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Thermal Annealing Effect on the Structure, Optical and Electrical Properties of Lanthanum Manganite Thin Films Prepared by Reactive Co-Sputtering 热退火对反应共溅射制备锰酸镧薄膜结构、光电性能的影响
Pub Date : 2022-09-30 DOI: 10.3390/electronicmat3040025
W. Hourani, C. Rousselot, Kouamé Boko Joël-Igor N’Djoré, A. Billard, M. Arab Pour Yazdi, Y. Makoudi
Lanthanum manganite (LMO) thin films were deposited by co-sputtering La and Mn targets in an Ar and O2 gas mixture. The films were synthesized on silicon and fused silica substrates. The influences of thermal annealing on the structure, optical and electrical properties of LMO films were investigated. The results exhibited a correlation between these properties. In the amorphous state, an increase in annealing temperature improved the optical transmission and decreased the electrical capacitance. The beginning of crystallization at 600 °C was manifested by a strong increase in the capacitance and a decrease in the optical transmission. At higher annealing temperature, polycrystalline films were obtained with different optical and electrical characteristics. On the other hand, the annealed LMO films showed a photocurrent effect during exposure to a weak LED light.
在Ar和O2混合气体中,采用共溅射法制备了镧锰酸盐薄膜。薄膜是在硅和熔融硅衬底上合成的。研究了热处理对LMO薄膜结构、光学和电学性能的影响。结果显示了这些性质之间的相关性。在非晶态下,退火温度的升高提高了光传输率,减小了电容。在600°C时开始结晶,表现为电容的强烈增加和光透射率的下降。在较高的退火温度下,得到了具有不同光学和电学特性的多晶薄膜。另一方面,退火后的LMO薄膜在弱LED光照射下表现出光电流效应。
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引用次数: 0
Direct Comparison of the Effect of Processing Conditions in Electrolyte-Gated and Bottom-Gated TIPS-Pentacene Transistors 电解门控与底门控tips -五苯晶体管加工条件影响的直接比较
Pub Date : 2022-09-27 DOI: 10.3390/electronicmat3040024
Nicolò Lago, Marco Buonomo, F. Prescimone, S. Toffanin, M. Muccini, A. Cester
Among the plethora of soluble and easy processable organic semiconductors, 6,13-Bis(triisopropylsilylethynyl)pentacene (TIPS-P5) is one of the most promising materials for next-generation flexible electronics. However, based on the information reported in the literature, it is difficult to exploit in field-effect transistors the high-performance characteristics of this material. This article correlates the HMDS functionalization of the silicon substrate with the electrical characteristics of TIPS-P5-based bottom gate organic field-effect transistors (OFETs) and electrolyte-gated organic field-effect transistors (EGOFETs) fabricated over the same platform. TIPS-P5 transistors with a double-gate architecture were fabricated by simple drop-casting on Si/SiO2 substrates, and the substrates were either functionalized with hexamethyldisilazane (HMDS) or left untreated. The same devices were characterized both as standard bottom-gate transistors and as (top-gate) electrolyte-gated transistors, and the results with and without HMDS treatment were compared. It is shown that the functionalization of the silicon substrate negatively influences EGOFETs performance, while it is beneficial for bottom-gate OFETs. Different device architectures (e.g., bottom-gate vs. top-gate) require specific evaluation of the fabrication protocols starting from the effect of the HMDS functionalization to maximize the electrical characteristics of TIPS-P5-based devices.
