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Preventing Enzymatic Damage to Hides by Timely Inhibition of Trypsin Activity with Soybean Flour during Bating Process 在打浆过程中用大豆粉及时抑制胰蛋白酶活性,防止生皮受到酶损伤
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2023-06-01 DOI: 10.34314/jalca.v118i6.7659
Tingyuan Chen, Yunhang Zeng, Bi Shi
Enzymatic bating is important for producing clean, soft, and high-yield leather. However, it is prone to cause damage to hide collagen fibers and result in loose grain or damaged grain surface due to the longer enzymatic hydrolysis time of the grain layer than the middle layer caused by the slow mass transfer and the rapid hydrolysis reaction of the bating agent in hide. Considering trypsin is the most common bating agent, soybean flour (SF) that contains environmental friendly Kunitz trypsin inhibitor (KTI) was used after delimed hides were treated with trypsin for a certain time to opportunely inhibit its activity in the grain and avoid bating defects. The fluorescence micrographs of hides bated with fluorescently labelled trypsin and KTI showed that KTI could cover only the surface layers when it was added after bating for a certain time, whereas trypsin could penetrate the hide completely. When sufficient SF was added to the bating float at 2 h, the damage to hide collagen caused by trypsin was effectively reduced. In particular, the grain surface remained intact after bating for 8 h. The decrease in the strength of leather caused by bating was also reduced. In addition, the usage of SF scarcely affected the fiber dispersion of the middle layer, thereby ensuring the softness of leather. In summary, opportunely inhibiting the activity of trypsin in the grain could prevent hide damage and improve the quality of leather.
酶法打浆对生产清洁、柔软和高产皮革非常重要。然而,由于质量传递缓慢,加弹剂在皮革中的水解反应迅速,导致粒面层的酶水解时间长于中间层,因此容易对皮革胶原纤维造成破坏,导致粒面松散或粒面受损。考虑到胰蛋白酶是最常见的糊化剂,因此在用胰蛋白酶处理划线生皮一定时间后,使用含有环保型库尼茨胰蛋白酶抑制剂(KTI)的大豆粉(SF),以适时抑制其在谷粒中的活性,避免出现糊化缺陷。用荧光标记的胰蛋白酶和 KTI 标记的生皮的荧光显微照片显示,当 KTI 在标记生皮一定时间后加入时,只能覆盖表层,而胰蛋白酶可以完全渗透生皮。如果在 2 小时后向打浆浮渣中加入足量的 SF,则可有效减少胰蛋白酶对牛皮胶原蛋白的破坏。尤其是在浸渍 8 小时后,纹理表面仍保持完好。此外,使用 SF 几乎不会影响中层纤维的分散,从而确保了皮革的柔软性。总之,适时抑制谷粒中胰蛋白酶的活性可防止皮革损伤,提高皮革质量。
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引用次数: 0
Application of Acid Protease for Eco-friendly Pre-treatment of Goat Skin to Improve Antimicrobial Finish Using Herbal Natural Extracts 应用酸性蛋白酶对山羊皮进行环保型预处理,利用草药天然提取物改善抗菌效果
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2023-06-01 DOI: 10.34314/jalca.v118i6.7588
Mona Vajpayee, Mumal Singh, Hemen Dave, Lalita Ledwani
Due to its moisture retention capacity and huge surface area, leather is highly prone to microbial proliferation and biodeterioration; hence, leather products desired have an antimicrobial finish. In this study, acid protease enzyme pre-treatment of goat skin was utilized as an eco-friendly substitute for conventional wet-chemical processing. The treatment can impart the desired surface properties to improve the antimicrobial finish with natural extracts obtained from leaves of Azadirachta indica (Neem Tree), Ocimum sanctum (Holy Basil, Tulsi), and Camellia sinensis (Green Tea). The procedure was optimized for different process parameters, including enzyme concentration, pH, material to liquor ratio (MLR), treatment time, and temperature. The effect of the treatment on bulk and surface properties of the skin was characterized by weight loss analysis, X-Ray Diffraction (XRD), Thermal Gravimetric Analysis (TGA), and Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR), X-Ray Photoelectron Spectroscopy (XPS), Water contact angle measurement, Scanning Electron Microscopy (SEM) respectively. The effect of the enzymatic treatment on organoleptic properties and the mechanical strength of the skin was also studied. The enzymatic treatment resulted in weight loss, and removal of non-collagen components, thus opening the fibrous collagen matrix of the skin. Hence, the skin treated with acid protease enzyme provides better affinity and accessibility for phytoactive compounds from the natural extracts and better attachment by electrostatic attachment due to an increase in surface functional groups after the enzymatic treatment compared to untreated skin. The effectiveness of the antimicrobial finish was measured as a zone of inhibition and with a modified Hohenstein test against test microorganisms E. coli and S. aureus.Azadirachta indica (Neem Tree) extract showed the highest inhibitory activity (97%) against E. coli, while the Ocimum sanctum (Holy Basil, Tulsi) extract exhibited the highest inhibitory activity (95%) against S. aureus.
