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Ultrasound sensing with optical microcavities 利用光学微腔进行超声波传感
Q1 OPTICS Pub Date : 2024-07-09 DOI: 10.1038/s41377-024-01480-8
Xuening Cao, Hao Yang, Zu-Lei Wu, Bei-Bei Li

Ultrasound sensors play an important role in biomedical imaging, industrial nondestructive inspection, etc. Traditional ultrasound sensors that use piezoelectric transducers face limitations in sensitivity and spatial resolution when miniaturized, with typical sizes at the millimeter to centimeter scale. To overcome these challenges, optical ultrasound sensors have emerged as a promising alternative, offering both high sensitivity and spatial resolution. In particular, ultrasound sensors utilizing high-quality factor (Q) optical microcavities have achieved unprecedented performance in terms of sensitivity and bandwidth, while also enabling mass production on silicon chips. In this review, we focus on recent advances in ultrasound sensing applications using three types of optical microcavities: Fabry-Perot cavities, π-phase-shifted Bragg gratings, and whispering gallery mode microcavities. We provide an overview of the ultrasound sensing mechanisms employed by these microcavities and discuss the key parameters for optimizing ultrasound sensors. Furthermore, we survey recent advances in ultrasound sensing using these microcavity-based approaches, highlighting their applications in diverse detection scenarios, such as photoacoustic imaging, ranging, and particle detection. The goal of this review is to provide a comprehensive understanding of the latest advances in ultrasound sensing with optical microcavities and their potential for future development in high-performance ultrasound imaging and sensing technologies.

超声波传感器在生物医学成像、工业无损检测等领域发挥着重要作用。使用压电传感器的传统超声波传感器在微型化时面临灵敏度和空间分辨率的限制,其尺寸通常在毫米到厘米之间。为了克服这些挑战,光学超声传感器应运而生,它具有高灵敏度和高空间分辨率,是一种很有前途的替代方案。特别是,利用高质量系数(Q)光学微腔的超声波传感器在灵敏度和带宽方面实现了前所未有的性能,同时还能在硅芯片上进行大规模生产。在这篇综述中,我们将重点介绍使用三种光学微腔的超声波传感应用的最新进展:法布里-珀罗腔、π 相移布拉格光栅和耳语廊模式微腔。我们概述了这些微腔采用的超声波传感机制,并讨论了优化超声波传感器的关键参数。此外,我们还考察了利用这些基于微腔的方法进行超声波传感的最新进展,重点介绍了它们在光声成像、测距和粒子探测等不同探测场景中的应用。本综述的目的是全面介绍利用光学微腔进行超声波传感的最新进展及其在高性能超声波成像和传感技术方面的未来发展潜力。
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引用次数: 0
Electroluminescence from pure resonant states in hBN-based vertical tunneling junctions 基于氢溴萘的垂直隧道结中纯谐振态的电致发光
Q1 OPTICS Pub Date : 2024-07-08 DOI: 10.1038/s41377-024-01491-5
Magdalena Grzeszczyk, Kristina Vaklinova, Kenji Watanabe, Takashi Taniguchi, Konstantin S. Novoselov, Maciej Koperski

Defect centers in wide-band-gap crystals have garnered interest for their potential in applications among optoelectronic and sensor technologies. However, defects embedded in highly insulating crystals, like diamond, silicon carbide, or aluminum oxide, have been notoriously difficult to excite electrically due to their large internal resistance. To address this challenge, we realized a new paradigm of exciting defects in vertical tunneling junctions based on carbon centers in hexagonal boron nitride (hBN). The rational design of the devices via van der Waals technology enabled us to raise and control optical processes related to defect-to-band and intradefect electroluminescence. The fundamental understanding of the tunneling events was based on the transfer of the electronic wave function amplitude between resonant defect states in hBN to the metallic state in graphene, which leads to dramatic changes in the characteristics of electrons due to different band structures of constituent materials. In our devices, the decay of electrons via tunneling pathways competed with radiative recombination, resulting in an unprecedented degree of tuneability of carrier dynamics due to the significant sensitivity of the characteristic tunneling times on the thickness and structure of the barrier. This enabled us to achieve a high-efficiency electrical excitation of intradefect transitions, exceeding by several orders of magnitude the efficiency of optical excitation in the sub-band-gap regime. This work represents a significant advancement towards a universal and scalable platform for electrically driven devices utilizing defect centers in wide-band-gap crystals with properties modulated via activation of different tunneling mechanisms at a level of device engineering.

