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Biosynthetic Gold Nanoparticles as Sensitive and Selective Colorimetric Method for Mercury Ions 生物合成金纳米颗粒对汞离子的灵敏选择性比色法
Pub Date : 2023-07-12 DOI: 10.18596/jotcsa.1300270
Maryam ABDULGHAFOR AHMED, Safana AHMED FARHAN, Rasha MONİEM DADOOSH, Abdulkadir MOHAMMED NOORİ JASSİM
Gold nanoparticles (AuNPs) are widely studied materials that have intense applications in various fields. Different methods use to synthesize the AuNPs, one of them is eco-friendly biological method, known as "green synthesis" a simple and inexpensive method. The Synthesis of AuNPs, using ginger extract is described here. The components found in ginger work as a stabilizing and reducing agent. Hydrogen tetrachloroaurate (HAuCl4) are mixed with the ginger extract to produce AuNPs. The Surface Plasmon Resonance (SPR) measured at λmax = 540 nm. UV-Vis, FTIR and Zeta potential are used to identify AuNPs, as well as AFM and SEM. Data indicate that AuNPs has a spherical structure. The results demonstrate that AuNPs stabilized by ascorbic acid were used as a colorimetric probe for Hg2+ ions, based on the production of (Au-Hg) amalgamate which made changes in their absorbance, due to its ability to reduce Hg2+ to Hg0, to enhance amalgamation. Practically, this procedure has successfully worked to detect Hg2+ in tap water as a sensitive and selective probe with upper limit of detection equal to 120 µM as well as the limit of detection (LOD) equal to 0.65 µM, so the method proved to be sensitive and selective probe.
金纳米颗粒是一种被广泛研究的材料,在各个领域都有广泛的应用。合成aunp的方法不同,其中一种是生态友好的生物方法,被称为“绿色合成”,是一种简单而廉价的方法。本文介绍了用生姜提取物合成AuNPs的方法。生姜中的成分是一种稳定剂和还原剂。四氯酸氢(HAuCl4)与姜提取物混合生成aunp。在λmax = 540 nm处测量的表面等离子体共振(SPR)。利用UV-Vis, FTIR和Zeta电位以及AFM和SEM对AuNPs进行鉴定。数据表明,AuNPs具有球形结构。结果表明,抗坏血酸稳定的AuNPs作为Hg2+离子的比色探针,基于(Au-Hg)汞齐的产生,由于其能够将Hg2+还原为Hg0,从而增强汞齐,从而改变了它们的吸光度。在实际应用中,该方法成功地检测了自来水中的Hg2+,检测上限为120µM,检测限(LOD)为0.65µM,是一种灵敏的选择性探针。
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引用次数: 0
Production of SBS Reinforced Polyester Composite: Characterization of Physical and Chemical Properties SBS增强聚酯复合材料的生产:物理和化学性能表征
Pub Date : 2023-07-12 DOI: 10.18596/jotcsa.1208503
H. Şahal, E. Aydoğmuş
In this study, dissolved styrene butadiene styrene (SBS) copolymer is homogeneously reinforced into orthophthalic unsaturated polyester (UP) resin. Polyester composite production is carried out with the help of methyl ethyl ketone peroxide (MEKP) and cobalt octoate (Co Oc) catalysts. The density, Shore D hardness, thermal conductivity coefficient, thermal stability, morphological surface structure, and chemical bond structure of the obtained composite have been examined. According to the results, SBS reinforcement decreases the density of the composite and increases the thermal conductivity coefficient. The addition of SBS at different weight ratios (1%, 3%, 5%, 7%, and 10% w/w) reduces both the hardness and thermal stability of the polyester composite. According to the test and analysis results, 5 wt.% SBS reinforced polyester composite production is determined as the optimum ratio. 7 wt.% and above SBS reinforcement negatively affect the physical and chemical properties of the obtained composite. For example, when 10 wt.% SBS reinforced composite is examined by scanning electron microscope (SEM), and irregular pores are observed in the surface morphology. Also, it is understood by Fourier transform infrared spectroscopy (FTIR) that there is a physical interaction between SBS and polyester and that no chemical bond is formed. The thermal decomposition behavior of the composite has been determined according to the decrease in the activation energy. As SBS ratio increases, it is understood that the thermal stability of the product obtained with the decrease in the activation energy of the polyester composite weakens.
