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Monatomic Gold Nanochains and their encapsulation in Au60Au9 tubular structure 单原子金纳米链及其在Au60Au9管状结构中的包封
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609298
Sumali Bansal, Priyanka, R. Bhandari, K. Dharamvir
Under tensile deformation at 0K, gold nanowires progressively thin through a series of metastable ordered structures such as closed structure bond formations, kinks, Zig - Zag chain, straightening of the chain and then finally leading to its breaking at various stages of stretching possessing both structural and mechanical stabilities. Using atomistic simulations, we study the impact of stretching on the structural evolution of Monatomic gold nanochains (MACs) undergoing elongation along with its application in Tubular gold structure using SIESTA (Spanish Initiative for Electronic Simulation with Thousands of Atoms), the computational code based on Density Functional theory method. In particular, our simulations result in a large number of monatomic chains and intermediate structures.
在0K的拉伸变形下,金纳米线通过一系列亚稳态有序结构,如闭合结构键形成、扭结、之字形链、链的拉直,最终导致其在拉伸的各个阶段断裂,从而逐渐变细,具有结构和机械稳定性。本文利用SIESTA (Spanish Initiative for Electronic Simulation with thousand Atoms)基于密度泛函理论方法的计算程序,研究了拉伸对单原子金纳米链(MACs)结构演化的影响及其在管状金结构中的应用。特别是,我们的模拟得到了大量的单原子链和中间结构。
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引用次数: 2
Enhanced optical limiting of solubilized carbon nanotubesdecorated with Pt/Pd nanoparticles Pt/Pd纳米粒子修饰的增溶碳纳米管增强光学限制
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609274
Prabin Pradhan, V. Muthukumar, Muralikrishna Molli, S. Srivastava, S. Sai, S. Mitra
We report here the nonlinear optical response of Solubilized Multiwalled Carbon Nanotubes (MWNTs) and these decorated with Platinum and Palladium Nanoparticles. Pristine MWNTs were functionalized with COOH group through microwave assisted synthesis route which rendered them soluble in water and other solvents too. Metal salts of Platinum and Palladium were further reduced to metal nanoparticles in presence of MWNT-COOH under microwave irradiation. These hybrid metal decorated carbon nanostructures were morphologically and functionally well characterized using SEM, EDAX, FTIR, UV-Visible etc., Using Z-scan technique, we carried out nonlinear optical studies on aqueous dispersions (stable) of these metal decorated (Pt/Pd-MWNT-COOH) using a high power Nd:YAG Laser with 532 nm excitation with 10 nanosecond pulse width. These samples exhibited significant nonlinear absorption and scattering. The metal decorated MWNT-COOH (Pt-MWNT-COOH:2 Jcm-2; Pd-MWNT-COOH: 1.7Jcm-2) exhibited enhanced optical limiting which is more than plain MWNT-COOH samples and similar Metal-Graphene hybrid dispersions reported earlier in literature. These could be ideally suited for optical power limiting applications.
本文报道了溶解多壁碳纳米管(MWNTs)的非线性光学响应,以及这些碳纳米管被铂和钯纳米粒子装饰。采用微波辅助合成的方法,将原始MWNTs与COOH基团进行官能团化,使其可溶于水和其他溶剂。微波辐照下,铂和钯的金属盐在MWNT-COOH存在下进一步还原为金属纳米颗粒。利用SEM、EDAX、FTIR、uv -可见等手段对这些杂化金属修饰碳纳米结构进行了形貌和功能表征。利用z扫描技术,利用532 nm激发、10纳秒脉冲宽的高功率Nd:YAG激光器,对这些金属修饰(Pt/Pd-MWNT-COOH)的水分散体(稳定性)进行了非线性光学研究。这些样品表现出明显的非线性吸收和散射。金属装饰MWNT-COOH (Pt-MWNT-COOH:2 Jcm-2;Pd-MWNT-COOH: 1.7Jcm-2)表现出比普通MWNT-COOH样品和早期文献报道的类似金属-石墨烯杂化分散体更强的光学极限。这些可能非常适合于光功率限制应用。
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引用次数: 2
Prediction on tensile properties of cow dung powder filled glass- polyester hybrid composites 牛粪粉填充玻璃-聚酯混杂复合材料拉伸性能预测
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609394
T. D. K. Reddy, T. Rao, R. P. Suvarna, M. Kumar
In this paper the tensile strength and modulus of cow dung powder filled glass- polyester hybrid composites were studied. Two different hybrid composites such as treated and untreated cow dung fibers were fabricated and effect of alkali treatment of the cow dung fibers on these properties were studied. It was observed that, tensile strength and modulus of the hybrid composites increases with increase of cow dung percentage of weight. These properties found to be higher when alkali treated cow dung fibers were used in the hybrid composites. The eradication of amorphous hemi-cellulose with alkali treatment leading to higher crystalline of the cow dung fibers with alkali treatment might responsible for these observations. The effect of alkali treatment on the bonding between glass / cow dung composites was also studied. Scanning electron microscope (SEM) was also conducted on the cross sections of fractured surfaces.
