Pub Date : 2024-10-21DOI: 10.1016/j.indcrop.2024.119880
The nondestructive, high-precision measurement of the phenotypic parameters of broadleaf tree seedlings is critical for seedling growth monitoring. In this paper, we take broadleaf tree seedlings as the research object and design a complete set of equipment, models, and methods ranging from automatic tree seedling image acquisition to seedling image segmentation, branch and leaf separation, image restoration of occluded branches, and final plant phenotype measurement. The experimental results show that the mean intersection over union (mIoU) of the proposed segmentation model for tree seedling branches and leaves reaches 87.95 and 98.37 %, respectively, and that the mean pixel accuracy (mPA) reaches 93.16 and 99.24 %, respectively. The structural similarity index (SSIM) and peak signal-to-noise ratio (PSNR) of branch restoration reach 98.5 % and 41.48 dB, respectively. By calculating the phenotypic parameters of tree seedling, we can keep the mean average precision error (MAPE) of the tree seedling height, ground diameter, canopy width, and canopy layer within 6 %. The results indicate that the proposed methods can more accurately extract the branch and leaf regions of a tree seedling and recover the missing parts of branches and trunks, providing a new nondestructive method of plant phenotypic measurement for broadleaf tree seedling cultivation and growth monitoring.
{"title":"Phenotypic measurements of broadleaf tree seedlings based on improved UNet and Pix2PixHD","authors":"","doi":"10.1016/j.indcrop.2024.119880","DOIUrl":"10.1016/j.indcrop.2024.119880","url":null,"abstract":"<div><div>The nondestructive, high-precision measurement of the phenotypic parameters of broadleaf tree seedlings is critical for seedling growth monitoring. In this paper, we take broadleaf tree seedlings as the research object and design a complete set of equipment, models, and methods ranging from automatic tree seedling image acquisition to seedling image segmentation, branch and leaf separation, image restoration of occluded branches, and final plant phenotype measurement. The experimental results show that the mean intersection over union (mIoU) of the proposed segmentation model for tree seedling branches and leaves reaches 87.95 and 98.37 %, respectively, and that the mean pixel accuracy (mPA) reaches 93.16 and 99.24 %, respectively. The structural similarity index (SSIM) and peak signal-to-noise ratio (PSNR) of branch restoration reach 98.5 % and 41.48 dB, respectively. By calculating the phenotypic parameters of tree seedling, we can keep the mean average precision error (MAPE) of the tree seedling height, ground diameter, canopy width, and canopy layer within 6 %. The results indicate that the proposed methods can more accurately extract the branch and leaf regions of a tree seedling and recover the missing parts of branches and trunks, providing a new nondestructive method of plant phenotypic measurement for broadleaf tree seedling cultivation and growth monitoring.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142534763","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-21DOI: 10.1016/j.indcrop.2024.119853
The promotion of vegetative branching in plants after topping has been observed without a clear understanding of the underlying mechanism. This study aimed to investigate the role of isopentenyl transferase (IPT) and cytokinins in the regulation of vegetative branching in cotton (Gossypium hirsutum L.), hypothesizing that they play key roles in this process. Plant topping was implemented at peak flowering stage in field-grown cotton, and seedcotton yield, yield components, vegetative branching, fruiting, and cytokinin levels were examined over two consecutive years. The results showed that plant topping significantly enhanced the growth and development of vegetative branches, as evidenced by increased biomass, leaf area, and fruiting of vegetative branches, along with an accumulation of cytokinin accumulation at the tips of vegetative branches. This led to a 10.3 % rise in boll density and an 11.4 % increase in seedcotton yield compared with the non-topped control. The analysis of RNA-seq and qRT-PCR data revealed significant differences in the expression patterns of IPT genes, suggesting their importance in regulating the growth and development of vegetative branches. Furthermore, examing the IPT gene families in diploid and tetraploid cotton species identified a total of 8, 8, 16, and 16 IPT genes, categorized into 6 groups. Prediction of cis-acting elements of GhIPT gene family promoters and analysis of their expression profiles demonstrated the involvement of GhIPT genes in multiple plant growth pathways with specific spatio-temporal expression. The findings underline that plant topping enhances cytokinins accumulation at vegetative branch tips by up-regulating IPT genes, leading to increased vegetative branching, fruiting, and ultimately, seedcotton yield. This study provides valuable insights into enhancing cotton yield formation through the regulation of growth and development of vegetative branches by GhIPTs and offers a crucial reference for further investigations into the functions of IPT genes.