由于皮革的保湿能力和巨大的表面积,它极易受到微生物增殖和生物劣化的影响;因此,皮革制品需要具有抗菌表面效果。本研究利用酸性蛋白酶酶预处理山羊皮,作为传统湿化学处理的环保型替代品。这种处理方法可赋予皮革所需的表面特性,从而利用从印度楝树、圣檀(圣罗勒、图尔西)和山茶(绿茶)叶中提取的天然提取物改善皮革的抗菌表面效果。该程序针对不同的工艺参数进行了优化,包括酶浓度、pH 值、料液比 (MLR)、处理时间和温度。分别通过失重分析、X 射线衍射(XRD)、热重力分析(TGA)、衰减全反射傅立叶变换红外光谱(ATR-FTIR)、X 射线光电子能谱(XPS)、水接触角测量、扫描电子显微镜(SEM)来表征处理对表皮的体积和表面特性的影响。此外,还研究了酶处理对表皮感官特性和机械强度的影响。酶处理导致重量减轻,非胶原成分被去除,从而打开了皮肤的纤维胶原基质。因此,与未经处理的皮肤相比,经过酸性蛋白酶处理的皮肤对天然提取物中的植物活性化合物具有更好的亲和力和可及性,并且由于酶处理后表面官能团的增加,静电附着性更好。楝树提取物对大肠杆菌的抑制活性最高(97%),而圣罗勒(Ocimum sanctum)提取物对金黄色葡萄球菌的抑制活性最高(95%)。
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引用次数: 0
The Kinetic Study on Potassium Persulfate Accelerated Fish Oil Oxidation-An Agreeing Conclusion on Chamois Tanning 过硫酸钾加速鱼油氧化的动力学研究--关于鞣革的一致结论
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2023-06-01 DOI: 10.34314/jalca.v118i6.7660
B. Sahu, Diya Deepak Sharma, Yogesh Sekar, Akash Bhalla, J. Alla
The oxidation of fish oil is a type of chain reaction. The use of oxidizing agents enhances the rate of oxidation of the same. This study predominantly focuses on the role of potassium persulfate as an accelerating agent in fish oil oxidation, its kinetics, and application in rapid fish oil tanning. The use of potassium persulfate (1%) completes the fish oil oxidation within 4 days, confirmed by its kinetic studies. Chamois leathers made using potassium persulfate (1%) exhibited excellent water absorption capacity (454%). The physical parameters such as tensile strength, shrinkage temperature, surface morphology, and organoleptic properties of the experimental leather exhibit better results than control leathers.
鱼油的氧化是一种连锁反应。氧化剂的使用可提高鱼油的氧化速度。本研究主要关注过硫酸钾作为加速剂在鱼油氧化中的作用、其动力学以及在快速鞣制鱼油中的应用。过硫酸钾(1%)可在 4 天内完成鱼油氧化,其动力学研究证实了这一点。使用过硫酸钾(1%)制成的麂皮具有出色的吸水能力(454%)。实验皮革的拉伸强度、收缩温度、表面形态和感官特性等物理参数均优于对照皮革。
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引用次数: 0
Research on the Production of Parchment from Turkey Skin and its Decorative Use 用火鸡皮制作羊皮纸及其装饰用途的研究
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2022-04-29 DOI: 10.34314/jalca.v117i5.4916
E. E. Bayramoğlu
In this study, parchment was made of waste turkey skin and some tests were done. These tests were: Determination of thickness (TS 4117 EN ISO 2589), Determination of tensile strength and elongation (TS EN ISO 3376), Determination of tear load - Part 2: (Double edge tear) (TS 4118-2 EN ISO 3377-2), Leather - of distension and strength of grain (TS 4137 EN ISO 3379), Color fastness to water spotting (TS EN ISO 15700). Due to the low strength properties of turkey skin, a different usage area was tried to be created by making a decorative flower design. In this research, it has been tried to show how a waste material can be transformed into a product with a very high added value.
