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Combining Density Fractionation and Ca K-Edge XANES Reveals Contrasting SOM–Mineral Association Patterns Shaped by Parent Material in Forest Soil O Horizons 结合密度分异和Ca - K-Edge XANES揭示森林土壤O层母质形成的som -矿物组合模式
IF 2.8 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-05-13 DOI: 10.1002/jpln.12015
Gabriela Villalba-Ayala, Luis Carlos Colocho Hurtarte, Wantana Klysubun, Jörg Prietzel

Background

Soil organic matter (SOM) accumulation in forest soils is strongly influenced by interactions with inorganic constituents derived from parent material mineralogy. However, their role in the forest floor remains underexplored.

Aims and methods

This study investigates how different bedrock types (basalt, paragneiss, dolomite, limestone) influence SOM–mineral associations in organic (Of, Oh) and mineral (Ah) horizons of temperate forest soils, exploring the role of Ca in soil organic carbon (SOC) accumulation. We applied sequential density fractionation to separate SOM into low- (<1.4 g cm−3, SOM–metal cation complexes), intermediate- (1.4–1.6 g cm−3, SOM–metal complexes and mineral associations), and heavy-density fractions (>1.6 g cm−3, mineral-associated SOM). We quantified SOC, total Al, Fe, Ca, and Mg, and identified Ca species using Ca K-edge x-ray absorption near-edge structure (XANES) spectroscopy.

Results

In organic layers from calcareous bedrock, SOM–metal cation complexes—particularly Ca-organic complexes (e.g., Ca-carboxylates, Ca-phenols, Ca-phytates)—dominated in low- and intermediate-density fractions, likely driven by enhanced Ca2+ availability. This was associated with higher SOC concentrations (Of: 487–451 mg g−1; Oh: 458–415 mg g−1). In contrast, silicate soils—especially basalt—showed higher inorganic material contents (Of: 19%, Oh: 43%) and larger mineral-associated SOM pools (Of: 13%, Oh: 38%), likely due to intensive bioturbation and abundant pedogenic Al and Fe minerals. Ca-XANES revealed that Ca-bearing mineral types in O layers strongly depended on bedrock composition and soil pedogenesis.

Conclusions

This study highlights the role of parent material in shaping SOM–mineral associations and interactions, underscoring the importance of Ca in SOC accumulation on the forest floor.

森林土壤中土壤有机质(SOM)的积累受到来自母质矿物学的无机成分的相互作用的强烈影响。然而,它们在森林地面上的作用仍未得到充分探索。目的与方法研究了不同基岩类型(玄武岩、副辉岩、白云岩、石灰岩)对温带森林土壤有机质(Of、Oh)和矿物(Ah)层som -矿物组合的影响,探讨了Ca在土壤有机碳(SOC)积累中的作用。我们采用顺序密度分馏将SOM分离为低密度(<1.4 g cm−3,SOM -金属阳离子配合物)、中密度(>1.6 g cm−3,SOM -金属配合物和矿物结合物)和高密度部分(>1.6 g cm−3,矿物相关SOM)。我们量化了SOC,总Al, Fe, Ca和Mg,并使用Ca k -边缘x射线吸收近边缘结构(XANES)光谱鉴定了Ca的种类。结果:在钙质基岩的有机层中,som -金属阳离子络合物-特别是钙有机络合物(例如,羧酸钙、钙酚、钙植酸盐)-在低密度和中密度部分占主导地位,可能是由于Ca2+可用性增强所致。这与较高的SOC浓度有关(Of: 487-451 mg g - 1; Oh: 458-415 mg g - 1)。相比之下,硅酸盐土壤(尤其是玄武岩)表现出较高的无机物质含量(Of: 19%, Oh: 43%)和较大的矿物相关SOM池(Of: 13%, Oh: 38%),可能是由于强烈的生物扰动和丰富的成土Al和Fe矿物。Ca-XANES揭示了O层含钙矿物类型强烈依赖于基岩组成和土壤成土作用。本研究强调了母质在形成som -矿物结合和相互作用中的作用,强调了Ca在森林地面有机碳积累中的重要性。
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引用次数: 0
Soil Organic Carbon (SOC) Stocks of Mineral Arable Soils in Schleswig-Holstein and Their Future Carbon Storage Potential 石勒苏益格-荷尔斯泰因州矿质耕地土壤有机碳储量及其未来碳储量潜力
IF 2.8 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-05-09 DOI: 10.1002/jpln.12016
Ragna-Marleen Fey, Conrad Wiermann

Background

Agricultural soils have the potential for long-term carbon sequestration by building up and maintaining soil organic carbon (SOC) to mitigate climate crisis. Organic soils under grassland use are often highlighted in this regard. However, given that approximately two-thirds of Schleswig-Holstein's (SH's) (Northern Germany) agriculturally used area is classified as arable land, these large areas have a potential for additional carbon storage, too.