研究了牛粪粉填充玻璃-聚酯混杂复合材料的拉伸强度和模量。制备了处理过的牛粪纤维和未处理过的牛粪纤维两种不同的杂化复合材料,研究了碱处理对牛粪纤维性能的影响。结果表明,复合材料的拉伸强度和模量随牛粪重量百分比的增加而增加。经碱处理的牛粪纤维在复合材料中具有较高的性能。碱处理能消除无定形半纤维素,使牛粪纤维的结晶度提高,这可能是造成上述现象的原因。研究了碱处理对玻璃/牛粪复合材料粘结性能的影响。对断口断面进行了扫描电镜(SEM)观察。
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引用次数: 2
Entropy coding of H.264/AVC using Exp-Golomb coding and CAVLC coding H.264/AVC的熵编码采用Exp-Golomb编码和CAVLC编码
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609386
Savita Nargundmath, Archana Nandibewoor
As the costs for both processing power and memory have reduced, network support for coded video data has diversified, and advances in video coding technology have progressed, the need has arisen for an industry standard for compressed video representation with substantially increased coding efficiency and enhanced robustness to network environments. The H.264/AVC standard aims to enable significantly improved compression performance compared to all existing video coding standards. In this project we employ two schemes of coding transform coefficients namely exponential Golomb coding & context adaptive variable length coding (CAVLC).And the major part of the contribution is the decoding strategy applied for decoding which results in performance enhancement saving the memory and decoding time which are the most important factors for bandwidth utilization. The transform coefficients are obtained using a simple zigzag scan technique. The consensus among the major players of the communications and video industry on H.264 might provide the major thrust for this new standard.
随着处理能力和内存成本的降低,对编码视频数据的网络支持多样化,以及视频编码技术的进步,对压缩视频表示的行业标准的需求已经出现,该标准要大大提高编码效率,增强对网络环境的鲁棒性。与所有现有的视频编码标准相比,H.264/AVC标准旨在显著提高压缩性能。在这个项目中,我们采用了两种编码变换系数的方案,即指数Golomb编码和上下文自适应变长编码(CAVLC)。其中最主要的贡献是译码时采用的译码策略,从而提高了性能,节省了影响带宽利用率的最重要因素——内存和译码时间。变换系数是用简单的之字形扫描技术得到的。通信和视频行业的主要参与者对H.264的共识可能会为这个新标准提供主要推动力。
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引用次数: 8
Numerical simulation of dry and wet oxidation of Silicon by TCAD Sprocess 硅干、湿氧化TCAD过程的数值模拟
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609351
A. Anusha, Chithra Parameswaran, P. Revathi, V. Velmurugan
The oxide thickness is of great concern today. The basic idea is to grow SiO2 layer on Silicon. The oxide is grown on intrinsic silicon substrate by thermal oxidation i.e., wet oxidation and dry oxidation. The thickness is compared for both the oxidation processes after different oxidation cycles. The capacitance per unit length is also calculated for the oxide growth in above. The percentage oxide thickness is also estimated and the oxide is found to grow more into the substrate with time and number of cycles.