{"title":"Genome-wide identification of isopentenyl transferase genes in cotton and their roles in regulating vegetative branching after topping","authors":"","doi":"10.1016/j.indcrop.2024.119853","DOIUrl":"10.1016/j.indcrop.2024.119853","url":null,"abstract":"<div><div>The promotion of vegetative branching in plants after topping has been observed without a clear understanding of the underlying mechanism. This study aimed to investigate the role of isopentenyl transferase (<em>IPT</em>) and cytokinins in the regulation of vegetative branching in cotton (<em>Gossypium hirsutum</em> L.), hypothesizing that they play key roles in this process. Plant topping was implemented at peak flowering stage in field-grown cotton, and seedcotton yield, yield components, vegetative branching, fruiting, and cytokinin levels were examined over two consecutive years. The results showed that plant topping significantly enhanced the growth and development of vegetative branches, as evidenced by increased biomass, leaf area, and fruiting of vegetative branches, along with an accumulation of cytokinin accumulation at the tips of vegetative branches. This led to a 10.3 % rise in boll density and an 11.4 % increase in seedcotton yield compared with the non-topped control. The analysis of RNA-seq and qRT-PCR data revealed significant differences in the expression patterns of <em>IPT</em> genes, suggesting their importance in regulating the growth and development of vegetative branches. Furthermore, examing the <em>IPT</em> gene families in diploid and tetraploid cotton species identified a total of 8, 8, 16, and 16 <em>IPT</em> genes, categorized into 6 groups. Prediction of cis-acting elements of <em>GhIPT</em> gene family promoters and analysis of their expression profiles demonstrated the involvement of <em>GhIPT</em> genes in multiple plant growth pathways with specific spatio-temporal expression. The findings underline that plant topping enhances cytokinins accumulation at vegetative branch tips by up-regulating <em>IPT</em> genes, leading to increased vegetative branching, fruiting, and ultimately, seedcotton yield. This study provides valuable insights into enhancing cotton yield formation through the regulation of growth and development of vegetative branches by <em>GhIPTs</em> and offers a crucial reference for further investigations into the functions of <em>IPT</em> genes.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142451995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-20DOI: 10.1016/j.indcrop.2024.119884
Textiles with passive cooling capabilities offer an efficient way to optimize personal thermal regulation. However, the simultaneous achievement of passive cooling, durability, and comfort in a single fabric poses a significant challenge. Herein, an ingenious cotton fabric that can be fabricated through a facile dip-dry technique is proposed. Carboxylated cellulose nanocrystals are grafted onto the fiber surfaces, and then covalently linked with hydroxylated boron nitride nanosheets to form a nanostructured coating. The resulting fabric demonstrates a remarkable enhancement of 69 % in its thermal conductivity and an impressive 56 % rise in in-plane thermal diffusivity, when compared to the pristine cotton fabric. This has the potential to raise the comfort setpoint temperature of indoor cooling equipment by 2.1 °C, thereby reducing cooling energy consumption by 22.2 %, while significantly enhancing the perceived cooling effect on the skin. Under the direct sunlight, the nanostructured fabric cools the skin by 1.21 °C below ambient temperature, preventing an excessive increase of 8.2 °C in skin temperature. Moreover, the resulting fabric maintains comparable levels of comfort and wearability as that of the original cotton fabric. This study presents an innovative strategy towards the development of passive cooling textiles.