Aims

The aim is to determine the current SOC stocks of mineral arable soils in SH and derive additional carbon storage potentials based on these data to predict additional storage potentials for the main soil type groups and geological regions. Additionally, we aim to identify the most promising agricultural practices in arable farming to exploit these potentials.

Methods

Soil data from mineral arable sites in SH were compiled, and current carbon stocks were calculated at depths of 0–30 cm and 30–100 cm. A new method (the median method) to predict additional SOC storage potentials was developed. To evaluate management practices for enhancing SOC stocks and exploit the calculated storage potentials, an optimized scenario was designed.

Results

The mean calculated SOC stocks of mineral arable soils in SH are 113 t SOC ha−1 (1 m) or 71 t SOC ha−1 (30 cm). The additional SOC storage potential in the topsoil (30 cm) of the total area of 9.1 Mt SOC was calculated, that is, an average potential of 13 t SOC ha−1. The scenario with five promising management practices showed that the predicted storage potential of the topsoil could be utilized by 6% in 2030 and 21% in 2040. It will take until 2090 to fully exploit the calculated potential.

Conclusions

The soils in SH show slightly higher SOC stocks and lower SOC storage potentials compared to other studies. These differences are due to variations in climate and parent material (especially marshlands), as well as the inherent limitations of the median method, which is a robust but potentially underestimating approach. It can be concluded that the exploitation of the calculated storage potentials can only be achieved through a comprehensive and long-term implementation of management practices.

农业土壤通过积累和维持土壤有机碳(SOC)来缓解气候危机,具有长期固碳的潜力。草地利用下的有机土壤往往是这方面的重点。然而,考虑到石勒苏益格-荷尔斯泰因州(德国北部)大约三分之二的农业用地被归类为耕地,这些大片地区也有可能储存额外的碳。目的确定盐湖矿质耕地土壤当前的有机碳储量,并根据这些数据推导出额外的碳储存潜力,以预测主要土壤类型组和地质区域的额外碳储存潜力。此外,我们的目标是确定最有前途的农业实践在耕地农业开发这些潜力。方法收集湖南矿质耕地土壤资料,计算0 ~ 30 cm和30 ~ 100 cm土壤土壤碳储量。提出了一种新的预测有机碳额外储存电位的方法(中位数法)。为了评价提高土壤有机碳储量的管理措施,并利用计算出的储量潜力,设计了一个优化方案。结果盐湖矿质耕地土壤有机碳储量分别为113 t ha - 1 (1 m)和71 t ha - 1 (30 cm)。计算了总面积为9.1 Mt的表层土壤(30 cm)的额外有机碳储存潜力,即平均潜力为13 t SOC ha - 1。采用五种有前景的管理措施的情景表明,预测的表土储存潜力在2030年可以利用6%,在2040年可以利用21%。要到2090年才能充分开发计算出的潜力。结论与其他研究区相比,沙河流域土壤有机碳储量略高,但有机碳储量潜力较低。这些差异是由于气候和母质(特别是沼泽地)的变化,以及中位数方法的固有局限性,这是一种稳健但可能低估的方法。可以得出结论,只有通过全面和长期的管理实践,才能实现计算存储潜力的开发。
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引用次数: 0
Soil Quality Indicators Based on the Agroecological Family Farmers’ Perception in São Lourenço do Sul, Brazil 基于农业生态家庭农民感知的巴西南<s:1>洛伦帕拉多州土壤质量指标
IF 2.8 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-05-02 DOI: 10.1002/jpln.12014
Eduardo Saldanha Vogelmann, Sara Evangelista do Vale, Germano Ehlert Pollnow, Arisandro Rodrigues Mendes, Tiruneh Gizachew Ayalew

Background

To promote the adoption of agroecological practices, it is important to value the knowledge and farmers’ perception, who have an intimate natural relationship, cultivating their agroecosystem based on observation and popular experimentation.