在本研究中,溶解的苯乙烯-丁二烯-苯乙烯(SBS)共聚物被均匀增强成邻苯二甲酸不饱和聚酯(UP)树脂。在过氧化甲乙酮(MEKP)和八酸钴(Co Oc)催化剂的帮助下,进行了聚酯复合材料的生产。测试了复合材料的密度、邵氏硬度、导热系数、热稳定性、表面形态结构和化学键结构。结果表明,SBS增强降低了复合材料的密度,提高了导热系数。不同重量比(1%、3%、5%、7%和10% w/w)的SBS的加入降低了聚酯复合材料的硬度和热稳定性。根据试验分析结果,确定了5 wt.% SBS增强聚酯复合材料的最佳配比。7 wt.%及以上的SBS增强对得到的复合材料的物理和化学性能有负面影响。例如,当用扫描电镜观察10 wt.% SBS增强复合材料时,在表面形貌上观察到不规则的孔隙。此外,通过傅里叶变换红外光谱(FTIR)可以了解SBS与聚酯之间存在物理相互作用,而没有形成化学键。根据活化能的降低来确定复合材料的热分解行为。据了解,随着SBS比的增加,随着聚酯复合材料活化能的降低而得到的产品的热稳定性减弱。
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引用次数: 0
Ethnomedicinal Uses, Phytochemistry and Pharmacology of Few Species of Genus Atalantia (Rutaceae): A Review 芦花属少数种的民族药用、植物化学和药理研究进展
Pub Date : 2023-07-11 DOI: 10.18596/jotcsa.1252184
Pournima Shelar, Santoshkumar Singh
Synthetic drugs show major side effects, as well as the fact that they have been discovered to be extremely harmful to human assistance, many synthetic medications claimed to be used for treatment are of the least interest today. Therefore, herbal medicines have acquired prominence in recent decades. This review's primary objective is to give a complete overview of three distinct species of the Genus Atalantia mainly Atalantia monophylla (Roxb) DC, Atalantia racemaosa Wight, Atalantia wightii Tanaka. The Genus Atalantia belongs to Rutaceae family and there are 22 accepted species of which three species are selected because these are available in Western Ghat region of Maharashtra, these species have ethnopharmacological significance and many of their facets are still unexplored. The Atalantia genus is utilized in conventional medicine to treat a diverse array of ailments like fever, rheumatic pains, cough, allergy, swelling, and as a blood purifier, etc. The current work is a comprehensive analysis of the published literature on phytochemical and pharmacological reports of the above species of Atalantia genus in an effort to deliver comprehensive information and suggest future research avenues. Out of these three species, Atalantia monophylla has received the most research attention but the remaining two species are not much explored. The aim of this review is to discuss the potential application of these three species as herbal medicine. The plant characteristics, ethnobotanical uses, phytochemistry, and pharmacological activities are summarized as a guide for phytochemical and pharmacological investigations.
