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TasteMolNet: A machine learning-driven platform for sweet, bitter, and tasteless compounds prediction in food chemistry TasteMolNet:一个机器学习驱动的平台,用于预测食品化学中的甜、苦和无味化合物
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-08 DOI: 10.1016/j.jfca.2026.108888
Peiqin Shi , Mengfei Yang , Rui Chang , Hongli Yao
The identification of sweet and bitter compounds is essential for improving the sensory quality of foods, yet traditional analytical methods remain time-consuming and costly. To overcome this limitation, we developed a machine learning framework for high-throughput taste prediction of sweet, bitter, and tasteless compounds. Our optimized model achieved an F1 score of 88.0 %, and its reliability was validated through electronic tongue analysis and molecular docking. Furthermore, we implemented this model into an online platform named TasteMolNet (http://www.bstchem.fun/), which serves as a practical tool to accelerate sweetener discovery and bitterness modulation in food research.
甜味和苦味化合物的鉴定对于提高食品的感官质量至关重要,但传统的分析方法仍然耗时且昂贵。为了克服这一限制,我们开发了一个机器学习框架,用于高通量预测甜、苦和无味化合物的味道。优化后的模型F1得分为88.0 %,通过电子舌分析和分子对接验证了模型的可靠性。此外,我们将该模型应用于一个名为TasteMolNet的在线平台(http://www.bstchem.fun/),该平台可作为加速甜味剂发现和食品研究中苦味调节的实用工具。
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引用次数: 0
Effects of major drying methods on the stability and retention of vitamin C, B group vitamins, fat-soluble vitamins, and carotenoids in kiwifruits 主要干燥方法对猕猴桃中维生素C、B族维生素、脂溶性维生素和类胡萝卜素稳定性和保持性的影响
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-08 DOI: 10.1016/j.jfca.2026.108880
Ilknur Alibas, Servet Sami Ipek
This study investigates the effects of five drying methods—freeze, vacuum, microwave, convective, and natural—on the nutritional and visual quality of kiwifruit, focusing on the vitamin C, B-group vitamins, fat-soluble vitamins, and carotenoids. Fresh samples contained 5.57 mg/g ascorbic acid, and freeze drying retained the highest level (3.13 mg/g), followed by vacuum drying (2.63 mg/g), while natural and convective drying resulted in severe reductions (1.06 and 1.21 mg/g). Riboflavin, initially 1.59 μg/g, decreased to 0.91 μg/g after freeze drying, 0.82 μg/g after vacuum drying, and 0.54 μg/g under natural drying. Carotenoids followed similar trends, with β-carotene declining from 2.88 μg/g in fresh samples to 2.24 μg/g after freeze drying and below 1 μg/g with natural drying. Freeze and vacuum drying best preserved vitamin content and color by minimizing oxidation and thermal damage, whereas natural and convective drying led to greater losses due to prolonged heat exposure and oxidative stress. Color changes strongly correlated with nutrient degradation. Notably, ΔE was negatively associated with ascorbic acid (−0.96) and thiamine (−0.95), while hue angle correlated positively with carotenoids and fat-soluble vitamins. These results show that color parameters reliably indicate nutritional retention, offering a practical approach for quality assessment in dried fruits.
