Pub Date : 2023-12-09DOI: 10.1177/08927057231219946
N. Khanoonkon, Kunat Kongsin, Wannapa Jampanit, Chinchuta Chanwetwirot, Ramitanun Malakul, R. Chollakup, Suteera Witayakran, P. Chatakanonda, J. Boonyarit, T. Kittikorn
Alkaline pretreated hemp fibers were modified by steam explosion and/or silanization before being compounded with polylactic acid (PLA). The fungal biodegradation of the PLA/hemp fibers composite was investigated using Aspergillus niger TISTR 3153 in an aqueous medium for 28 days, following the ISO 846: 1997 standard method. The influence of the different physicochemical modifications of hemp fibers on the fungal biodegradation of the composite was evaluated in terms of molecular weight, chemical structure, mechanical properties, thermal properties, and hygroscopic properties. The results showed that the modulus of all composites were averagely increased by 109%, compared to neat PLA. All the PLA/hemp fiber composites better retained their properties after fungal biodegradation than neat PLA. Therefore, the physicochemical treatments of fibers after alkaline pretreatment promoted the resistance of the composite to fungal biodegradation. The treatment of hemp fibers in the present work was alkalization followed by silanization, which resulted in a PLA-based composite that was suitable for outdoor applications.
{"title":"Effect of steam explosion and silanization of hemp fibers on polylactic acid biocomposites; analysis of mechanical-thermal properties and fungal biodegradation","authors":"N. Khanoonkon, Kunat Kongsin, Wannapa Jampanit, Chinchuta Chanwetwirot, Ramitanun Malakul, R. Chollakup, Suteera Witayakran, P. Chatakanonda, J. Boonyarit, T. Kittikorn","doi":"10.1177/08927057231219946","DOIUrl":"https://doi.org/10.1177/08927057231219946","url":null,"abstract":"Alkaline pretreated hemp fibers were modified by steam explosion and/or silanization before being compounded with polylactic acid (PLA). The fungal biodegradation of the PLA/hemp fibers composite was investigated using Aspergillus niger TISTR 3153 in an aqueous medium for 28 days, following the ISO 846: 1997 standard method. The influence of the different physicochemical modifications of hemp fibers on the fungal biodegradation of the composite was evaluated in terms of molecular weight, chemical structure, mechanical properties, thermal properties, and hygroscopic properties. The results showed that the modulus of all composites were averagely increased by 109%, compared to neat PLA. All the PLA/hemp fiber composites better retained their properties after fungal biodegradation than neat PLA. Therefore, the physicochemical treatments of fibers after alkaline pretreatment promoted the resistance of the composite to fungal biodegradation. The treatment of hemp fibers in the present work was alkalization followed by silanization, which resulted in a PLA-based composite that was suitable for outdoor applications.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"14 2","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138585650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-01DOI: 10.1177/08927057231216741
Yajun Liu, T. Natsuki, Daisuke Suzuki, Canyi Huang, Lina Cui, Q. Ni
The development of impact-resistant composite materials for protective applications such as helmet and body armor has attracted considerable attention. In this study, a novel aramid fiber-woven thermoplastic-epoxy composite was developed. Furthermore, three types of woven textiles, namely three-dimensional (3D) orthogonal-woven (3DOW), 3D angle-interlock woven (3DAIW), and two-dimensional plain-woven (2DPW) textiles, were used as reinforcement structures. To study the effect of the woven structure, impact energy, and damage repairment on impact-resistance performance of these composites, low-velocity drop-weight impact tests with various impact scenarios, such as single-impact, repeated-impact, as well as multiple-impact with hot-press damage repairment, were conducted. The results revealed that the woven structure exhibited an obvious effect on the composite impact-resistance performance and failure modes when subjected to specific impact scenarios. For the single-impact scenario, especially under high impact energy levels (10 and 20 J), the 3DOW structure exhibited superior impact-resistance performance as well as damage tolerance, followed by 3DAIW and 2DPW structures. Furthermore, 3DOW achieved superior impact-resistance to the other two structures for the 10-J repeated-impact scenario. The 3DAIW structure, in which debonding or delamination as well as severe resin cracks dominated, achieved superior impact-resistance to multiple impacts with damage repairment.
