Pub Date : 2024-09-01DOI: 10.1016/j.jmst.2024.08.012
Jie Kuang, Wei Wen, Pengming Cheng, Gang Liu, Jinyu Zhang, Jun Sun
Molybdenum (Mo) alloys are essential for applications requiring outstanding mechanical properties at high temperatures across various industrial sectors. Understanding and predicting the creep properties of Mo alloys is crucial for service safety and the design of new materials. This study introduces a physics-based crystallographic creep model dedicated to the characteristic hierarchical microstructure of Mo–La2O3 alloys. By sourcing most parameters from existing literature and calibrating others within recommended ranges, the model efficiently predicts creep behavior beyond its initial calibration scope. Through the integration of microstructure descriptors, we systematically explored the impact of different microstructural features on creep behavior and identified underlying mechanisms. This analysis yielded two pivotal concepts: the minimum acceptable grain size and the necessary nanoparticle number density. These metrics, readily obtainable from the model, quantify the requisite grain size and nanoparticle content to achieve the target steady-state creep rates for operational demands, thus providing essential insights for the creep condition-oriented design of Mo–La2O3 alloys. The model is also expected to be adaptable for developing other Mo alloys reinforced by second phase particles, aimed at achieving desired creep properties under specified conditions, assuming that relevant parameters are accessible through literature or lower-scale simulations.
{"title":"Creep condition-oriented design of molybdenum alloys with La2O3 addition assisted by microstructure-based crystal plasticity modeling","authors":"Jie Kuang, Wei Wen, Pengming Cheng, Gang Liu, Jinyu Zhang, Jun Sun","doi":"10.1016/j.jmst.2024.08.012","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.012","url":null,"abstract":"<p>Molybdenum (Mo) alloys are essential for applications requiring outstanding mechanical properties at high temperatures across various industrial sectors. Understanding and predicting the creep properties of Mo alloys is crucial for service safety and the design of new materials. This study introduces a physics-based crystallographic creep model dedicated to the characteristic hierarchical microstructure of Mo–La<sub>2</sub>O<sub>3</sub> alloys. By sourcing most parameters from existing literature and calibrating others within recommended ranges, the model efficiently predicts creep behavior beyond its initial calibration scope. Through the integration of microstructure descriptors, we systematically explored the impact of different microstructural features on creep behavior and identified underlying mechanisms. This analysis yielded two pivotal concepts: the minimum acceptable grain size and the necessary nanoparticle number density. These metrics, readily obtainable from the model, quantify the requisite grain size and nanoparticle content to achieve the target steady-state creep rates for operational demands, thus providing essential insights for the creep condition-oriented design of Mo–La<sub>2</sub>O<sub>3</sub> alloys. The model is also expected to be adaptable for developing other Mo alloys reinforced by second phase particles, aimed at achieving desired creep properties under specified conditions, assuming that relevant parameters are accessible through literature or lower-scale simulations.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-01DOI: 10.1016/j.jmst.2024.08.010
Yuhang Wang, Yang Zhao, Shaogang Wang, Ji Chen, Tao Zhang, Fuhui Wang
A principle was proposed for designing a method to seal anodized aluminum used in semiconductor processing apparatuses. Thermodynamic calculations and Fick's second law were used to reveal trends in the metal ion deposition, deposition product stability, vapor pressures of halides for selected metal ions, the holding temperature, and time. Interactions between ion concentrations and the sealing temperature were also revealed. According to the design principles, anodized aluminum dipped in 1 mM Cr3+ ion solution and steam-sealed for 18 h exhibited the highest corrosion resistance when exposed to 5 wt.% HCl solution and HCl gas, verifying the designed results.
