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Robust lithium-ion battery state of health estimation based on recursive feature elimination-deep Bidirectional long short-term memory model using partial charging data 基于递归特征消除的锂离子电池健康状态鲁棒估计——基于局部充电数据的深度双向长短期记忆模型
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-28 DOI: 10.1016/j.ijoes.2024.100891
Fengxun Tian , Shuwen Chen , Xiaofan Ji , Jiongyuan Xu , Mingkun Yang , Ran Xiong
Accurate perception of the state of health (SOH) of lithium-ion batteries is crucial for their safety and reliable operation. To meet this demand, a recursive feature elimination-deep bidirectional long short-term memory (RFE-DBiLSTM) model suitable for partial charging data is proposed to effectively estimate the SOH of lithium-ion batteries. In this study, the recursive feature elimination (RFE) method is used to screen multiple charging features for obtaining the key features that best represent the SOH under two scenarios with different charging segment lengths. Due to the robust noise-filtering capability and strong ability to capture complex and multi-level temporal dependencies, the deep bidirectional long short-term memory (DBiLSTM) model is used for time series data training, verification, and testing during aging. Experimental results show that compared with benchmark time series models such as long short-term memory (LSTM) and gated recurrent unit (GRU), the proposed method significantly reduces the estimated mean absolute error (MAE) and root mean square error (RMSE) on diverse batteries in the above scenarios. In the scenario for missing partial constant current (CC) charging data, the MAE and RMSE of B0005 cell are 0.0062 and 0.0094, the MAE and RMSE of B0006 cell are 0.0294 and 0.0314, the MAE and RMSE of CS2_36 cell are 0.0510 and 0.0601, the MAE and RMSE of B0029 cell are 0.0057 and 0.0072, and the MAE and RMSE of B0030 cell are 0.0088 and 0.0102. This research innovatively combines the RFE method with the DBiLSTM model to improve the accuracy and robustness of SOH estimation.
准确感知锂离子电池的健康状态(SOH)对锂离子电池的安全可靠运行至关重要。针对这一需求,提出了一种适用于局部充电数据的递归特征消除-深度双向长短期记忆(RFE-DBiLSTM)模型,以有效估计锂离子电池的SOH。本研究采用递归特征消去(RFE)方法对多个充电特征进行筛选,获得两种不同充电段长度场景下最能代表SOH的关键特征。由于深度双向长短期记忆(deep bidirectional long - short- memory, DBiLSTM)模型具有鲁棒的噪声滤波能力和较强的捕获复杂和多层次时间依赖性的能力,该模型被用于时间序列数据在老化过程中的训练、验证和测试。实验结果表明,与长短期记忆(LSTM)和门控循环单元(GRU)等基准时间序列模型相比,该方法在上述场景下显著降低了不同电池的估计平均绝对误差(MAE)和均方根误差(RMSE)。在缺少部分恒流充电数据的情况下,B0005电池的MAE和RMSE分别为0.0062和0.0094,B0006电池的MAE和RMSE分别为0.0294和0.0314,CS2_36电池的MAE和RMSE分别为0.0510和0.0601,B0029电池的MAE和RMSE分别为0.0057和0.0072,B0030电池的MAE和RMSE分别为0.0088和0.0102。本研究创新性地将RFE方法与DBiLSTM模型相结合,提高了SOH估计的精度和鲁棒性。
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引用次数: 0
Advances in electrochemical methods for the determination of ephedrine: Current status and future trends 电化学方法测定麻黄碱的研究进展:现状及未来趋势
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-27 DOI: 10.1016/j.ijoes.2024.100903
Mingfan Cai , Wentao Wang
The accurate and reliable detection of ephedrine-type alkaloids has become increasingly critical due to their dual role in legitimate therapeutic applications and potential misuse in illicit drug production. The development of rapid and sensitive detection methods is particularly important for pharmaceutical quality control, anti-doping monitoring in sports, and law enforcement agencies conducting on-site screening, where traditional chromatographic techniques may be impractical due to their complexity and cost. This review examines recent developments in electrochemical methods for ephedrine detection, focusing on advances in electrode materials, surface modification strategies, and analytical methodologies. We discuss the fundamental aspects of ephedrine's electrochemical behavior, including electron transfer mechanisms, pH effects, and mass transport phenomena. Particular attention is given to innovative electrode modifications incorporating nanomaterials, conducting polymers, and molecular recognition elements that have dramatically enhanced detection capabilities. The emergence of novel composite materials, including carbon-metal oxide hybrids and molecularly imprinted polymers, has enabled unprecedented levels of sensitivity and selectivity. We evaluate various analytical approaches, from fundamental voltammetric techniques to sophisticated flow-based systems, highlighting their strengths and limitations. The integration of these methods into practical applications across pharmaceutical quality control, environmental monitoring, food safety, and clinical diagnostics is critically assessed. The review concludes with an examination of current challenges and emerging trends, including the development of portable detection systems and the integration of artificial intelligence for signal processing.