{"title":"Low-velocity impact-resistance of aramid fiber three-dimensional woven textile-reinforced thermoplastic-epoxy composites","authors":"Yajun Liu, T. Natsuki, Daisuke Suzuki, Canyi Huang, Lina Cui, Q. Ni","doi":"10.1177/08927057231216741","DOIUrl":"https://doi.org/10.1177/08927057231216741","url":null,"abstract":"The development of impact-resistant composite materials for protective applications such as helmet and body armor has attracted considerable attention. In this study, a novel aramid fiber-woven thermoplastic-epoxy composite was developed. Furthermore, three types of woven textiles, namely three-dimensional (3D) orthogonal-woven (3DOW), 3D angle-interlock woven (3DAIW), and two-dimensional plain-woven (2DPW) textiles, were used as reinforcement structures. To study the effect of the woven structure, impact energy, and damage repairment on impact-resistance performance of these composites, low-velocity drop-weight impact tests with various impact scenarios, such as single-impact, repeated-impact, as well as multiple-impact with hot-press damage repairment, were conducted. The results revealed that the woven structure exhibited an obvious effect on the composite impact-resistance performance and failure modes when subjected to specific impact scenarios. For the single-impact scenario, especially under high impact energy levels (10 and 20 J), the 3DOW structure exhibited superior impact-resistance performance as well as damage tolerance, followed by 3DAIW and 2DPW structures. Furthermore, 3DOW achieved superior impact-resistance to the other two structures for the 10-J repeated-impact scenario. The 3DAIW structure, in which debonding or delamination as well as severe resin cracks dominated, achieved superior impact-resistance to multiple impacts with damage repairment.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":" 13","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138620241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-12-01DOI: 10.1177/08927057231219928
Krishnakumar S, Senthilvelan T
The objective of this research work is to study the in vitro degradation behavior of as-fabricated and annealed Poly Lactic Acid (PLA) composites reinforced with varying volume fractions of carbon fiber (CF).The composites are prepared by fused filament fabrication technique (FFF). Specimens are immersed in simulated body fluid (SBF) for 8 weeks to study the degradation behavior of the composites by examining the change in weight, change in pH and degradation in mechanical properties. The obtained results show that the addition of carbon fiber reinforcement reduces the tensile strength, flexural strength, impact strength and compressive strength of the composites. Further, CF addition enhances the tensile modulus of the composite. The mechanical properties of annealed composites are enhanced when compared to as-fabricated composites. Differential Scanning Calorimeter (DSC) is employed to study the thermal characteristics of the composites and % crystallinity of the composites. CF addition reduces the crystallinity of the composites. Fractographs of the tensile fractured specimens are studied using a scanning electron microscope (SEM). The addition of the carbon fiber reinforcement is found to accelerate the degradation behavior of the composites. There is significant change in weight and pH as well as degradation in mechanical properties of PLA-CF composites immersed in SBF than pure PLA composites. Annealed composites show better degradation resistance than as-fabricated composites. SEM is employed to study the surface morphology of the composites immersed in SBF.