{"title":"Thermodynamics-based sealing method for anodized aluminum used in semiconductor processing apparatuses","authors":"Yuhang Wang, Yang Zhao, Shaogang Wang, Ji Chen, Tao Zhang, Fuhui Wang","doi":"10.1016/j.jmst.2024.08.010","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.010","url":null,"abstract":"<p>A principle was proposed for designing a method to seal anodized aluminum used in semiconductor processing apparatuses. Thermodynamic calculations and Fick's second law were used to reveal trends in the metal ion deposition, deposition product stability, vapor pressures of halides for selected metal ions, the holding temperature, and time. Interactions between ion concentrations and the sealing temperature were also revealed. According to the design principles, anodized aluminum dipped in 1 mM Cr<sup>3+</sup> ion solution and steam-sealed for 18 h exhibited the highest corrosion resistance when exposed to 5 wt.% HCl solution and HCl gas, verifying the designed results.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-01DOI: 10.1016/j.jmst.2024.07.049
Xin Liu, Yulong Zhang, Mingyang Tang, Xiaodan Ren, Liqing Hu, Yike Wang, Zhuo Xu, Liwei D. Geng, Yongke Yan
The types of dopants lead to distinctive microstructural evolution behavior and physical properties in materials. In this study, the effect of stoichiometric and non-stoichiometric Mn modification, namely Pb(Mn1/3Nb2/3)O3 (PMnN) and MnO2, on the microstructure and properties of Pb(Yb1/2Nb1/2)O3-PbZrO3-PbTiO3 (PYN-PZT) piezoelectric ceramics are systematically investigated. It was found that stoichiometric PMnN modification inhibits the grain growth while non-stoichiometric MnO2 modification promotes it, and thus the former yields stronger high-power characteristics (higher internal bias field Ei and larger mechanical quality factor Qm) than the latter. Specifically, with an equivalent amount of Mn modification (2 mol%), PMnN and MnO2 modification PYN-PZT ceramics exhibit significantly different values for average grain size (1.21 μm vs. 14.12 μm), Ei (8.5 kV/cm vs. 5 kV/cm), and Qm (2376 vs.1134). To further evaluate high-power performance, the vibration velocity v of these two modified PYN-PZT under high driving conditions was measured. Under an AC electric field of 3.5 V/mm, the PYN-PZT+6PMnN ceramics exhibit a v of up to 0.95 m/s, larger than both MnO2-doped PYN-PZT (0.72 m/s) and unmodified PYN-PZT ceramics (0.1 m/s), and far outperformance than both PZT-4 and PZT-8 ceramics. Furthermore, to elucidate the origin of the exceptional high-power performance of PMnN-modified PYN-PZT, we performed phase-field simulations revealing a pinning effect of the grain boundary on domain wall motion. Consequently, the small grain size (high grain boundary density) in PMnN-modified PYN-PZT exhibits a strong pinning effect, resulting in a large Qm and outstanding high-power performance.
{"title":"Stoichiometric and non-stoichiometric Mn modification on high-power properties in PYN-PZT piezoelectric ceramics","authors":"Xin Liu, Yulong Zhang, Mingyang Tang, Xiaodan Ren, Liqing Hu, Yike Wang, Zhuo Xu, Liwei D. Geng, Yongke Yan","doi":"10.1016/j.jmst.2024.07.049","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.07.049","url":null,"abstract":"<p>The types of dopants lead to distinctive microstructural evolution behavior and physical properties in materials. In this study, the effect of stoichiometric and non-stoichiometric Mn modification, namely Pb(Mn<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub> (PMnN) and MnO<sub>2</sub>, on the microstructure and properties of Pb(Yb<sub>1/2</sub>Nb<sub>1/2</sub>)O<sub>3</sub>-PbZrO<sub>3</sub>-PbTiO<sub>3</sub> (PYN-PZT) piezoelectric ceramics are systematically investigated. It was found that stoichiometric PMnN modification inhibits the grain growth while non-stoichiometric MnO<sub>2</sub> modification promotes it, and thus the former yields stronger high-power characteristics (higher internal bias field <em>E</em><sub>i</sub> and larger mechanical quality factor <em>Q</em><sub>m</sub>) than the latter. Specifically, with an equivalent amount of Mn modification (2 mol%), PMnN and MnO<sub>2</sub> modification PYN-PZT ceramics exhibit significantly different values for average grain size (1.21 μm <em>vs.