合成药物显示出主要的副作用,以及它们被发现对人体极其有害的事实,许多声称用于治疗的合成药物今天是最不感兴趣的。因此,近几十年来,草药获得了突出的地位。本文综述了三种不同的亚特兰大属植物:单叶亚特兰大(Roxb) DC、总状亚特兰大(Atalantia racemaosa wright)和田中亚特兰大(Atalantia wightii Tanaka)。Atalantia属芸香科,共有22种,其中3种是在马哈拉施特拉邦的西高特地区发现的,这些物种具有民族药理学意义,它们的许多方面仍未被探索。亚特兰大属在传统医学中用于治疗各种疾病,如发烧,风湿痛,咳嗽,过敏,肿胀,并作为血液净化剂等。本文对已发表的关于上述植物的植物化学和药理报道进行了综合分析,以期提供全面的信息,并为今后的研究方向提出建议。在这三个物种中,Atalantia monophylla受到了最多的研究关注,但其余两个物种的探索并不多。本文的目的是讨论这三种植物作为草药的潜在应用。概述了植物的特性、民族植物学用途、植物化学和药理活性,为植物化学和药理研究提供了指导。
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引用次数: 0
Tyramine Adsorption Using the Modification of Takari Natural Sand-Based Silica with Bovine Serum Albumin (BSA) 利用牛血清白蛋白 (BSA) 对 Takari 天然砂基二氧化硅进行改性来吸附酪胺
Pub Date : 2023-07-10 DOI: 10.18596/jotcsa.1244774
Johnson Naat, Yantus A. B. Neolaka, Yosep Lawa, Petrus Noni̇ng, Ayu W.m Menno, R. Rosni̇ta, Fransiskus B.o. Weo, Dewi Lestarani, Sri Sugiarti, Diah Iswanti̇ni̇
In this article, we use a batch method to convey tyramine adsorption by modifying Takari natural sand-based silica with BSA and tyramine adsorption. The research stages include the optimization of adsorbent mass, pH, temperature, determination of the isotherm model, and thermodynamic parameters of tyramine adsorption. The tyramine concentration was determined using UV-Vis. The characterizations carried out were functional groups using FT-IR and surface morphology using SEM. The results of FT-IR characterization demonstrated the success of BSA modification, as observed in the C-H, N-H, and C-N groups, which are the typical functional groups of BSA. The SEM image of SiO2@BSA before tyramine adsorption revealed unevenly sized particles, uneven distribution, and agglomeration, leading to larger particles. The morphology of SiO2@BSA-tyramine appeared to be more uniform, exhibiting a smoother shape with a slightly uneven surface. The optimum pH was 5 (qe=11.74 mg/g), and the optimum temperature was 303 K (qe= 2.47 mg/g). The isotherm study showed that the adsorption adhered to the Redlich-Peterson isotherm model with an R2 value of 0.987 (qe=5.157 mg/g and n =3.759). The thermodynamic study demonstrated ∆Ho = 49.08 kJ/mol, ∆Go =-17.84; -20.05 and -22.26 kJ/mol, and ∆So =0.22 kJ/mol.K. These results indicated that the tyramine adsorption process on SiO2@BSA adsorbent occurred endothermically and spontaneously at the temperature of 303 K, and the adsorption was of a physical-chemical adsorption type.
本文采用批次法,通过对 Takari 天然砂基硅石进行 BSA 改性并吸附酪胺,来传递酪胺吸附。研究阶段包括吸附剂质量、pH 值、温度的优化,等温线模型和酪胺吸附热力学参数的确定。使用紫外可见光谱测定了酪胺浓度。利用傅立叶变换红外光谱和扫描电子显微镜进行了官能团表征和表面形貌表征。傅立叶变换红外光谱的表征结果表明,BSA 的典型官能团 C-H、N-H 和 C-N 基团成功地进行了修饰。SiO2@BSA吸附酪胺前的扫描电镜图像显示,颗粒大小不均、分布不均、团聚,导致颗粒变大。SiO2@BSA-tyramine 的形态似乎更加均匀,形状更加平滑,表面略有凹凸。最佳 pH 值为 5(qe=11.74 毫克/克),最佳温度为 303 K(qe=2.47 毫克/克)。等温线研究表明,吸附符合 Redlich-Peterson 等温线模型,R2 值为 0.987(qe=5.157 毫克/克,n =3.759)。热力学研究表明 ∆Ho = 49.08 kJ/mol,∆Go =-17.84; -20.05 和 -22.26 kJ/mol,∆So =0.22 kJ/mol.K。这些结果表明,SiO2@BSA 吸附剂对酪胺的吸附过程是在 303 K 温度下自发发生的,属于物理化学吸附类型。
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引用次数: 0
Assessment of Total Phenolic Compounds, Antioxidant Capacity, β-Carotene Bioaccessibility, HMF Formation, and Color Degradation Kinetics in Pumpkin Pestils 南瓜瘟病病中总酚类化合物、抗氧化能力、β-胡萝卜素生物可及性、HMF形成和颜色降解动力学的评估
Pub Date : 2023-06-26 DOI: 10.18596/jotcsa.1302567
Azime ÖZKAN KARABACAK