Aims

This project aims to develop soil quality indicators in São Lourenço do Sul by integrating scientific knowledge with the agroecological perceptions of family farmers.

Materials and Methods

Afterward, a structured questionnaire was developed and applied to the group of family farmers in São Lourenço do Sul, between March 13 and April 1, 2024.

Results

Farmers highlighted organic matter as a key indicator of soil quality, emphasizing the role of manure, compost, and green manure in maintaining it. They also associated the presence of earthworms with healthy soils. Overall, there is a strong link between organic matter and soil chemical quality. The responses show that spreading knowledge about management practices is crucial for improving soil quality.

Conclusion

The soil quality indicators are useful for adjusting management practices and highlight the value of combining farmers’ experience with scientific knowledge to shape locally appropriate policies. The development of indicators with farmers recognizes popular knowledge, increasing their interest in monitoring the soil quality of their agroecosystem.

为了促进农业生态实践的采用,重要的是要重视知识和农民的感知,他们有着密切的自然关系,在观察和流行实验的基础上培育他们的农业生态系统。该项目旨在通过将科学知识与家庭农民的农业生态观念相结合,在南洛伦帕拉多省制定土壤质量指标。材料与方法随后,于2024年3月13日至4月1日对南洛伦帕拉多州的家庭农民进行了结构化问卷调查。结果农户强调有机质是土壤质量的关键指标,强调粪肥、堆肥和绿肥在维持土壤质量中的作用。他们还将蚯蚓的存在与健康的土壤联系起来。总的来说,有机质和土壤化学质量之间有很强的联系。这些回应表明,传播有关管理实践的知识对改善土壤质量至关重要。结论土壤质量指标有助于调整管理实践,突出了结合农民经验和科学知识制定因地制宜政策的价值。与农民一起制定指标是对大众知识的认可,提高了他们对监测其农业生态系统土壤质量的兴趣。
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引用次数: 0
Rhizodeposit Carbon Gradients: Potentials and Limitations of Destructive Rhizosphere Sampling on a Millimeter-Scale 根际沉积物碳梯度:毫米尺度破坏性根际取样的潜力和局限性
IF 2.8 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-04-28 DOI: 10.1002/jpln.12011
Martina I. Gocke, Andrea Scheibe, Manuel Vergara Sosa, Doris Vetterlein, Johanna Pausch, Eva Lippold, Eva Lehndorff

Background

Despite the availability of modern techniques for high-resolution non-destructive rhizosphere analysis, destructive examinations yielding a certain minimum soil amount are often required to provide detailed insights into organic matter composition.

Methods

We compared an established approach for destructive rhizosphere sampling via root brushing to a new millimeter-scale gradient sampling approach, expecting that the latter allows to characterize spatial patterns of rhizodeposit-carbon (C) distribution and relate them to root traits and soil texture. A tool to sample soil in 2 mm steps around a root was developed. Maize with and without root hairs was grown under field conditions until the end of tassel emergence, either in loam or in sand, and labeled with 13CO2 one day before harvest.

Results

Both approaches showed an enrichment of C and 13C in sandy and partially in loamy rhizosphere, but no δ13C gradient could be statistically demonstrated due to high variability. The major uncertainty of both approaches was the potential masking of bulk soil organic C concentration and isotopic composition by non-target roots. The new gradient sampling approach offers uniform, pre-defined, and thus neutral conditions with respect to sampling distance independent of root and soil properties; yields at least 100–200 mg of soil on a millimeter-scale from one individual root segment; and can be applied in natural settings without root growth artifacts. The presented techniques integrated signals from fine roots and root hairs.

Conclusions

For root systems with longer unbranched segments, the new approach has potential for tracing 13C released by roots and for analyzing plant and microbial remains at the millimeter-scale.

