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Izvestiya of Saratov University. New Series. Series: Chemistry. Biology. Ecology最新文献

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Quantum chemical analysis of reactivity of several chromenopyrazoles 几种氯硝唑反应性的量子化学分析
Pub Date : 2022-03-22 DOI: 10.18500/1816-9775-2022-22-1-26-32
I. E. Menyailo, M. V. Pozharov, T. Zacharova, A. Y. Kostrickiy, I. A. Demeshko
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引用次数: 0
Some aspects of antimicrobial photodynamic effects 抗菌光动力效应的一些方面
Pub Date : 2022-03-22 DOI: 10.18500/1816-9775-2022-22-1-33-46
E. Tuchina
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引用次数: 0
The characteristics of the elemental composition of the scots pine wood in accordance with the conditions of a growing site and a vegetation phase 苏格兰松木的元素组成特征与生长地点和植被阶段的条件相一致
Pub Date : 2022-03-22 DOI: 10.18500/1816-9775-2022-22-1-47-56
A. Khokh, V. B. Zviagintsev
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引用次数: 0
Electroanalytical properties of planar sensors in aqueous environments of amoxicillin 平面传感器在阿莫西林水环境中的电分析性能
Pub Date : 2022-03-22 DOI: 10.18500/1816-9775-2022-22-1-16-25
E. G. Kulapina, R. K. Mursalov
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引用次数: 0
Evolutionary role of apomixis: S. S. Khokhlov’s hypothesis in the light of modern data 无融合的进化作用:从现代资料看S. S. Khokhlov的假说
Pub Date : 2022-03-22 DOI: 10.18500/1816-9775-2022-22-1-89-98
O. I. Yudakova, E. Kaybeleva
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引用次数: 0
Morphometry and seed productivity of some representatives of the Lamiaceae family of a plot of medicinal plants of the Botanical Garden of the Orеnburg State University orobernburg州立大学植物园药用植物片地lamiiaceae一些代表性植物的形态测定学和种子产量
Pub Date : 2022-03-22 DOI: 10.18500/1816-9775-2022-22-1-74-81
E. V. Pikalova
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引用次数: 0
Species composition of microorganisms of the trophic chain: Cereal plants – aphids 营养链微生物的种类组成:谷类植物-蚜虫
Pub Date : 2022-03-22 DOI: 10.18500/1816-9775-2022-22-1-99-109
A. .. Dymnich, E. Glinskaya
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引用次数: 0
Synthesis and structural features of 5-(4-bromophenyl)-3-((6-amino-2-mercaptopyrimidine)-4-amino))methylidene)-3Н-furan-2-one 5-(4-溴苯基)-3-((6-氨基-2-巯基嘧啶)-4-氨基))亚甲基)-3Н-furan-2-one的合成及结构特征
Pub Date : 2022-03-22 DOI: 10.18500/1816-9775-2022-22-1-4-8
А. S. Tikhomolova, O. A. Mayorova, A. Egorova
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引用次数: 0
The prospect of using Shewhart control charts in assessing the quality of ionometric measurements by the method of adding a sample to a standard 用休哈特控制图评价离子计量测量质量的前景
Pub Date : 2021-12-16 DOI: 10.18500/1816-9775-2021-21-4-399-404
V. M. Shatunov, A. I. Fokina, T. Ashikhmina
Modern methods of quantitative physical and chemical measurements should necessarily include procedures for quality control of research results. Recently, the procedure for quality control of measurements using control charts is gaining particular popularity in the practice of analytical measurements. To date, the methods of potentiometric studies operating in the territory of the Russian Federation, in most cases, do not include quality control using this control procedure. However, despite the complexity of the implementation and interpretation of its results, it is the use of control charts that allows you to control the quality of ionometric measurements. This is especially important for potentiometric determinations based on the addition method, since the instability of the slope of the electrode function and its deviation significantly contribute to the uncertainty of the measurement results. This article presents the main results of evaluating the use of the Shewhart control chart method for monitoring the repeatability and accuracy of measurement results. The measurement results have been obtained using an improved method of quantitative potentiometric determination of high concentrations (more than 1 gm/cdm) of ammonium ions by the method of adding a sample to the standard. In addition, an experimental substantiation of the fact that the value of the slope of the electrode function significantly affects the accuracy of measurements by the addition method has been presented. It has been revealed that when the angular coefficient of the electrode function is more than 62 mV/pNH4+ at (25±5)°C, deviations of the measurement results from the control standard by more than 50% are observed. It has been found that at (25±5)°С the most accurate results of quantitative determination are achieved when the angular coefficient of the electrode function is from 54 mV/pNH4+ to 62 mV/pNH4+ inclusive.