{"title":"In vitro degradation analysis and mechanical characterization of PLA-CF composites prepared by fused filament fabrication technique for bio-medical applications","authors":"Krishnakumar S, Senthilvelan T","doi":"10.1177/08927057231219928","DOIUrl":"https://doi.org/10.1177/08927057231219928","url":null,"abstract":"The objective of this research work is to study the in vitro degradation behavior of as-fabricated and annealed Poly Lactic Acid (PLA) composites reinforced with varying volume fractions of carbon fiber (CF).The composites are prepared by fused filament fabrication technique (FFF). Specimens are immersed in simulated body fluid (SBF) for 8 weeks to study the degradation behavior of the composites by examining the change in weight, change in pH and degradation in mechanical properties. The obtained results show that the addition of carbon fiber reinforcement reduces the tensile strength, flexural strength, impact strength and compressive strength of the composites. Further, CF addition enhances the tensile modulus of the composite. The mechanical properties of annealed composites are enhanced when compared to as-fabricated composites. Differential Scanning Calorimeter (DSC) is employed to study the thermal characteristics of the composites and % crystallinity of the composites. CF addition reduces the crystallinity of the composites. Fractographs of the tensile fractured specimens are studied using a scanning electron microscope (SEM). The addition of the carbon fiber reinforcement is found to accelerate the degradation behavior of the composites. There is significant change in weight and pH as well as degradation in mechanical properties of PLA-CF composites immersed in SBF than pure PLA composites. Annealed composites show better degradation resistance than as-fabricated composites. SEM is employed to study the surface morphology of the composites immersed in SBF.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":" 89","pages":""},"PeriodicalIF":3.3,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138612129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Polyetheretherketone (PEEK), with good biocompatibility and similar mechanical properties to natural bone, is extensively employed in the manufacture of prostheses. However, the precision and mechanical properties of current implants are major challenges for clinical applications. In this study, the effect of pore size, raster angle and printing temperature were investigated on length, width, thickness, material consumption, compressive strength and Young’s modulus. Taguchi design of experiment method was used to reduce the number of experiments and optimize the printing process parameters. Finally, predictive analysis was exploited to give the optimal set of process parameters. Experimental results indicated that the approach applied in this work provided more accurate predictions and control of the response variables. The maximum compressive strength and compressive modulus of PEEK scaffolds reached 43.4 MPa and 253.3 MPa, respectively. Therefore, the methodology of present work has the potential to meet the demand of design precision and manufacture of customized bone substitutes.
{"title":"Optimizing process parameters of fused deposition molding for 3D printing customized control of polyetheretherketone scaffolds","authors":"Jingfeng Sun, Mantao Chen, Hui Zhao, Wenxu Zheng, Wuyi Zhou","doi":"10.1177/08927057231216745","DOIUrl":"https://doi.org/10.1177/08927057231216745","url":null,"abstract":"Polyetheretherketone (PEEK), with good biocompatibility and similar mechanical properties to natural bone, is extensively employed in the manufacture of prostheses. However, the precision and mechanical properties of current implants are major challenges for clinical applications. In this study, the effect of pore size, raster angle and printing temperature were investigated on length, width, thickness, material consumption, compressive strength and Young’s modulus. Taguchi design of experiment method was used to reduce the number of experiments and optimize the printing process parameters. Finally, predictive analysis was exploited to give the optimal set of process parameters. Experimental results indicated that the approach applied in this work provided more accurate predictions and control of the response variables. The maximum compressive strength and compressive modulus of PEEK scaffolds reached 43.4 MPa and 253.3 MPa, respectively. Therefore, the methodology of present work has the potential to meet the demand of design precision and manufacture of customized bone substitutes.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"34 28","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134953651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-13DOI: 10.1177/08927057231214655
{"title":"Corrigendum to “Study on buried polyethylene pipe reinforced by steel wires under internal pressure and foundation settlement”","authors":"","doi":"10.1177/08927057231214655","DOIUrl":"https://doi.org/10.1177/08927057231214655","url":null,"abstract":"","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"127 51","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136351424","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-07DOI: 10.1177/08927057231214468
Trimeche Monia
Biopolymers are materials specifically engineered to interact with biological systems. They can be derived from either natural or synthetic sources, depending on the biological resources used or the manufacturing process employed. Over recent decades, these materials have gained significant popularity within the medical field due to their remarkable attributes such as biodegradability, bioactivity, and compatibility with human tissue. One notable application is their use as scaffolds for bone regeneration. Biopolymers, being renewable biomaterials, provide opportunities for continuous manufacturing and technological progress across various industries. These biomaterials have demonstrated great promise in medical sectors, including nerve regeneration and the production of surgical devices. Additionally, their versatility extends to non-biomedical applications, like food packaging. This paper aims to provide a comprehensive overview of different biopolymers, elucidating their properties, showcasing their latest applications, and delving into the state-of-the-art manufacturing technologies used in their production. Special emphasis is placed on their suitability as bone tissue repair and regeneration scaffolds, owing to their unique properties, which render them an ideal choice for this specific application.
