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Surface modification of carbonised waste rice husks by mild hydrothermal treatment 轻度水热处理对碳化废弃稻壳的表面改性
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2021-04-12 DOI: 10.1504/IJSURFSE.2021.10037024
W. Karen, J. X. Ooi, Zhipeng Wang, N. J. Siambun, W. Liew, W. Muzammil, K. Sopian, G. Melvin
Carbonisation process is a way in exploiting rice husk to produce alternative carbon material. In this study, rice husk was carbonised at 500°C, 2 h in inert environment. Mild hydrothermal treatment of carbonised rice husk was conducted by using potassium hydroxide (KOH) and potassium persulfate (KPS) as reactants in different parameters: 1) the reactants molar ratio; 2) reaction time. The treated carbonised rice husks were tested for its dispersion, morphology observation, elements and functional groups determination. From the results, the modified carbonised rice husks showed improvement in its dispersion with polar solvent while no defects in the structures were observed from the SEM images. High oxygen content was found in EDX analysis for modified carbonised rice husks treated in KOH: KPS with molar ratio of 3:1. The presence of hydroxyl and carboxyl groups from the FTIR spectra shows that the treatment successfully introduced functional group to the carbonised rice husk surface.
碳化工艺是利用稻壳生产替代碳材料的一种方法。在本研究中,稻壳在惰性环境中于500°C下碳化2小时。以氢氧化钾(KOH)和过硫酸钾(KPS)为反应物,在不同参数下对碳化稻壳进行了温和水热处理:1)反应物摩尔比;2) 反应时间。对处理后的碳化稻壳进行了分散性、形态观察、元素和官能团测定。结果表明,改性后的碳化稻壳在极性溶剂中的分散性有所改善,而SEM图像中没有观察到结构缺陷。在摩尔比为3:1的KOH:KPS中处理的改性碳化稻壳的EDX分析中发现高氧含量。FTIR光谱中羟基和羧基的存在表明,该处理成功地将官能团引入了碳化稻壳表面。
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引用次数: 4
Enhanced surface properties of M2 steel by plasma nitriding pre-treatment and magnetron sputtered TiN coating 等离子渗氮预处理和磁控溅射镀TiN增强M2钢表面性能
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-12-23 DOI: 10.1504/ijsurfse.2020.10034487
M. S. Libório, E. Almeida, S. Alves, T. Costa, M. Feitor, R. M. Nascimento, R. Sousa, M. Naeem, Mohsan Jelani
AISI M2 high-speed steels are widely used in cutting/forming tools due to their easy machinability and balanced toughness. Unfortunately, they exhibit severe cutting edge wear, which reduces their useful lifetime. The lifetime of such steels can be improved by titanium nitride hard coating. However, in sliding wear applications having a metal-to-metal contact, such coatings exhibit low adhesion to the substrate due to substantial hardness differences among coating and substrate. Here, plasma nitriding is performed before the deposition of magnetron sputtered-TiN coating using various nitriding parameters to find whether the surface properties of the duplex treated sample can be altered by changing these parameters or not. It is found that the surface hardness and hardening depth can be improved by using the duplex treatment as compared to only TiN coating. A significant decrease in wear rate is attained using the duplex treatment and substantial improvement by altering the plasma nitriding parameters.