在这项研究中,用废弃的火鸡皮制作羊皮纸,并进行了一些测试。这些试验是:厚度测定(TS 4117 EN ISO 2589)、拉伸强度和伸长率测定(TS EN ISO 3376)、撕裂负荷测定-第2部分:(双面撕裂)(TS 4118-2 EN ISO 3377-2)、皮革-颗粒膨胀和强度测定(TS 4137 EN ISO 3379)、耐水渍色牢度测定(TS EN ISO 15700)。由于火鸡皮的强度较低,因此试图通过制作装饰性的花朵设计来创造不同的使用区域。在这项研究中,它试图展示如何将废料转化为具有非常高附加值的产品。
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引用次数: 0
Application of L-Ascorbic Acid as an Antioxidative Colorment in Leather Finishing l -抗坏血酸作为抗氧化剂在皮革涂饰中的应用
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2022-04-29 DOI: 10.34314/jalca.v117i5.4909
Sultan Çivi, E. E. Bayramoğlu
In this study, chrome tanned bovine crust leathers were dyed white during finishing process. Experiments with 1%, 2%, 3%, 4% and 5% L-ascorbic acid addition were performed on the finishing layer of the finishing application. L-ascorbic acid was not added to the control group and processed according to the standard method. After these processes, color measurement analyzes were performed on Konica Minolta CM 3600d spectrophotometer. In order to investigate the effects of L-ascorbic acid on other performance properties of leather, light fastness test according to TS 1008 EN ISO 105-B02 (2001 TS EN ISO 11640 2001) and dry rub fastness test according to standard method were performed. The results of the study were statistically evaluated according to the NCSS (Number Cruncher Statistical System) method. As a result of the research, it was observed that L-ascorbic acid gave a pearly pink color to the leathers. It was found that the dry rubbing fastness of the leathers treated with L-ascorbic acid improved. In the light fastness tests, the results of the experimental group leathers were recorded better by the blue scale.
以铬鞣牛皮为原料,在整理过程中将其染成白色。在整理后的整理层上分别添加1%、2%、3%、4%和5%的l -抗坏血酸。对照组不添加l -抗坏血酸,按标准方法加工。在这些过程之后,在柯尼卡美能达CM 3600d分光光度计上进行颜色测量分析。为了考察l -抗坏血酸对皮革其他性能的影响,按照TS 1008 EN ISO 105-B02 (2001 TS EN ISO 11640 2001)进行了耐光牢度试验,并按照标准方法进行了干摩擦牢度试验。根据NCSS (Number Cruncher Statistical System)方法对研究结果进行统计评价。研究结果显示,l -抗坏血酸使皮革呈珍珠粉色。结果表明,经l -抗坏血酸处理后,皮革的干摩擦牢度有所提高。在耐光性测试中,实验组皮革用蓝标记录的结果较好。
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引用次数: 0
Silica-Embedded Polyurea Microspheres with Rough Surface for Matte Leather Finishing 表面粗糙的二氧化硅嵌入聚脲微球,用于哑光皮革整理
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2022-04-29 DOI: 10.34314/jalca.v117i5.4913
Liang Jia, Li Duo Wang, Jing Li, Jun Xiang, Yi Chen, H. Fan
A type of polyurea microspheres with rough surfaces and different sizes (1-12 μm), which was used for waterborne polyurethane matte leather coating, were prepared by precipitation polymerization in H 2 O/acetonitrile system, using isophorone diisocyanate as polymerized monomer, 2,4-diaminobenzenesulfonic acid sodium salt as hydrophilic monomer and nano-SiO 2 as surface roughener. The effect of the loading of isophorone diisocyanate and 2,4-diaminobenzenesulfonic acid sodium salt, the volume ratio of H 2 O/acetonitrile and the addition stage of nano-SiO 2 on the particle size and surface roughness were investigated so as to achieve the excellent matte effect of the coating. The results indicated that the adding of hydrophilic monomer can reduce the particle size of microspheres and improve its re-dispersibility in water, while the increase of the proportion of acetonitrile in the mixed solvent and the loading of polymerized monomer can enlarge the size of the polyurea microspheres. As surface roughener, with the increase of nano-SiO 2 loading, the surface roughness and the particle size of microspheres increase. When nano-SiO 2 is added at the stage of the reaction system getting turbid, the maximum surface roughness of polyurea microspheres can be achieved. Polyurea microspheres with particle size (1-2 μm) and high surface roughness have better matting effect, and the gloss of the prepared waterborne polyurethane coating can be adjusted to less than 1.6° (60°-incident Angle).