{"title":"Sustainable natural biopolymers for biomedical applications","authors":"Trimeche Monia","doi":"10.1177/08927057231214468","DOIUrl":"https://doi.org/10.1177/08927057231214468","url":null,"abstract":"Biopolymers are materials specifically engineered to interact with biological systems. They can be derived from either natural or synthetic sources, depending on the biological resources used or the manufacturing process employed. Over recent decades, these materials have gained significant popularity within the medical field due to their remarkable attributes such as biodegradability, bioactivity, and compatibility with human tissue. One notable application is their use as scaffolds for bone regeneration. Biopolymers, being renewable biomaterials, provide opportunities for continuous manufacturing and technological progress across various industries. These biomaterials have demonstrated great promise in medical sectors, including nerve regeneration and the production of surgical devices. Additionally, their versatility extends to non-biomedical applications, like food packaging. This paper aims to provide a comprehensive overview of different biopolymers, elucidating their properties, showcasing their latest applications, and delving into the state-of-the-art manufacturing technologies used in their production. Special emphasis is placed on their suitability as bone tissue repair and regeneration scaffolds, owing to their unique properties, which render them an ideal choice for this specific application.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"327 6","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135475442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-03DOI: 10.1177/08927057231213534
Mert Yücetürk, Buket Yücetürk, Gizem Yegane
Mineral-based flame retardants are widely used worldwide as they are both effective and inexpensive solutions. Especially alumina trihydrate (ATH) and magnesium hydroxide (MDH) are the first mineral additives that come to mind industrially due to their environmental friendliness and easy availability. In this study, the effectiveness of huntite-hydromagnesite mineral, which is not as widely used as the other two minerals, and its differences from its counterparts were investigated. For this purpose, composites with polyethylene carrier were produced by extruder method using binders at various ratios, and various physical, mechanical, and combustion properties of these samples were investigated. According to the data obtained, the samples containing huntite-hydromagnesite showed UL94 V0 class flame retardant performance with 5% less filler than their counterparts. The same samples showed superior mechanical properties in tensile strength between 23.4% and 70.8% and elongation at break between 60.7% and 73.1%.
{"title":"Investigation of flame retardancy and physical-mechanical properties of mineral-based polyethylene composites","authors":"Mert Yücetürk, Buket Yücetürk, Gizem Yegane","doi":"10.1177/08927057231213534","DOIUrl":"https://doi.org/10.1177/08927057231213534","url":null,"abstract":"Mineral-based flame retardants are widely used worldwide as they are both effective and inexpensive solutions. Especially alumina trihydrate (ATH) and magnesium hydroxide (MDH) are the first mineral additives that come to mind industrially due to their environmental friendliness and easy availability. In this study, the effectiveness of huntite-hydromagnesite mineral, which is not as widely used as the other two minerals, and its differences from its counterparts were investigated. For this purpose, composites with polyethylene carrier were produced by extruder method using binders at various ratios, and various physical, mechanical, and combustion properties of these samples were investigated. According to the data obtained, the samples containing huntite-hydromagnesite showed UL94 V0 class flame retardant performance with 5% less filler than their counterparts. The same samples showed superior mechanical properties in tensile strength between 23.4% and 70.8% and elongation at break between 60.7% and 73.1%.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"116 3‐4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135818375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-03DOI: 10.1177/08927057231211226
Alp Şık, Hamed Tanabi, H. Evren Çubukçu, Baris Sabuncuoglu
Mechanical properties of short fiber reinforced composites manufactured with fused deposition modeling is affected by variables such as printing properties and internal structure of the composite. In this study, the relation between the tensile properties of 3D-printed short fiber reinforced composites, printing orientation and internal structure is inspected. Samples of different printing orientations are manufactured. These samples are inspected under X-ray micro computed tomography (micro-CT) and their fiber orientation distributions and fiber properties are determined. Then, these internal structure properties are applied to analytical material models to estimate the tensile properties of composites. Estimated material properties are compared with tensile test results. It turns out that analytical models that consider internal structure properties provide more accurate estimations than other analytical models that does not take these into account.