由于麻黄素类生物碱在合法治疗应用和在非法药物生产中可能被滥用的双重作用,准确和可靠地检测麻黄素类生物碱已变得越来越重要。发展快速、灵敏的检测方法对于药品质量控制、体育运动中的反兴奋剂监测以及执法机构进行现场筛选尤为重要,而传统的色谱技术由于其复杂性和成本而可能不切实际。本文综述了电化学方法检测麻黄碱的最新进展,重点介绍了电极材料、表面修饰策略和分析方法的进展。我们讨论了麻黄碱电化学行为的基本方面,包括电子传递机制、pH效应和质量传递现象。特别关注的是创新的电极修饰,包括纳米材料,导电聚合物和分子识别元素,这些元素大大增强了检测能力。新型复合材料的出现,包括碳-金属氧化物杂化物和分子印迹聚合物,使灵敏度和选择性达到了前所未有的水平。我们评估了各种分析方法,从基本的伏安技术到复杂的基于流动的系统,强调了它们的优势和局限性。将这些方法整合到药品质量控制、环境监测、食品安全和临床诊断等实际应用中进行了严格评估。该报告最后审查了当前的挑战和新兴趋势,包括便携式检测系统的发展和信号处理人工智能的集成。
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引用次数: 0
Synthesis and cyclic voltammetric studies of azo dye compounds derived from 1,5-dihydroxynaphthalene and their application as corrosion inhibitors for carbon steel in hydrochloric acid solution 1,5-二羟基萘偶氮染料化合物的合成和循环伏安研究及其在盐酸溶液中作为碳钢缓蚀剂的应用
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-26 DOI: 10.1016/j.ijoes.2024.100892
Majda Alfakeer , Rasha N. Felaly , Salih S. Al-Juaid , D.F. Seyam , E.M. Mabrouk , Metwally Abdallah
New bis-azo dyes derived from 1,5-dihydroxynaphthalene were synthesized and characterized by elemental analysis, Fourier-transform infrared (FTIR) and proton nuclear magnetic resonance spectroscopy (1H NMR). These compounds were examined using differential pulse polarography (DPP) and cyclic voltammetry (CV) in Britton-Robinson buffer solutions with pH values ranging from 2 to 12. When the two NN centers of the examined azo compounds were cleaved to form the amine group, the bis-azo group was reduced with the loss of eight electrons, resulting in an irreversible diffusion-controlled cathodic peak. The reduction mechanism was postulated in view of the data obtained was found to be H+, e, e, H+. The application of these azo compounds as corrosion inhibitors for carbon steel in hydrochloric acid solution was investigated and the inhibition efficiency was found to be increasing with both time and concentration, reaching 97 % after 24 hours in the presence of 10−3 M for the three azo compounds. The Langmuir adsorption isotherm indicates that the suppression of corrosion is caused by the inhibitor molecules donating electrons to the empty d-orbitals of the surface of the carbon steel (chemical adsorption), as the calculated Gibbs free energy (∆Gads) is found to be around −40 kJ/mol. The influence of temperature on the parameters of corrosion was examined, and the thermodynamic parameters of corrosion were computed and examined. The results showed that increasing temperature causes increasing of the inhibition efficiency of the tested bis-azo dyes. The order of inhibition efficiency followed their donating affinity which increases in the order p-OCH3 > p-CH3 > m-CH3. Also, the results showed that these compounds causes decrease in entropy, enthalpy and activation energy due to their chemical interaction with the metal surface.