尽管现代技术可用于高分辨率非破坏性根际分析,但通常需要产生一定最小土壤量的破坏性检查来提供对有机质组成的详细了解。方法将已有的根刷破坏性根际取样方法与毫米尺度梯度取样方法进行比较,发现后者能够表征根沉积物碳(C)分布的空间格局,并将其与根系性状和土壤质地联系起来。开发了一种以根周围2毫米的步骤取样土壤的工具。有根毛和没有根毛的玉米在田间条件下生长,直到穗子出芽结束,分别在壤土或沙子中生长,并在收获前一天用13CO2标记。结果两种方法均显示C和13C在砂质根际和部分壤土根际富集,但δ13C梯度由于变异较大而无法统计。两种方法的主要不确定性在于非目标根对土壤有机碳浓度和同位素组成的潜在掩盖。新的梯度采样方法提供了统一的,预定义的,因此中性的条件,相对于独立的根和土壤性质的采样距离;从单个根段产生至少100-200毫克毫米尺度的土壤;并且可以应用在自然环境中,没有根生长的工件。该技术综合了细根和根毛的信号。结论对于非分枝段较长的根系,新方法具有追踪根系释放13C的潜力,并可用于毫米尺度的植物和微生物残留物分析。
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引用次数: 0
Optimizing Nutrient Delivery in Agronomic Crops: A Review of Enhanced Efficiency Fertilizers 优化作物养分输送:高效肥料研究进展
IF 2.8 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-04-27 DOI: 10.1002/jpln.12010
Kulpreet Singh, Ravinder Singh, Nkem J. Nwosu, Peter Omara, Lakesh Sharma, Bruce L. Dunn, Hardeep Singh

The global population has been increasing for the past century, but global food production has been able to keep up with growing population growth because of fertilizer use, which has increased by 21% in the last two decades. Nevertheless, the nutrient use efficiency (NUE) is low, ranging from 10% to 55% across different crops for macronutrients with overfertilization of nutrients imposing environmental risks. There is a pressing need for better NUE for sustainable food production to meet the growing population's demand without impacting the environment. Enhanced efficiency fertilizers (EEFs) can potentially increase NUE and mitigate environmental risks by coupling their nutrient release with crop nutrient uptake. EEFs have gained significant recognition in agricultural research. This detailed review discusses the basics, classification, and benefits of EEFs worldwide in various crops, and the coating material and release mechanism of EEFs are discussed in extensive detail along with the application of EEFs with other best management practices. Additionally, the review outlines the challenges and considerations regarding EEFs that impact their adoption at a global scale and emphasizes the significance of investigating future strategies and directions, stressing the importance of a comprehensive approach to address research gaps and ways to unlock the full potential of EEFs for sustainable agriculture. The assessment underscores the efficacy of EEFs as an innovative solution to enhance NUE and mitigate environmental impacts related to fertilization.

在过去的一个世纪里,全球人口一直在增长,但由于化肥的使用,全球粮食产量能够跟上人口增长的步伐,在过去的二十年里,化肥的使用增加了21%。然而,不同作物对大量养分的利用效率(NUE)较低,在10% ~ 55%之间,过量施肥会造成环境风险。迫切需要提高可持续粮食生产的氮肥利用率,以在不影响环境的情况下满足不断增长的人口需求。增效肥料通过将养分释放与作物养分吸收相结合,有可能提高氮肥利用效率并减轻环境风险。电子效应在农业研究中得到了广泛的认可。本文详细介绍了外源电磁场的基本原理、分类和在各种作物中的应用,并对外源电磁场的涂层材料和释放机理进行了详细的讨论,以及外源电磁场与其他最佳管理实践的应用。此外,该综述概述了影响全球范围内EEFs采用的挑战和考虑因素,并强调了调查未来战略和方向的重要性,强调了采用综合方法解决研究差距的重要性,以及释放EEFs对可持续农业的全部潜力的方法。该评估强调了EEFs作为提高氮肥利用效率和减轻与施肥有关的环境影响的创新解决方案的有效性。
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引用次数: 0
The Contribution of Zn Uptake and Grain Zn Loading Intensity to Achieving Zn Biofortification Breeding Targets in Rice 锌吸收和籽粒锌负荷强度对实现水稻锌生物强化育种目标的贡献
IF 2.8 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-04-27 DOI: 10.1002/jpln.12013
Mbolatantely Rakotondramanana, James Stangoulis, Cécile Grenier, Matthias Wissuwa

Background

Increasing Zinc (Zn) concentrations in rice grains is targeted in Zn-biofortification breeding but most rice varieties have grain Zn concentrations far below breeding targets.

