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Water trees-growth rate and model concept 水树——生长率和模型概念
R. Patsch
Results of numerical computations show that a growth model based on the water treeing model concept of dielectrophoresis leads to the size distributions of water trees found in high-voltage cables removed from service. After some time a peaked distribution of water tree sizes occurs, whereby the shift of the maximum in time decreases with increasing length of the water trees. The model predicts in increase of the growth rate with increasing water concentration in the trees. The influence of the characteristic parameters of the defect that initiated the water tree diminishes with increasing length of the water tree.<>
数值计算结果表明,基于介电电泳水树模型概念的生长模型可以得到退役高压电缆中水树的尺寸分布。一段时间后,水树大小出现峰值分布,随着水树长度的增加,最大值在时间上的偏移减小。该模型预测,随着水分浓度的增加,树木的生长速度也会增加。随着水树长度的增加,引发水树的缺陷特征参数的影响逐渐减小
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引用次数: 2
Electrical ageing of polyethylene during constant AC stress 恒定交流应力下聚乙烯的电老化
P. Rohl, K. Nissen, W. Rose
The authors investigated the ageing of polyethylene under inhomogeneous electric fields well below the intrinsic breakdown field strength (>570 kV/mm RMS) but above a local critical field strength at which charge injection takes place. They observed partial discharge and the treeing behavior under different conditions of AC and DC stressing. Additional experiments with samples impregnated with an electronegative gas (SF/sub 6/) yielded further information on the process of polymer degradation. The results show that there is no deterioration during DC ageing; the polarity reversal that occurs under AC stressing is necessary for the ageing process. The observation of brittle walls of the tree structure indicates that the rate of impingement of hot electrons on the polymer is relatively low. Therefore the heat produced may be easily dissipated without appreciable rise of the temperature within the treed region. The experiments with the impregnated samples are in agreement with the assumption of a hot electron process. The SF/sub 6/ captures hot electrons and therefore reduces the probability of damage; in the present case no deterioration is observable up to 600 h.<>
作者研究了聚乙烯在非均匀电场下的老化,远低于固有击穿场强(>570 kV/mm RMS),但高于发生电荷注入的局部临界场强。他们观察了不同交直流应力条件下的局部放电和树形行为。对浸渍了电负性气体(SF/sub 6/)的样品进行了进一步的实验,得到了聚合物降解过程的进一步信息。结果表明:直流老化过程中无劣化现象;在交流应力下发生的极性反转是老化过程所必需的。对树状结构脆性壁的观察表明,热电子对聚合物的撞击率相对较低。因此,产生的热量可以很容易地消散,而不会在树木区域内出现明显的温度上升。用浸渍试样进行的实验符合热电子过程的假设。SF/sub 6/捕获热电子,因此降低了损坏的可能性;在这种情况下,在600小时内没有观察到劣化。
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引用次数: 2
Degradation and electrical behavior of aged XLPE cable models 老化交联聚乙烯电缆模型的退化和电气性能
A. Motori, F. Sandrolini, G. Montanari
Results of DC electrical conductivity measurements performed at different aging times on cross-linked polyethylene (XLPE) cable models subjected to thermal and combined thermal-electrical stresses are discussed. It is shown that the variations of electrical conductivity with aging time are related to those of other properties (density, crystallinity, electric strength, and microstructure) and hence to the aging processes. Electrical conductivity is shown to be a bulk property well able to indicate the degradation of an insulating material due to electrical and thermal stresses, even if the failure due to electrical stress is primarily a localized phenomenon.<>
讨论了不同老化时间下交联聚乙烯(XLPE)电缆模型在热应力和热电复合应力作用下的直流电导率测量结果。结果表明,电导率随时效时间的变化与其他性能(密度、结晶度、电强度和微观结构)的变化有关,因此与时效过程有关。电导率是一种整体特性,能够很好地表明绝缘材料由于电应力和热应力而退化,即使电应力引起的失效主要是局部现象。
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引用次数: 15
Connection of aluminum and boron nitride ceramic building with conduction 铝与氮化硼陶瓷建筑的连接与传导
V. V. Lopatin, A. Kabyshev