{"title":"Nanostructured cotton fabrics for personal passive cooling with enhanced thermal conduction and energy saving","authors":"","doi":"10.1016/j.indcrop.2024.119884","DOIUrl":"10.1016/j.indcrop.2024.119884","url":null,"abstract":"<div><div>Textiles with passive cooling capabilities offer an efficient way to optimize personal thermal regulation. However, the simultaneous achievement of passive cooling, durability, and comfort in a single fabric poses a significant challenge. Herein, an ingenious cotton fabric that can be fabricated through a facile dip-dry technique is proposed. Carboxylated cellulose nanocrystals are grafted onto the fiber surfaces, and then covalently linked with hydroxylated boron nitride nanosheets to form a nanostructured coating. The resulting fabric demonstrates a remarkable enhancement of 69 % in its thermal conductivity and an impressive 56 % rise in in-plane thermal diffusivity, when compared to the pristine cotton fabric. This has the potential to raise the comfort setpoint temperature of indoor cooling equipment by 2.1 °C, thereby reducing cooling energy consumption by 22.2 %, while significantly enhancing the perceived cooling effect on the skin. Under the direct sunlight, the nanostructured fabric cools the skin by 1.21 °C below ambient temperature, preventing an excessive increase of 8.2 °C in skin temperature. Moreover, the resulting fabric maintains comparable levels of comfort and wearability as that of the original cotton fabric. This study presents an innovative strategy towards the development of passive cooling textiles.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142451424","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-20DOI: 10.1016/j.indcrop.2024.119871
The dietary and biological advantages of mushrooms are driving a global boom in the mushroom industry. The widespread production of mushrooms corresponds to disposal challenge, generating a significant volume of biowaste known as spent mushroom substrate. Their use as a catalyst can assist in lowering the expense of producing catalyst and the issue related to their disposal. Hence, the current study focused on developing a nanocatalyst for biodiesel synthesis from a blend of eight different types of oil. The catalyst was synthesized by using spent mushroom substrate (sawdust) of Ganoderma lucidum as the foundation of the catalyst, which was impregnated by BaO and K2CO3 via the wet-impregnation method followed by calcination. The developed nanocatalyst CSA/BaO@K2CO3 (CSA, calcined spent substrate ash) was characterized via various sophisticated methods like XRD (X-ray Diffraction), BET (Brunauer-Emmett-Teller), FT-IR (Fourier Transform Infrared Spectroscopy), FESEM (Field Emission Scanning Electron Microscopy) - EDX (Energy Dispersive Spectroscopy), XPS (X-ray photoelectron spectroscopy), HRTEM (High Resolution Transmission Electron Microscopy), and SAED (Selected Area Electron Diffraction). The HRTEM data showed that the average particle size of CSA/BaO@K2CO3 was 14.368 ± 0.262 nm, which confirmed it as a nanocatalyst. The synthesized catalyst’s catalytic activity was investigated for the transesterification of the blended oil (BO), where the influence of different optimum parameters was investigated. The catalyst consisted of a BET surface area of 16.441 m2 g−1 and resulted in the highest biodiesel yield of 94.36 ± 0.29 % under the optimized reaction conditions of 10 wt% of catalyst load, 9:1 of methanol to oil molar ratio (MTOMR), 65 ℃ of reaction temperature, and 34.67 ± 0.58 min of reaction duration. The biodiesel conversion under the optimized condition was also determined and found to be 95.85 %. The conversion of biodiesel was confirmed using spectroscopic techniques. The reusability test was carried out and found that the catalyst was reusable for up to three cycles. The energy of activation for transesterification using the synthesized catalyst was evaluated to be 83.55 kJ/mol.