Aims

High-Zn donors have been identified and our aim is to investigate whether higher grain Zn concentrations in these donors were the result of superior Zn uptake during the reproductive stage, of higher Zn loading intensities or caused by an extended Zn loading period.

Methods

Field experiments comparing two high-Zn donors to two low-Zn modern varieties were conducted over two seasons in Madagascar and tissue Zn concentrations and content determined from heading to maturity.

Results

Zn uptake between heading and maturity was not limiting grain Zn concentrations. Neither did studied genotypes differ significantly in the duration of Zn loading, which peaked 8–12 days after flowering and strongly decreased thereafter, even in high-Zn donors. Instead, the Zn loading intensity during grain filling differed with peak loading rates exceeding 60 ng Zn day−1 in high-Zn donors compared to 13–37 ng Zn day−1 in low-Zn varieties. This high Zn loading intensity was further evident when Zn and biomass grain loading rates were compared. Donor IRIS-9368 loaded up to 40 ng Zn mg−1 grain biomass compared to 12–21 ng Zn mg−1 in low-Zn varieties. This high loading intensity resulted in a zinc harvest index of 47.7% in IRIS-9368 compared to 26.1% for local variety X265 despite similar reproductive-stage Zn uptake.

Conclusions

We hypothesize that xylem-to-phloem transfer of Zn at upper nodes is more efficient in high-Zn donor IRIS-9368.

背景提高水稻籽粒锌含量是锌生物强化育种的目标,但大多数水稻品种籽粒锌含量远低于育种目标。高锌供体已经确定,我们的目的是研究这些供体中较高的籽粒锌浓度是由于生殖阶段锌吸收较好、锌负荷强度较高还是由于锌负荷期延长所致。方法对两个高锌供体和两个低锌现代品种在马达加斯加进行了两个季节的田间试验,测定了抽穗至成熟期的组织锌浓度和含量。结果抽穗至成熟期的锌吸收不限制籽粒锌浓度。研究的基因型在锌负荷持续时间上也没有显著差异,开花后8-12天达到峰值,此后急剧下降,即使在高锌供体中也是如此。相反,灌浆过程中锌的加载强度不同,高锌供体的峰值加载率超过60 ng Zn d - 1,而低锌品种的峰值加载率为13 ~ 37 ng Zn d - 1。当比较Zn和生物量籽粒加载速率时,这种高Zn加载强度进一步明显。供体IRIS-9368的生物量可达40 ng Zn mg - 1,而低锌品种的生物量为12-21 ng Zn mg - 1。这种高负荷强度导致IRIS-9368的锌收获指数为47.7%,而本地品种X265的锌收获指数为26.1%。结论高锌供体IRIS-9368的上节木质部向韧皮部的锌转移效率更高。
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引用次数: 0
From Sea to Land: Setting a Size Definition of Plastics for Soil Ecosystem Studies 从海洋到陆地:为土壤生态系统研究设定塑料的尺寸定义
IF 2.6 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-04-26 DOI: 10.1002/jpln.12006
Ryan Bartnick, Eva Lehndorff

In soil studies, the current definition of microplastics as particles <5 mm was adopted directly from marine research. To our opinion, a more precise and differentiated size definition is needed to focus studies on specific challenges plastics cause for soil ecosystems. As relevant soil functions such as water, carbon, and nutrient retention and provision are mainly controlled by soil structure, biota, and chemical processes dominantly appearing in the micro- to nanoscale, we suggest adapting size ranges of plastics to the respective process scales in soil ecosystem studies. Even more, we expect that larger particles will not be incorporated into soil until they reach a size threshold compatible to soil structure (<1000 µm, depending on soil properties). Redefining plastic sizes in accordance with soil processes and the International System of Units (SI) should be implemented to focus research. A unified definition of microplastics (1–1000 µm) and nanoplastics (1–1000 nm) will set a standard to further allow relating plastic sizes across research disciplines.