Pestil, often known as fruit leather, is one of the most significant traditional foods manufactured and consumed throughout Türkiye. Due to its practical consumption, the availability of numerous nutrients, and the ability to meet energy requirements, pestil is recognized as a snack food. The aim of this study was to evaluate the bioaccessibility of total phenolic compounds (TPC), antioxidant capacity (AOC), and β-carotene in pumpkin pestils dried by hot air drying (HAD), vacuum drying (VCD), and microwave drying (MD) methods using an in vitro digestion model. Additionally, 5-hydroxymethylfurfural (HMF) formation and color degradation of pestils were evaluated. Changes in TPC and AOC were determined using spectrophotometric methods, whereas the detections of β-carotene and HMF were carried out with high performance liquid chromatography–photodiode array detector (HPLC–PDA). Significantly higher TPC (10.99–105.70%) and AOC (15.30–118.58%, 21.88–401.04% and 89.28–482.14%, in CUPRAC, FRAP, and DPPH assays, respectively) values were observed after drying (p<0.05). Moreover, it was observed that there were statistically significant increases in TPC and AOC values after digestion for all pumpkin pestils compared to undigested samples (p<0.05). Drying process resulted in lower β-carotene content (between 32.15–61.11%) in pumpkin pestils; however, it increased the percentage of bioaccessible β-carotene (max 62.16%) in the pestil samples. Compared to HD and VCD techniques, pumpkin pestils dried with MD exhibited significantly higher TPC, AOC and β-carotene content (p<0.05). All of the pumpkin pestils except those dried by MD at 180 W contain HMF below the Turkish Standards Institute legal limit of 50 mg/kg. L* value of pestils were described adequately to the zero- and first-order kinetic models while a* and b* values were only fitted to zero-order model. In conclusion, the findings obtained in this study pointed out that drying processes (especially by MD method) increased the bioaccessibility of TPC, AOC, and β-carotene.
疫皮,通常被称为果皮,是整个挪威生产和消费的最重要的传统食品之一。由于其实际消耗,大量营养物质的可用性,以及满足能量需求的能力,鼠疫被公认为休闲食品。采用体外消化模型,研究了热风干燥(HAD)、真空干燥(VCD)和微波干燥(MD)三种干燥方法对南瓜皮中总酚类化合物(TPC)、抗氧化能力(AOC)和β-胡萝卜素的生物可及性。此外,还评价了5-羟甲基糠醛(HMF)的形成和颜色降解。采用分光光度法测定TPC和AOC的变化,采用高效液相色谱-光电二极管阵列检测器(HPLC-PDA)检测β-胡萝卜素和HMF。干燥后的TPC(10.99 ~ 105.70%)和AOC(15.30 ~ 118.58%, 21.88 ~ 401.04%, 89.28 ~ 482.14%)显著提高(p<0.05)。与未消化样品相比,消化后各南瓜病斑的TPC和AOC值均显著升高(p<0.05)。干燥处理导致南瓜枯萎病中β-胡萝卜素含量降低(32.15 ~ 61.11%);但可提高鼠疫菌样品中生物可及性β-胡萝卜素的含量,最高可达62.16%。与HD和VCD处理相比,MD处理的南瓜果实TPC、AOC和β-胡萝卜素含量显著高于HD和VCD处理(p<0.05)。除经MD在180瓦下干燥的南瓜外,所有南瓜的HMF含量均低于土耳其标准协会规定的50毫克/公斤的法定限量。L*值适合于零级和一阶动力学模型,而a*和b*值只适合于零级动力学模型。综上所述,本研究结果表明,干燥工艺(特别是MD法)提高了TPC、AOC和β-胡萝卜素的生物可及性。
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引用次数: 1
Comparison on Total Phenolics and Flavonoids and Antioxidant Activities of Methanol Extract of Horseshoe Crab (Tachypleus gigas) Eggs 马蹄蟹卵甲醇提取物总酚类、总黄酮及抗氧化活性的比较
Pub Date : 2023-06-25 DOI: 10.18596/jotcsa.1243140
Elvira Ratna Ai̇sa, T. Tukiran
The marine environment can be a source of abundant bioactive compounds. One of the horseshoe crab species scattered in Indonesian sea waters is Tachypleus gigas. It was reported that the eggs of T. gigas contained flavonoids, saponins, alkaloids, and steroids. Flavonoids are polyphenol compounds that have the ability as natural antioxidants. In this study, total phenolics, flavonoids, and antioxidant activity tests were carried out on the methanol extract of T. gigas eggs. The total phenolics content used the Folin Ciocalteu method, the total flavonoids used the aluminum chloride colorimetric method, and the antioxidant activity test used the FRAP and DPPH methods. The test results showed that the total phenolics and flavonoids were 0.53506 ± 0.001335 mg GAE/g extract and 0.52067 ± 0.000731 mg QE/g extract, respectively. Meanwhile, the results of the antioxidant activity test with the FRAP method obtained a total antioxidant capacity of 29.85 μmol in the medium category and antioxidant activity with the DPPH method obtained an IC50 value of 597.0397 μg/mL in the very weak category.