{"title":"Spent mushroom substrate of Ganoderma lucidum developed nanocatalyst (CSA/BaO@K2CO3) for efficient biodiesel synthesis from blended oil feedstock","authors":"","doi":"10.1016/j.indcrop.2024.119871","DOIUrl":"10.1016/j.indcrop.2024.119871","url":null,"abstract":"<div><div>The dietary and biological advantages of mushrooms are driving a global boom in the mushroom industry. The widespread production of mushrooms corresponds to disposal challenge, generating a significant volume of biowaste known as spent mushroom substrate. Their use as a catalyst can assist in lowering the expense of producing catalyst and the issue related to their disposal. Hence, the current study focused on developing a nanocatalyst for biodiesel synthesis from a blend of eight different types of oil. The catalyst was synthesized by using spent mushroom substrate (sawdust) of <em>Ganoderma lucidum</em> as the foundation of the catalyst, which was impregnated by BaO and K<sub>2</sub>CO<sub>3</sub> via the wet-impregnation method followed by calcination. The developed nanocatalyst CSA/BaO@K<sub>2</sub>CO<sub>3</sub> (CSA, calcined spent substrate ash) was characterized via various sophisticated methods like XRD (X-ray Diffraction), BET (Brunauer-Emmett-Teller), FT-IR (Fourier Transform Infrared Spectroscopy), FESEM (Field Emission Scanning Electron Microscopy) - EDX (Energy Dispersive Spectroscopy), XPS (X-ray photoelectron spectroscopy), HRTEM (High Resolution Transmission Electron Microscopy), and SAED (Selected Area Electron Diffraction). The HRTEM data showed that the average particle size of CSA/BaO@K<sub>2</sub>CO<sub>3</sub> was 14.368 ± 0.262 nm, which confirmed it as a nanocatalyst. The synthesized catalyst’s catalytic activity was investigated for the transesterification of the blended oil (BO), where the influence of different optimum parameters was investigated. The catalyst consisted of a BET surface area of 16.441 m<sup>2</sup> g<sup>−1</sup> and resulted in the highest biodiesel yield of 94.36 ± 0.29 % under the optimized reaction conditions of 10 wt% of catalyst load, 9:1 of methanol to oil molar ratio (MTOMR), 65 ℃ of reaction temperature, and 34.67 ± 0.58 min of reaction duration. The biodiesel conversion under the optimized condition was also determined and found to be 95.85 %. The conversion of biodiesel was confirmed using spectroscopic techniques. The reusability test was carried out and found that the catalyst was reusable for up to three cycles. The energy of activation for transesterification using the synthesized catalyst was evaluated to be 83.55 kJ/mol.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142450298","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.indcrop.2024.119848
Coriander is an important herb with prodigious application as a flavoring agent, including in the food, beverage, and pharmaceutical industries. Considering the short-lived span of commonly found coriander, Eryngium foetidum is a first-rate alternative, considering it is perennial with a higher shelf life. Taking into account the emerging global market demand, a stable, high essential oil-yielding variety of E. foetidum is the need of the hour. Considering this, in the present study, thirty-five germplasm (seeds) of E. foetidum, which were collected from different regions of Northeast India, were planted in Randomized Block Design (RBD) in the experimental farm of CSIR-NEIST, Jorhat. All the agronomical and essential oil data were recorded as per standard protocol for two consecutive years (2018, 2019, and 2020). In the selection trial, one high essential oil-rich line was selected and planted at four different locations in NE India during the rabi season. By considering four environments of the genotypes, stability was checked using AMMI and the Eberhart-Russell model for four check varieties along with the identified strain, which was named Jor Lab LC-1. The identified variety was found to be more stable considering both the genotype and the environment interaction than the other genotypes. GC-FID and GC/MS analysis of Jor Lab LC-1 essential oil showed that trans-2-dodecenal (62.34 %) is the main component. Moreover, to the best of our knowledge, this is the first report on stability studies on E. foetidum. Therefore, Jor Lab LC-1 can be considered an elite genotype that has the potential to open up new doors for industrial uses, ranging from pharmaceuticals to agriculture, and can contribute to both conservation and cultivation efforts, ultimately safeguarding this valuable plant species for future generations.