本研究考察了冷冻、真空、微波、对流和自然五种干燥方法对猕猴桃营养和视觉质量的影响,重点研究了维生素C、b族维生素、脂溶性维生素和类胡萝卜素。新鲜样品的抗坏血酸含量为5.57 mg/g,冷冻干燥的含量最高(3.13 mg/g),其次是真空干燥(2.63 mg/g),而自然干燥和对流干燥的含量则显著降低(1.06和1.21 mg/g)。核黄素最初为1.59 μg/g,冷冻干燥后降至0.91 μg,真空干燥后降至0.82 μg,自然干燥后降至0.54 μg/g。类胡萝卜素也有类似的变化趋势,新鲜样品中β-胡萝卜素含量从2.88 μg/g下降到冷冻干燥后的2.24 μg/g,自然干燥后则低于1 μg/g。冷冻和真空干燥通过最大限度地减少氧化和热损伤,最好地保存维生素含量和颜色,而自然和对流干燥由于长时间的热暴露和氧化应激导致更大的损失。颜色变化与养分降解密切相关。值得注意的是,ΔE与抗坏血酸(- 0.96)和硫胺素(- 0.95)呈负相关,而色相角与类胡萝卜素和脂溶性维生素呈正相关。这些结果表明,颜色参数可靠地反映了干果的营养保留,为干果质量评价提供了实用的方法。
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引用次数: 0
Determination of multiple bioactive components in Chrysanthemum morifolium (Hangbaiju) using hyperspectral imaging and task-incremental learning 利用高光谱成像和任务增量学习技术测定杭白菊中多种生物活性成分
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-08 DOI: 10.1016/j.jfca.2026.108885
Zeyi Cai , Xue Guo , Mengyu He , Cheng Li , Hengnian Qi , Ruibin Bai , Jian Yang , Chu Zhang
Chrysanthemum morifolium (Hangbaiju), as a flower tea, contains various bioactive components, exhibiting numerous pharmacological effects. Establishing a rapid-adaptation model for multiple components quantification is challenging. This study utilized hyperspectral imaging (HSI) and machine learning (ML) to quantify 28 Hangbaiju components. When modeled on individual bioactive components, Partial Least Squares Regression (PLSR) showed superior overall prediction, whereas deep learning (DL) excels on specific components. For some components, Residual Predictive Deviation (RPD) values of testing set shifted by more than 6. Task-incremental learning (task-IL) was applied to achieve continual learning for various regression tasks. The model rapidly adapted to new tasks by adding and training only task-specific modules within an already trained base network, while maintaining performance on previous prediction tasks. A linear relationship exists between the performance of the task-IL model and its base network, highlighting the importance of the feature extraction and cross-task generalization capabilities of base network in task-IL. This study demonstrates the potential of DL in the field of quality detection of flower teas and provides a framework for integrating HSI and DL in handling real-world scenarios across various fields.
杭白菊作为一种花茶,含有多种生物活性成分,具有多种药理作用。建立多组分定量的快速适应模型具有一定的挑战性。本研究利用高光谱成像技术(HSI)和机器学习技术(ML)对杭白酒的28种成分进行了定量分析。当对单个生物活性成分进行建模时,偏最小二乘回归(PLSR)显示出更好的整体预测能力,而深度学习(DL)在特定成分上表现出色。对于某些成分,测试集的残差预测偏差(RPD)值偏移超过6。采用任务增量学习(task-IL)实现对各种回归任务的持续学习。该模型通过在已训练的基础网络中添加和只训练特定于任务的模块来快速适应新任务,同时保持先前预测任务的性能。任务- il模型的性能与其基网络之间存在线性关系,突出了任务- il中基网络的特征提取和跨任务泛化能力的重要性。本研究展示了DL在花茶质量检测领域的潜力,并提供了一个框架,将HSI和DL结合起来处理各个领域的实际情况。
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引用次数: 0
Data driven modeling of nutritional profiles for caloric prediction using advanced machine learning techniques 利用先进的机器学习技术对营养概况进行数据驱动建模,以进行热量预测
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-08 DOI: 10.1016/j.jfca.2026.108891
Yasser Alharbi , Kusum Yadav , Lulwah M. Alkwai , Debashis Dutta , Samim Sherzod
Caloric estimation remains a cornerstone of nutritional modeling, yet formula‑based methods often fail to capture nonlinear interactions among nutrients that influence real energy yield. This study aimed to develop and evaluate machine learning models capable of accurately predicting food caloric content from standardized nutrient profiles, thereby improving estimation precision for diverse food types. A dataset of 410 food items from the USDA FoodData Central was standardized and examined for outliers using leverage statistics, ensuring uniform predictor distribution and data integrity. Seven nutritional variables, including protein, fat, carbohydrates, sugar, fiber, sodium, and potassium, served as predictors of caloric content. Six algorithms were trained and validated: Decision Tree, AdaBoost, Random Forest, Support Vector Regression, and Multi‑Layer Perceptron, with model optimization via 5‑fold cross‑validation. Among tested algorithms, the MLP achieved the highest coefficient of determination (R²≈0.996) reflecting the strong deterministic relationship between nutrient composition and calories within the standardized USDA dataset. SHAP analysis identified carbohydrates, sugar, fat, and protein as the most influential predictors, consistent with physiological expectations. The findings demonstrate that data‑driven models can replicate theoretical caloric relationships with high fidelity while capturing minor nonlinear effects absent in conventional methods. This work contributes a transparent and reproducible framework for machine learning‑based caloric estimation and underscores the potential of deep learning architectures for enhanced nutritional prediction.
