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Investigation on carbide dispersion modified by magnesium and rare earth in high-carbon martensitic stainless steel 高碳马氏体不锈钢中镁和稀土改性碳化物分散体的研究
4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-01-01 DOI: 10.1051/metal/2023068
Yutang Li, Haoran Zhu, Dengping Ji, Bin Luo, Jianxun Fu
Fine and uniform carbides play a beneficial role in the high hardness and wear resistance of martensitic stainless steel. This paper investigates the effect of magnesium and rare earth(RE) on the dispersion of carbides in a high-carbon martensitic stainless steel. The results show that RE-Al-O and RE-Al-O-S inclusions were generated in RE-containing steel, while Mg-Al-O+(Ca, Mn)S and MgO+CaS inclusions were in Mg-containing steel. MC, M 7 C 3 , and M 23 C 6 types of carbides were detected in both RE-containing and Mg-containing steels, which is consistent with thermodynamic calculation. The RE-Al-O inclusion can act as heterogeneous nuclei for carbides, while Mg-containing inclusions do not promote carbide precipitation for sulfur enrichment. The three-dimensional etching test suggests that RE-containing steel has more serious network carbides and larger carbide sizes than Mg-containing steel. The carbon segregation ratio presents an “M” shape due to δ→γ phase transformation. Rare earth is easy to combine with S and weaken the inhibiting effect of carbon segregation. Thus, magnesium has a stronger inhibitory effect on carbon segregation than rare earth.
细小均匀的碳化物对马氏体不锈钢的高硬度和耐磨性起着有益的作用。研究了镁和稀土对高碳马氏体不锈钢中碳化物分散的影响。结果表明:含re钢中生成了RE-Al-O和RE-Al-O-S夹杂物,含mg钢中生成了Mg-Al-O+(Ca, Mn)S和MgO+CaS夹杂物。在含re钢和含mg钢中均检测到MC、m7c3和m23c6型碳化物,与热力学计算结果一致。RE-Al-O包裹体可以作为碳化物的非均相核,而含mg包裹体不促进碳化物析出以富集硫。三维刻蚀试验表明,含re钢的网状碳化物比含mg钢更严重,碳化物尺寸更大。由于δ→γ相变,碳偏析率呈“M”形。稀土容易与S结合,削弱了碳偏析的抑制作用。因此,镁对碳偏析的抑制作用强于稀土。
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引用次数: 0
Bend forming of aluminum alloy integral panel: a review 铝合金整体板的弯曲成形:综述
4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2023-01-01 DOI: 10.1051/metal/2023070
Xiao-Xiao Zhang, Yong-Hua Li
As the main structural component of aircraft skin, aluminum alloy integral panel is characterized by smooth aerodynamic configuration, light weight, high specific strength and stiffness, short fabrication cycle and so on. It is imperative to develop effective forming technology to manufacture integral panel with high configuration and dimension accuracy from flat or profiled sheet metal. Bend forming has advantages over other processes. Significant research work has been carried out in recent decades. This literature covers a review of the research and development of bend forming of aluminum alloy integral panels regarding principles, applications, forming processes and defects like buckling and fracture based on experiments and finite element simulations. Future research directions are also pointed out.
铝合金整体板作为飞机蒙皮的主要结构部件,具有气动外形光滑、重量轻、比强度和刚度高、制造周期短等特点。开发有效的成形技术,以制造具有高外形和尺寸精度的平板或异形板材是当务之急。弯曲成形比其他工艺有优点。近几十年来开展了重要的研究工作。本文以实验和有限元模拟为基础,综述了铝合金整体板弯曲成形的原理、应用、成形工艺和屈曲、断裂等缺陷的研究进展。并指出了今后的研究方向。
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引用次数: 0
Comparison study of rust layers formed on Q420 and weathering steel after 6 years of exposure in marine atmospheres Q420与耐候钢在海洋大气中曝露6年后锈层形成的对比研究
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2022-01-01 DOI: 10.1051/metal/2022008
Yunxiang Chen, X. Xia, Yao Huang, Y. Hong, Deyuan Lin, Yanjin Lu
In this study, the corrosion products formed on Q420 and weathering steel (WS) after 6 years of exposure in marine atmospheres in Pingtan, Fujian Province in China was examined. The evolution of the rust layers in terms of surface and cross-sectional morphologies were observed by SEM, while the consisted phases on the Q420 and WS were detected by XRD. The protective effect of the rust layers on the steels was studied by the electrochemical tests. The results of weight loss indicated that the Q420 had a relatively higher corrosion rate than that of the WS steel. The SEM observation showed that the WS steel could form a relative compact with fewer cracks after a long time of exposure concerning the Q420 steel. The electrochemical tests suggested the rust layer formed in the initial stage for the Q420 steel showed a better protective effect than that one formed at a later stage, whereas a better protective effect of the rust layer was formed at the later stage for the WS steels.