{"title":"Deciphering the stability of Eryngium foetidum L. through AMMI and Eberhart and Russell model for herbage and essential oil yield","authors":"","doi":"10.1016/j.indcrop.2024.119848","DOIUrl":"10.1016/j.indcrop.2024.119848","url":null,"abstract":"<div><div>Coriander is an important herb with prodigious application as a flavoring agent, including in the food, beverage, and pharmaceutical industries. Considering the short-lived span of commonly found coriander, <em>Eryngium foetidum</em> is a first-rate alternative, considering it is perennial with a higher shelf life<em>.</em> Taking into account the emerging global market demand, a stable, high essential oil-yielding variety of <em>E. foetidum</em> is the need of the hour. Considering this, in the present study, thirty-five germplasm (seeds) of <em>E. foetidum</em>, which were collected from different regions of Northeast India, were planted in Randomized Block Design (RBD) in the experimental farm of CSIR-NEIST, Jorhat. All the agronomical and essential oil data were recorded as per standard protocol for two consecutive years (2018, 2019, and 2020). In the selection trial, one high essential oil-rich line was selected and planted at four different locations in NE India during the <em>rabi</em> season. By considering four environments of the genotypes, stability was checked using AMMI and the Eberhart-Russell model for four check varieties along with the identified strain, which was named Jor Lab LC-1. The identified variety was found to be more stable considering both the genotype and the environment interaction than the other genotypes. GC-FID and GC/MS analysis of Jor Lab LC-1 essential oil showed that trans-2-dodecenal (62.34 %) is the main component. Moreover, to the best of our knowledge, this is the first report on stability studies on <em>E. foetidum</em>. Therefore, Jor Lab LC-1 can be considered an elite genotype that has the potential to open up new doors for industrial uses, ranging from pharmaceuticals to agriculture, and can contribute to both conservation and cultivation efforts, ultimately safeguarding this valuable plant species for future generations.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142534841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.indcrop.2024.119876
Ramie fiber, recognized as king of natural fibers, is one of the strongest and longest natural fiber. The fabric made of ramie fibers exhibits the compelling features of being crisp and cool, fast moisture absorption and heat dissipation, as well as favorable air permeability and antibacterial. Since cellulose fibers in raw ramie are stuck tightly by gummy substances consisting of pectin, hemicellulose and lignin, a degumming process is necessary to separate these gummy materials prior to the downstream spinning process. High purified ramie cellulose fibers are supposed to be extracted with high degumming efficiency. However, currently most commonly adopted degumming methods show some inevitable defects, such as long degumming process, high operating cost, serious environmental pollution, and uncontrollable fiber quality. These mentioned issues should be properly addressed in future research work to promote the advancement of ramie fiber industry. The development of green, ecological, environmentally friendly, clean and efficient ramie degumming methods has attracted more and more attention. In this review, the methodologies of degumming processing, including mechanical, chemical, biological and combined degumming methods, are summarized systematically and the resultant properties are also covered. In addition, some research conclusions will be drawn by analyzing the latest process in this field, as well as the views on the remaining challenges and some scientific perspectives or outlook will be finally given for potential readers.
{"title":"Research progress in Ramie fiber extraction: Degumming method, working mechanism, and fiber performance","authors":"","doi":"10.1016/j.indcrop.2024.119876","DOIUrl":"10.1016/j.indcrop.2024.119876","url":null,"abstract":"<div><div>Ramie fiber, recognized as king of natural fibers, is one of the strongest and longest natural fiber. The fabric made of ramie fibers exhibits the compelling features of being crisp and cool, fast moisture absorption and heat dissipation, as well as favorable air permeability and antibacterial. Since cellulose fibers in raw ramie are stuck tightly by gummy substances consisting of pectin, hemicellulose and lignin, a degumming process is necessary to separate these gummy materials prior to the downstream spinning process. High purified ramie cellulose fibers are supposed to be extracted with high degumming efficiency. However, currently most commonly adopted degumming methods show some inevitable defects, such as long degumming process, high operating cost, serious environmental pollution, and uncontrollable fiber quality. These mentioned issues should be properly addressed in future research work to promote the advancement of ramie fiber industry. The development of green, ecological, environmentally friendly, clean and efficient ramie degumming methods has attracted more and more attention. In this review, the methodologies of degumming processing, including mechanical, chemical, biological and combined degumming methods, are summarized systematically and the resultant properties are also covered. In addition, some research conclusions will be drawn by analyzing the latest process in this field, as well as the views on the remaining challenges and some scientific perspectives or outlook will be finally given for potential readers.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142534561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.indcrop.2024.119806