热量估算仍然是营养建模的基石,但基于公式的方法往往无法捕捉到影响实际能量产出的营养物质之间的非线性相互作用。本研究旨在开发和评估能够从标准化营养概况准确预测食物热量含量的机器学习模型,从而提高对不同食物类型的估计精度。来自美国农业部食品数据中心的410种食品的数据集被标准化,并使用杠杆统计检查异常值,确保统一的预测分布和数据完整性。7个营养变量,包括蛋白质、脂肪、碳水化合物、糖、纤维、钠和钾,作为热量含量的预测因子。我们训练并验证了六种算法:决策树、AdaBoost、随机森林、支持向量回归和多层感知器,并通过5倍交叉验证对模型进行优化。在测试的算法中,MLP获得了最高的决定系数(R²≈0.996),反映了标准化USDA数据集中营养成分和卡路里之间的强确定性关系。SHAP分析确定碳水化合物、糖、脂肪和蛋白质是最具影响力的预测因子,与生理预期一致。研究结果表明,数据驱动的模型可以高保真地复制理论热量关系,同时捕获传统方法中缺乏的微小非线性效应。这项工作为基于机器学习的热量估计提供了一个透明和可重复的框架,并强调了深度学习架构在增强营养预测方面的潜力。
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引用次数: 0
Distribution characteristics of catechins, alkaloids and gallic acid in Chinese famous green tea and its application in authenticity identification 中国名品绿茶中儿茶素、生物碱和没食子酸的分布特征及其在真品鉴别中的应用
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-08 DOI: 10.1016/j.jfca.2026.108889
Zheng-Yun He , Jun Xiang , Xing-Zi Ding , Qing-Qing Luo , Hui-Wen Gu , Xiao-Li Yin
This study investigated the distribution of signature components in renowned Chinese green teas to develop a method for authenticity identification. By employing high-performance liquid chromatography-diode array detection (HPLC-DAD) coupled with the alternating trilinear decomposition (ATLD) algorithm, a second-order calibration model was constructed that effectively addressed the challenge of co-elution peaks in complex tea matrices. The method demonstrated satisfactory accuracy, with spiked recoveries ranging from 93.5 % to 119.6 % and relative standard deviations (RSDs) below 1.10 % for all analytes. Using the established ATLD-enhanced HPLC method, a quantitative analysis of ten major components in 37 Chinese green teas was conducted, and their distribution patterns were visualized. Based on these quantitative results, multivariate statistical analysis methods, principal component analysis (PCA) and orthogonal projections to latent structures discriminant analysis (OPLS-DA) were subsequently employed to effectively utilize the data for authenticity discrimination concerning the geographical origin, variety, and grade of the teas. The results revealed that characteristic components varied significantly with tea origin, variety, and grade, enabling the authenticity identification of green tea. These findings not only confirm the efficacy of key catechins for authenticity identification but also establish an analytical strategy for quality evaluation, providing a powerful framework for industrial quality control and origin verification.
本研究考察了中国著名绿茶中特征成分的分布,以建立一种鉴别真伪的方法。采用高效液相色谱-二极管阵列检测(HPLC-DAD)结合交替三线性分解(ATLD)算法,建立了二阶校正模型,有效解决了复杂茶叶基质中共洗脱峰的难题。该方法具有良好的准确度,加标回收率为93.5 % ~ 119.6 %,相对标准偏差(rsd)小于1.10 %。采用建立的高效液相色谱法,对37种中国绿茶中10种主要成分进行了定量分析,并得到了它们的分布规律。在此基础上,采用多元统计分析、主成分分析(PCA)和正交投影潜结构判别分析(OPLS-DA)等方法,对茶叶的产地、品种和品级进行真伪判别。结果表明,不同产地、品种和等级的绿茶特征成分差异显著,可用于绿茶的真伪鉴别。这些发现不仅证实了关键儿茶素在真品鉴别中的有效性,而且建立了质量评价的分析策略,为工业质量控制和产地验证提供了强有力的框架。
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引用次数: 0
Classification of Iranian king of spices (saffron) types by texture features 伊朗香料之王(藏红花)的质地特征分类
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-08 DOI: 10.1016/j.jfca.2026.108883
Amir Kazemi , Mostafa Khojastehnazhand
Precise authentication of saffron types in Iran, as the main producer not only prevents economic losses for producers and consumers, but also minimizes the threat of adulteration. Therefore, in the present research, combination of machine vision method and texture feature extraction algorithms was applied to classify 3 main types of Iran commercial saffron including Sargol, Negin, and Pushal. Three texture feature extraction algorithms including Local Binary Pattern (LBP), Gray Level Co-occurrence Matrix (GLCM), and Gray Level Run Length Matrix (GLRM) and combination of them were employed. Various machine learning models including Discriminant Analysis (DA), Support Vector Machine (SVM), K-Nearest Neighbor (KNN), and Artificial Neural Network (ANN) models were applied to evaluate the results of classification. SVM model with Linear kernel and all features had the best outcome with 87.22 % for test dataset. Furthermore, four feature selection algorithms including Chi-Square Test (CST), Minimum Redundancy Maximum Relevance (MRMR), ReliefF, and Kruskal Wallis were used to select the most important features. Selected features by CST algorithm with SVM model had the best outcome with the accuracy of 76.7 %. The results of present research confirm the applicability of machine vision technique for classification of commercial saffron types which is significant in saffron industry.