以1,5-二羟基萘为原料合成了新型双偶氮染料,并用元素分析、傅里叶变换红外(FTIR)和质子核磁共振(1H NMR)对其进行了表征。用差分脉冲极谱(DPP)和循环伏安法(CV)在pH值为2 ~ 12的布里顿-罗宾逊缓冲溶液中对这些化合物进行了检测。当被检测的偶氮化合物的两个NN中心被切割成胺基时,双偶氮基被还原,失去8个电子,导致不可逆的扩散控制阴极峰。根据所得数据为H+, e, e, H+,推测了还原机理。研究了这三种偶氮化合物在盐酸溶液中作为碳钢缓蚀剂的应用,发现它们的缓蚀效率随时间和浓度的增加而增加,在10−3 M的存在下,24 小时后,3种偶氮化合物的缓蚀效率达到97 %。Langmuir吸附等温线表明,缓蚀剂分子将电子提供给碳钢表面的空d轨道(化学吸附)是抑制腐蚀的原因,计算出的吉布斯自由能(∆Gads)约为−40 kJ/mol。考察了温度对腐蚀参数的影响,并对腐蚀热力学参数进行了计算和校核。结果表明,温度升高会导致双偶氮染料的缓蚀效率提高。抑制效率依次为给体亲和,p-OCH3 >的顺序依次增大;p-CH3祝辞m-CH3。结果表明,这些化合物由于与金属表面的化学相互作用而导致熵、焓和活化能的降低。
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引用次数: 0
Numerical simulation and experimental study on electrochemical recovery of copper using cylindrical and conical flow reactors 圆柱形和锥形流动反应器电化学回收铜的数值模拟与实验研究
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-26 DOI: 10.1016/j.ijoes.2024.100894
Tzu-Hsuan Tsai , Sivakumar Musuvadhi Babulal , Yung-Fu Wu
This study investigates the electrochemical recovery of copper from wastewater using cylindrical and conical flow reactors. Electrochemical approaches offer advantages such as environmental compatibility, operational versatility, and energy efficiency for heavy metal remediation. However, effective recovery from dilute effluents remains challenging due to mass transfer limitations. In this work, numerical simulations were conducted to analyze the flow field and current distribution in the reactors, with a focus on the copper reduction process. Experimental results were compared with transient simulations to assess the influence of geometry and operating parameters on the performance of the reactors. The study identified that conical reactors, particularly those with a narrowing electrode gap, enhanced mass transfer rates, leading to improved copper removal efficiency. Key findings include the relationship between electrolyte flow rates, Coulombic efficiency, and copper recovery efficiency. This work contributes to the investigation of electrochemical processes for sustainable heavy metal remediation.
研究了采用圆柱流反应器和锥形流反应器对废水中铜进行电化学回收的方法。电化学方法为重金属修复提供了环境兼容性、操作通用性和能源效率等优点。然而,由于传质限制,从稀废水中有效回收仍然具有挑战性。本文以铜还原过程为研究对象,对反应器内的流场和电流分布进行了数值模拟分析。将实验结果与瞬态模拟结果进行了比较,以评估几何形状和操作参数对反应器性能的影响。研究发现,锥形反应器,特别是电极间隙缩小的锥形反应器,提高了传质率,从而提高了铜的去除效率。主要发现包括电解质流速、库仑效率和铜回收率之间的关系。这项工作有助于研究电化学方法对重金属的可持续修复。
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引用次数: 0
Surface characterization of bis-amide calix[4]arene doped SWCNT nanocomposite and its application as an electrochemical sensor for the determination of Al3+ ion 双酰胺杯[4]芳烃掺杂swcnts纳米复合材料的表面表征及其作为电化学传感器测定Al3+离子的应用
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-23 DOI: 10.1016/j.ijoes.2024.100890
A. Rouis , M. Echabaane , S. Khlifi , I. Bonnamour
This study focuses on the optical, wettability, morphological and sensing properties of the chromogenic bis-amide calix[4]arene-SWCNT nanocomposite thin film. Nanocomposite solution was done by mixing single-walled carbon nanotubes with 5,17-bis(phenylazo)-26,28 bis{[(ethoxycarbonyl)methylcarbamoyl] methoxy}-25,27-di(ethoxycarbonylmethoxy)-calix[4]arene in chlorobenzene. The possible interactions between bis-amide calixarene and SWCNT that may be responsible for enhancement in certain properties of the nanocomposite were highlighted. Firstly, the surface of the modified electrode was characterized by using UV–visible spectrophotometer and contact angle measurement (CAM). The effect of the SWCNT loading in the solution and the heating process on the film properties plays a crucial role in the optical and wettability properties of the CNTs based films. Then, morphological study was examined before and after CNT incorporation by using scanning electron microscopy. Finally, the sensing properties of bis-amide calix[4]arene-SWCNT thin film coated gold electrode were investigated using electrochemical impedance spectroscopy (EIS) toward the detection of Al3+ ion.