The relationship between macrodefects and conduction in BN and AlN ceramics was investigated using optical and electron microscopy and X-ray analysis. Ceramic-sintering-assisted additives in the form of new impurity phases are found to exist at the aggregate interfaces only as crystalline and amorphous inclusions. Expressions that qualitatively describe the measurement results on boron nitride of different structures in the temperature range from 300 to 1800 K are obtained.<>
利用光学和电子显微镜以及 X 射线分析研究了 BN 和 AlN 陶瓷中的宏观缺陷与传导之间的关系。研究发现,陶瓷烧结辅助添加剂以新杂质相的形式存在于集合界面上,仅作为结晶和无定形夹杂物存在。在 300 至 1800 K 的温度范围内,获得了定性描述不同结构氮化硼测量结果的表达式。
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引用次数: 0
Determination of charge carrier mobility in doped low density polyethylene using DC transients 利用直流瞬态测定掺杂低密度聚乙烯的载流子迁移率
M. Khalil, P. Henk, M. Henriksen
Charge carrier mobility was determined for plain and doped low-density polyethylene (LDPE) using DC transient currents. Barium titanate was used as a strongly polar dopant and titanium dioxide as a semiconductor dopant. The values of the mobility obtained were on the order of 10/sup -10/ cm/sup 2/ v/sup -1/ s/sup -1/. Results indicate that the inclusion of 1% by weight of BaTiO/sub 3/ and TiO/sub 2/ has a considerable effect on the conduction properties of the polymer. BaTiO/sub 3/ increased the charge carrier mobility by a factor of three and also increased the conductivity of the polymer. TiO/sub 2/ increased the charge carrier mobility by a factor of five. Charge trapping and space charge formation were modified by the introduction of titanium dioxide.<>
利用直流瞬态电流测定了普通和掺杂低密度聚乙烯(LDPE)的载流子迁移率。钛酸钡作为强极性掺杂剂,二氧化钛作为半导体掺杂剂。得到的迁移率值为10/sup -10/ cm/sup 2/ v/sup -1/ s/sup -1/。结果表明,BaTiO/sub - 3/和TiO/sub - 2/的掺入量为1%,对聚合物的导电性能有较大影响。BaTiO/ sub3 /将载流子迁移率提高了三倍,同时也提高了聚合物的导电性。TiO/sub /将载流子迁移率提高了五倍。引入二氧化钛对电荷捕获和空间电荷形成进行了改进。
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引用次数: 8
Migration of impurities from cable shields and tree initiation in XLPE XLPE中电缆屏蔽层中杂质的迁移和树形起始
A. Belhadfa, A. Houdayer, P. Hinrichsen, G. Kajrys, J. Crine, R. Gilbert
The authors present laboratory results obtained with plaques of cable-grade XLPE (cross-linked polyethylene) pressed on plaques made of commercial shield compound. The samples were kept at various temperatures in air and in water for several weeks. The local impurity contents were measured at various distances from the shield-insulation interface by micro-PIXE (proton induced X-ray emission). The correlation between the impurity kinetics thus measured and impurities detected in water trees grown in XLPE cables is discussed. In addition to the elemental analysis, ionic content measurements were also performed on resins, and the ions detected correspond to the major elemental contaminants. Although it is not yet clear whether impurities affect tree growth, the fact that water and electrical trees are heavily contaminated suggests the possible influence of contamination. The nature of the most mobile impurities is also the same as those of the major contaminants in trees. The inorganic ions also correspond to these elements, which adds further evidence for their possibly detrimental role in XLPE cable aging.<>
作者介绍了将电缆级XLPE(交联聚乙烯)斑块压在商用屏蔽化合物制成的斑块上的实验室结果。这些样品在空气和水中以不同的温度保存了几个星期。在距离屏蔽-绝缘界面不同距离处,用质子诱导x射线微发射仪测量了局部杂质含量。讨论了所测杂质动力学与在交联聚乙烯电缆中生长的水树中检测到的杂质之间的关系。除了元素分析外,还对树脂进行了离子含量测量,检测到的离子与主要元素污染物相对应。虽然目前尚不清楚杂质是否会影响树木的生长,但水树和电树受到严重污染的事实表明,污染可能会产生影响。最易移动的杂质的性质也与树木中的主要污染物的性质相同。无机离子也与这些元素相对应,这进一步证明了它们在XLPE电缆老化中可能起的有害作用。
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引用次数: 4
Drilling effects of corona streamers on insulating films 电晕流光在绝缘薄膜上的钻孔效应
L. Zibin, M. Goldman, A. Goldman, J. Gatellet