在土壤研究中,目前对微塑料的定义是5毫米的颗粒,直接来自海洋研究。在我们看来,需要一个更精确和差异化的尺寸定义来集中研究塑料对土壤生态系统造成的具体挑战。土壤的水、碳和养分的保持和供应等相关功能主要受土壤结构、生物群和化学过程的控制,这些过程主要出现在微纳米尺度上,因此我们建议在土壤生态系统研究中调整塑料的尺寸范围以适应各自的过程尺度。更重要的是,我们预计较大的颗粒在达到与土壤结构兼容的尺寸阈值(1000µm,取决于土壤性质)之前不会被纳入土壤中。应根据土壤过程和国际单位制(SI)重新定义塑料尺寸,以集中研究。微塑料(1-1000微米)和纳米塑料(1-1000纳米)的统一定义将设定一个标准,进一步允许跨研究学科的塑料尺寸相关。
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引用次数: 0
Deviation From the Regression of Yield on Nitrogen Fertiliser Rate as a Tool for Detecting Fraud in Organic Banana Production 有机香蕉生产中氮肥用量对产量回归偏差的检测
IF 2.8 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-04-26 DOI: 10.1002/jpln.12009
Albrecht Benzing, Hans-Peter Piepho, Ryan Orr, Juan-Carlos Ullauri

Background and aims

Bananas are demanding in nitrogen (N) input; therefore, there is a temptation for organic farmers for using synthetic N fertilisers, which are not allowed under organic standards. The aim of our study was to develop a tool that identifies high banana yields obtained with suspiciously low organic N input.

Methods

We systematically reviewed literature from experimental studies on N fertilisation in bananas from all over the world. We also developed a simplified N balance model for organic bananas. Furthermore, N fertilisation and banana yield data from organic and conventional farmers in different countries were collected. From these, a subset of trustworthy organic farms was identified, as a reference concerning plausible ratios of yield versus fertilisation. A model was developed to estimate the deviation from the regression of trustworthy farms and thus identify suspicious cases.

Results

Neither literature nor the N balance led to a meaningful benchmark for differentiating plausible from non-plausible yields. The regression of yield on N fertiliser rate from the trustworthy organic farmers, however, turned out to be a helpful reference, and the deviation from this regression helps to achieve our aim. Depending on the alert limit, that is, the probability of obtaining false positive results, 4, 6, or 9 out of 157 data-pairs from organic farmers turned out to be suspicious.

Conclusion

Measuring deviation from the regression of the trustworthy farms is a useful tool for identifying organic banana farmers suspected to be using synthetic N fertilisers but is not in itself a proof of fraud. The model will improve as more data becomes available.