本文研究了显色双酰胺杯[4]芳烃- swcnts纳米复合薄膜的光学、润湿性、形态学和传感性能。将单壁碳纳米管与5,17-二(苯基偶氮)-26,28 -二{[(乙氧羰基)甲基氨基甲氧基]甲氧基}-25,27-二(乙氧羰基甲氧基)杯芳烃在氯苯中混合制备纳米复合溶液。强调了双酰胺杯芳烃与swcnts之间可能的相互作用,这可能是纳米复合材料某些性能增强的原因。首先,利用紫外可见分光光度计和接触角测量(CAM)对修饰电极的表面进行了表征。纳米碳管在溶液中的负载和加热过程对薄膜性能的影响对纳米碳管基薄膜的光学性能和润湿性起着至关重要的作用。然后用扫描电镜观察碳纳米管掺入前后的形态学变化。最后,利用电化学阻抗谱(EIS)研究了双酰胺杯[4]芳烃- swcnts薄膜包覆金电极对Al3+离子的传感性能。
{"title":"Surface characterization of bis-amide calix[4]arene doped SWCNT nanocomposite and its application as an electrochemical sensor for the determination of Al3+ ion","authors":"A. Rouis ,&nbsp;M. Echabaane ,&nbsp;S. Khlifi ,&nbsp;I. Bonnamour","doi":"10.1016/j.ijoes.2024.100890","DOIUrl":"10.1016/j.ijoes.2024.100890","url":null,"abstract":"<div><div>This study focuses on the optical, wettability, morphological and sensing properties of the chromogenic bis-amide calix[4]arene-SWCNT nanocomposite thin film. Nanocomposite solution was done by mixing single-walled carbon nanotubes with 5,17-bis(phenylazo)-26,28 bis{[(ethoxycarbonyl)methylcarbamoyl] methoxy}-25,27-di(ethoxycarbonylmethoxy)-calix[4]arene in chlorobenzene. The possible interactions between bis-amide calixarene and SWCNT that may be responsible for enhancement in certain properties of the nanocomposite were highlighted. Firstly, the surface of the modified electrode was characterized by using UV–visible spectrophotometer and contact angle measurement (CAM). The effect of the SWCNT loading in the solution and the heating process on the film properties plays a crucial role in the optical and wettability properties of the CNTs based films. Then, morphological study was examined before and after CNT incorporation by using scanning electron microscopy. Finally, the sensing properties of bis-amide calix[4]arene-SWCNT thin film coated gold electrode were investigated using electrochemical impedance spectroscopy (EIS) toward the detection of Al<sup>3+</sup> ion.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 1","pages":"Article 100890"},"PeriodicalIF":1.3,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142747260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of soil variability on the corrosion of buried hot-dip galvanized steel 土壤变化对埋地热浸镀锌钢腐蚀的影响
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-22 DOI: 10.1016/j.ijoes.2024.100889
Cheng He , Zongjiang Wang , Yi You , Xinxin Wang , Puzhi Zhao , Zhushi Yang , Lifeng Zhou
A reliable electricity supply is vital to national economies and human livelihoods, making the protection of grid infrastructure essential. The metallic grounding network of power grids buried underground is exposed to complex soil conditions, including varying moisture, resistivity, and pH levels. Nine soil sites in northern China were selected for the analysis of physicochemical properties. The corrosion behavior of hot-dip galvanized Q235 steel was examined through corrosion morphology and product analysis. And the corrosion products at different stages were analyzed and mainly included oxides or hydroxides of both Zn and Fe with different contents. As the soil corrosiveness and exposure time increased, the corrosion severity intensified. The galvanized coating initially protected the steel matrix, but its effectiveness diminished over time. Monitoring corrosion and implementing targeted anti-corrosion measures are crucial for ensuring the safe and stable operation of power grid equipment.