{"title":"Experimental and analytical investigation of the tensile behavior of 3D-printed composites based on micro-CT analysis","authors":"Alp Şık, Hamed Tanabi, H. Evren Çubukçu, Baris Sabuncuoglu","doi":"10.1177/08927057231211226","DOIUrl":"https://doi.org/10.1177/08927057231211226","url":null,"abstract":"Mechanical properties of short fiber reinforced composites manufactured with fused deposition modeling is affected by variables such as printing properties and internal structure of the composite. In this study, the relation between the tensile properties of 3D-printed short fiber reinforced composites, printing orientation and internal structure is inspected. Samples of different printing orientations are manufactured. These samples are inspected under X-ray micro computed tomography (micro-CT) and their fiber orientation distributions and fiber properties are determined. Then, these internal structure properties are applied to analytical material models to estimate the tensile properties of composites. Estimated material properties are compared with tensile test results. It turns out that analytical models that consider internal structure properties provide more accurate estimations than other analytical models that does not take these into account.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"12 10","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135873768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-02DOI: 10.1177/08927057231208970
Asif Khan, Heung Soo Kim
This article proposes a framework for the damage assessment of and effect of temperature variations in laminated composites using Lamb waves and unsupervised autonomous features. A network of piezoelectric transducers is employed to generate data for 18 health states of a laminated composite plate. The data is processed with sparse autoencoder (SAE) for unsupervised autonomous features. The discriminative capabilities of the extracted features are confirmed by processing the feature space in the supervised and unsupervised frameworks of machine learning. The confusion matrices of supervised learning provided physical insights into the problem. The feature space was also visualized in two dimensions in an unsupervised manner through principal component analysis (PCA), which revealed physically consistent results for the effect of temperature variations, damage of different severity levels, and the undamaged paths between the actuator and sensors. The healthy state data and information on the paths between the actuator and sensors was processed via SAE for damage localization. The proposed approach can be employed for the autonomous assessment of composite structures for the presence of damage and variations of operating temperatures while using both supervised and unsupervised machine learning algorithms.