海洋环境可以是丰富的生物活性化合物的来源。分布在印度尼西亚海域的马蹄蟹品种之一是大闸蟹。据报道,大菱鲆卵含有黄酮类化合物、皂苷、生物碱和类固醇。类黄酮是一种多酚化合物,具有天然抗氧化剂的能力。本研究对巨虾虫卵甲醇提取物进行了总酚、总黄酮和抗氧化活性试验。总酚含量采用Folin Ciocalteu法测定,总黄酮含量采用氯化铝比色法测定,抗氧化活性采用FRAP和DPPH法测定。试验结果表明,总酚和总黄酮含量分别为0.53506±0.001335 mg GAE/g提取物和0.52067±0.000731 mg QE/g提取物。同时,FRAP法抗氧化活性测试结果显示,中类总抗氧化能力为29.85 μmol, DPPH法抗氧化活性的IC50值为597.0397 μg/mL,属极弱类。
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引用次数: 0
Structural Properties, Photoluminescence, and Judd-Ofelt Parameters of Eu3+- Doped CoNb2O6 Phosphor Eu3+掺杂CoNb2O6荧光粉的结构性质、光致发光和Judd-Ofelt参数
Pub Date : 2023-06-23 DOI: 10.18596/jotcsa.1294230
M. İlhan, Lütfiye Feray Güleryüz, M. K. Ekmekçİ
Trivalent Eu-activated CoNb2O6 phosphors were fabricated using the molten salt method, which provides enhanced homogeneity and low sintering temperature. The ceramic samples were examined by spectral and structural analyses. In X-ray diffractions, the single phase of orthorhombic columbite type CoNb2O6 structure was obtained for 0.5-10 mol% Eu3+ doping concentrations, while a two theta peak shift towards the smaller angles occurred. SEM examinations show an irregular morphology and sub-micron grain sizes. In photoluminescence (PL) spectra, the phosphors showed typical Eu3+ emissions with the 5F0 → 7FJ (J=0, 1, 2, 3, 4) transitions, and high emission peaks were observed at the 5D0 → 7F2 transition. The photoluminescence of CoNb2O6:Eu3+ decreased over 5 mol% because of the concentration quenching. The energy transfer mechanism and critical distance of the phosphor are the dipole-dipole (d–d) interaction, and 15.70 Å, respectively. The spectral features of the phosphors were assessed by calculating the Judd-Ofelt intensity parameters (Ω2, Ω4) from the PL emission spectrum. The low Ω2 parameter values or/and the Ω4>Ω2 trend for CoNb2O6:Eu3+ phosphors were related to the less covalent or more ionic character of the Eu3+–O2˗ bond and the high local symmetry of the Eu3+ sites, while the high Ω4 parameter values may be ascribed to the decrease in the electron density in the ligands.