宽带隙晶体中的缺陷中心因其在光电和传感器技术中的应用潜力而备受关注。然而,嵌入高绝缘晶体(如金刚石、碳化硅或氧化铝)中的缺陷因其内阻大而难以电激发。为了应对这一挑战,我们在六方氮化硼(hBN)中以碳中心为基础,在垂直隧道结中实现了激发缺陷的新模式。通过范德华技术对器件进行合理设计,使我们能够提高和控制与缺陷带和缺陷内电致发光相关的光学过程。对隧道事件的基本理解是基于石墨烯中共振缺陷态与金属态之间电子波函数振幅的转移,由于组成材料的带状结构不同,这导致了电子特性的巨大变化。在我们的设备中,电子通过隧穿途径衰减与辐射重组竞争,由于隧穿时间特性对势垒的厚度和结构非常敏感,因此载流子动力学的可调节性达到了前所未有的程度。这使我们能够实现对缺陷内跃迁的高效电激发,其效率比亚带隙制度下的光激发效率高出几个数量级。这项工作标志着我们在利用宽带隙晶体中的缺陷中心实现电驱动器件的通用和可扩展平台方面取得了重大进展。
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引用次数: 0
Anneal-free ultra-low loss silicon nitride integrated photonics 无退火超低损耗氮化硅集成光子技术
Q1 OPTICS Pub Date : 2024-07-08 DOI: 10.1038/s41377-024-01503-4
Debapam Bose, Mark W. Harrington, Andrei Isichenko, Kaikai Liu, Jiawei Wang, Nitesh Chauhan, Zachary L. Newman, Daniel J. Blumenthal

Heterogeneous and monolithic integration of the versatile low-loss silicon nitride platform with low-temperature materials such as silicon electronics and photonics, III–V compound semiconductors, lithium niobate, organics, and glasses has been inhibited by the need for high-temperature annealing as well as the need for different process flows for thin and thick waveguides. New techniques are needed to maintain the state-of-the-art losses, nonlinear properties, and CMOS-compatible processes while enabling this next generation of 3D silicon nitride integration. We report a significant advance in silicon nitride integrated photonics, demonstrating the lowest losses to date for an anneal-free process at a maximum temperature 250 °C, with the same deuterated silane based fabrication flow, for nitride and oxide, for an order of magnitude range in nitride thickness without requiring stress mitigation or polishing. We report record low anneal-free losses for both nitride core and oxide cladding, enabling 1.77 dB m-1 loss and 14.9 million Q for 80 nm nitride core waveguides, more than half an order magnitude lower loss than previously reported sub 300 °C process. For 800 nm-thick nitride, we achieve as good as 8.66 dB m−1 loss and 4.03 million Q, the highest reported Q for a low temperature processed resonator with equivalent device area, with a median of loss and Q of 13.9 dB m−1 and 2.59 million each respectively. We demonstrate laser stabilization with over 4 orders of magnitude frequency noise reduction using a thin nitride reference cavity, and using a thick nitride micro-resonator we demonstrate OPO, over two octave supercontinuum generation, and four-wave mixing and parametric gain with the lowest reported optical parametric oscillation threshold per unit resonator length. These results represent a significant step towards a uniform ultra-low loss silicon nitride homogeneous and heterogeneous platform for both thin and thick waveguides capable of linear and nonlinear photonic circuits and integration with low-temperature materials and processes.

由于需要高温退火以及薄波导和厚波导需要不同的工艺流程,一直以来都阻碍着多功能低损耗氮化硅平台与硅电子和光子、III-V 族化合物半导体、铌酸锂、有机物和玻璃等低温材料的异质和单片集成。我们需要新技术来保持最先进的损耗、非线性特性和 CMOS 兼容工艺,同时实现下一代三维氮化硅集成。我们报告了氮化硅集成光子学的重大进展,证明了迄今为止在最高温度为 250 °C 的无退火工艺中,采用相同的基于氘化硅烷的制造流程,氮化物和氧化物的损耗最低,氮化物厚度在数量级范围内无需应力减缓或抛光。我们的报告显示,氮化物内核和氧化物包层的无退火损耗都创下了新低,80 纳米氮化物内核波导的损耗为 1.77 dB m-1,Q 值为 1,490 万,比之前报告的 300 ℃ 以下工艺的损耗低了半个数量级以上。对于 800 nm 厚的氮化物,我们实现了高达 8.66 dB m-1 的损耗和 403 万 Q 值,这是目前报道的具有同等器件面积的低温加工谐振器的最高 Q 值,损耗和 Q 值的中值分别为 13.9 dB m-1 和 259 万。我们利用一个薄氮化物基准腔演示了激光稳定,频率噪声降低了 4 个数量级以上;利用一个厚氮化物微谐振器演示了 OPO、两个倍频程以上的超连续产生、四波混频和参数增益,单位谐振器长度的光参量振荡阈值最低。这些成果标志着我们向统一的超低损耗氮化硅同质和异质平台迈出了重要的一步,该平台适用于薄波导和厚波导,能够制作线性和非线性光子电路,并与低温材料和工艺集成。
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引用次数: 0
Extending the detection limit: innovations in infrared quantum dot photodetectors reaching up to 18 μm 扩展探测极限:红外量子点光电探测器的创新,最高可达 18 μm
Q1 OPTICS Pub Date : 2024-07-08 DOI: 10.1038/s41377-024-01504-3
Chong Wu Wang, Qi Jie Wang