<div><div>Experiments were conducted using a fixed-bed pyrolysis system and a thermo-gravimetric analyzer to investigate the effect of <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> and <span><math><mrow><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span> atmosphere on thermal degradation, physicochemical, structural, and elemental characteristics of <em>Bambusa tulda</em> and its char. A kinetic study was conducted at four different heating rates to determine the activation energy, pre-exponential factor, and kinetic model. The results indicate significant weight loss during the second stage of pyrolysis, primarily due to the thermal degradation of low molecular weight compounds such as hemicelluloses, cellulose, and a small fraction of lignin. The <span><math><mrow><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span>atmosphere leads to more significant weight loss compared to<span><math><mrow><mspace></mspace><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></mrow></math></span> atmosphere, with an average weight loss of about 80 % under <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn><mspace></mspace></mrow></msub></math></span> and approximately 95 % under <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>. This difference is likely due to specific gas-phase reactions and the consumption of carbon fuel induced by <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>. Iso-conversional methods determined that the average activation energy of <em>Bambusa tulda</em> in the presence of <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> was 160.05 kJ mol<sup>−1</sup>, whereas under<span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>, it was 105.51 kJ mol<sup>−1</sup>. The kinetic mechanism of <em>B. Tulda</em> for both the atmosphere was validated using Cardio’s master plots. The data points for activation energy and pre-exponential factors show a strong linear fit across incremental conversion fractions, indicating the presence of the kinetic compensation effect. Biochar produced in <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> atmosphere (BCC) exhibited larger pores than biochar generated in <span><math><mrow><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span> atmosphere (BCN). BCN has a porous, organized structure, while BCC displays pores with a channel-like structure due to the development of an aromatic structure. The carbon content and calorific value of <em>Bambusa tulda</em> char are noteworthy, with values of 81.23 % and 25.36 MJ kg<sup>−1</sup> for N<sub>2</sub> atmosphere, and 85.16 % and 29.44 MJ kg<sup>−1</sup> for <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn
{"title":"Experimental and kinetic analysis of Bambusa tulda pyrolysis in carbon dioxide and nitrogen atmosphere","authors":"","doi":"10.1016/j.indcrop.2024.119806","DOIUrl":"10.1016/j.indcrop.2024.119806","url":null,"abstract":"<div><div>Experiments were conducted using a fixed-bed pyrolysis system and a thermo-gravimetric analyzer to investigate the effect of <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> and <span><math><mrow><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span> atmosphere on thermal degradation, physicochemical, structural, and elemental characteristics of <em>Bambusa tulda</em> and its char. A kinetic study was conducted at four different heating rates to determine the activation energy, pre-exponential factor, and kinetic model. The results indicate significant weight loss during the second stage of pyrolysis, primarily due to the thermal degradation of low molecular weight compounds such as hemicelluloses, cellulose, and a small fraction of lignin. The <span><math><mrow><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span>atmosphere leads to more significant weight loss compared to<span><math><mrow><mspace></mspace><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></mrow></math></span> atmosphere, with an average weight loss of about 80 % under <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn><mspace></mspace></mrow></msub></math></span> and approximately 95 % under <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>. This difference is likely due to specific gas-phase reactions and the consumption of carbon fuel induced by <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>. Iso-conversional methods determined that the average activation energy of <em>Bambusa tulda</em> in the presence of <span><math><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> was 160.05 kJ mol<sup>−1</sup>, whereas under<span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span>, it was 105.51 kJ mol<sup>−1</sup>. The kinetic mechanism of <em>B. Tulda</em> for both the atmosphere was validated using Cardio’s master plots. The data points for activation energy and pre-exponential factors show a strong linear fit across incremental conversion fractions, indicating the presence of the kinetic compensation effect. Biochar produced in <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn>2</mn></mrow></msub></math></span> atmosphere (BCC) exhibited larger pores than biochar generated in <span><math><mrow><msub><mrow><mi>N</mi></mrow><mrow><mn>2</mn></mrow></msub><mspace></mspace></mrow></math></span> atmosphere (BCN). BCN has a porous, organized structure, while BCC displays pores with a channel-like structure due to the development of an aromatic structure. The carbon content and calorific value of <em>Bambusa tulda</em> char are noteworthy, with values of 81.23 % and 25.36 MJ kg<sup>−1</sup> for N<sub>2</sub> atmosphere, and 85.16 % and 29.44 MJ kg<sup>−1</sup> for <span><math><msub><mrow><mi>CO</mi></mrow><mrow><mn","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142534842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.indcrop.2024.119776
Windmill palm fibers, as a new type of cellulose fiber, have several advantages such as being environmentally friendly, lightweight, and having excellent mechanical properties. In this paper, different types of windmill palm fibers were used to prepare fabrics. Then, the fabrics were used to prepare palm fabric reinforced composites. The structure and mechanical properties of the raw, alkalized, as well as bleached windmill palm fibers, fabrics, and composites were characterized. The results showed that the windmill palm fibers with removed hemicellulose had the highest mechanical performance, with tensile strength and Young's modulus being 252.72±60.42 MPa and 1.07±0.32 GPa. At the same time, the palm reinforced composites with alkalized windmill palm fiber were endowed with higher mechanical properties with a tensile strength of 69.89±6.30 MPa. The bleached windmill palm fiber exhibited the highest wear resistance. While the alkalized windmill palm fiber had a well UV resistant property. Both alkali treatment and bleach treatment had a positive effect on enhancing the mechanical properties of the palm reinforced composites. The palm reinforced composites are partially degradable, which plays a positive role in promoting carbon neutrality.