本文研究了Q420和耐候钢(WS)在福建平潭海洋大气中暴露6年后形成的腐蚀产物。利用扫描电镜(SEM)观察了锈层的表面形貌和横截面形貌的演变,并用XRD对Q420和WS的组成相进行了检测。通过电化学试验研究了锈层对钢的保护作用。失重结果表明,Q420的腐蚀速率相对高于WS钢。SEM观察表明,Q420钢经过长时间的暴露后,WS钢形成相对致密,裂纹较少。电化学试验结果表明,Q420钢在初始阶段形成的锈层比后期形成的锈层具有更好的保护作用,而WS钢在后期形成的锈层具有更好的保护作用。
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引用次数: 0
Effect of Si-based reductive modifying auxiliary on the recovery of iron and the cementitious reactivity of modified EAF slag 硅基还原性改性助剂对改性电炉渣铁回收率及胶凝反应性的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2022-01-01 DOI: 10.1051/metal/2021094
Xiao-ming Li, Yuqing Wu, Yuwei Ma, H. Xie, Xiangdong Xing
Si sludge was used as reductive modifying auxiliary during the iron component in the electric arc furnace (EAF) slag was reduced by carbon. The reduction behavior of the iron component in the EAF slag and the relationship between the mineral structure and the cementitious reactivity of the secondary slag were explored. The results show that the Si sludge can effectively reduce the iron-containing compounds in the slag. When the amount of Si sludge added is greater than 10 wt.%, the iron recovery rate exceeded 92% when reduced at 1773 K for 30 min. Si sludge has a modifying effect on EAF slag. When the amount of Si sludge is low (<10 wt.%), the content of cementitious components in the modified EAF slag is reduced, and low-activity merwinite crystals are precipitated in the slag, which reduces the cementitious reactivity. When Si sludge addition is greater than 10 wt.%, the amorphous phase content and reaction activity in the modified slag increased. The 28d compressive strength of the secondary slag with sludge addition of 14 wt.% reached 45.7 MPa.
以硅泥为还原剂,对电弧炉炉渣中的铁组分进行碳还原。探讨了电炉渣中铁组分的还原行为以及矿物结构与二次渣胶凝反应性的关系。结果表明,硅泥能有效地还原炉渣中的含铁化合物。当硅污泥添加量大于10wt时。在1773 K还原30 min时,铁的回收率超过92%。硅泥对电炉炉渣有改性作用。当硅泥量较低(<10 wt.%)时,改性电炉渣中胶凝组分含量降低,渣中析出低活性的墨温石晶体,降低了胶凝反应活性。当硅泥添加量大于10wt时。%,改性渣中非晶相含量和反应活性提高。污泥添加量为14wt的二次渣28d抗压强度。%达到45.7兆帕。
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引用次数: 0
Influence of hot forging on microstructure in double tempered H11 hot forging dies 热锻对双回火H11热锻模具组织的影响
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2022-01-01 DOI: 10.1051/metal/2022004
Sam Joshy, Jayadevan K.R., Merin Sarah George, Benrose Prasad
Hot forging dies are exposed to severe in-service thermomechanical stress, which induces microstructural changes leading to die failures. Thus, research in forging industries is focussed on study of in-service microstructural changes in hot forging dies. Hot forging tests were performed on double tempered AISI H11 steel dies for test duration of 100 and 500 forging strokes. Further, microstructural analyses were conducted on die surface. From microstructural analyses on die surface, it was revealed that chromium rich carbides grows in size with increase in number of forging cycles. Further, quantitative analysis of the carbide distribution was performed.