在众多可溶且易于加工的有机半导体中,6,13-二(三异丙基乙基)并五烯(TIPS-P5)是下一代柔性电子器件中最有前途的材料之一。然而,根据文献报道的信息,很难在场效应晶体管中利用这种材料的高性能特性。本文将硅衬底的HMDS功能化与在同一平台上制造的基于tips - p5的底栅有机场效应晶体管(ofet)和电解质门控有机场效应晶体管(egofet)的电学特性联系起来。采用简单滴铸法在Si/SiO2衬底上制备了双栅极结构的TIPS-P5晶体管,衬底采用六甲基二矽氮杂烷(HMDS)进行功能化或不进行处理。将同一器件分别表征为标准底栅晶体管和(顶栅)电解门控晶体管,并比较了经过HMDS处理和未经过HMDS处理的结果。结果表明,硅衬底的功能化对效应场效应管的性能有负面影响,而对底栅效应场效应管是有利的。不同的器件架构(例如,底门与顶门)需要从HMDS功能化的影响开始对制造协议进行具体评估,以最大限度地提高基于tips - p5器件的电气特性。
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引用次数: 1
Characterization of Organic Conductive Materials as an Ecological Solution for RF Applications 表征有机导电材料作为射频应用的生态解决方案
Pub Date : 2022-09-26 DOI: 10.3390/electronicmat3040023
Bruna Cruz, P. Eschlwech, Michael Hani, Erwin M. Biebl
The use of nonmetallic conductor materials in RF applications has recently become a highlighted issue when it comes to sustainability in the electronics industry, mainly because of the waste problems associated with heavy metals and the necessity of reducing and managing them. The replacement of metal in functional applications such as in electronics is therefore very important. Among these new materials, organic conductors are of great interest since they are, in general, biocompatible and biodegradable, allowing for the disposal of electronic devices, which reduces the negative environment impact caused by electronics waste. In this work, PEDOT:PSS and Carbon are investigated. Since these materials are available as conducting pastes or inks, the production of conducting patterns by printing techniques such as screen printing is possible, which can make the process less harmful to the environment, since it permits the use of organic substrates such as paper. In order to investigate the feasibility of these materials for RF signal transmission, screen printed PEDOT:PSS and Carbon transmission lines have been designed, fabricated and characterized. Results regarding conductivity, thickness, electric permittivity and S21 parameter are presented and will serve as a foundation for the development of further reaching applications utilizing organic materials.
当涉及到电子工业的可持续性时,非金属导体材料在射频应用中的使用最近已成为一个突出的问题,主要是因为与重金属相关的废物问题以及减少和管理它们的必要性。因此,在电子等功能应用中替代金属是非常重要的。在这些新材料中,有机导体引起了极大的兴趣,因为它们通常具有生物相容性和可生物降解性,允许处理电子设备,从而减少了电子废物对环境的负面影响。本研究对PEDOT:PSS和Carbon进行了研究。由于这些材料可作为导电浆料或油墨,因此可以通过丝网印刷等印刷技术生产导电图案,这可以使该过程对环境的危害较小,因为它允许使用有机基材,如纸。为了研究这些材料用于射频信号传输的可行性,我们设计、制作并表征了网印PEDOT:PSS和Carbon传输线。给出了有关导电率、厚度、介电常数和S21参数的结果,并将为进一步利用有机材料的应用开发奠定基础。
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引用次数: 1
Characterization of Electronic Materials 电子材料的表征
Pub Date : 2022-09-14 DOI: 10.3390/electronicmat3030022
W. Pisula
Electronic materials are of great interest due to their potential to be applied in a broad range of important electronic devices including transistors, sensors, solar cells and others [...]
电子材料因其广泛应用于晶体管、传感器、太阳能电池等重要电子器件的潜力而备受关注。
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引用次数: 0
A Study on the Optimization of the Conductive Ball Manufacturing Process, Used for Anisotropic Conductive Films 各向异性导电膜用导电球制造工艺的优化研究
Pub Date : 2022-08-19 DOI: 10.3390/electronicmat3030021
Jong-Keun Choi, Young-Gyun Kim, K. Han
Currently, as the next-generation of display progresses—with high performance and high integration—the surface mounting technology of components is very important. In particular, in the case of flexible displays, such as rollable and bendable displays, ACF that connects wires to any curvature is essential. However, the conductive ball used inside the ACF has had problems with particle size and non-uniform metal coating. It was confirmed that the presence of solvent and oxygen, which are used in polymer synthesis, affects the sphere formation of polymer beads. By optimizing the factors affecting the polymer beads, a perfect spherical polymer bead was manufactured. In addition, the conductive ball manufacturing process was optimized by confirming the factors affecting the metal coating. The metal coating on the surface of the polymer bead was applied with a uniform thickness by considering the specific surface area and concentration of the conductive balls, and, through this optimized process, conductive balls for anisotropic conductive films with uniform size and metal thickness were obtained.