背景与目的香蕉对氮(N)的输入是有要求的;因此,有机农民有使用合成氮肥的诱惑,这在有机标准中是不允许的。我们研究的目的是开发一种工具,可以识别在可疑的低有机氮投入下获得的高香蕉产量。方法系统回顾了国内外香蕉施氮试验研究文献。我们还建立了一个简化的有机香蕉氮平衡模型。此外,还收集了不同国家有机和传统农民的氮肥和香蕉产量数据。从这些,一个值得信赖的有机农场的子集被确定,作为参考有关产量与施肥的合理比例。开发了一个模型来估计可信农场回归的偏差,从而识别可疑病例。结果无论是文献还是氮素平衡都没有得出一个有意义的基准来区分合理和不合理的产量。然而,可靠的有机农民的氮肥产量回归是一个有益的参考,偏离该回归有助于实现我们的目标。根据警报限制,即获得假阳性结果的概率,来自有机农民的157对数据中有4、6或9对被证明是可疑的。结论测量可信农场的回归偏差是识别疑似使用合成氮肥的有机香蕉农户的有用工具,但本身并不能证明欺诈行为。随着更多数据的出现,该模型将得到改进。
{"title":"Deviation From the Regression of Yield on Nitrogen Fertiliser Rate as a Tool for Detecting Fraud in Organic Banana Production","authors":"Albrecht Benzing,&nbsp;Hans-Peter Piepho,&nbsp;Ryan Orr,&nbsp;Juan-Carlos Ullauri","doi":"10.1002/jpln.12009","DOIUrl":"https://doi.org/10.1002/jpln.12009","url":null,"abstract":"<div>\u0000 \u0000 \u0000 <section>\u0000 \u0000 <h3> Background and aims</h3>\u0000 \u0000 <p>Bananas are demanding in nitrogen (N) input; therefore, there is a temptation for organic farmers for using synthetic N fertilisers, which are not allowed under organic standards. The aim of our study was to develop a tool that identifies high banana yields obtained with suspiciously low organic N input.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Methods</h3>\u0000 \u0000 <p>We systematically reviewed literature from experimental studies on N fertilisation in bananas from all over the world. We also developed a simplified N balance model for organic bananas. Furthermore, N fertilisation and banana yield data from organic and conventional farmers in different countries were collected. From these, a subset of trustworthy organic farms was identified, as a reference concerning plausible ratios of yield versus fertilisation. A model was developed to estimate the deviation from the regression of trustworthy farms and thus identify suspicious cases.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Results</h3>\u0000 \u0000 <p>Neither literature nor the N balance led to a meaningful benchmark for differentiating plausible from non-plausible yields. The regression of yield on N fertiliser rate from the trustworthy organic farmers, however, turned out to be a helpful reference, and the deviation from this regression helps to achieve our aim. Depending on the alert limit, that is, the probability of obtaining false positive results, 4, 6, or 9 out of 157 data-pairs from organic farmers turned out to be suspicious.</p>\u0000 </section>\u0000 \u0000 <section>\u0000 \u0000 <h3> Conclusion</h3>\u0000 \u0000 <p>Measuring deviation from the regression of the trustworthy farms is a useful tool for identifying organic banana farmers suspected to be using synthetic N fertilisers but is not in itself a proof of fraud. The model will improve as more data becomes available.</p>\u0000 </section>\u0000 </div>","PeriodicalId":16802,"journal":{"name":"Journal of Plant Nutrition and Soil Science","volume":"188 4","pages":"604-615"},"PeriodicalIF":2.8,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/jpln.12009","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144782840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Rapid In-Field Soil Extraction Procedure to Measure Plant-Available Soil P and K Using an ISFET Multi-Sensor 利用ISFET多传感器测量植物有效土壤磷和钾的快速田间土壤提取程序
IF 2.8 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-04-25 DOI: 10.1002/jpln.12007
Elena Najdenko, Vadim Riedel, Klaus Dittert, Arno Ruckelshausen, Frank Lorenz, Hans-Werner Olfs

Background

Knowledge of plant-available soil nutrients is important for determining fertilizer requirements. Collecting this data rapidly and directly in the field could be beneficial for improving nutrient utilization efficiency.

Aim

Evaluation of the comparability of plant-available soil phosphorus (Ppa) and potassium (Kpa) measurements with a newly developed rapid soil extraction procedure based on a nutrient measurement system using an ISFET (ion-sensitive field-effect transistor) multi-sensor module (“FieldLab”) under quasi-realistic field conditions with the results of a lab-based soil analysis.

Methods

Following calibration of the FieldLab measurement system with the calcium-acetate-lactate (CAL) extraction method commonly used in Germany, the ability of the ISFET multi-sensor module to measure Ppa and Kpa under in-field conditions was investigated. For this purpose, a set of dried soil samples from 15 fields in northwest Germany was used, representing very different soil nutrient levels as well as various soil texture and soil organic matter contents. The soils were assessed using the standard lab procedure or the rapid FieldLab extraction, followed by lab measurements or nutrient quantification with the ISFET multi-sensor, respectively.

Results

Soil extraction using the FieldLab procedure showed a high correlation with the lab results (R2 0.97 and 0.92 for Ppa and Kpa, respectively). The combination of the rapid soil extraction followed by the ISFET measurement revealed significant correlations with the laboratory data (R2 0.80 and 0.79 for Ppa and Kpa, respectively).

Conclusion

The developed ISFET-based FieldLab procedure is an innovative and reliable approach for rapid in-field nutrient analysis of Ppa and Kpa, and it has the potential to enable the timely calculation of P and K fertilizer recommendations.