热锻模在使用过程中受到严重的热机械应力,导致微观组织变化导致模具失效。因此,锻造行业的研究重点是研究热锻模在使用过程中的微观组织变化。对双回火aisih11钢模具进行了100和500次锻造冲程的热锻试验。进一步对模具表面进行了显微组织分析。通过对模具表面的显微组织分析,发现随着锻造循环次数的增加,富铬碳化物的尺寸逐渐增大。进一步对碳化物的分布进行了定量分析。
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引用次数: 0
Recycling of chromium sludge to promote aggregation and growth of metal during self-reduction of nickel laterite ore 铬污泥循环利用促进红土镍矿自还原过程中金属的聚集和生长
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2022-01-01 DOI: 10.1051/metal/2022002
H. Yu, Sheng-qiang Song, R. Cromarty, G. Hang, Qian Hu, Wenke Zhang, Dongming Liu, Z. Xue
Addition of stainless steel pickling sludge, which contains hazardous hexavalent chromium, to low-grade nickel laterite ore has the potential to eliminate the hexavalent chromium and promote the aggregation and growth of iron-nickel particles during reduction with anthracite. The effect of chromium sludge on the aggregation and growth of metal particles during a self-reduction process of nickel laterite ore has been studied. The detoxification effect of hexavalent chromium in the sludge was evaluated using the standard TRGS 613 leaching test. Results showed that with increasing chromium sludge addition, the size of metal particles increased. With the addition of 13.94% by mass chromium sludge the average metal particle size in the reduce ore increased from 0.42 µm to 1.38 µm while the recovery of Fe, Ni and Cr increased from 53.73%, 19.39% and 33.36% to 78.33%, 69.22% and 58.26%, respectively. It is proposed that a low melting point eutectic phase of FeS formed in the reduced products, significantly promoted the migration and aggregation of metal particles. Leaching tests indicated that the original chromium sludge released > 600 mg/kg Cr(VI) while the slag from the combined laterite and chromium sludge released less than the EPA limit of 2 mg/kg Cr(VI).
在低品位镍红土矿中加入含有有害六价铬的不锈钢酸洗污泥,在无烟煤还原过程中有可能消除六价铬,促进铁镍颗粒的聚集和生长。研究了红土镍矿自还原过程中铬污泥对金属颗粒聚集和生长的影响。采用标准TRGS 613浸出试验评价了污泥中六价铬的解毒效果。结果表明,随着铬污泥添加量的增加,金属颗粒尺寸增大。当质量铬污泥添加量为13.94%时,还原矿中平均金属粒度由0.42µm提高到1.38µm, Fe、Ni和Cr的回收率分别由53.73%、19.39%和33.36%提高到78.33%、69.22%和58.26%。在还原产物中形成了低熔点的FeS共晶相,显著促进了金属颗粒的迁移和聚集。浸出试验表明,原铬污泥释放量> 600 mg/kg Cr(VI),而红土与铬污泥混合后的渣释放量小于EPA规定的2 mg/kg Cr(VI)。
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引用次数: 2
Thermodynamics and mechanisms of silver tailings roasting processes 银尾矿焙烧过程热力学及机理研究
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2022-01-01 DOI: 10.1051/metal/2022001
Jie Chang, Aifang Pan, Yuzhao Ma, Yue Sun, Shentao Hu, Kuimeng Li
To separate and extract all the useful components of tailings, taking silver tailings as the object, the thermodynamics of silver tailings during the roasting processes was investigated, and the phases transformation mechanism of major minerals were obtained. Based on the mineralogy characteristics of silver tailings, the standard Gibbs free energy changes for the chemical reactions in the roasting processes were calculated; the thermal chemical behaviors and the mineral phases transformation were investigated using TG/DTG-DSC and XRD; and the microstructure changes with chemical composition of microregions were characterized through SEM-EDS. The thermochemical reaction characteristics for the roasting activation of tailings and sodium carbonate at different temperatures were as follows: at 450–650 °C, the ankerite, siderite and sulfide in tailings were oxidized and decomposed, while the crystal transformation of quartz and chlorite occurred; at 650–750 °C, quartz, muscovite and chlorite decomposed to form soluble sodium silicate, sodium aluminum silicate, diopside, sodium ferrite and copper ferrite etc; at 750–800 °C, due to the increase in products with low melting point, the roasted samples melted. During the roasting processes, the surface of minerals depressed and the structures were destroyed. These results can provide a theoretical foundation for thoroughly resource utilization of tailings.