伊朗作为主要生产国,对藏红花类型进行精确认证,不仅可以防止生产者和消费者的经济损失,还可以最大限度地减少掺假的威胁。因此,本研究将机器视觉方法与纹理特征提取算法相结合,对伊朗商业藏红花Sargol、Negin、Pushal三种主要类型进行分类。采用局部二值模式(LBP)、灰度共生矩阵(GLCM)和灰度运行长度矩阵(GLRM)三种纹理特征提取算法及其组合。采用判别分析(DA)、支持向量机(SVM)、k近邻(KNN)和人工神经网络(ANN)等机器学习模型对分类结果进行评价。对于测试数据集,采用线性核和所有特征的SVM模型的准确率为87.22 %。此外,使用卡方检验(CST)、最小冗余最大相关性(MRMR)、ReliefF和Kruskal Wallis四种特征选择算法来选择最重要的特征。CST算法结合SVM模型选择特征的准确率为76.7 %,效果最好。本文的研究结果证实了机器视觉技术在商品藏红花分类中的适用性,这在藏红花工业中具有重要意义。
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引用次数: 0
Exploring the chemistry and craft behind coffee flavour underpinned by the growing coffee industry in China (Yunnan): A review 在中国(云南)不断发展的咖啡工业的支持下,探索咖啡风味背后的化学和工艺:综述
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-08 DOI: 10.1016/j.jfca.2026.108886
Xiaoyu Xu , Yanwen Yang , Siyuan Zhang , Zhiwei Ye , Xuejun Li , Yanyu Jin , Trungtín Hoàng , Tao Liu , Qing Liu , Xudong Wu , Hong Li
The rapid expansion of the global coffee industry has positioned China as a dynamic and evolving market, transitioning from a traditionally tea-centric culture to an emerging centre of coffee production and consumption. This review focuses on the science of coffee flavour with particular attention to Yunnan province, a leading region for high-quality Coffea arabica industry. Chemical foundations of flavour are examined, highlighting the contributions of a variety of compounds in shaping sensory perception. Advances in analytical methodologies, including gas and liquid chromatography-mass spectrometry, nuclear magnetic resonance, and electronic sensory systems, are reviewed for their roles in flavour profiling. Beyond chemistry, influence of genetics, climate, post-harvest processing, and microbial fermentation were discussed, as well as the emerging applications of machine learning and artificial intelligence, especially their use in flavour prediction and process optimization. Compared to traditional origins, Yunnan Arabica often exhibits a smoother body and milder acidity than the bright, wine-like acidity characteristic of Ethiopian coffees, a less pronounced nutty chocolate profile than some Brazilian counterparts, and a distinct floral and herbal complexity that differs from the balanced, caramel-like notes of high-quality Colombian beans. This unique profile positions Yunnan as a distinct and valuable origin within the global specialty coffee spectrum.