可靠的电力供应对国民经济和人类生活至关重要,因此保护电网基础设施至关重要。埋在地下的电网金属接地网暴露在复杂的土壤条件下,包括不同的湿度、电阻率和 pH 值。研究人员选取了中国北方的 9 个土壤地点进行理化性质分析。通过腐蚀形态和产物分析,研究了热镀锌 Q235 钢的腐蚀行为。分析了不同阶段的腐蚀产物,主要包括不同含量的锌和铁的氧化物或氢氧化物。随着土壤腐蚀性和暴露时间的增加,腐蚀的严重程度也在加剧。镀锌层最初能保护钢基体,但随着时间的推移,其效果逐渐减弱。监测腐蚀情况并采取有针对性的防腐蚀措施对于确保电网设备的安全稳定运行至关重要。
{"title":"Influence of soil variability on the corrosion of buried hot-dip galvanized steel","authors":"Cheng He ,&nbsp;Zongjiang Wang ,&nbsp;Yi You ,&nbsp;Xinxin Wang ,&nbsp;Puzhi Zhao ,&nbsp;Zhushi Yang ,&nbsp;Lifeng Zhou","doi":"10.1016/j.ijoes.2024.100889","DOIUrl":"10.1016/j.ijoes.2024.100889","url":null,"abstract":"<div><div>A reliable electricity supply is vital to national economies and human livelihoods, making the protection of grid infrastructure essential. The metallic grounding network of power grids buried underground is exposed to complex soil conditions, including varying moisture, resistivity, and pH levels. Nine soil sites in northern China were selected for the analysis of physicochemical properties. The corrosion behavior of hot-dip galvanized Q235 steel was examined through corrosion morphology and product analysis. And the corrosion products at different stages were analyzed and mainly included oxides or hydroxides of both Zn and Fe with different contents. As the soil corrosiveness and exposure time increased, the corrosion severity intensified. The galvanized coating initially protected the steel matrix, but its effectiveness diminished over time. Monitoring corrosion and implementing targeted anti-corrosion measures are crucial for ensuring the safe and stable operation of power grid equipment.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 1","pages":"Article 100889"},"PeriodicalIF":1.3,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142719862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Artificial intelligence-aided electrochemical sensors for capturing and analyzing fingerprint profiles of medicinal materials 用于捕捉和分析药用材料指纹图谱的人工智能辅助电化学传感器
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-22 DOI: 10.1016/j.ijoes.2024.100887
Zuzheng Chang , Hongwei Sun
This study explores the application of artificial intelligence-aided electrochemical sensors for authenticating medicinal materials, focusing on sika deer antler cap powder. Utilizing differential pulse voltammetry and graphene-modified screen-printed electrodes, we developed a novel method to capture unique electrochemical fingerprints of authentic, counterfeit, and adulterated samples. Three machine learning models—Support Vector Machine (SVM), Random Forest (RF), and Extreme Learning Machine (ELM)—were evaluated using both full voltammogram and principal component analysis (PCA) reduced features. The SVM model with PCA-reduced features emerged as the optimal approach, achieving a classification accuracy of 97.9 % while reducing training time by 65.6 % (from 3.2 s to 1.1 s) and prediction time by 71.4 % (from 0.07 s to 0.02 s per sample) compared to using full voltammogram features. This reduction in computational complexity was achieved by decreasing the input dimensionality from 601 to 5 features through PCA, while maintaining high classification performance across all sample categories. This model demonstrated high sensitivity (>97 %) and specificity (>98 %) across all sample categories, with a notably low limit of detection for adulteration at 2.8 %. Characteristic peaks, such as the pantocrin peak at 0.25 V for authentic samples, provided a robust basis for differentiation. The method's effectiveness in detecting subtle adulterations was evidenced by its ability to identify samples with as low as 5 % adulteration. Furthermore, the approach showed excellent generalization, maintaining 97.0 % accuracy on an independent validation set. These findings highlight the potential of this technique for rapid, accurate, and cost-effective authentication of medicinal materials, addressing the growing challenge of counterfeit products in the pharmaceutical industry.