A regrowth method was used to synthesize large-sized colloidal quantum dots (CQDs). With the assistance of doping engineering, the synthesized CQD detectors demonstrate exceptional long-wavelength infrared detection performance, reaching up to 18 μm, significantly extending the spectral response limit for CQD-based infrared detectors. These detectors also achieve a reasonably high detectivity of 6.6 × 108 Jones.

利用再生长方法合成了大尺寸胶体量子点(CQDs)。在掺杂工程的帮助下,合成的 CQD 探测器显示出卓越的长波长红外探测性能,最高可达 18 μm,大大扩展了基于 CQD 的红外探测器的光谱响应极限。这些探测器还实现了 6.6 × 108 琼斯的相当高的探测率。
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引用次数: 0
Enhanced photothermoelectric conversion in self-rolled tellurium photodetector with geometry-induced energy localization 自轧碲光电探测器中增强的光热电转换与几何诱导的能量局域化
Q1 OPTICS Pub Date : 2024-07-04 DOI: 10.1038/s41377-024-01496-0
Jiayuan Huang, Chunyu You, Binmin Wu, Yunqi Wang, Ziyu Zhang, Xinyu Zhang, Chang Liu, Ningge Huang, Zhi Zheng, Tingqi Wu, Suwit Kiravittaya, Yongfeng Mei, Gaoshan Huang

Photodetection has attracted significant attention for information transmission. While the implementation relies primarily on the photonic detectors, they are predominantly constrained by the intrinsic bandgap of active materials. On the other hand, photothermoelectric (PTE) detectors have garnered substantial research interest for their promising capabilities in broadband detection, owing to the self-driven photovoltages induced by the temperature differences. To get higher performances, it is crucial to localize light and heat energies for efficient conversion. However, there is limited research on the energy conversion in PTE detectors at micro/nano scale. In this study, we have achieved a two-order-of-magnitude enhancement in photovoltage responsivity in the self-rolled tubular tellurium (Te) photodetector with PTE effect. Under illumination, the tubular device demonstrates a maximum photovoltage responsivity of 252.13 V W−1 and a large detectivity of 1.48 × 1011 Jones. We disclose the mechanism of the PTE conversion in the tubular structure with the assistance of theoretical simulation. In addition, the device exhibits excellent performances in wide-angle and polarization-dependent detection. This work presents an approach to remarkably improve the performance of photodetector by concentrating light and corresponding heat generated, and the proposed self-rolled devices thus hold remarkable promises for next-generation on-chip photodetection.

光子探测在信息传输方面备受关注。虽然实现光子检测主要依赖于光子探测器,但它们主要受到有源材料固有带隙的限制。另一方面,光热电(PTE)探测器由于温度差引起的自驱动光电压,在宽带检测方面具有广阔的前景,因此引起了大量研究兴趣。要获得更高的性能,关键是要将光能和热能本地化,以实现高效转换。然而,有关微米/纳米尺度 PTE 探测器能量转换的研究还很有限。在这项研究中,我们在具有 PTE 效应的自卷曲管状碲(Te)光电探测器中实现了两个数量级的光电压响应性增强。在照明条件下,该管状器件的最大光电压响应率为 252.13 V W-1,探测率高达 1.48 × 1011 Jones。我们通过理论模拟揭示了管状结构中 PTE 转换的机理。此外,该器件在广角和偏振相关探测方面表现出色。这项工作提出了一种通过集中光和相应产生的热量来显著提高光电探测器性能的方法,因此所提出的自卷绕器件为下一代片上光电探测带来了广阔的前景。
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引用次数: 0
Brillouin expanded time-domain analysis based on dual optical frequency combs 基于双光学频率梳的布里渊扩展时域分析
Q1 OPTICS Pub Date : 2024-07-02 DOI: 10.1038/s41377-024-01499-x
Jae Hyeong Youn, Kwang Yong Song, Sonia Martin-Lopez, Miguel Gonzalez-Herraez, María R. Fernández-Ruiz