</em> 14.12 μm), <em>E</em><sub>i</sub> (8.5 kV/cm <em>vs.</em> 5 kV/cm), and <em>Q</em><sub>m</sub> (2376 <em>vs.</em>1134). To further evaluate high-power performance, the vibration velocity <em>v</em> of these two modified PYN-PZT under high driving conditions was measured. Under an AC electric field of 3.5 V/mm, the PYN-PZT+6PMnN ceramics exhibit a <em>v</em> of up to 0.95 m/s, larger than both MnO<sub>2</sub>-doped PYN-PZT (0.72 m/s) and unmodified PYN-PZT ceramics (0.1 m/s), and far outperformance than both PZT-4 and PZT-8 ceramics. Furthermore, to elucidate the origin of the exceptional high-power performance of PMnN-modified PYN-PZT, we performed phase-field simulations revealing a pinning effect of the grain boundary on domain wall motion. Consequently, the small grain size (high grain boundary density) in PMnN-modified PYN-PZT exhibits a strong pinning effect, resulting in a large <em>Q</em><sub>m</sub> and outstanding high-power performance.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this study, Ge4+-substituted cordierite, Mg2Al4(Si1–xGex)5O18 ceramics, were successfully prepared by the traditional solid-state method to broaden its application potential. Notably, the excellent dielectric properties with εr = 4.90, Q·f = 128,200 GHz, and τf = −21.01 ppm °C–1 were achieved. The increase in εr value is mainly due to the heightened content of Ge4+ with high polarizability. The Q·f value improved by 2.21 times compared to the cordierite matrix, which can be primarily attributed to enhanced lattice energy, bond covalency, and hexagonal ring symmetry. The alteration in τf value arises from the variation of bond energy, bond strength, and distortion in the [MgO6] octahedra. These conclusions provide valuable insights for the design of silicate ceramics with higher Q·f values. In addition, the dielectric properties in the microwave and terahertz bands were compared. The higher Q·f and lower εr values in the terahertz band mainly result from the withdrawal of partial polarization mechanisms and differences in measurement methods. Mg2Al4(Si0.92Ge0.08)5O18 ceramics, demonstrating an ultra-low εr value of 4.54 and an ultra-high Q·f value of 286,533 GHz in the terahertz band, emerge as formidable contenders for future terahertz communications materials. Finally, a microstrip patch antenna was fabricated, achieving a bandwidth of 150 MHz at 4.78 GHz, which confirms the application in the n79 band for wireless communication.
{"title":"Effect of Ge4+-substituted on the structure characteristics and microwave/terahertz dielectric properties of ultra-low εr, high Q·f cordierite ceramics","authors":"Huanrong Tian, Yiyun Zhang, Ruihan Wang, Haitao Wu, Lianwei Shan","doi":"10.1016/j.jmst.2024.08.008","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.008","url":null,"abstract":"<p>In this study, Ge<sup>4+</sup>-substituted cordierite, Mg<sub>2</sub>Al<sub>4</sub>(Si<sub>1–</sub><em><sub>x</sub></em>Ge<em><sub>x</sub></em>)<sub>5</sub>O<sub>18</sub> ceramics, were successfully prepared by the traditional solid-state method to broaden its application potential. Notably, the excellent dielectric properties with <em>ε</em><sub>r</sub> = 4.90, <em>Q</em>·<em>f</em> = 128,200 GHz, and <em>τ</em><sub>f</sub> = −21.01 ppm °C<sup>–1</sup> were achieved. The increase in <em>ε</em><sub>r</sub> value is mainly due to the heightened content of Ge<sup>4+</sup> with high polarizability. The <em>Q</em>·<em>f</em> value improved by 2.21 times compared to the cordierite matrix, which can be primarily