为分离提取尾矿中所有有用组分,以银尾矿为对象,对银尾矿在焙烧过程中的热力学进行了研究,获得了主要矿物的相变机理。根据银尾矿的矿物学特征,计算了焙烧过程中化学反应的标准吉布斯自由能变化;采用TG/DTG-DSC和XRD研究了其热化学行为和矿物相转变;通过扫描电子能谱仪(SEM-EDS)表征了微区化学成分对微观结构的影响。不同温度下尾矿与碳酸钠焙烧活化的热化学反应特征为:在450 ~ 650℃时,尾矿中的铁白云石、菱铁矿和硫化物发生氧化分解,石英和绿泥石发生结晶转变;在650-750℃下,石英、白云母和绿泥石分解形成可溶的水玻璃钠、硅酸铝钠、透辉石、铁氧体钠和铁氧体铜等;在750-800℃时,由于低熔点产品的增加,焙烧样品熔化。在焙烧过程中,矿物表面凹陷,结构被破坏。研究结果可为尾矿资源化的彻底利用提供理论依据。
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引用次数: 1
Alkaline refining of crude lead: a method of arsenic removal and the behavior of arsenic in the process 粗铅的碱性精炼:一种除砷的方法及过程中砷的行为
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2022-01-01 DOI: 10.1051/metal/2021090
R. Zhu, Hailin Long, Haoyu Li, Huimin Xie, Shao-hua Yin, Yongmi Wang, Libo Zhang, Shiwei Li
In this work, the alkaline refining of arsenic in crude lead was studied with a mixture of sodium hydroxide and sodium carbonate as alkaline refining agents. Taking the arsenic removal rate as the research object, the effects of reaction temperature, holding time, Na2CO3:NaOH, the dosage of refining agent were investigated. The arsenic removal rate is 79.09% under the optimum experimental conditions as follows: reaction temperature 823 K, holding time 60 min, Na2CO3:NaOH 1:4, refining agent dosage 10%. The oxidation purification mechanism of arsenic was studied by XPS, SEM-EDS, XRD and FT-IR. The results show that arsenic in the crude lead is gradually oxidized by oxygen and lead oxide during arsenic removal process, and the arsenic trioxide is eventually converted into sodium arsenate (Na3AsO4) and lead arsenate (Pb2As2O7) in the slag.
以氢氧化钠和碳酸钠的混合物为碱性精制剂,对粗铅中砷的碱性精制进行了研究。以砷的去除率为研究对象,考察了反应温度、保温时间、Na2CO3:NaOH、精炼剂用量等因素对砷去除率的影响。最佳实验条件为:反应温度823 K,保温时间60 min, Na2CO3:NaOH: 1:4,精炼剂用量10%,砷的去除率为79.09%。采用XPS、SEM-EDS、XRD、FT-IR等方法对砷的氧化净化机理进行了研究。结果表明:在除砷过程中,粗铅中的砷逐渐被氧和氧化铅氧化,三氧化二砷最终在渣中转化为砷酸钠(Na3AsO4)和砷酸铅(Pb2As2O7);
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引用次数: 0
Defects analysis of the ultra-thick steel pipes using a mixed explicit–implicit FEM 用显隐混合有限元法分析超厚钢管的缺陷
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2022-01-01 DOI: 10.1051/metal/2021101
Yong-Zheng Jiang, Ya-Fan Hu, Z. Fu, Shengqing Zhu
The ultra-thick wall steel pipes are very likely to have quality defects in stretch-reduction hot rolling process, and it is preferred to study these defects by simulation methods. However, traditional FEM often has the problems of convergency difficulty and time consuming for solving complex large deformation problems. Therefore, in this study, a mixed explicit-implicit FEM, was adopted for solving the thermo-mechanical coupled process of the stretch-reduction hot rolling. Multidimensional heat transfer as well as mechanical boundary conditions were acted simultaneously, and the accuracy of the model was validated by industrial experiments. Results showed that the simulation results are very consistent with the actual rolling results. Three typical rolling defects were accurately predicted, i.e., inner hexagon, thickened ends and linear mark. Besides, it is discovered that the uneven distributions of stress, strain and temperature are important causes for the rolling defects, and these influences are also presented and discussed. This paper presents an efficient and precise numerical modelling method so as to provide theoretical guidance for the production of ultra-thick wall pipes.