{"title":"Mechanical performance of windmill palm reinforced textile fabrics and their sustainable composite","authors":"","doi":"10.1016/j.indcrop.2024.119776","DOIUrl":"10.1016/j.indcrop.2024.119776","url":null,"abstract":"<div><div>Windmill palm fibers, as a new type of cellulose fiber, have several advantages such as being environmentally friendly, lightweight, and having excellent mechanical properties. In this paper, different types of windmill palm fibers were used to prepare fabrics. Then, the fabrics were used to prepare palm fabric reinforced composites. The structure and mechanical properties of the raw, alkalized, as well as bleached windmill palm fibers, fabrics, and composites were characterized. The results showed that the windmill palm fibers with removed hemicellulose had the highest mechanical performance, with tensile strength and Young's modulus being 252.72±60.42 MPa and 1.07±0.32 GPa. At the same time, the palm reinforced composites with alkalized windmill palm fiber were endowed with higher mechanical properties with a tensile strength of 69.89±6.30 MPa. The bleached windmill palm fiber exhibited the highest wear resistance. While the alkalized windmill palm fiber had a well UV resistant property. Both alkali treatment and bleach treatment had a positive effect on enhancing the mechanical properties of the palm reinforced composites. The palm reinforced composites are partially degradable, which plays a positive role in promoting carbon neutrality.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142534559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.indcrop.2024.119850
Sunflower (Helianthus annuus) is the fourth major oilseed crop in the world, with remarkable tolerance in saline-alkali soils. The VTE1 gene encodes tocopherol cyclase (TC), an enzyme pivotal in the biosynthesis of both vitamin E and vitamin K1. Despite its integral role in the synthesis of these crucial vitamins, the functional analysis of VTE1 under abiotic stress in sunflowers remains scant. In the present investigation, a structural analysis of the VTE1 protein across 155 diverse species revealed a highly conserved evolutionary trace. The expression profiling of HaVTE1 depicted that the HaVTE1 was responsive to the ABA pathway. Transgenic results confirmed that overexpression of HaVTE1 in Arabidopsis and sunflower showed decreased sensitivity to ABA while knocking-down in sunflower exhibited the opposite phenotype. Furthermore, biochemical experiments displayed that HaVTE1 decreases ABA sensitivity by scavenging superoxide contents. Concurrently, the transcriptome analysis revealed that HaVTE1 blocked the upstream of the ABA signaling cascade, which was further confirmed by luciferase assay, resulting in reduced sensitivity to ABA of HaVTE1 overexpression plants. The findings shed light on a theoretical basis for the sunflower responses to ABA signaling and abiotic stresses.