本研究探讨了人工智能辅助电化学传感器在鉴定药用材料方面的应用,重点是梅花鹿鹿茸盖粉。利用差分脉冲伏安法和石墨烯修饰的丝网印刷电极,我们开发了一种新方法来捕捉真品、假货和掺假样品的独特电化学指纹。我们使用全伏安图和主成分分析(PCA)缩减特征对支持向量机(SVM)、随机森林(RF)和极限学习机(ELM)这三种机器学习模型进行了评估。使用 PCA 缩减特征的 SVM 模型成为最佳方法,分类准确率达到 97.9%,与使用完整伏安图特征相比,训练时间减少了 65.6%(从 3.2 秒减少到 1.1 秒),预测时间减少了 71.4%(每个样本从 0.07 秒减少到 0.02 秒)。计算复杂度的降低是通过 PCA 将输入维度从 601 个特征减少到 5 个特征实现的,同时在所有样本类别中保持了较高的分类性能。该模型在所有样品类别中均表现出较高的灵敏度(97%)和特异度(98%),掺假检测限明显较低,仅为 2.8%。特征峰,如真品样品中 0.25 V 的泛素峰,为鉴别提供了可靠的依据。该方法能够识别掺假率低至 5% 的样品,这证明了它在检测细微掺假方面的有效性。此外,该方法还显示出卓越的通用性,在独立验证集上保持了 97.0% 的准确率。这些研究结果凸显了该技术在快速、准确和经济高效地鉴定药用材料方面的潜力,从而应对制药行业日益严峻的假冒产品挑战。
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引用次数: 0
Electrochemical behavior of Ni seed layers on polysilicon wafer for solar cells 太阳能电池多晶硅片上镍种子层的电化学行为
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-20 DOI: 10.1016/j.ijoes.2024.100886
Yeqiang Mo , Gangzhou Sui , Sanming Chen
The stripping behaviors of Ni seeds on polysilicon wafers, which were formed by galvanic displacement in a solution containing fluorine ions, were characterized by cyclic voltammetry and the surface morphologies were observed by scanning electron microscopy. It is discovered that the anodic stripping behaviors of the Ni seed layers are impacted by the duration of deposition. Two types of Ni seed layers can be distinguished. One is formed with the deposition duration less than 10 s, which corresponds to the stripping behavior of the Ni-Si structure with monolayer deposition. The other is formed with a duration greater than 10 s, which is attributed to the stripping behavior of the Ni-Ni-Si structure with bulk deposition.
多晶硅晶片上的镍种子层是在含氟离子的溶液中通过电位移形成的,通过循环伏安法对其剥离行为进行了表征,并通过扫描电子显微镜对其表面形态进行了观察。研究发现,镍种子层的阳极剥离行为受沉积时间的影响。可以区分出两种类型的镍种子层。一种是在沉积持续时间小于 10 秒时形成的,这与单层沉积的镍硅结构的剥离行为一致。另一种是在持续时间大于 10 秒的情况下形成的,这归因于块状沉积的镍-镍-硅结构的剥离行为。
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引用次数: 0
Enhanced model for axisymmetric stability analysis of propagating circular defect-driven coating delamination under combined compressive and diffusion-induced stresses 在压应力和扩散应力共同作用下对圆形缺陷驱动的涂层脱层进行轴对称稳定性分析的增强模型
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-18 DOI: 10.1016/j.ijoes.2024.100876
M.H. Nazir , Z.A. Khan , Syed Zohaib Javaid Zaidi , Muhammad Majid Hussain , O.O. Taiwo
This paper examines the delamination of palladium (Pd) coatings bonded to a steel substrate under equi-biaxial compression coupled with diffusion-induced stress. The study focuses on circular delaminations. Large delaminations cause the coating to debond, forming blisters, which generate a driving force on the edge crack tip. A two-part theoretical model is developed: axisymmetric blister propagation in a stable circular pattern and non-axisymmetric perturbation of the blister leading to branching. Detailed experimental studies validate the theoretical predictions. The experiments show that non-axisymmetric crack tip instabilities during propagation result in worm-like patterns.