超厚壁钢管在拉伸收缩热轧过程中极易出现质量缺陷,采用模拟方法对这些缺陷进行研究是可取的。然而,传统有限元法在求解复杂的大变形问题时往往存在收敛困难和耗时等问题。因此,本研究采用显隐混合有限元法求解减张热轧的热-力耦合过程。同时考虑了多维传热和力学边界条件,并通过工业实验验证了模型的准确性。结果表明,模拟结果与实际轧制结果非常吻合。准确预测了三种典型的轧制缺陷,即内六边形缺陷、端部加厚缺陷和线形缺陷。此外,还发现应力、应变和温度分布的不均匀是造成轧制缺陷的重要原因,并对这些影响进行了分析和讨论。本文提出了一种高效、精确的数值模拟方法,为超厚壁管材的生产提供理论指导。
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引用次数: 0
Research progress on granulation process of iron and steel slag 钢铁渣造粒工艺研究进展
IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2022-01-01 DOI: 10.1051/metal/2021100
Wen-long Lin, Hui Wang, Donghui Liu, Hongwei Xing, Chao Liu, Yuzhu Zhang, S. Li
Efficient utilization of iron and steel slag is one of the important measures to achieve peak carbon emissions and carbon neutrality in the iron and steel industry. Improving the recycling rate of iron and steel slag has become an urgent problem to be solved by scholars and enterprises at home and abroad. Therefore, it is of great significance to continuously optimize the recycling process of iron and steel slag and waste heat recovery technology. By comparing and analyzing the advantages and disadvantages of different granulation processes for iron and steel slag, the disadvantages of using dry or wet granulation processes alone for iron and steel slag are pointed out in this paper. Then, a combined granulation process mode combining dry and wet processes is proposed to improve the processing efficiency of molten slag. The increase in resource conversion rate and the quality of granulated slag after primary granulating of iron and steel slag contribute to reducing the amount of slag to be treated secondarily. Furthermore, the energy consumption and pollutant emissions of slag secondary treatment will be decreased as well. It is intended to provide a reference for slag treatment technology and slag utilization rate expansion in iron and steel enterprises.
高效利用钢渣是钢铁工业实现碳排放峰值和碳中和的重要措施之一。提高钢渣的回收率已成为国内外学者和企业亟待解决的问题。因此,不断优化钢渣回收工艺和余热回收技术具有重要意义。通过对不同炼钢渣制粒工艺的优缺点进行比较分析,指出了单独采用干法或湿法炼钢渣制粒工艺的缺点。在此基础上,提出了干湿相结合的组合造粒工艺模式,提高了熔渣的处理效率。钢铁渣一次制粒后,资源转化率提高,制粒渣质量提高,有利于减少二次处理渣量。此外,还可以降低渣二次处理的能耗和污染物排放。旨在为钢铁企业的渣处理技术和渣利用率的提高提供参考。
{"title":"Research progress on granulation process of iron and steel slag","authors":"Wen-long Lin, Hui Wang, Donghui Liu, Hongwei Xing, Chao Liu, Yuzhu Zhang, S. Li","doi":"10.1051/metal/2021100","DOIUrl":"https://doi.org/10.1051/metal/2021100","url":null,"abstract":"Efficient utilization of iron and steel slag is one of the important measures to achieve peak carbon emissions and carbon neutrality in the iron and steel industry. Improving the recycling rate of iron and steel slag has become an urgent problem to be solved by scholars and enterprises at home and abroad. Therefore, it is of great significance to continuously optimize the recycling process of iron and steel slag and waste heat recovery technology. By comparing and analyzing the advantages and disadvantages of different granulation processes for iron and steel slag, the disadvantages of using dry or wet granulation processes alone for iron and steel slag are pointed out in this paper. Then, a combined granulation process mode combining dry and wet processes is proposed to improve the processing efficiency of molten slag. The increase in resource conversion rate and the quality of granulated slag after primary granulating of iron and steel slag contribute to reducing the amount of slag to be treated secondarily. Furthermore, the energy consumption and pollutant emissions of slag secondary treatment will be decreased as well. It is intended to provide a reference for slag treatment technology and slag utilization rate expansion in iron and steel enterprises.","PeriodicalId":18527,"journal":{"name":"Metallurgical Research & Technology","volume":"298 2 1","pages":""},"PeriodicalIF":1.1,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72928325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Metallurgical Research & Technology
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