AISI M2高速钢因其易于切削加工和韧性平衡而广泛应用于切削/成形工具中。不幸的是,它们表现出严重的切削刃磨损,这减少了它们的使用寿命。氮化钛硬质涂层可提高此类钢的使用寿命。然而,在具有金属对金属接触的滑动磨损应用中,由于涂层和基体之间存在巨大的硬度差异,这种涂层对基体的附着力较低。在磁控溅射tin涂层沉积之前,使用不同的渗氮参数进行等离子体渗氮,以确定是否可以通过改变这些参数来改变双相处理样品的表面性能。结果表明,与单纯镀TiN相比,采用双相处理可提高表面硬度和硬化深度。采用双相处理可显著降低磨损率,通过改变等离子体渗氮参数可显著改善磨损率。
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引用次数: 8
Activity modification of a new type of carbamide-based non-polluting solid powdery medium used in the sulphonitrocarburising process 一种用于亚硝基渗碳工艺的新型酰胺基无污染固体粉状介质的活性改性
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-12-23 DOI: 10.1504/ijsurfse.2020.10034488
M. Cojocaru, M. Branzei, M. Ion, L. Drugặ
Carbamide (technical grade urea) is frequently used as a highly efficient active component in the mediums used for ferritic or austenitic nitrocarburising processes, and across a wide range of temperature values, ranging from values below 590°C required for achieving the ferritic nitrocarburising process, to values above 800°C required for the austenitic nitrocarburising process. The carbamide activity generates a particularly intense layer of growth kinetics. This paper studies the ability of carbamide to supply nitrogen and carbon, in the temperature range 550-950°C. It was concluded that this process varies by temperature, and for a composition of the solid powdery medium (35% carbamide, 50% carbon, 10% sulphur and 5% ammonium chloride) at 820°C the carbon potential level is higher compared to the nitrogen one.
碳酰胺(工业级尿素)经常被用作铁素体或奥氏体氮碳共渗工艺所用介质中的高效活性成分,并且在各种温度值范围内使用,从实现铁素体氮碳共熔工艺所需的590°C以下到奥氏体氮碳碳共渗过程所需的800°C以上。脲的活性产生了一层特别强烈的生长动力学。本文研究了尿素在550~950°C的温度范围内提供氮和碳的能力。得出的结论是,该过程随温度而变化,对于820°C下固体粉末介质(35%尿素、50%碳、10%硫和5%氯化铵)的组成,碳势水平高于氮势水平。
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引用次数: 0
Surface microporous formation on AISI 4140 using combination of diffusion treatment after nitriding gas in muffle reactor 马弗反应器渗氮后复合扩散处理在AISI 4140表面形成微孔
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-12-23 DOI: 10.1504/ijsurfse.2020.10034489
K. Widi, W. Sujana, T. Rahardjo
Steel with microporous formation on surface layers is very important as self-lubricant and damping material. In this new method, AISI 4140 steel was subjected in two step combination treatment. First step is boost nitriding gas in fluidised bed reactor for 4 hours at 550°C and the second step is diffusion nitriding gas for 2 h at 550°C in muffle reactors. The diffusion without protective gas where air was present was applied after nitriding treatment in muffle reactors to release excess nitrogen which leads to microporous formation. This mechanism significantly increases surface porosity. The microporous formation at e layer during diffusion at nitriding process is controlled by reaction formation of N2, NO, Cr2O3 and Fe2O3 which depends on the atmosphere condition in the muffle reactor. The dynamics of atoms during these formations create tensile and compressive stress in the grain boundary that increases porosity formation.
钢在表层形成微孔是一种重要的自润滑和阻尼材料。采用该方法对AISI 4140钢进行了两步组合处理。第一步是在550℃的流化床反应器中升压氮化气体4小时,第二步是在550℃的马弗反应器中扩散氮化气体2小时。在马弗反应器中进行氮化处理后,在空气存在的情况下进行无保护气体的扩散,释放过量的氮,导致微孔的形成。这一机制显著增加了表面孔隙率。氮化扩散过程中e层微孔的形成受N2、NO、Cr2O3和Fe2O3的反应控制,这取决于马弗反应器的气氛条件。在这些形成过程中,原子的动力学在晶界产生拉伸和压缩应力,从而增加孔隙度的形成。
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引用次数: 1
Investigation on slurry erosion of Al2O3 incorporated glass/epoxy composites Al2O3掺入玻璃/环氧复合材料的浆液侵蚀研究
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-12-23 DOI: 10.1504/ijsurfse.2020.10034486
A. G. Joshi, M. P. Kumar, S. Basavarajappa
The jet erosion of fibre reinforced plastics (FRPs) has been reported in many literatures available, but very few have reported on their slurry erosion behaviour of FRPs. Furthermore, limited studies have paid attention on slurry erosion characterisation of filler incorporated FRPs. Hence, present study was focused on slurry erosion behaviour of alumina fillers incorporated glass/epoxy composites. The parameters considered were slurry concentration, contact angle and impact velocity. The experimental results reveal that increase in filler percentage increased the erosion resistance of glass/epoxy composites. The increase in slurry concentration and impact velocity has resulted in higher amount of erosion of studied composites. The material loss due to erosion increased with increase of impact angle till 45°, whereas further increase in impact angle caused reduction in wear. Erosion mechanisms were studied through SEM image of eroded samples. Worn surface analysis revealed that plastic deformation, matrix debonding with microcutting, microploughing, and pulverisation were dominant erosion mechanisms at 45° to 60° impact angle.