attributed to enhanced lattice energy, bond covalency, and hexagonal ring symmetry. The alteration in <em>τ</em><sub>f</sub> value arises from the variation of bond energy, bond strength, and distortion in the [MgO<sub>6</sub>] octahedra. These conclusions provide valuable insights for the design of silicate ceramics with higher <em>Q</em>·<em>f</em> values. In addition, the dielectric properties in the microwave and terahertz bands were compared. The higher <em>Q</em>·<em>f</em> and lower <em>ε</em><sub>r</sub> values in the terahertz band mainly result from the withdrawal of partial polarization mechanisms and differences in measurement methods. Mg<sub>2</sub>Al<sub>4</sub>(Si<sub>0.92</sub>Ge<sub>0.08</sub>)<sub>5</sub>O<sub>18</sub> ceramics, demonstrating an ultra-low <em>ε</em><sub>r</sub> value of 4.54 and an ultra-high <em>Q</em>·<em>f</em> value of 286,533 GHz in the terahertz band, emerge as formidable contenders for future terahertz communications materials. Finally, a microstrip patch antenna was fabricated, achieving a bandwidth of 150 MHz at 4.78 GHz, which confirms the application in the n79 band for wireless communication.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
With the rapid development of 5G technology and the interconnection of industrial production, electromagnetic pollution has become a serious problem. Achieving lightweight and controllable loads of absorbers while obtaining corrosion-resistant absorbers with high electromagnetic response properties is still considered a huge challenge. In this work, carbon fiber with a multichannel hollow structure is obtained by PAN/PS hybrid electrospinning and subsequent high-temperature roasting process. The spatial structure inside the carbon fiber plays an active role in optimizing the impedance matching characteristics of the absorber. In addition, bimetallic metal-organic frameworks (MOFs) derivatives are obtained by a precisely controlled ion exchange as well as a high-temperature gas-phase selenization process. The resulting introduction of a non-homogeneous interface induces interfacial polarization and improves the absorption behavior of the absorber. The analysis of the experimental results shows that the electromagnetic wave (EMW) absorption performance can be effectively enhanced due to the mechanisms of interface polarization and dipole polarization. The prepared NiSe/ZnSe/MHCFs composite can obtain excellent EMW absorption properties in C, X, and Ku bands by adjusting the thickness. Structural design and component modulation play a crucial role in realizing the strong absorption and wide bandwidth of the absorber. Radar cross-section calculations indicate that NiSe/ZnSe/MHCFs have tremendous potential in practical military stealth technology. And the prepared composite coating can provide periodic corrosion resistance to Q235 steel sheet when dealing with complex and extreme environments.
{"title":"MOF derivatives anchored to multichannel hollow carbon fibers with gradient structures for corrosion resistance and efficient electromagnetic wave absorption","authors":"Yuhang Cheng, Di Lan, Zirui Jia, Zhenguo Gao, Xuehua Liu, Xuetao Shi, Mukun He, Hua Guo, Guanglei Wu","doi":"10.1016/j.jmst.2024.08.004","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.004","url":null,"abstract":"<p>With the rapid development of 5G technology and the interconnection of industrial production, electromagnetic pollution has become a serious problem. Achieving lightweight and controllable loads of absorbers while obtaining corrosion-resistant absorbers with high electromagnetic response properties is still considered a huge challenge. In this work, carbon fiber with a multichannel hollow structure is obtained by PAN/PS hybrid electrospinning and subsequent high-temperature roasting process. The spatial structure inside the carbon fiber plays an active role in optimizing the impedance