当前,随着下一代显示技术向高性能、高集成度的方向发展,器件的表面贴装技术显得尤为重要。特别是,在柔性显示器的情况下,如可卷曲和可弯曲的显示器,连接电线到任何曲率的ACF是必不可少的。然而,ACF内部使用的导电球存在粒度和不均匀金属涂层的问题。结果表明,聚合物合成中所使用的溶剂和氧的存在对聚合物珠球的形成有影响。通过对影响聚合物珠的因素进行优化,制备出完美的球形聚合物珠。此外,通过确定影响金属镀层的因素,对导电球的制造工艺进行了优化。考虑导电球的比表面积和浓度,在聚合物珠表面涂覆均匀厚度的金属涂层,得到尺寸均匀、金属厚度均匀的各向异性导电膜用导电球。
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引用次数: 0
Progress in Hexagonal Boron Nitride (h-BN)-Based Solid-State Neutron Detector 六方氮化硼(h-BN)基固体中子探测器的研究进展
Pub Date : 2022-08-03 DOI: 10.3390/electronicmat3030020
Samiul Hasan, Iftikhar Ahmad
This article will briefly review the progress of h-BN based solid-state metal semiconductor metal (MSM) neutron detectors. In the last decade, several groups have been working on hexagonal boron nitride (h-BN)-based solid-state neutron detectors. Recently, the detection efficiency of 59% has been reported. Efficient, low-cost neutron detectors made from readily available materials are essential for various applications. Neutron detectors are widely used to detect fissile materials and nuclear power plants for security applications. The most common and widely used neutron detectors are 3He based, which are sometimes bulky, difficult to transport, have high absorption length, need relatively high bias voltage (>1000 V), and have low Q-value (0.764 MeV). In addition, 3He is not a readily available material. Thus, there is a strong need to find an alternative detection material. The 10B isotope has a high neutron absorption cross-section, and it has been tested as a coating on the semiconducting materials. Due to the two-step process, neutron capture through 10B and then electron–hole pair generation in a typical semiconducting material, the efficiency of these devices is not up to the mark. The progress in h-BN based detectors requires a review to envision the further improvement in this technology.
本文简要介绍了氢氮化硼基固态金属半导体金属(MSM)中子探测器的研究进展。在过去的十年里,几个小组一直在研究基于六方氮化硼(h-BN)的固态中子探测器。最近有报道称,检测效率为59%。由现成材料制成的高效、低成本中子探测器对于各种应用都是必不可少的。中子探测器广泛用于检测裂变材料和核电站的安全应用。最常见和应用最广泛的是基于3He的中子探测器,它们体积大,运输困难,吸收长度高,需要相对高的偏置电压(>1000 V), q值低(0.764 MeV)。此外,3He不是现成的材料。因此,迫切需要找到一种替代检测材料。10B同位素具有较高的中子吸收截面,并已作为半导体材料的涂层进行了测试。在典型的半导体材料中,由于两步过程,通过10B捕获中子,然后产生电子-空穴对,这些设备的效率不达标。氢氮化硼基探测器的进展需要回顾,以展望该技术的进一步改进。
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引用次数: 1
Tunnel Spin-Polarization of Ferromagnetic Metals and Ferrimagnetic Oxides and Its Effect on Tunnel Magnetoresistance 铁磁金属和铁磁氧化物的隧道自旋极化及其对隧道磁电阻的影响
Pub Date : 2022-07-28 DOI: 10.3390/electronicmat3030019
G. Suchaneck
This work presents an examination and unification of fragmented data on spin polarization in half-metallic, ferrimagnetic oxides. It also includes well understood ferromagnetic metals for comparison. The temperature and disorder dependencies of the spin polarization are evaluated. Both the temperature dependence of the tunnel magnetoresistance and, for the very first time, its temperature coefficient are calculated based on the simplified Julliére model. The tunnel magnetoresistance in the magnetic tunnel junctions deteriorates due to the temperature dependence of the spin polarization the lower the Curie temperature is. As a result, magnetic tunnel junctions—consisting of ferromagnetic oxides with a Curie temperature not far above room temperature—are not promising for room temperature applications. Additionally, ferrimagnetic oxides possessing a Curie temperature below 650 K are not suitable for room temperature applications because of an unacceptable temperature coefficient exceeding −2%.