已有许多文献报道了纤维增强塑料(FRPs)的射流侵蚀,但很少有文献报道其浆料侵蚀行为。此外,有限的研究关注掺入填料的FRP的浆料侵蚀特性。因此,本研究的重点是氧化铝填料掺入玻璃/环氧树脂复合材料的浆料侵蚀行为。所考虑的参数包括浆料浓度、接触角和冲击速度。实验结果表明,填料比例的增加提高了玻璃/环氧树脂复合材料的耐侵蚀性。浆料浓度和冲击速度的增加导致所研究的复合材料的侵蚀量更高。由于侵蚀导致的材料损失随着冲击角的增加而增加,直到45°,而冲击角的进一步增加导致磨损减少。通过侵蚀样品的扫描电镜图像研究了侵蚀机理。磨损表面分析表明,在45°至60°的冲击角下,塑性变形、基体微切削脱粘、微剥落和粉碎是主要的侵蚀机制。
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引用次数: 0
Investigation UV-treatment and surface modifications effect on surface energy and aging behaviour of biomedical surfaces 研究紫外线处理和表面改性对生物医学表面表面能和老化行为的影响
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-10-08 DOI: 10.1504/ijsurfse.2020.10032738
A. G. Bulutsuz
Biomedical Ti6Al4V Eli alloy discs were subjected to blasting, anodisation and ultra viola (UV) treatments under the same manufacturing conditions with implants. These different surface modification effects on topography and wetting performance were investigated in detail with optical tensiometer for autoclaved and non-autoclaved samples. Surface contact angle changes after packing of the surfaces were investigated for initial, 1 and 3 months later. The topographical investigation by scanning electron microscope (SEM) showed that blasted 350 V had the mean 1.842 ± 102 nm pores size and blasted 280 V treated surfaces had the mean 771 ± 85 nm pore size. Autoclaving decreased wettability capabilities of all surfaces, especially for the blasted specimen group. According to the repetitive measurement results, after the 1st month the wettability's of the surfaces were similar compared to the initial. After the 3rd month, a decreasing trend was observed for wetting capability. But beyond all groups, the contact angle was the same with non-UV treated state for the blasted 350 V group after 3rd month.
