中起关键作用的酶。尽管 VTE1 在这些重要维生素的合成过程中发挥着不可或缺的作用,但对向日葵非生物胁迫下 VTE1 的功能分析仍然很少。本研究对 155 个不同物种的 VTE1 蛋白进行了结构分析,发现了其高度保守的进化轨迹。对 HaVTE1 的表达谱分析表明,HaVTE1 对 ABA 途径具有响应性。转基因结果证实,在拟南芥和向日葵中过表达 HaVTE1 会降低对 ABA 的敏感性,而在向日葵中敲除 HaVTE1 则表现出相反的表型。此外,生化实验表明,HaVTE1 通过清除超氧化物含量来降低对 ABA 的敏感性。同时,转录组分析表明,HaVTE1 阻断了 ABA 信号级联的上游,这一点在荧光素酶检测中得到了进一步证实,从而导致 HaVTE1 过表达植株对 ABA 的敏感性降低。这些发现为向日葵对 ABA 信号和非生物胁迫的响应提供了理论依据。
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引用次数: 0
A clean deconstruction of steam-exploded corn straw into high purity cellulose nanosheets and well-defined lignin nanotubes 将蒸汽爆破的玉米秸秆清洁解构为高纯度纤维素纳米片和定义明确的木质素纳米管
IF 5.6 1区 农林科学 Q1 AGRICULTURAL ENGINEERING Pub Date : 2024-10-19 DOI: 10.1016/j.indcrop.2024.119765
The efficient and structure-protective isolation of the main components of lignocellulosic biomass remains challenging for value-added utilization. In this study, we used corn straw waste, a vast yet underexplored biomass from agricultural residues, as the raw material to extract high-purity cellulose nanosheets and recycle the lignin components as well-defined lignin nanotubes (LNTs) in a tandem process. The process consisted of a feasible dilute alkali-assisted wet ball milling treatment of steam-exploded corn straw into high-purity cellulose nanosheets and a lignin solution, which was further transferred into LNTs by a molecular assembly method. Purity, morphology, chemical structure, and thermal behavior of high-purity cellulose nanosheets and LNTs were examined. The 98.9 wt% purity of the high-purity cellulose nanosheets was achieved with a crystallinity of 36.9 %, providing a solid foundation for further chemical modification. The LNTs exhibited remarkable antioxidant activity, opening new avenues for the development of lignin-based functional materials and fundamental research.
高效分离木质纤维素生物质的主要成分并保护其结构,对于增值利用而言仍是一项挑战。在这项研究中,我们以玉米秸秆废料(一种来自农业残留物的大量但尚未得到充分开发的生物质)为原料,通过串联工艺提取高纯度纤维素纳米片,并将木质素成分回收为定义明确的木质素纳米管(LNTs)。该工艺包括采用可行的稀碱辅助湿球磨法将蒸汽爆破的玉米秸秆处理成高纯度的纤维素纳米片和木质素溶液,再通过分子组装法将其转化为 LNT。研究了高纯度纤维素纳米片和 LNT 的纯度、形态、化学结构和热行为。高纯度纤维素纳米片的纯度为 98.9%,结晶度为 36.9%,为进一步的化学改性奠定了坚实的基础。LNTs 具有显著的抗氧化活性,为木质素基功能材料的开发和基础研究开辟了新途径。
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引用次数: 0
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