matching characteristics of the absorber. In addition, bimetallic metal-organic frameworks (MOFs) derivatives are obtained by a precisely controlled ion exchange as well as a high-temperature gas-phase selenization process. The resulting introduction of a non-homogeneous interface induces interfacial polarization and improves the absorption behavior of the absorber. The analysis of the experimental results shows that the electromagnetic wave (EMW) absorption performance can be effectively enhanced due to the mechanisms of interface polarization and dipole polarization. The prepared NiSe/ZnSe/MHCFs composite can obtain excellent EMW absorption properties in C, X, and Ku bands by adjusting the thickness. Structural design and component modulation play a crucial role in realizing the strong absorption and wide bandwidth of the absorber. Radar cross-section calculations indicate that NiSe/ZnSe/MHCFs have tremendous potential in practical military stealth technology. And the prepared composite coating can provide periodic corrosion resistance to Q235 steel sheet when dealing with complex and extreme environments.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-30DOI: 10.1016/j.jmst.2024.07.046
Jin Liang, Zhiheng Wei, Xiaoyi Chen, Zongcheng Li, Xiaoshan Li, Chenyang Zhang, Jun Chen, Jie Kong
Highly developed electronic information technology has undoubtedly resulted in numerous benefits to the military and public life. However, the resulting electromagnetic wave (EW) pollution cannot be ignored. Therefore, the application of highly efficient EW materials is becoming an important requirement. In this study, magnetic-dielectric heterointerface strategy was applied to construct absorbers with desirable electromagnetic wave properties. A novel CoO/Co nanoparticle anchored to N-doped mesoporous carbon (CoO/Co/N-CMK-3) composites was fabricated by facile precipitation reaction and the electromagnetic characteristics have been well optimized by adjusting pyrolysis temperature. The CoO/Co/N-CMK-3 yielded its highest performance at an annealing temperature of 800 °C, with an extended effective absorption bandwidth of 5.83 GHz and unusually low minimum reflection loss of−63.82 dB, even at a thickness of just 1.8 mm and low filler loading (10%). For the excellent microwave absorption property, the advantages of the CoO/Co/N-CMK-3 can be summed up as follows. Firstly, the incorporation of heterointerfaces among N-CMK-3, CoO, and Co introduces abundant polarization centers, triggering various polarization effects and increasing dielectric losses. Secondly, the CoO/Co magnetic component introduced the strong magnetic loss and improved the impedance matching capability of CoO/Co/N-CMK-3. Thirdly, the extraordinary magnetic-dielectric behavior is supported by multiple magnetic coupling networks and enriched air-material heterointerfaces, boosted the magnetoelectric cooperative loss for further optimizing the electromagnetic dissipation and broadening the effective absorption frequency band. Moreover, the CST simulation results validate the impressive operational bandwidth and reflection loss characteristics of the obtained absorbers. This study demonstrates a novel heterointerface engineering strategy for designing lightweight, wide-band, and high-performance EW absorbers.
高度发达的电子信息技术无疑为军事和公众生活带来了诸多益处。然而,由此产生的电磁波(EW)污染也不容忽视。因此,高效电磁波材料的应用成为一项重要需求。本研究采用磁介质异质界面策略来构建具有理想电磁波特性的吸收体。通过简便的沉淀反应,制备了一种新型的锚定于掺杂 N 的介孔碳(CoO/Co/N-CMK-3)的 CoO/Co 纳米粒子复合材料,并通过调节热解温度对其电磁特性进行了优化。CoO/Co/N-CMK-3 在退火温度为 800 ℃ 时性能最高,有效吸收带宽扩展到 5.83 GHz,最小反射损耗低至 63.82 dB,即使厚度仅为 1.8 mm 且填料含量较低(10%)时也是如此。CoO/Co/N-CMK-3 具有优异的微波吸收特性,其优势可归纳为以下几点。首先,N-CMK-3、CoO 和 Co 之间的异质界面引入了丰富的极化中心,引发了各种极化效应,增加了介电损耗。其次,CoO/Co 磁性成分引入了强磁损耗,提高了 CoO/Co/N-CMK-3 的阻抗匹配能力。第三,多重磁耦合网络和丰富的空气材料异质界面支持了非凡的磁介行为,提高了磁电协同损耗,从而进一步优化了电磁耗散并拓宽了有效吸收频带。此外,CST 仿真结果验证了所获得的吸收器令人印象深刻的工作带宽和反射损耗特性。这项研究为设计轻质、宽带和高性能的电磁波吸收器展示了一种新颖的异质表面工程策略。