生物医学Ti6Al4V Eli合金盘在与植入物相同的制造条件下进行了爆破、阳极氧化和紫外线处理。利用光学张力计对蒸压和非蒸压样品的表面改性对形貌和润湿性能的影响进行了详细的研究。在初始、1个月和3个月后对表面包装后的表面接触角变化进行了研究。扫描电镜(SEM)形貌分析表明,350 V喷砂处理表面的平均孔径为1.842±102 nm, 280 V喷砂处理表面的平均孔径为771±85 nm。高压灭菌降低了所有表面的润湿性,特别是对被炸试样组。根据重复测量结果,第1个月后,表面的润湿性与初始相似。第3个月后,润湿能力呈下降趋势。但在3个月后,350 V喷砂组的接触角与未uv处理状态相同。
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引用次数: 0
Study of the additives influence in the CMP slurry for the surfaces planarisation covered by selective transfer CMP浆料中添加剂对选择性转移覆盖表面平面化影响的研究
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-06-24 DOI: 10.1504/ijsurfse.2020.10030172
F. Ilie, G. Ipate
Chemical mechanical planarisation (CMP) is the only effective technique for obtaining surfaces with higher resolution and flatness, by removing the metal excess obtained in the selective-transfer process. The CMP process of the selective-layer assumes layer surface oxidation, protection its, and passivation layer removal from the tops of the protrusions by abrasive particles mechanical action. The selective-layer slurry consists of hydrogen peroxide (H2O2) as an oxidiser, organic acids as complexing and etching agents, benzotriazole (BTA) as a corrosion inhibitor and silica (SiO2) particles as abrasive. To a higher removal rate and better slurry stability was used the citric acid, and BTA controlled adding in slurry could change the removal and etching rate of the selective-layer. This paper analyses the additives effect in CMP slurry on the polishing of covered surfaces through selective-transfer, considering removal and etching rates, as well as the slurry behaviour with different types and concentrations of additives, in various proportions.
化学机械平面化(CMP)是通过去除在选择性转移工艺中获得的过量金属来获得具有更高分辨率和平坦度的表面的唯一有效技术。选择层的CMP工艺假定层表面氧化、保护层和钝化层通过研磨颗粒的机械作用从突起的顶部去除。选择性层浆料由作为氧化剂的过氧化氢(H2O2)、作为络合剂和蚀刻剂的有机酸、作为缓蚀剂的苯并三唑(BTA)和作为研磨剂的二氧化硅(SiO2)颗粒组成。为了获得更高的去除率和更好的浆料稳定性,使用柠檬酸,并且在浆料中控制加入BTA可以改变选择性层的去除和蚀刻速率。本文分析了CMP浆料中的添加剂对通过选择性转移抛光覆盖表面的影响,考虑了去除率和蚀刻率,以及不同类型和浓度的添加剂在不同比例下的浆料行为。
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引用次数: 0
Surface morphology investigation of miniature gears manufactured by abrasive water jet machining 磨料水射流加工微型齿轮的表面形貌研究
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-06-24 DOI: 10.1504/ijsurfse.2020.10030179
K. Gupta, M. A. Khan, S. Pathak
In this paper, surface morphology investigation of miniature spur gears manufactured by abrasive water jet machining is discussed. Water jet pressure, abrasive flow rate and stand-off-distance are the varying input parameters to study the surface morphology (surface roughness and topography) of the machined gears. From the investigation, the water jet pressure has highly influenced (with 47% contribution) the surface quality and found as a predominant process parameter. SEM micrograph study found that wear scars and clinging effects are the major surface defects found over the machined surfaces of the gear teeth. Maximum and minimum peaks of the wear tracks are observed with white light spectroscope. The best surface morphology with average surface roughness value 1.08 μm was achieved at 350 MPa water jet pressure, 225 g/min abrasive mass flow rate, and 1mm stand-off distance. The present work identifies the potential of AWJM process for manufacturing of high quality miniature gears.