以二异氰酸酯异福尔酮为聚合单体,2,4-二氨基苯磺酸钠盐为亲水性单体,纳米二氧化硅为表面粗糙剂,在乙腈体系中采用沉淀聚合法制备了一种表面粗糙、尺寸不同(1 ~ 12 μm)的聚脲微球,用于水性聚氨酯哑光皮革涂料。考察了二异氰酸酯异峰酮和2,4-二氨基苯磺酸钠盐的负载、h2o /乙腈的体积比和纳米sio2的添加阶段对涂层粒径和表面粗糙度的影响,以获得优异的哑光效果。结果表明,亲水性单体的加入可以减小聚脲微球的粒径,提高其在水中的再分散性,而混合溶剂中乙腈比例的增加和聚合单体的负载可以增大聚脲微球的粒径。作为表面粗化剂,随着纳米二氧化硅负荷量的增加,微球的表面粗糙度增大,颗粒尺寸增大。在反应体系混浊阶段加入纳米二氧化硅,可使聚脲微球的表面粗糙度达到最大。粒径(1 ~ 2 μm)、表面粗糙度高的聚脲微球具有较好的消光效果,制备的水性聚氨酯涂料光泽度可调至1.6°(60°入射角)以内。
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引用次数: 1
ACLA Spring Council Meeting Minutes ACLA春季理事会会议记录
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2022-04-29 DOI: 10.34314/jalca.v117i5.4923
Jalca Editor
ACLA Spring Council Meeting Minutes
ACLA春季理事会会议记录
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引用次数: 0
High Performance Leather based on in Situ Formation of Reduced Graphene Oxide in Chrome Tanning 基于还原氧化石墨烯在铬鞣中原位形成的高性能皮革
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2022-04-29 DOI: 10.34314/jalca.v117i5.4917
Xinle Yang, Yanchun Li, Mao Yang, Xugang Dang, Shan Cao
A novel method of high performance leather prepared via in situ reduction of graphene oxide after tanning was proposed in this research. First, nano-graphene oxide (GO) was prepared by an improved Hummers method. Then, the prepared GO was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Finally, GO was added during the chrome tanning process, and GO was reduced by ascorbic acid after the chrome tanning was completed. Moreover, the shrinkage temperature, tensile strength, tear strength and thermal conductivity of the finished leather were investigated. The results showed that the absorption of chrome tanning agent was significantly improved by the addition of GO. The tensile strength, tear strength, and the thermal conductivity of the resulted leather obviously surpassed the leather tanned by chrome tanning agent. Specifically, the tensile strength and tear strength of the leather reached 21.25 MPa and 163.95 N·mm-1 , respectively, when the amount of reducing agent was ten times the amount of GO. A combination of the tanning of leather and the in situ reduction of GO is expected to become a new processing method for preparation of high performance.