The interactions of streamers with polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET) films were studied experimentally. Streamers impinging on polymers subjected to corona discharges were found to add localized disruptive effects to the dispersed chemical effects produced by the corona-activated gas. The time elapsing before disruption of a polymer film has been used to analyze the phenomenon as function of the foil thickness and the discharge current. It is shown that there are at least two different possible mechanisms of disruption, ion sputtering which has been observed on PE films, and another mechanism, observed on PP and PET films, which produces blistering effects like tears.<>
实验研究了飘带与聚乙烯(PE)、聚丙烯(PP)和聚对苯二甲酸乙二醇酯(PET)薄膜的相互作用。研究发现,在受电晕放电影响的聚合物上撞击的拖缆,会在电晕活化气体产生的分散化学效应之外,增加局部破坏效应。利用聚合物薄膜破裂前的时间,分析了这种现象与薄膜厚度和放电电流的关系。结果表明,至少存在两种不同的破坏机制,即在PE薄膜上观察到的离子溅射,以及在PP和PET薄膜上观察到的另一种机制,即产生像撕裂一样的起泡效应。
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引用次数: 0
The influence of the polymer structure on the electrical properties 聚合物结构对电性能的影响
H. Hansel
The TSDC (thermally stimulated depolarization current) method was used to study the effect of polymer structure on electrical properties for poly(phenylquinooxaline). Seven relaxation regions were distinguished in the TSDC spectrum. The probability of observing the regions depends strongly on the degree of annealing of the samples. The TSDC in PETP is also found to be influenced by the physical structure. The TSDC spectrum of pure and saponificated poly(methylmethacrylate) was investigated. Three relaxation regions were observed: the beta - and alpha -relaxation and a space charge relaxation.<>
采用TSDC(热刺激去极化电流)方法研究了聚合物结构对聚苯基喹啉电学性能的影响。在TSDC谱中可分辨出7个弛豫区。观察到这些区域的概率很大程度上取决于样品的退火程度。PETP中的TSDC也受到物理结构的影响。研究了纯聚甲基丙烯酸甲酯和皂化聚甲基丙烯酸甲酯的TSDC光谱。观察到三个弛豫区:-弛豫区和-弛豫区以及空间电荷弛豫区。
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引用次数: 0
A model of aging of dielectric extruded cables 介质挤压电缆的老化模型
J. Crine, J. Parpal, G. Lessard
The authors present a model of electrical aging of extruded cables based on actual data and realistic experimental conditions. It is shown that a simple model partially based on the rate theory associated with the name of Eyring describes very well the aging of polyethylene (PE), crosslinked PE, and ethylene-propylene rubber cables under a wide variety of conditions. The significance of the physical and thermodynamic parameters used in the model is discussed in relation to the polymer morphology. It is speculated that severe and irreversible electric aging of dielectrics is preceded by the formation of microcavities in the 50-100-AA range.<>
根据实际数据和实际实验条件,建立了挤压电缆的电老化模型。结果表明,一个部分基于速率理论的简单模型很好地描述了聚乙烯(PE)、交联聚乙烯(PE)和乙烯丙烯橡胶电缆在各种条件下的老化。讨论了模型中使用的物理和热力学参数与聚合物形态的关系。据推测,在50-100-AA范围内,电介质发生严重且不可逆的电老化之前会形成微腔。
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引用次数: 51
Temperature influence on the anomalous breakdown phenomena in XLPE insulated cables 温度对交联聚乙烯绝缘电缆异常击穿现象的影响
T. Eish
The author reports results of investigations of the anomalous breakdown in XLPE (cross-linked polyethylene) insulated cables immersed in transformer oil under alternating (50 Hz) voltage when the temperature of the oil is increased. The study confirms that anomalous breakdown occurs in XLPE insulated power cables subjected to alternating voltages and that the breakdown voltage decreases as the insulation temperature increases. The distance of breakdown site from the high-voltage electrode decreases with increasing temperature up to 80 degrees C. Above that value, the entire breakdown is of direct type; no anomalous breakdown occurs.<>
作者报告了交联聚乙烯绝缘电缆在交变(50hz)电压下浸入变压器油中,当油温升高时,其异常击穿的研究结果。研究证实交联聚乙烯绝缘电力电缆在交变电压作用下发生异常击穿,击穿电压随绝缘温度的升高而降低。当温度达到80℃时,击穿部位与高压电极的距离随着温度的升高而减小,超过80℃时,整个击穿为直接击穿;无异常故障发生。>
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Proceedings of the 3rd International Conference on Conduction and Breakdown in Solid Dielectrics
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