Brillouin Optical Time-Domain Analysis (BOTDA) is a widely-used distributed optical fiber sensing technology employing pulse-modulated pump waves for local information retrieval of the Brillouin gain or loss spectra. The spatial resolution of BOTDA systems is intrinsically linked to pulse duration, so high-resolution measurements demand high electronic bandwidths inversely proportional to the resolution. This paper introduces Brillouin Expanded Time-Domain Analysis (BETDA) as a modified BOTDA system, simultaneously achieving high spatial resolution and low detection bandwidth. Utilizing two optical frequency combs (OFCs) with different frequency intervals as pump and probe, local Brillouin gain spectra are recorded by their spectral beating traces in an expanded time domain. A 2-cm-long hotspot located in a 230 m single-mode fiber is successfully measured in the time domain with a detection bandwidth of less than 100 kHz using dual OFCs with tailored spectral phase, line spacing, and bandwidth.

布里渊光学时域分析(BOTDA)是一种广泛使用的分布式光纤传感技术,它采用脉冲调制泵浦波,对布里渊增益或损耗光谱进行局部信息检索。BOTDA 系统的空间分辨率与脉冲持续时间有内在联系,因此高分辨率测量需要与分辨率成反比的高电子带宽。本文介绍的布里渊扩展时域分析(BETDA)是一种改进的 BOTDA 系统,可同时实现高空间分辨率和低探测带宽。利用两个不同频率间隔的光学频率梳(OFC)作为泵浦和探头,通过它们在扩展时域中的光谱跳动轨迹记录局部布里渊增益光谱。利用具有定制光谱相位、线间距和带宽的双 OFC,成功地在时域中测量了位于 230 米长单模光纤中的一个 2 厘米长的热点,其探测带宽小于 100 kHz。
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引用次数: 0
Replica symmetry breaking in 1D Rayleigh scattering system: theory and validations 一维瑞利散射系统中的复制对称破缺:理论与验证
Q1 OPTICS Pub Date : 2024-07-02 DOI: 10.1038/s41377-024-01475-5
Yifei Qi, Longqun Ni, Zhenyu Ye, Jiaojiao Zhang, Xingyu Bao, Pan Wang, Yunjiang Rao, Ernesto P. Raposo, Anderson S. L. Gomes, Zinan Wang

Spin glass theory, as a paradigm for describing disordered magnetic systems, constitutes a prominent subject of study within statistical physics. Replica symmetry breaking (RSB), as one of the pivotal concepts for the understanding of spin glass theory, means that under identical conditions, disordered systems can yield distinct states with nontrivial correlations. Random fiber laser (RFL) based on Rayleigh scattering (RS) is a complex disordered system, owing to the disorder and stochasticity of RS. In this work, for the first time, a precise theoretical model is elaborated for studying the photonic phase transition via the platform of RS-based RFL, in which we clearly reveal that, apart from the pump power, the photon phase variation in RFL is also an analogy to the temperature term in spin-glass phase transition, leading to a novel insight into the intrinsic mechanisms of photonic phase transition. In addition, based on this model and real-time high-fidelity detection spectral evolution, we theoretically predict and experimentally observe the mode-asymmetric characteristics of photonic phase transition in RS-based RFL. This finding contributes to a deeper understanding of the photonic RSB regime and the dynamics of RS-based RFL.