了解植物有效土壤养分对确定肥料需要量很重要。在田间快速、直接地收集这些数据有利于提高养分利用效率。目的评价新开发的基于ISFET(离子敏感场效应晶体管)多传感器模块(“FieldLab”)养分测量系统的快速土壤提取程序在准实际现场条件下植物有效土壤磷(Ppa)和钾(Kpa)测量结果与实验室土壤分析结果的相似性。方法采用德国常用的醋酸钙-乳酸(CAL)萃取法对FieldLab测量系统进行校准后,研究了ISFET多传感器模块在现场条件下测量Ppa和Kpa的能力。为此,我们使用了一组来自德国西北部15块田地的干燥土壤样品,这些样品代表了非常不同的土壤养分水平,以及不同的土壤质地和土壤有机质含量。使用标准实验室程序或快速FieldLab提取对土壤进行评估,然后分别使用ISFET多传感器进行实验室测量或养分定量。结果使用FieldLab程序的土壤提取结果与实验室结果高度相关(Ppa和Kpa分别为R2 0.97和0.92)。快速土壤提取与ISFET测量的结合显示了与实验室数据的显著相关性(Ppa和Kpa的R2分别为0.80和0.79)。结论开发的基于isfet的田间实验室程序是一种创新、可靠的快速田间养分分析方法,可用于及时计算磷钾肥推荐用量。
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引用次数: 0
Iron (Fe) Biofortification Using Fe-Aminochelates in Sunflower Growing in Calcareous Soils 铁-氨基螯合物在向日葵钙质土壤中铁(铁)的生物强化
IF 2.6 3区 农林科学 Q1 AGRONOMY Pub Date : 2025-04-17 DOI: 10.1002/jpln.12004
Mina Alipour Babadi, Mojtaba Norouzi Masir, Abdol Amir Moezzi, Afrasyab Rahnama, Mehdi Taghavi

Background

Efficient agronomic approaches should be developed to alleviate iron (Fe) deficiency in lime-rich soils.

Aims

The present study aimed to investigate the efficiency of eco-friendly synthesized Fe-aminochelates in remediating Fe deficiency and improving the yield and nutritional quality of sunflower (Helianthus annuus L.), compared to FeSO₄ in calcareous soil.

Methods

Fe (glycine)2 [Fe (Gly)2] and Fe (methionine)2 [Fe (Met)2] aminochelates were synthesized and characterized via a CHN analyzer, H1 NMR and FT-IR spectroscopy. In a field experiment, Fe-aminochelates and FeSO₄ were applied using three methods (priming, fertigation, and foliar spray) at various plant growth stages.

Results

The application of [Fe (Gly)2] and [Fe (Met)2] through different methods significantly improved the biomass yield, nutritional quality, and yield attributes, compared with those of FeSO4. Compared with the control, foliar application of [Fe (Met)2] increased seed yield (73.9%), oil yield (125.8%), and seed protein content (60%). In addition, antioxidant enzyme activities, total soluble protein (TSP), and seed nutrients such as Fe, N, and S concentrations, as well as the Fe concentration in leaves, also increased in response to [Fe (Gly)2] and [Fe (Met)2] application, whereas the N/S ratio decreased with increasing seed oil content.

Conclusions

These results suggest that the application of Fe-aminochelates may be a promising way to promote Fe biofortification and overcome Fe deficiency under calcareous conditions.

背景:应开发有效的农艺方法来缓解富石灰土壤中的铁(Fe)缺乏。目的研究生态友好型合成氨螯合铁(Fe-aminochelates)与硫酸铁(FeSO₄)在钙质土壤中修复向日葵(Helianthus annuus L.)缺铁、提高产量和营养品质的效果。方法合成Fe(甘氨酸)2 [Fe (Gly)2]和Fe(蛋氨酸)2 [Fe (Met)2]氨基螯合物,并通过CHN分析仪、H1 NMR和FT-IR光谱对其进行表征。在田间试验中,采用三种施肥方法(灌浆、施肥和叶面喷施)在植物生长的不同阶段施用氨螯合铁和硫酸铁。结果与FeSO4相比,不同方式施用[Fe (Gly)2]和[Fe (Met)2]显著提高了产量、营养品质和产量属性。与对照相比,叶面施用[Fe (Met)2]提高了种子产量(73.9%)、油分产量(125.8%)和种子蛋白质含量(60%)。施用[Fe (Gly)2]和[Fe (Met)2]后,抗氧化酶活性、总可溶性蛋白(TSP)、籽粒铁、氮、硫等营养物质浓度以及叶片铁含量均显著升高,氮硫比随籽粒含油量的增加而降低。结论铁胺螯合物的应用可能是促进铁生物强化和克服钙化条件下铁缺乏的有效途径。
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引用次数: 0
期刊
Journal of Plant Nutrition and Soil Science
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