采用熔盐法制备了三价铕活化的CoNb2O6荧光粉,具有较好的均匀性和较低的烧结温度。对陶瓷样品进行了光谱和结构分析。在x射线衍射中,当Eu3+掺杂浓度为0.5-10 mol%时,获得了正交柱状CoNb2O6结构的单相,同时出现了向较小角度移动的2个θ峰。扫描电镜检查显示其形貌不规则,晶粒尺寸为亚微米级。在光致发光(PL)光谱中,荧光粉在5F0→7FJ (J= 0,1,2,3,4)跃迁时表现出典型的Eu3+发射,在5D0→7F2跃迁处出现高发射峰。由于浓度猝灭,CoNb2O6:Eu3+的光致发光降低了5 mol%以上。荧光粉的能量传递机制为偶极-偶极(d-d)相互作用,临界距离为15.70 Å。通过计算PL发射光谱中的Judd-Ofelt强度参数(Ω2, Ω4)来评估荧光粉的光谱特征。CoNb2O6:Eu3+的低Ω2参数值或/和Ω4>Ω2趋势与Eu3+ -O2的低共价或高离子特征以及Eu3+位点的高局部对称性有关,而高Ω4参数值可能与配体中电子密度的降低有关。
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引用次数: 0
Development of Two Simple Spectrophotometric Methods to Assay Phenylephrine-HCl as Pure Form And in Its Drug Forms 两种简单分光光度法测定盐酸苯肾上腺素的纯态和剂型
Pub Date : 2023-06-22 DOI: 10.18596/jotcsa.1260666
Hanan Hameed, Salim Ali
This work includes the development of two spectrophotometric methods which are sensitive, accurate, stable, and has good recovery for the determination of phenylephrine-HCl as free form and in the pharmaceutical preparations. In the method (A), phenylephrine is oxidized by potassium permanganate in a basic solution of sodium hydroxide and the bluish-green color of the resulting manganate (MnO 42- ) is measured at wavelength 610 nm, which is linearly proportional to the amount of phenylephrine-HCl. Method (B), is involved the oxidation of phenylephrine-HCl by using an excess amount of N-bromosuccinimide in an acidic medium of hydrochloric acid solution, the remaining (unreacted) amount of N-bromosuccinimide is used to bleach indigo carmine dye and the absorbance of the blue color of the remaining dye is measured at the wavelength of 610 nm. which is directly proportional to the concentration of phenylephrine-HCl. The molar absorptivity coefficients of methods (A) and (B) are estimated and equal to 1.5722×10 4 and 5.5191×10 4 L/mol.cm, respectively. Beer’s law of the both methods are linear in the concentration ranges 0.2–8.0 µg/mL (method A) and 0.2–3.5 µg/mL (method B). The relative standard deviation values of methods (A) and (B) are also found to be better than 0.0286 and 0.0114, respectively. The two proposed methods are applied to estimate phenylephrine-HCl in injection and drop.
建立了两种灵敏、准确、稳定、回收率高的分光光度法测定游离形态盐酸苯肾上腺素和制剂中的盐酸苯肾上腺素。在方法(A)中,苯肾上腺素在氢氧化钠的碱性溶液中被高锰酸钾氧化,在波长610 nm处测量得到的锰酸盐(mno42 -)的蓝绿色,该波长与苯肾上腺素- hcl的量成线性比例。方法(B),在盐酸溶液的酸性介质中使用过量的n -溴代琥珀酰亚胺氧化盐酸苯甲素,用剩余(未反应的)n -溴代琥珀酰亚胺漂白靛蓝胭脂红染料,在波长610 nm处测量剩余染料的蓝色吸光度。它与盐酸苯肾上腺素的浓度成正比。方法(A)和(B)的摩尔吸收系数分别为1.5722×10 4和5.5191×10 4 L/mol。厘米,分别。两种方法的Beer’s定律在0.2 ~ 8.0µg/mL(方法A)和0.2 ~ 3.5µg/mL(方法B)的浓度范围内均呈线性关系,方法A和方法B的相对标准偏差值分别优于0.0286和0.0114。应用这两种方法对盐酸苯肾上腺素注射液和滴剂进行了评价。
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引用次数: 0
Design, Synthesis and Structural Characterization of Novel Thioanthraquinone Analogues from 1,5-Dichloroanthraquinone 1,5-二氯蒽醌类新型硫代蒽醌类似物的设计、合成及结构表征
Pub Date : 2023-06-22 DOI: 10.18596/jotcsa.1240673
Funda Özkök
Anthraquinone and its derivatives are considered intermediate agents with superior properties due to their activities in chemical and biological reaction. A new, economical, practical and one-step synthesis method was developed by our research team for the synthesis of amino and thioanthraquinones in previous studies (1). With this synthesis method, thioanthraquinone analogs 2(a-d) were obtained from 1,5-Dichloroanthraquinone (1) and bioactive thiols. The synthesized organic molecules were purified by column chromatography and their structures were identified with spectroscopic methods. Fluorescence analyzes of synthesized thioanthraquinone analogues were performed. It was determined that all thioanthraquinone analogues synthesized and characterized in the study showed fluorescence activity. These new analogues with fluorescence are expected to find application in drug delivery systems and sensor studies.