{"title":"Heterointerface engineering of CoO/Co with ordered carbon for synergistic magnetoelectric coupling to enhance wideband microwave absorption","authors":"Jin Liang, Zhiheng Wei, Xiaoyi Chen, Zongcheng Li, Xiaoshan Li, Chenyang Zhang, Jun Chen, Jie Kong","doi":"10.1016/j.jmst.2024.07.046","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.07.046","url":null,"abstract":"<p>Highly developed electronic information technology has undoubtedly resulted in numerous benefits to the military and public life. However, the resulting electromagnetic wave (EW) pollution cannot be ignored. Therefore, the application of highly efficient EW materials is becoming an important requirement. In this study, magnetic-dielectric heterointerface strategy was applied to construct absorbers with desirable electromagnetic wave properties. A novel CoO/Co nanoparticle anchored to N-doped mesoporous carbon (CoO/Co/N-CMK-3) composites was fabricated by facile precipitation reaction and the electromagnetic characteristics have been well optimized by adjusting pyrolysis temperature. The CoO/Co/N-CMK-3 yielded its highest performance at an annealing temperature of 800 °C, with an extended effective absorption bandwidth of 5.83 GHz and unusually low minimum reflection loss of−63.82 dB, even at a thickness of just 1.8 mm and low filler loading (10%). For the excellent microwave absorption property, the advantages of the CoO/Co/N-CMK-3 can be summed up as follows. Firstly, the incorporation of heterointerfaces among N-CMK-3, CoO, and Co introduces abundant polarization centers, triggering various polarization effects and increasing dielectric losses. Secondly, the CoO/Co magnetic component introduced the strong magnetic loss and improved the impedance matching capability of CoO/Co/N-CMK-3. Thirdly, the extraordinary magnetic-dielectric behavior is supported by multiple magnetic coupling networks and enriched air-material heterointerfaces, boosted the magnetoelectric cooperative loss for further optimizing the electromagnetic dissipation and broadening the effective absorption frequency band. Moreover, the CST simulation results validate the impressive operational bandwidth and reflection loss characteristics of the obtained absorbers. This study demonstrates a novel heterointerface engineering strategy for designing lightweight, wide-band, and high-performance EW absorbers.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-30DOI: 10.1016/j.jmst.2024.08.005
D.H. Chung, J. Lee, Q.F. He, Y.K. Kim, K.R. Lim, H.S. Kim, Y. Yang, Y.S. Na
No Abstract
无摘要
{"title":"Corrigendum to “Hetero-deformation promoted strengthening and toughening in BCC rich eutectic and near eutectic high entropy alloys”","authors":"D.H. Chung, J. Lee, Q.F. He, Y.K. Kim, K.R. Lim, H.S. Kim, Y. Yang, Y.S. Na","doi":"10.1016/j.jmst.2024.08.005","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.005","url":null,"abstract":"No Abstract","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-30DOI: 10.1016/j.jmst.2024.07.047
Wenquan Lu, Liang Zhao, Zhun Su, Jianguo Li, Qiaodan Hu
Laser additive manufacturing (LAM) has been widely used in high-end manufacturing fields such as aerospace, nuclear power, and shipbuilding. However, it is a grand challenge for direct and continuous observation of complex laser-matter interaction, melt flow, and defect formation during LAM due to extremely large temperature gradient, fast cooling rate, and small time (millisecond) and space (micron) scales. The emergence of synchrotron radiation provides a feasible approach for in situ observation of the LAM process. This paper outlines the current development in real-time characterization of LAM by synchrotron radiation, including laser-matter interaction, molten pool evolution, solidification structure evolution, and defects formation and elimination. Furthermore, the future development direction and application-oriented research are also discussed.