全球咖啡产业的快速扩张使中国成为一个充满活力和不断发展的市场,从传统的以茶为中心的文化转变为新兴的咖啡生产和消费中心。本文重点介绍了咖啡风味的科学,并以云南为重点,重点介绍了高品质阿拉比卡咖啡的主要产区。化学基础的味道进行了检查,突出了各种化合物在塑造感官知觉的贡献。分析方法的进展,包括气相色谱和液相色谱-质谱,核磁共振和电子感觉系统,回顾了它们在风味分析中的作用。除了化学之外,还讨论了遗传、气候、收获后加工和微生物发酵的影响,以及机器学习和人工智能的新兴应用,特别是它们在风味预测和工艺优化方面的应用。与传统产地相比,云南阿拉比卡咖啡的口感更顺滑,酸度更温和,而埃塞俄比亚咖啡的酸度则更明亮,像葡萄酒一样;与一些巴西咖啡相比,云南阿拉比卡咖啡的坚果巧克力味不那么明显;与高品质哥伦比亚咖啡豆的焦糖味平衡不同,云南阿拉比卡咖啡有独特的花香和草药味。这一独特的概况使云南成为全球精品咖啡谱系中独特而有价值的原产地。
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引用次数: 0
Macro-, micro- and potential toxic elements in commercial Algerian date syrup: Safety aspects and dietary risk assessment 商业阿尔及利亚枣糖浆中的宏、微和潜在有毒元素:安全性和膳食风险评估
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-08 DOI: 10.1016/j.jfca.2026.108887
Qada Benameur , Angela Giorgia Potortì , Vincenzo Nava , Federica Litrenta , Nadra Rechidi-Sidhoum , Meki Boutaiba Benklaouz , Benedetta Sgrò , Ambrogina Albergamo , Giuseppa Di Bella
Date syrup, a traditional Saharan product, is attracting attention as a natural sugar alternative for the North African food sector. Its beneficial dietary and medicinal effects are attributed to its natural antioxidants, sugars, and minerals. However, poor agricultural practices and environmental factors may cause contaminants to be released into date syrup. Therefore, mineral content of seven commercial date syrups from various Algerian areas was analyzed by ICP-MS, including for the first time toxic and potentially toxic elements. Estimated dietary intakes (EDIs) were calculated for children (1–3 years) and adults, based on a daily serving of 10 g/day and 30 g/day. The plausibility of chronic non-carcinogenic risks was assessed by calculating the hazard quotient (HQ). Mineral profile was dominated by K, followed by Ca, Mg, Na, Fe, and Zn in most samples. Pb concentrations were always below the maximum limit permitted by European Regulation 915/2023 (0.1 mg/kg). EDIs did not exceed the reference limits. However, since the As percentage absorbed by children in some cases covered 38 % of its TDI, it is essential to strenghten monitor programs on this natural sweeting agent and establish evidence-based guidelines for its correct consumption.
枣糖浆是一种传统的撒哈拉产品,作为北非食品部门的天然糖替代品正引起人们的注意。其有益的饮食和药用作用归因于其天然抗氧化剂,糖和矿物质。然而,不良的农业实践和环境因素可能导致污染物释放到枣糖浆中。因此,采用ICP-MS分析了来自阿尔及利亚不同地区的七种商业枣糖浆的矿物质含量,首次包括有毒和潜在有毒元素。儿童(1-3岁)和成人的估计膳食摄入量(EDIs)是根据每日摄入量10 克/天和30 克/天计算的。通过计算危害商数(HQ)来评估慢性非致癌风险的合理性。矿物分布以K为主,其次为Ca、Mg、Na、Fe和Zn。铅浓度始终低于欧洲法规915/2023允许的最大限值(0.1 mg/kg)。EDIs未超过参考限值。然而,由于儿童在某些情况下吸收的a百分比占TDI的38% %,因此必须加强对这种天然甜味剂的监测计划,并为其正确食用建立基于证据的指导方针。
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引用次数: 0
Genetic diversity and nutritional variation in food crops in Ghana: A systematic review 加纳粮食作物的遗传多样性和营养变异:系统综述
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-07 DOI: 10.1016/j.jfca.2026.108878
Eunice Afia Amponsah , Amma Larbi , Moses Etsey , Gifty Yeboah , Linda Nana Esi Aduku , Charles Apprey , Herman Erick Lutterodt , Reginald Adjetey Annan
Genetic diversity, which encompasses variations in gene sequences within a species, significantly impacts traits such as yield, nutrient content, resilience, and adaptability. This systematic review focuses on the nutritional profiles of key food crops: cassava (Manihot esculenta), tomato (Solanum lycopersicum), bambara groundnut (Vigna subterranea), and fonio (Digitaria exilis), following Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines and examining studies from the past 20 years. After a comprehensive search of four databases, 5 studies on cassava, 9 on tomato, 6 on bambara groundnut, and 1 on fonio were selected. The findings reveal notable nutritional variations based on genotype: cassava genotypes exhibited high range hydrogen cyanide levels and starch content; tomato genotypes varied moderately in lycopene levels, and bambara groundnut accessions showed moderate protein levels and polyunsaturated fatty acids (PUFA) content up to 51.6 %. Although fonio exhibited limited genetic diversity, it maintained unique nutritional properties. Overall, the review indicates that utilising genetic diversity can aid in breeding nutrient-rich, resilient crops, enhancing food and nutrition security in resource-limited areas.