{"title":"Damage assessment of laminated composites using unsupervised autonomous features","authors":"Asif Khan, Heung Soo Kim","doi":"10.1177/08927057231208970","DOIUrl":"https://doi.org/10.1177/08927057231208970","url":null,"abstract":"This article proposes a framework for the damage assessment of and effect of temperature variations in laminated composites using Lamb waves and unsupervised autonomous features. A network of piezoelectric transducers is employed to generate data for 18 health states of a laminated composite plate. The data is processed with sparse autoencoder (SAE) for unsupervised autonomous features. The discriminative capabilities of the extracted features are confirmed by processing the feature space in the supervised and unsupervised frameworks of machine learning. The confusion matrices of supervised learning provided physical insights into the problem. The feature space was also visualized in two dimensions in an unsupervised manner through principal component analysis (PCA), which revealed physically consistent results for the effect of temperature variations, damage of different severity levels, and the undamaged paths between the actuator and sensors. The healthy state data and information on the paths between the actuator and sensors was processed via SAE for damage localization. The proposed approach can be employed for the autonomous assessment of composite structures for the presence of damage and variations of operating temperatures while using both supervised and unsupervised machine learning algorithms.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"204 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135933286","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-02DOI: 10.1177/08927057231211224
M. Salah, Ehab Ahmed Salem, Ashraf Maher Abdel-Ghaffar, Ismail M. Helal
The synthesis of Poly(PVA/St/Ag NPs) nanocomposite by using of gamma radiation was carried out. The progress of the reaction was examined by using different techniques such as Fourier transform infrared (FTIR), transmission electron microscopy (TEM), UV, XRD, and scanning electron microscopy (SEM). The FTIR show the successful preparation of the Poly(PVA/St/Ag NPs) nanocomposite by gamma radiation at a dose of 5 kGy. The TEM analysis displays the particle size distribution of Ag NPs and it is observed that the Ag NPs size was in the range of 21-30 nm. The SEM images show a good distribution of silver nanoparticles in the Poly(PVA/St/Ag NPs) nanocomposite. matrix, but with little agglomerations or aggregates observed on the surface of the Poly(PVA/St/Ag NPs) nanocomposite. The XRD analysis indicates that amorphous regions are enhanced in the Poly(PVA/St/Ag NPs) nanocomposite. The coating of Citrus fruits by of Poly(PVA/St/Ag NPs) nanocomposite showed better performance in inhibition of the growth of P. digitatum on citrus fruits than free Ag NPs at concentration of 30 ppm. The incorporation of Ag NPs in Poly(PVA/St/Ag NPs) nanocomposite has extremely obvious antifungal activities against P. digitatum due to the nanometer range of Ag NPs that can interact with P. digitatum surface and/or its core where it enters inside the cell, as a result, cellular metabolism is inhibited causing death of P. digitatum and subsequently exhibits antifungal activities.
{"title":"Radiation preparation and antimicrobial activity of Poly(PVA/starch/Ag NPs) nanocomposite towards <i>Penicillium digitatum</i> on citrus fruits","authors":"M. Salah, Ehab Ahmed Salem, Ashraf Maher Abdel-Ghaffar, Ismail M. Helal","doi":"10.1177/08927057231211224","DOIUrl":"https://doi.org/10.1177/08927057231211224","url":null,"abstract":"The synthesis of Poly(PVA/St/Ag NPs) nanocomposite by using of gamma radiation was carried out. The progress of the reaction was examined by using different techniques such as Fourier transform infrared (FTIR), transmission electron microscopy (TEM), UV, XRD, and scanning electron microscopy (SEM). The FTIR show the successful preparation of the Poly(PVA/St/Ag NPs) nanocomposite by gamma radiation at a dose of 5 kGy. The TEM analysis displays the particle size distribution of Ag NPs and it is observed that the Ag NPs size was in the range of 21-30 nm. The SEM images show a good distribution of silver nanoparticles in the Poly(PVA/St/Ag NPs) nanocomposite. matrix, but with little agglomerations or aggregates observed on the surface of the Poly(PVA/St/Ag NPs) nanocomposite. The XRD analysis indicates that amorphous regions are enhanced in the Poly(PVA/St/Ag NPs) nanocomposite. The coating of Citrus fruits by of Poly(PVA/St/Ag NPs) nanocomposite showed better performance in inhibition of the growth of P. digitatum on citrus fruits than free Ag NPs at concentration of 30 ppm. The incorporation of Ag NPs in Poly(PVA/St/Ag NPs) nanocomposite has extremely obvious antifungal activities against P. digitatum due to the nanometer range of Ag NPs that can interact with P. digitatum surface and/or its core where it enters inside the cell, as a result, cellular metabolism is inhibited causing death of P. digitatum and subsequently exhibits antifungal activities.","PeriodicalId":17446,"journal":{"name":"Journal of Thermoplastic Composite Materials","volume":"95 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135933184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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