{"title":"Recent progress on in-situ characterization of laser additive manufacturing process by synchrotron radiation","authors":"Wenquan Lu, Liang Zhao, Zhun Su, Jianguo Li, Qiaodan Hu","doi":"10.1016/j.jmst.2024.07.047","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.07.047","url":null,"abstract":"<p>Laser additive manufacturing (LAM) has been widely used in high-end manufacturing fields such as aerospace, nuclear power, and shipbuilding. However, it is a grand challenge for direct and continuous observation of complex laser-matter interaction, melt flow, and defect formation during LAM due to extremely large temperature gradient, fast cooling rate, and small time (millisecond) and space (micron) scales. The emergence of synchrotron radiation provides a feasible approach for <em>in situ</em> observation of the LAM process. This paper outlines the current development in real-time characterization of LAM by synchrotron radiation, including laser-matter interaction, molten pool evolution, solidification structure evolution, and defects formation and elimination. Furthermore, the future development direction and application-oriented research are also discussed.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142101101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1016/j.jmst.2024.07.028
Hong Yang, Jingjing Li, Han Shen, Dongxu Jia, Yujuan Jia, Zhu Wang, Qian Yu, Zhenya Shen, Yanxia Zhang
Myocardial infarction (MI) continues to be the primary cause of death globally. Oxidative stress in the initial phase of MI, followed by uncontrolled and excessive myocardial fibrosis, significantly impedes cardiac repair efficiency post-MI, culminating in adverse ventricular remodeling and potential heart failure. To address the diverse pathological stages of MI, an injectable composite hydrogel containing versatile nanoparticles was developed. In this study, mesoporous silicon nanoparticles (MSNs) served as carriers for encapsulating microRNA-29b (miR-29b) mimics with antifibrotic activity, subsequently coated with a complex of natural antioxidant tannic acid and zinc ions (TA/Zn). These nanoparticles were then embedded into a biocompatible alginate hydrogel to enhance retention within the infarcted myocardium. Upon injection into the infarcted region of MI mice, the composite hydrogel gradually released the nanoparticles as it degraded. Initially, the TA/Zn complex on the outer layer scavenged reactive oxygen species, thereby inhibiting cell apoptosis. The subsequent dissociation of the TA/Zn complex led to the release of the encapsulated miR-29b mimics that could inhibit the activation of cardiac fibroblasts and collagen production, thereby alleviating fibrosis progression. Overall, this composite hydrogel demonstrated the potential to reduce infarct size and improve cardiac function, suggesting its promise as a synergistic therapeutic approach for repairing infarcted myocardium.
{"title":"An injectable hydrogel containing versatile nanoparticles with antioxidant and antifibrotic properties for myocardial infarction treatment","authors":"Hong Yang, Jingjing Li, Han Shen, Dongxu Jia, Yujuan Jia, Zhu Wang, Qian Yu, Zhenya Shen, Yanxia Zhang","doi":"10.1016/j.jmst.2024.07.028","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.07.028","url":null,"abstract":"<p>Myocardial infarction (MI) continues to be the primary cause of death globally. Oxidative stress in the initial phase of MI, followed by uncontrolled and excessive myocardial fibrosis, significantly impedes cardiac repair efficiency post-MI, culminating in adverse ventricular remodeling and potential heart failure. To address the diverse pathological stages of MI, an injectable composite hydrogel containing versatile nanoparticles was developed. In this study, mesoporous silicon nanoparticles (MSNs) served as carriers for encapsulating microRNA-29b (miR-29b) mimics with antifibrotic activity, subsequently coated with a complex of natural antioxidant tannic acid and zinc ions (TA/Zn). These nanoparticles were then embedded into a biocompatible alginate hydrogel to enhance retention within the infarcted myocardium. Upon injection into the infarcted region of MI mice, the composite hydrogel gradually released the nanoparticles as it degraded. Initially, the TA/Zn complex on the outer layer scavenged reactive oxygen species, thereby inhibiting cell apoptosis. The subsequent dissociation of the TA/Zn complex led to the release of the encapsulated miR-29b mimics that could inhibit the activation of cardiac fibroblasts and collagen production, thereby alleviating fibrosis progression. Overall, this composite hydrogel demonstrated the potential to reduce infarct size and improve cardiac function, suggesting its promise as a synergistic therapeutic approach for repairing infarcted myocardium.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142090501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-29DOI: 10.1016/j.jmst.2024.08.003