向日葵(Helianthus annuus)是世界第四大油料作物,对盐碱土具有显著的耐受性。VTE1 基因编码生育酚环化酶(TC),这是一种在维生素 E 和维生素 K1 的生物合成中起关键作用的酶。尽管 VTE1 在这些重要维生素的合成过程中发挥着不可或缺的作用,但对向日葵非生物胁迫下 VTE1 的功能分析仍然很少。本研究对 155 个不同物种的 VTE1 蛋白进行了结构分析,发现了其高度保守的进化轨迹。对 HaVTE1 的表达谱分析表明,HaVTE1 对 ABA 途径具有响应性。转基因结果证实,在拟南芥和向日葵中过表达 HaVTE1 会降低对 ABA 的敏感性,而在向日葵中敲除 HaVTE1 则表现出相反的表型。此外,生化实验表明,HaVTE1 通过清除超氧化物含量来降低对 ABA 的敏感性。同时,转录组分析表明,HaVTE1 阻断了 ABA 信号级联的上游,这一点在荧光素酶检测中得到了进一步证实,从而导致 HaVTE1 过表达植株对 ABA 的敏感性降低。这些发现为向日葵对 ABA 信号和非生物胁迫的响应提供了理论依据。
{"title":"HaVTE1 confers ABA insensitivity by blocking the ABA signaling pathway in sunflowers (Helianthus annuus L.)","authors":"","doi":"10.1016/j.indcrop.2024.119850","DOIUrl":"10.1016/j.indcrop.2024.119850","url":null,"abstract":"<div><div>Sunflower (<em>Helianthus annuus</em>) is the fourth major oilseed crop in the world, with remarkable tolerance in saline-alkali soils. The <em>VTE1</em> gene encodes tocopherol cyclase (TC), an enzyme pivotal in the biosynthesis of both vitamin E and vitamin K1. Despite its integral role in the synthesis of these crucial vitamins, the functional analysis of <em>VTE1</em> under abiotic stress in sunflowers remains scant. In the present investigation, a structural analysis of the VTE1 protein across 155 diverse species revealed a highly conserved evolutionary trace. The expression profiling of <em>HaVTE1</em> depicted that the <em>HaVTE1</em> was responsive to the ABA pathway. Transgenic results confirmed that overexpression of <em>HaVTE1</em> in <em>Arabidopsis</em> and sunflower showed decreased sensitivity to ABA while knocking-down in sunflower exhibited the opposite phenotype. Furthermore, biochemical experiments displayed that <em>HaVTE1</em> decreases ABA sensitivity by scavenging superoxide contents. Concurrently, the transcriptome analysis revealed that <em>HaVTE1</em> blocked the upstream of the ABA signaling cascade, which was further confirmed by luciferase assay, resulting in reduced sensitivity to ABA of <em>HaVTE1</em> overexpression plants. The findings shed light on a theoretical basis for the sunflower responses to ABA signaling and abiotic stresses.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142534560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-10-19DOI: 10.1016/j.indcrop.2024.119765
The efficient and structure-protective isolation of the main components of lignocellulosic biomass remains challenging for value-added utilization. In this study, we used corn straw waste, a vast yet underexplored biomass from agricultural residues, as the raw material to extract high-purity cellulose nanosheets and recycle the lignin components as well-defined lignin nanotubes (LNTs) in a tandem process. The process consisted of a feasible dilute alkali-assisted wet ball milling treatment of steam-exploded corn straw into high-purity cellulose nanosheets and a lignin solution, which was further transferred into LNTs by a molecular assembly method. Purity, morphology, chemical structure, and thermal behavior of high-purity cellulose nanosheets and LNTs were examined. The 98.9 wt% purity of the high-purity cellulose nanosheets was achieved with a crystallinity of 36.9 %, providing a solid foundation for further chemical modification. The LNTs exhibited remarkable antioxidant activity, opening new avenues for the development of lignin-based functional materials and fundamental research.
{"title":"A clean deconstruction of steam-exploded corn straw into high purity cellulose nanosheets and well-defined lignin nanotubes","authors":"","doi":"10.1016/j.indcrop.2024.119765","DOIUrl":"10.1016/j.indcrop.2024.119765","url":null,"abstract":"<div><div>The efficient and structure-protective isolation of the main components of lignocellulosic biomass remains challenging for value-added utilization. In this study, we used corn straw waste, a vast yet underexplored biomass from agricultural residues, as the raw material to extract high-purity cellulose nanosheets and recycle the lignin components as well-defined lignin nanotubes (LNTs) in a tandem process. The process consisted of a feasible dilute alkali-assisted wet ball milling treatment of steam-exploded corn straw into high-purity cellulose nanosheets and a lignin solution, which was further transferred into LNTs by a molecular assembly method. Purity, morphology, chemical structure, and thermal behavior of high-purity cellulose nanosheets and LNTs were examined. The 98.9 wt% purity of the high-purity cellulose nanosheets was achieved with a crystallinity of 36.9 %, providing a solid foundation for further chemical modification. The LNTs exhibited remarkable antioxidant activity, opening new avenues for the development of lignin-based functional materials and fundamental research.</div></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":null,"pages":null},"PeriodicalIF":5.6,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142450302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}