本文研究了在等轴向压缩和扩散诱导应力作用下,粘结在钢基体上的钯 (Pd) 涂层的脱层问题。研究重点是圆形脱层。大面积脱层会导致涂层脱落,形成水泡,从而对边缘裂纹尖端产生驱动力。研究建立了一个由两部分组成的理论模型:以稳定的圆形模式进行轴对称水泡传播,以及对水泡进行非轴对称扰动以导致分支。详细的实验研究验证了理论预测。实验表明,非轴对称裂纹尖端在传播过程中的不稳定性会导致蠕虫状图案。
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引用次数: 0
Rational design of hedgehog-like NiMn2S4 architectures for energy storage devices 合理设计用于储能设备的刺猬状 NiMn2S4 结构
IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2024-11-17 DOI: 10.1016/j.ijoes.2024.100881
Adil Emin, Qunyang Li, Junshuai Li, Yali Li, Deyan He
In this work, the NiMn2S4 nanomaterials were prepared by a two-step hydrothermal method with an external morphology similar to that of a sea hedgehog, with an overall micro-spherical shape surrounded by nanosheets (NSs). This unique nanostructure helps enhance the electrode material's specific surface area (SSA) and achieve a better pore size distribution, facilitating complete interaction among the electrolyte and the active materials. Moreover, it promotes the quick flow of electrons and smooth transport of ions, thus improving NiMn2S4 electrode electrochemical performance. The NiMn2S4 electrode achieved an capacitance of 1426.2 mF cm−2 at 1 mA cm−2, with good rate performance (∼896.6 mF cm−2 at 10 mA cm−2) and cycle stability (∼83.8 % retention after 6000 cycles). Sweep voltammetry analysis of its electrochemical behavior reveals that the primary energy storage mechanism is the capacitive contribution based on surface diffusion. This finding lays a foundation for future work on regulating and optimizing the electrochemical properties.
在这项工作中,采用两步水热法制备了镍锰2S4纳米材料,其外部形态类似于海刺猬,整体呈微球形,周围环绕着纳米片(NSs)。这种独特的纳米结构有助于提高电极材料的比表面积(SSA),实现更好的孔径分布,促进电解质和活性材料之间的完全相互作用。此外,它还能促进电子的快速流动和离子的顺利传输,从而提高镍锰硒电极的电化学性能。NiMn2S4 电极在 1 mA cm-2 时的电容为 1426.2 mF cm-2,具有良好的速率性能(10 mA cm-2 时为 896.6 mF cm-2)和循环稳定性(6000 次循环后的保持率为 83.8%)。对其电化学行为的扫频伏安分析表明,主要的储能机制是基于表面扩散的电容贡献。这一发现为今后调节和优化电化学特性的工作奠定了基础。
{"title":"Rational design of hedgehog-like NiMn2S4 architectures for energy storage devices","authors":"Adil Emin,&nbsp;Qunyang Li,&nbsp;Junshuai Li,&nbsp;Yali Li,&nbsp;Deyan He","doi":"10.1016/j.ijoes.2024.100881","DOIUrl":"10.1016/j.ijoes.2024.100881","url":null,"abstract":"<div><div>In this work, the NiMn<sub>2</sub>S<sub>4</sub> nanomaterials were prepared by a two-step hydrothermal method with an external morphology similar to that of a sea hedgehog, with an overall micro-spherical shape surrounded by nanosheets (NSs). This unique nanostructure helps enhance the electrode material's specific surface area (SSA) and achieve a better pore size distribution, facilitating complete interaction among the electrolyte and the active materials. Moreover, it promotes the quick flow of electrons and smooth transport of ions, thus improving NiMn<sub>2</sub>S<sub>4</sub> electrode electrochemical performance. The NiMn<sub>2</sub>S<sub>4</sub> electrode achieved an capacitance of 1426.2 mF cm<sup>−2</sup> at 1 mA cm<sup>−2</sup>, with good rate performance (∼896.6 mF cm<sup>−2</sup> at 10 mA cm<sup>−2</sup>) and cycle stability (∼83.8 % retention after 6000 cycles). Sweep voltammetry analysis of its electrochemical behavior reveals that the primary energy storage mechanism is the capacitive contribution based on surface diffusion. This finding lays a foundation for future work on regulating and optimizing the electrochemical properties.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"19 12","pages":"Article 100881"},"PeriodicalIF":1.3,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142704279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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International Journal of Electrochemical Science
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