Cheng Qian, Kun Li, Yong Liu, Xin Zhang, Shuailong Zhang, Ji Zhang, Lijun Jiang, Huichao Cheng
The good combination of mechanical and wear properties for cemented carbides is crucial. In this work, the wear behavior of functionally graded cemented carbide (FGCC) and non-graded cemented carbide (CC), with CoNiFeCr multi-principal-element alloy (MPEA) binder, has been investigated by performing sliding wear tests and composition characterization. The results showed that compared with CC, FGCC had higher hardness, stronger fracture toughness, better wear performance, and similar TRS. FGCCs exhibited lower wear rates (3.44 × 10-7-6.95 × 10-6 mm3/(N·m)) and coefficients of friction (COFs) (0.27-0.39) than CCs from RT to 600 °C due to mitigation of multiple risks caused by binder removal, fragmentation and pull-out of WC grains, high-temperature oxidation and softening. In the low-temperature wear stage, the MPEA binder underwent dynamic recrystallization (DRX) and twinning deformation before removing from the surface. The binder removal caused dislocation pile-ups and stacking faults (SFs) to form under high stress, resulting in fragmentation and pull-out of WC grains. The low-temperature wear was dominated by abrasive wear and adhesive wear, with a low wear rate and a high and unstable COF. In the high-temperature wear stage, initial pitting oxidation of WC grains generated many subgrain boundaries, reducing heat transfer and exacerbating oxidation, resulting in an oxide layer enriched with WO3, MxOy, and MWO4. High-temperature wear was dominated by oxidation wear and high-temperature softening, with a high wear rate and a low and smooth COF. The results from the present study do not only provide theoretical guidance for an understanding of the antiwear mechanism of WC-CoNiFeCr, but also a new approach for the preparation of cemented carbides with high wear resistance.
{"title":"Wear behavior of functionally graded cemented carbides with CoNiFeCr multi-principal-element alloy binder","authors":"Cheng Qian, Kun Li, Yong Liu, Xin Zhang, Shuailong Zhang, Ji Zhang, Lijun Jiang, Huichao Cheng","doi":"10.1016/j.jmst.2024.08.003","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.003","url":null,"abstract":"<p>The good combination of mechanical and wear properties for cemented carbides is crucial. In this work, the wear behavior of functionally graded cemented carbide (FGCC) and non-graded cemented carbide (CC), with CoNiFeCr multi-principal-element alloy (MPEA) binder, has been investigated by performing sliding wear tests and composition characterization. The results showed that compared with CC, FGCC had higher hardness, stronger fracture toughness, better wear performance, and similar TRS. FGCCs exhibited lower wear rates (3.44 × 10<sup>-7</sup>-6.95 × 10<sup>-6</sup> mm<sup>3</sup>/(N·m)) and coefficients of friction (COFs) (0.27-0.39) than CCs from RT to 600 °C due to mitigation of multiple risks caused by binder removal, fragmentation and pull-out of WC grains, high-temperature oxidation and softening. In the low-temperature wear stage, the MPEA binder underwent dynamic recrystallization (DRX) and twinning deformation before removing from the surface. The binder removal caused dislocation pile-ups and stacking faults (SFs) to form under high stress, resulting in fragmentation and pull-out of WC grains. The low-temperature wear was dominated by abrasive wear and adhesive wear, with a low wear rate and a high and unstable COF. In the high-temperature wear stage, initial pitting oxidation of WC grains generated many subgrain boundaries, reducing heat transfer and exacerbating oxidation, resulting in an oxide layer enriched with WO<sub>3</sub>, M<em><sub>x</sub></em>O<em><sub>y</sub></em>, and MWO<sub>4</sub>. High-temperature wear was dominated by oxidation wear and high-temperature softening, with a high wear rate and a low and smooth COF. The results from the present study do not only provide theoretical guidance for an understanding of the antiwear mechanism of WC-CoNiFeCr, but also a new approach for the preparation of cemented carbides with high wear resistance.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142090500","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}