本文对磨料水射流加工微型直齿轮的表面形貌进行了研究。水射流压力、磨料流速和间隔距离是研究加工齿轮表面形态(表面粗糙度和形貌)的可变输入参数。根据调查,水射流压力对表面质量有很大影响(贡献率为47%),并被发现是主要的工艺参数。SEM显微照片研究发现,磨损痕和粘着效应是齿轮齿加工表面的主要表面缺陷。用白光光谱仪观察磨损轨迹的最大峰值和最小峰值。在350MPa的水射流压力、225g/min的磨料质量流量和1mm的间隔距离下,获得了平均表面粗糙度为1.08μm的最佳表面形态。目前的工作确定了AWJM工艺在制造高质量微型齿轮方面的潜力。
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引用次数: 0
The effect of different sputtering parameters on coating thickness and hardness in MoS2 coated films with and without interlayer 不同溅射参数对有间层和无间层MoS2涂层厚度和硬度的影响
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-06-24 DOI: 10.1504/ijsurfse.2020.10030174
M. Poyraz, R. Tunay
The aim of this study is; to examine the effect of different sputtering parameters on coating thickness and hardness in MoS2 films which are deposition of radio frequency (RF) magnetron sputtering method. Therefore, 440C steel substrates are coated with MoS2 thin films which exhibit lubrication as a solid lubricant and low friction characteristic during shear. MoS2 films with no interlayer and (Ti/Cr) with interlayer were deposited on the AISI 440C substrates. During the coating, by changing the deposition parameters such as the substrate deposition temperature and RF sputtering power, steel disc groups which are coated in 15 different deposition parameters were obtained. The thicknesses of the films were measured by using a SEM. The surface topographies were observed at different magnifications. The composition and structure were analysed by energy dispersive spectroscopy (EDS). A nano-indentation system was used to determine the hardness and elesticity modules of the coatings.
本研究的目的是;研究了不同溅射参数对射频(RF)磁控溅射法沉积MoS2薄膜厚度和硬度的影响。因此,在440C钢基体上涂覆二硫化钼薄膜,在剪切过程中表现出固体润滑剂的润滑作用和低摩擦特性。在aisi440c衬底上沉积了无夹层的MoS2薄膜和有夹层的(Ti/Cr)薄膜。在涂层过程中,通过改变衬底沉积温度和射频溅射功率等沉积参数,得到了15种不同沉积参数下涂层的钢盘组。利用扫描电镜对膜的厚度进行了测量。在不同的放大倍数下观察表面形貌。用能谱仪对其组成和结构进行了分析。采用纳米压痕系统测定了涂层的硬度和弹性模量。
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引用次数: 0
Identification of materials and coatings to minimise/eliminate Wankel rotary engine's apex seal/trochoid wear chatter 识别材料和涂层,以尽量减少/消除万克尔旋转发动机的顶点密封/齿面磨损颤振
IF 0.8 4区 工程技术 Q4 ENGINEERING, MECHANICAL Pub Date : 2020-06-24 DOI: 10.1504/ijsurfse.2020.10030176
Aakash Gupta, S. Jayaram, H. Mccormick
A well-known problem is existing in Wankel rotary engine that leads the engine to seize before it achieves operational loading conditions. Existing research literature shows one of the primary indications to cause engine seizure are the chatter marks. The present study focuses on performing bench testing to rank the combinations of chosen materials and coatings resulting in lowest friction and reduced chatter. A total combination of 11 materials and coatings were analysed and tested. It was found that titankote with PVD coating and nikasil coating with diamond particles on A-2 tool steel performed the best, resulting in no wear, scuffing or chattering, with an increased surface smoothness. The lowest coefficient of friction measured was 0.06 with HTCS-150 hard trochoid and C-Lee Cook apex seals. The maximum average face wear reduction obtained was 15 μm on titankote with PVD coated trochoid and 18 μm on ceramic apex seal.
汪克尔旋转发动机中存在一个众所周知的问题,该问题导致发动机在达到工作负载条件之前就卡住了。现有研究文献表明,导致发动机熄火的主要迹象之一是颤振痕迹。本研究的重点是进行台架测试,对所选材料和涂层的组合进行排序,以获得最低的摩擦和减少的颤振。对总共11种材料和涂层的组合进行了分析和测试。研究发现,在A-2工具钢上涂有PVD涂层的titankote和涂有金刚石颗粒的nikasil涂层表现最好,没有磨损、擦伤或抖振,表面光滑度提高。HTCS-150硬次摆线和C-Lee Cook顶点密封测得的最低摩擦系数为0.06。在涂有PVD的次摆线的钛铁矿上获得的最大平均表面磨损减少量为15μm,在陶瓷顶点密封上获得的平均表面磨损最大减少量为18μm。
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引用次数: 2
期刊
International Journal of Surface Science and Engineering
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