氧化物的厚度是当今人们非常关注的问题。基本原理是在硅上生长SiO2层。氧化物是通过热氧化,即湿氧化和干氧化在本质硅衬底上生长的。对两种氧化工艺经过不同氧化循环后的厚度进行了比较。单位长度的电容也计算了上面的氧化物生长。我们还估计了氧化物厚度的百分比,发现随着循环时间和次数的增加,氧化物在衬底中生长得更多。
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引用次数: 2
Degradation of methyl orange using bismuth oxide 氧化铋降解甲基橙
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609252
S. Iyyapushpam, S. Nishanthi, D. Padiyan
Bismuth oxide is prepared by a simple chemical route and it crystallizes in the monoclinic crystal system. The measured optical band gap value of 2.694(1) eV supported that the prepared bismuth oxide can be used as a visible light photocatalyst. The degradation property of bismuth oxide is studied using methyl orange as a model pollutant and a degradation of 85% is achieved in 4 h. The kinetics of bismuth oxide is fitted using pseudo first and second order equations.
氧化铋是用简单的化学方法制备的,它在单斜晶系中结晶。测得的光学带隙值为2.694(1)eV,表明所制备的氧化铋可以作为可见光光催化剂。以甲基橙为模型污染物,研究了氧化铋的降解性能,在4 h内降解率达到85%。氧化铋的动力学用拟一、二阶方程拟合。
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引用次数: 0
Graphene nanoribbon based static random access memory for better noise margin and power reduction 基于石墨烯纳米带的静态随机存取存储器,具有更好的噪声裕度和降低功耗
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609342
Abhishek Gune, Anu Gupta
In the post silicon era as the silicon reaches its fundamental scaling limits graphene nanoribbons is expected to take over and thus continue the Moore's law about the diminishing size of transistors. Graphene nanoribbons facilitates high speed low power switching applications. Low and high field mobilities of the graphene nanoribbons are found to be higher than the CNTs and CMOS keeping the same unit cell. Such properties of graphene nanoribbons are used in the paper to define RAM memory using GNRs as an effective substitute to CMOS and CNTFETs cache memory. Graphene nanoribbon crossbars are used as the basic programmable devices. This 2-D arrangement of GNRs creates programmable diodes at intersection of each horizontal and vertical GNR rod thus opening up new avenues for building high speed memory and digital devices. The graphene nanoribbons based memory is better than the SRAM in terms of speed, density and performance metrics as well. The noise margin of GNR based memory will be .2 volts higher with respect to lower and upper limits than CMOS counterpart used presently as demonstrated by simulations in the paper. GNR based memory would be operating in the 10 nanometres scale and would be 25-50 per cent denser than the existing SRAM.
在后硅时代,当硅达到其基本的尺度极限时,石墨烯纳米带有望取而代之,从而延续摩尔定律关于晶体管尺寸缩小的定律。石墨烯纳米带有助于高速低功耗开关应用。石墨烯纳米带的低场迁移率和高场迁移率均高于碳纳米管和CMOS。本文利用石墨烯纳米带的这些特性来定义使用gnr作为CMOS和cntfet缓存存储器的有效替代品的RAM存储器。石墨烯纳米带横杆是基本的可编程器件。这种GNR的二维排列在每个水平和垂直GNR杆的交叉处创建可编程二极管,从而为构建高速存储器和数字设备开辟了新的途径。基于石墨烯纳米带的存储器在速度、密度和性能指标方面都优于SRAM。基于GNR的存储器的噪声裕度相对于下限和上限将比目前使用的CMOS对应物高0.2伏,如本文中的模拟所示。基于GNR的存储器将在10纳米尺度上运行,并且比现有的SRAM密度高25- 50%。
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引用次数: 3
Studies on lead sulphide thin films deposited by photochemical method 光化学法沉积硫化铅薄膜的研究
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609311
T. Shyju, R. Gopalakrishnan
Nanocrystalline lead sulphide (PbS) thin films were deposited on glass and ITO coated glass substrates by photochemical method. To improve the adhesive nature and properties the films were deposited on ITO coated substrate using photochemical deposition. The deposited films were characterized to study their structural, morphological and electrical properties. The photochemically deposited PbS thin films possess tetragonal system. The dislocation densities of the deposited thin films were evaluated from the X-ray diffraction data. High Resolution Scanning Electron Micrographs of the deposited film shows the oval shape arrangement of particles. The elemental composition of the film was confirmed by Energy Dispersive X-ray analysis. Hall measurements were carried out for the films and their electrical parameters were evaluated. The as-deposited PbS films have positive Hall coefficient, which confirms p-type conductivity.