自旋玻璃理论作为描述无序磁性系统的范例,是统计物理学中的一个重要研究课题。复制对称性破缺(RSB)是理解自旋玻璃理论的关键概念之一,它意味着在相同条件下,无序系统可以产生具有非对称相关性的不同状态。由于瑞利散射(RS)的无序性和随机性,基于瑞利散射的随机光纤激光器(RFL)是一个复杂的无序系统。在这项工作中,我们首次通过基于 RS 的 RFL 平台,建立了研究光子相变的精确理论模型,清楚地揭示了除了泵浦功率之外,RFL 中的光子相变还类似于自旋玻璃相变中的温度项,从而对光子相变的内在机制提出了新的见解。此外,基于该模型和实时高保真探测光谱演化,我们从理论上预测并从实验上观测到了基于 RS 的 RFL 中光子相变的模非对称特性。这一发现有助于加深对光子 RSB 机制和基于 RS 的 RFL 动态的理解。
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引用次数: 0
High-rate intercity quantum key distribution with a semiconductor single-photon source 利用半导体单光子源实现高速率城际量子密钥分发
Q1 OPTICS Pub Date : 2024-07-02 DOI: 10.1038/s41377-024-01488-0
Jingzhong Yang, Zenghui Jiang, Frederik Benthin, Joscha Hanel, Tom Fandrich, Raphael Joos, Stephanie Bauer, Sascha Kolatschek, Ali Hreibi, Eddy Patrick Rugeramigabo, Michael Jetter, Simone Luca Portalupi, Michael Zopf, Peter Michler, Stefan Kück, Fei Ding

Quantum key distribution (QKD) enables the transmission of information that is secure against general attacks by eavesdroppers. The use of on-demand quantum light sources in QKD protocols is expected to help improve security and maximum tolerable loss. Semiconductor quantum dots (QDs) are a promising building block for quantum communication applications because of the deterministic emission of single photons with high brightness and low multiphoton contribution. Here we report on the first intercity QKD experiment using a bright deterministic single photon source. A BB84 protocol based on polarisation encoding is realised using the high-rate single photons in the telecommunication C-band emitted from a semiconductor QD embedded in a circular Bragg grating structure. Utilising the 79 km long link with 25.49 dB loss (equivalent to 130 km for the direct-connected optical fibre) between the German cities of Hannover and Braunschweig, a record-high secret key bits per pulse of 4.8 × 10−5 with an average quantum bit error ratio of ~ 0.65% are demonstrated. An asymptotic maximum tolerable loss of 28.11 dB is found, corresponding to a length of 144 km of standard telecommunication fibre. Deterministic semiconductor sources therefore challenge state-of-the-art QKD protocols and have the potential to excel in measurement device independent protocols and quantum repeater applications.

量子密钥分发(QKD)使信息传输能够安全地抵御窃听者的一般攻击。在 QKD 协议中使用按需量子光源有望帮助提高安全性和最大可容忍损耗。半导体量子点(QD)可确定性地发射高亮度、低多光子贡献的单光子,因此是量子通信应用的一个前景广阔的构件。在此,我们报告了首次使用明亮的确定性单光子源进行的城际 QKD 实验。利用嵌入环形布拉格光栅结构中的半导体 QD 发射的电信 C 波段高速率单光子,实现了基于极化编码的 BB84 协议。利用德国城市汉诺威和布伦瑞克之间长达 79 千米、损耗为 25.49 dB 的链路(相当于 130 千米的直连光纤),每个脉冲的密钥比特达到了创纪录的 4.8 × 10-5,平均量子比特误差率约为 0.65%。研究发现,渐近最大可容忍损耗为 28.11 dB,相当于 144 千米长的标准电信光纤。因此,确定性半导体源对最先进的 QKD 协议提出了挑战,并有可能在独立于测量设备的协议和量子中继器应用中大显身手。
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引用次数: 0
Quantitative phase imaging based on holography: trends and new perspectives 基于全息技术的定量相位成像:趋势与新视角
Q1 OPTICS Pub Date : 2024-06-27 DOI: 10.1038/s41377-024-01453-x
Zhengzhong Huang, Liangcai Cao

In 1948, Dennis Gabor proposed the concept of holography, providing a pioneering solution to a quantitative description of the optical wavefront. After 75 years of development, holographic imaging has become a powerful tool for optical wavefront measurement and quantitative phase imaging. The emergence of this technology has given fresh energy to physics, biology, and materials science. Digital holography (DH) possesses the quantitative advantages of wide-field, non-contact, precise, and dynamic measurement capability for complex-waves. DH has unique capabilities for the propagation of optical fields by measuring light scattering with phase information. It offers quantitative visualization of the refractive index and thickness distribution of weak absorption samples, which plays a vital role in the pathophysiology of various diseases and the characterization of various materials. It provides a possibility to bridge the gap between the imaging and scattering disciplines. The propagation of wavefront is described by the complex amplitude. The complex-value in the complex-domain is reconstructed from the intensity-value measurement by camera in the real-domain. Here, we regard the process of holographic recording and reconstruction as a transformation between complex-domain and real-domain, and discuss the mathematics and physical principles of reconstruction. We review the DH in underlying principles, technical approaches, and the breadth of applications. We conclude with emerging challenges and opportunities based on combining holographic imaging with other methodologies that expand the scope and utility of holographic imaging even further. The multidisciplinary nature brings technology and application experts together in label-free cell biology, analytical chemistry, clinical sciences, wavefront sensing, and semiconductor production.