遗传多样性,包括物种内基因序列的变化,对产量、营养成分、恢复力和适应性等性状有显著影响。本系统综述的重点是主要粮食作物的营养概况:木薯(Manihot esculenta),番茄(Solanum lycopersicum), bambara groundnut (Vigna subterranea)和fonio (Digitaria exilis),遵循系统综述和荟萃分析(PRISMA)指南的首选报告项目,并检查了过去20年的研究。通过对4个数据库的综合检索,筛选出木薯5篇,番茄9篇,竹花生6篇,玉米1篇。研究结果表明,不同基因型木薯的营养成分存在显著差异:基因型木薯氰化氢含量和淀粉含量范围较大;番茄红素水平在番茄基因型中有中等差异,花生基因型中蛋白质水平中等,多不饱和脂肪酸(PUFA)含量高达51.6% %。尽管fonio表现出有限的遗传多样性,但它保持了独特的营养特性。总体而言,该综述表明,利用遗传多样性有助于培育营养丰富、抗灾能力强的作物,增强资源有限地区的粮食和营养安全。
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引用次数: 0
Detection of Chloramphenicol in milk and honey by electrochemical sensors based on iron, cobalt, and nickel trimetals/carbon nanosheets 基于铁、钴和镍三金属/碳纳米片的电化学传感器检测牛奶和蜂蜜中的氯霉素
IF 4.6 2区 农林科学 Q2 CHEMISTRY, APPLIED Pub Date : 2026-01-07 DOI: 10.1016/j.jfca.2026.108879
Fangxun Liu, Yanrui Li, Shuang Liu, Pinyi Zhao, Xin Yang, Xin Li, Jinpeng Liu, Zheng Zhang, Genggeng Zhang, Peigang Han, Xianling Wang, Xinjian Yang, Huan Wang
In this paper, we designed and synthesized nitrogen, iron, cobalt and nickel trimetallic loaded carbon nanosheets to detect chloramphenicol (CAP). Melamine was used as the carbon source and cobalt acetate tetrahydrate, nickel nitrate hexahydrate and potassium iron oxalate as the metal sources. Under hydrothermal reaction, melamine reacted with cobalt acetate tetrahydrate and nickel nitrate hexahydrate to form melamine cobalt-nickel complex, and then under high temperature calcination, the carbon nanosheets were carbonized, the metal ions were reduced to metal nanoparticles, and at the same time iron and nitrogen were co-doped, and finally, a new type of metal nanomaterials with three-metal (Fe, Co, Ni) loaded carbon nanosheets was obtained. The electrochemical detection results showed that Co Ni Fe NPs@CNS showed good electrocatalytic performance for CAP, exhibiting a wide detection range (0.1 µM-1000 µM), low detection limit (0.008 µM) and high sensitivity (0.3342 µA/µM). The recovery rate range for honey samples is 97.20 %-101.87 %, the recovery rate range for milk samples is 96.9 %-102.60 %. It can be used for the detection of actual samples with strong anti-interference ability. The electrocatalyst we studied has significant advantages in food detection due to its low detection limit, low cost, and good selectivity, and it demonstrates broad application prospects in the field of food analysis and detection.
本文设计并合成了氮、铁、钴和镍三金属负载的碳纳米片,用于检测氯霉素(CAP)。以三聚氰胺为碳源,四水合乙酸钴、六水合硝酸镍和草酸铁钾为金属源。在水热反应下,三聚氰胺与四水合乙酸钴和六水合硝酸镍反应形成三聚氰胺钴镍配合物,然后在高温煅烧下对碳纳米片进行碳化,将金属离子还原为金属纳米粒子,同时对铁和氮进行共掺杂,最终得到了一种新型的三金属(Fe、Co、Ni)负载碳纳米片的金属纳米材料。电化学检测结果表明,Co Ni Fe NPs@CNS对CAP具有良好的电催化性能,检测范围宽(0.1µM-1000µM),检出限低(0.008 µM),灵敏度高(0.3342 µa /µM)。蜂蜜样品的回收率范围为97.20 % ~ 101.87 %,牛奶样品的回收率范围为96.9 % ~ 102.60 %。可用于实际样品的检测,抗干扰能力强。所研究的电催化剂检出限低、成本低、选择性好,在食品分析检测领域具有显著优势,在食品分析检测领域具有广阔的应用前景。
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引用次数: 0
期刊
Journal of Food Composition and Analysis
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