提出了一种利用氧化石墨烯原位还原法制备高性能皮革的新方法。首先,采用改进的Hummers法制备纳米氧化石墨烯(GO)。然后,利用傅里叶变换红外光谱(FT-IR)、x射线衍射(XRD)、扫描电镜(SEM)和x射线光电子能谱(XPS)对制备的氧化石墨烯进行表征。最后,在铬鞣过程中加入氧化石墨烯,铬鞣完成后氧化石墨烯被抗坏血酸还原。研究了成品皮革的收缩温度、拉伸强度、撕裂强度和导热系数。结果表明,氧化石墨烯的加入显著提高了铬鞣剂的吸收率。所得皮革的抗拉强度、撕裂强度和导热系数明显优于铬鞣剂鞣制的皮革。其中,当还原剂用量为氧化石墨烯用量的10倍时,皮革的拉伸强度和撕裂强度分别达到21.25 MPa和163.95 N·mm-1。皮革鞣制与氧化石墨烯原位还原相结合有望成为制备高性能皮革的一种新的加工方法。
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引用次数: 1
Manufacture of Exotic Leather and Small Leather Goods from Ovine Stomach 用羊胃制取异域皮革及小皮具
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2022-04-29 DOI: 10.34314/jalca.v117i5.4914
Peris N. Wainaina, B. Ongarora, Paul K Tanui
Leathers made from exotic skins or rare parts of animals have very good market value. The exotic leathers are usually preferred because of their patterns, naturally occurring marks and their unique structures. The objective of this study was to investigate the feasibility of tanning the ovine stomach into novelty leather and leather products. The ovine stomach was converted into an exotic leather using oil tanning methodology, with goat oil as a tanning agent. The rumen and reticulum parts of the stomach were taken through pre-tanning, tanning and post-tanning operation. The resultant leather had a different grain from the ordinary leather. Then mechanical operations like drying, toggling and staking were done. Physical properties of the leathers were analyzed by determining their thickness, tensile strength, elongation at break, tear strength, flex endurance and ball burst extension test. The grain structure of the leathers was analyzed using a light microscope. The results of physical tests were poor compared to the grains of conventional leathers since the composition of raw outer coverings of animals and those of the stomach are different. The leather processed from this non-conventional source has been found suitable for manufacturing fancy small leather goods like coin purse, key holders, purses and wallets.
用珍奇动物皮或稀有动物部位制成的皮革具有很好的市场价值。异国皮革通常是首选,因为它们的图案,自然产生的痕迹和其独特的结构。本研究的目的是探讨将羊胃鞣制成新型皮革和皮革制品的可行性。用山羊油作为鞣制剂,将羊胃转化为一种奇异的皮革。分别在晒前、晒后和晒后取瘤胃和胃网部分。合成的皮革具有与普通皮革不同的纹理。然后进行机械操作,如干燥、翻转和打桩。通过测定皮革的厚度、拉伸强度、断裂伸长率、撕裂强度、弯曲耐久性和球爆拉伸试验,分析了皮革的物理性能。用光学显微镜对皮革的颗粒结构进行了分析。与传统皮革的颗粒相比,物理测试的结果较差,因为动物的原始外层覆盖物和胃的成分不同。从这种非传统来源加工的皮革被发现适合制造精致的小皮革制品,如硬币钱包、钥匙夹、钱包和钱包。
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引用次数: 0
Ensemble of Fine-Tuned Deep Learning Networks for Wet-Blue Leather Segmentation 用于湿蓝皮革分割的微调深度学习网络集成
IF 0.9 4区 工程技术 Q3 Chemistry Pub Date : 2022-04-05 DOI: 10.34314/jalca.v117i4.4900
Masood Aslam, T. M. Khan, S. Naqvi, Geoff Holmes
As part of industrial quality control in the leather industry, it is important to segment features/defects in wet-blue leather samples. Manual inspection of leather samples is the current norm in industrial settings. To comply with the current industrial standards that advocate large-scale automation, visual inspection based leather processing is imperative. Visual inspection of wet-blue leather features is a challenging problem as the characteristics of these features can take on a variety of shapes and colour variations to constitute various normal and abnormal surface regions. The aim of this work is to automatically segment leather images to detect various features/defects along with the background through visual analysis of the surfaces. To accomplish this, a deep learning-based technique is developed that learns to segment wet-blue leather surface features. On our own curated leather images dataset, the proposed ensemble network performed well, with an F1-Score of 74 percent.
作为皮革工业质量控制的一部分,对湿蓝色皮革样品的特征/缺陷进行分割是很重要的。手工检查皮革样品是目前工业环境中的规范。为了符合目前提倡大规模自动化的工业标准,基于视觉检测的皮革加工势在必行。湿蓝色皮革特征的目视检查是一个具有挑战性的问题,因为这些特征的特征可以呈现各种形状和颜色变化,从而构成各种正常和异常的表面区域。这项工作的目的是通过对表面的视觉分析,自动分割皮革图像,以检测各种特征/缺陷以及背景。为了实现这一目标,开发了一种基于深度学习的技术,该技术可以学习分割湿蓝色皮革表面特征。在我们自己策划的皮革图像数据集上,提出的集成网络表现良好,F1-Score为74%。
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引用次数: 1
期刊
Journal of The American Leather Chemists Association
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