1948 年,丹尼斯-加博尔(Dennis Gabor)提出了全息概念,为定量描述光学波面提供了开创性的解决方案。经过 75 年的发展,全息成像已成为光学波前测量和定量相位成像的强大工具。这项技术的出现为物理学、生物学和材料科学注入了新的活力。数字全息(DH)具有宽视场、非接触、精确和动态测量复杂波的量化优势。通过测量光散射的相位信息,数字全息技术具有独特的光场传播能力。它能定量显示弱吸收样品的折射率和厚度分布,这在各种疾病的病理生理学和各种材料的表征中起着至关重要的作用。它为缩小成像和散射学科之间的差距提供了可能。波阵面的传播由复数振幅描述。复域中的复值由相机在实域中测量的强度值重建。在此,我们将全息记录和重构过程视为复域和实域之间的转换,并讨论重构的数学和物理原理。我们回顾了 DH 的基本原理、技术方法和应用范围。最后,我们介绍了在将全息成像与其他方法相结合的基础上出现的挑战和机遇,这些方法进一步扩大了全息成像的范围和实用性。多学科性质汇集了无标记细胞生物学、分析化学、临床科学、波前传感和半导体生产领域的技术和应用专家。
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引用次数: 0
When quantum dots meet blue phase liquid crystal elastomers: visualized full-color and mechanically-switchable circularly polarized luminescence 当量子点遇到蓝相液晶弹性体:可视化全彩机械切换圆偏振发光
Pub Date : 2024-06-14 DOI: 10.1038/s41377-024-01479-1
Shan Li, Yuqi Tang, Qingyan Fan, Ziyuan Li, Xinfang Zhang, Jingxia Wang, Jinbao Guo, Quan Li

Polymer-based circularly polarized luminescence (CPL) materials with the advantage of diversified structure, easy fabrication, high thermal stability, and tunable properties have garnered considerable attention. However, adequate and precise tuning over CPL in polymer-based materials remains challenging due to the difficulty in regulating chiral structures. Herein, visualized full-color CPL is achieved by doping red, green, and blue quantum dots (QDs) into reconfigurable blue phase liquid crystal elastomers (BPLCEs). In contrast to the CPL signal observed in cholesteric liquid crystal elastomers (CLCEs), the chiral 3D cubic superstructure of BPLCEs induces an opposite CPL signal. Notably, this effect is entirely independent of photonic bandgaps (PBGs) and results in a high glum value, even without matching between PBGs and the emission bands of QDs. Meanwhile, the lattice structure of the BPLCEs can be reversibly switched via mechanical stretching force, inducing on-off switching of the CPL signals, and these variations can be further fixed using dynamic disulfide bonds in the BPLCEs. Moreover, the smart polymer-based CPL systems using the BPLCEs for anti-counterfeiting and information encryption have been demonstrated, suggesting the great potential of the BPLCEs-based CPL active materials.

聚合物基圆极化发光(CPL)材料具有结构多样、易于制造、热稳定性高和性能可调等优点,因此受到了广泛关注。然而,由于手性结构难以调控,在聚合物基材料中充分、精确地调控 CPL 仍然具有挑战性。本文通过在可重构蓝相液晶弹性体(BPLCEs)中掺入红、绿、蓝量子点(QDs),实现了可视化全色 CPL。与在胆甾液晶弹性体(CLCEs)中观察到的 CPL 信号不同,BPLCEs 的手性三维立方上层结构会诱发相反的 CPL 信号。值得注意的是,这种效应完全不受光子带隙(PBGs)的影响,即使 PBGs 与 QDs 的发射带不匹配,也能产生很高的 Glum 值。同时,BPLCEs 的晶格结构可通过机械拉伸力进行可逆切换,从而诱导 CPL 信号的开关,这些变化可通过 BPLCEs 中的动态二硫键进一步固定。此外,基于 BPLCEs 的智能聚合物 CPL 系统已用于防伪和信息加密,这表明基于 BPLCEs 的 CPL 活性材料具有巨大的潜力。
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引用次数: 0
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