蒽醌及其衍生物因其在化学和生物反应中的活性而被认为是性能优越的中间体。本课题组在前期研究中开发了一种新的、经济实用的一步合成氨基蒽醌和硫代蒽醌的方法(1)。该合成方法从1,5-二氯蒽醌(1)和生物活性硫醇中得到了硫代蒽醌类似物2(A -d)。用柱层析法对合成的有机分子进行了纯化,并用波谱法对其结构进行了鉴定。对合成的硫代蒽醌类似物进行荧光分析。结果表明,本研究合成并表征的硫代蒽醌类似物均具有荧光活性。这些新的荧光类似物有望在药物输送系统和传感器研究中找到应用。
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引用次数: 0
A Simple, Stable, and Highly Sensitive Spectrophotometric Method for the Determination of Arsenic(III) from Different Biological Media in the Presence of Nanosilica-Cysteine Composite 一种简单、稳定、高灵敏度的分光光度法测定纳米硅-半胱氨酸复合物存在下不同生物培养基中砷(III)的含量
Pub Date : 2023-06-22 DOI: 10.18596/jotcsa.1273473
Omar Alnasra, F. Khalili
This paper describes a selective and fairly stable colorimetric approach to determine trace amounts of arsenic conjugated with nanosilica-cysteine composite in various aqueous and biological samples in milligram per liter (mg/L) using Leucocrystal Violet (LCV) as a chromogenic reagent. Attenuated total reflectance-Fourier-transform infrared (ATR-FTIR) spectroscopy analysis was applied to characterize the composite. Novelty of this method is dealing with the presence of nanosilica which is reflected in the difficulty of obtaining a clear solution. The maximum absorbance is measured and Beer's law shows linearity over the concentration range of (0.75 to 5.00 mg/L) of As(III) at 590 nm. The molar absorptivity, Sandell’s sensitivity, and detection limit of the method were found to be 6.00 × 105 L/mol.cm, 8.55 × 10-2 μg/cm2, and 0.043 mg/L, respectively. The optimum reaction conditions and other analytical parameters were evaluated. Arsenic was successfully detected in a variety of aqueous and biological samples using the proposed method.
本文介绍了一种选择性和相当稳定的比色法,以毫微克/升(mg/L)为显色剂,测定各种水样和生物样品中纳米硅-半胱氨酸复合物的痕量砷。采用衰减全反射-傅里叶变换红外(ATR-FTIR)光谱分析对复合材料进行了表征。这种方法的新颖之处在于处理纳米二氧化硅的存在,这反映在获得透明溶液的困难上。测定了最大吸光度,Beer定律在As(III)浓度范围(0.75 ~ 5.00 mg/L)为590nm时呈线性关系。该方法的摩尔吸光度、桑德尔灵敏度和检出限均为6.00 × 105 L/mol。分别为8.55 × 10-2 μg/cm2和0.043 mg/L。对最佳反应条件和其他分析参数进行了评价。该方法成功地检测了多种水样和生物样中的砷。
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引用次数: 1
期刊
Journal of the Turkish Chemical Society Section A: Chemistry
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