采用光化学方法在玻璃和ITO镀膜玻璃衬底上制备了纳米硫化铅(PbS)薄膜。为了提高薄膜的粘附性和性能,采用光化学沉积的方法在ITO涂层基底上沉积薄膜。对沉积膜的结构、形态和电学性能进行了表征。光化学沉积的PbS薄膜具有四方体系。利用x射线衍射数据对沉积薄膜的位错密度进行了评价。沉积膜的高分辨率扫描电镜显示颗粒呈椭圆形排列。通过能量色散x射线分析确定了薄膜的元素组成。对薄膜进行了霍尔测量,并对其电学参数进行了评价。沉积的PbS膜具有正的霍尔系数,证实了p型电导率。
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引用次数: 1
Magnetic and optical studies of Fe and Co co-doped ZnO Fe和Co共掺杂ZnO的磁性和光学研究
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609264
P. Vanga, M. Ashok
Fe and Co co-doped ZnO nanoparticles were synthesized by hydrothermal method. Limit of substitution was identified using XRD. Magnetic measurements at room temperature for doped samples showed paramagnetic and ferromagnetic in nature. The reflectance spectra exhibited the absorption peaks corresponding to both dopant and host ions. Emission spectra show defect related peaks, suppression of visible spectra peaks is observed in doped samples.
采用水热法制备了Fe和Co共掺杂ZnO纳米颗粒。用XRD确定了取代的极限。室温下对掺杂样品的磁测量显示出顺磁性和铁磁性。反射光谱显示出与掺杂离子和宿主离子相对应的吸收峰。发射光谱显示缺陷相关峰,掺杂样品可见光谱峰被抑制。
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引用次数: 0
Structural, raman, dielectric, magnetic and magnetoelectric properties of Ba and Mn doped BiFeO3 nanoparticles Ba和Mn掺杂BiFeO3纳米颗粒的结构、拉曼、介电、磁性和磁电性能
Pub Date : 2013-07-24 DOI: 10.1109/ICANMEET.2013.6609290
S. Chauhan, M. Kumar, S. Chhoker, S. C. Katyal
Ba and Mn doped BiFeO3 nanoparticles were synthesized by sol-gel method. X-ray diffraction and Raman spectroscopy results showed the presence of distorted rhombohedral structure for Bi0.85Ba0.15FeO3 nanoparticles and the substitution induced phase transition (rhombohedral to orthorhombic) phase for Bi0.85Mn0.15FeO3 nanoparticles. FESEM images of both the samples revealed grain size in the range from 50 to 100 nm. Magnetic measurement showed room temperature ferromagnetic behavior, which may be attributed to the antiferromagnetic core and the ferromagnetic surface of the nanoparticles, together with the structural distortion caused by Ba and Mn substitution in BiFeO3 samples. The magnetoelectric coupling was evidenced by the observation of the dielectric anomaly in the dielectric constant near antiferromagnetic Neel temperature in both the samples.
采用溶胶-凝胶法制备了Ba和Mn掺杂的BiFeO3纳米颗粒。x射线衍射和拉曼光谱结果表明,Bi0.85Ba0.15FeO3纳米颗粒存在畸变菱形结构,Bi0.85Mn0.15FeO3纳米颗粒存在取代诱导的相变(从菱形到正交)相。两种样品的FESEM图像显示晶粒尺寸在50到100 nm之间。磁测量结果表明,纳米颗粒具有室温铁磁性,这可能是由于纳米颗粒的反铁磁性核和铁磁性表面,以及BiFeO3样品中Ba和Mn取代引起的结构畸变所致。两种样品在反铁磁Neel温度附近的介电常数异常证明了磁电耦合。
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引用次数: 1
期刊
International Conference on Advanced Nanomaterials & Emerging Engineering Technologies
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