现代定量物理和化学测量方法必须包括对研究结果进行质量控制的程序。最近,使用控制图进行测量质量控制的程序在分析测量的实践中得到了特别的普及。迄今为止,在俄罗斯联邦境内进行的电位法研究方法在大多数情况下不包括使用这一控制程序进行质量控制。然而,尽管其结果的实现和解释很复杂,但正是控制图的使用使您能够控制离子计量测量的质量。这对于基于加法法的电位测定尤其重要,因为电极函数斜率的不稳定性及其偏差极大地影响了测量结果的不确定度。本文介绍了评价使用休哈特控制图法监测测量结果的可重复性和准确性的主要结果。采用在标准品中加入样品的方法,改进了高浓度(大于1 gm/cdm)铵离子的定量电位测定方法,得到了测量结果。此外,实验还证实了电极函数斜率的大小对加法法测量的精度有显著影响。结果表明,在(25±5)℃下,当电极函数的角系数大于62 mV/pNH4+时,测量结果与对照标准偏差大于50%。在(25±5)°С下,当电极函数的角系数在54 mV/pNH4+至62 mV/pNH4+范围内时,定量测定结果最准确。
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引用次数: 0
Features of the species composition and structure of fish communities in small anthropogenic reservoirs with different content of dissolved mineral nitrogen 不同溶解矿物氮含量的小型人为水库鱼类群落组成及结构特征
Pub Date : 2021-12-16 DOI: 10.18500/1816-9775-2021-21-4-466-477
B. G. Kotegov
In 22 small anthropogenic reservoirs with an area of 0.4 to 62 ha located in the territory of the Udmurt Republic, individuals of different fish species were captured and water samples were taken in late spring for analysis of NO3–, NO2– and NH4+ content. In many reservoirs, concentrations of ammonium exceed the maximum permissible according to the fishing standards for water quality, and in some this is also the case with nitrites. Ponds with zooplanktophages (bleak Alburnus alburnus (L.) and belica Leucaspius delineates (Heckel)) present in fish communities were statistically significantly different in the increased content of total dissolved mineral nitrogen from reservoirs where these two fish species were not registered. In perch and roach reservoirs, the numerical proportion of river perch Perca fluviatilis was negatively and statistically significantly related to the level of their contamination with nitrogen ionic forms.
在乌德穆尔特共和国境内面积为0.4 - 62公顷的22个小型人为水库中,捕获了不同鱼类的个体,并在春末采集了水样,分析了NO3 -、NO2 -和NH4+的含量。在许多水库中,铵的浓度超过了水质捕鱼标准所允许的最大浓度,在一些水库中,亚硝酸盐也是如此。存在浮游动物噬菌体(凄凉Alburnus Alburnus, L.)和belica Leucaspius delineates (Heckel))的池塘在未登记这两种鱼类的水库中总溶解矿物氮含量的增加具有统计学意义。在鲈鱼和蟑螂水库中,河鲈的数量比例与其氮离子形态污染水平呈显著负相关。
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引用次数: 0
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Izvestiya of Saratov University. New Series. Series: Chemistry. Biology. Ecology
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