这项工作提出了对半金属铁磁氧化物中自旋极化的碎片数据的检查和统一。它还包括很好理解的铁磁性金属进行比较。评估了自旋极化的温度依赖性和无序依赖性。本文首次基于简化的jullisamre模型计算了隧道磁电阻的温度依赖性和温度系数。居里温度越低,自旋极化的温度依赖性越强,隧道磁阻越差。因此,磁性隧道结(由居里温度略高于室温的铁磁性氧化物组成)在室温下的应用前景并不乐观。此外,居里温度低于650 K的铁磁性氧化物不适合室温应用,因为温度系数超过- 2%是不可接受的。
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引用次数: 0
Determination of stoichiometry deviation in wide-band II–VI semiconductors on the basis of equilibrium vapor phase composition 基于平衡气相组成的宽带II-VI半导体化学计量偏差测定
Pub Date : 2022-06-30 DOI: 10.3897/j.moem.8.2.90174
S. Kobeleva
A method has been suggested for determining stoichiometry deviation in cadmium and zinc chalcogenides based on the temperature dependence of the ratio of components partial pressures during evaporation of solid compounds in a limited volume. The new method differs from methods implying the collection of excessive component during evaporation in large volumes. The method includes measuring the partial pressures of vapor phase components during material heating to above 800 K, solving a set of material balance equations and the electric neutrality equation, and calculating the stoichiometry deviation in the initial compound at room temperature. Intrinsic point defect concentrations are calculated using the method of quasichemical reactions. The independent variables in the set of material balance equations are the sought stoichiometry deviation, the partial pressure of the metal and the concentration of free electrons. We show that the parameter of the material balance equation which determines the method’s sensitivity to stoichiometry deviation, i.e., the volume ratio of vapor and solid phases, can be considered constant during heating and evaporation if this parameter does not exceed 50. If the partial pressure is measured based on the optical density of the vapors, then the sensitivity of the method can be increased to not worse than 10–6 at.%.
提出了一种测定镉和锌硫族化合物化学计量偏差的方法,该方法基于固体化合物在有限体积内蒸发过程中组分分压比的温度依赖性。新方法不同于在大量蒸发过程中收集过量成分的方法。该方法包括测量材料加热到800k以上时气相组分的分压,求解一组物质平衡方程和电中性方程,计算室温下初始化合物的化学计量偏差。用准化学反应的方法计算了本征点缺陷浓度。这组物质平衡方程中的自变量是所寻求的化学计量偏差、金属的分压和自由电子的浓度。我们表明,在加热和蒸发过程中,决定该方法对化学计量偏差敏感性的物质平衡方程参数,即气相和固相的体积比,如果该参数不超过50,则可以认为是恒定的。如果分压是基于蒸汽的光密度测量的,那么该方法的灵敏度可以增加到不低于10 - 6% at.%。
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引用次数: 1
Development of a mobile independent solar power plant based on solid-state heterojunction photocells for agricultural purposes 基于固态异质结光电池的农用移动式独立太阳能发电厂的研制
Pub Date : 2022-06-30 DOI: 10.3897/j.moem.8.2.90062
S. Tokmoldin, V. V. Klimenov, D. V. Girin, N. Chuchvaga, K. Aimaganbetov, M. P. Kishkenebaev, S. N. Tarakanova, N. Tokmoldin
Mathematical simulation of temperature distribution on double-sided solar cells has been carried out. Differences in the configuration of photoelectric converters prove to solely amount to the fact that a double-sided solar cell has a more efficient heat sink at the rear side. Furthermore double-sided solar cells exhibit higher power conversion performance. Calculations confirm the correctness of giving preference to double-sided solar cells which is of great importance for the photoelectric converter design developed by us. Analysis of market-available photovoltaic technologies of solar energy to electric power conversion has led to the development of a photovoltaic converter on the basis of double-sided silicon heterojunction solar cells. The configuration developed is a moving platform having a photovoltaic cell array mounted on it and a light flux collector. A double-axis tracking system has been developed for the general case of planar attachment of solar cell modules. A 350 mm stroke drive provides for movement in the north-south direction and a 450 mm stroke drive, in the east-west direction. The task has been outlined to find the required arm for providing symmetrical positioning at the maximum rotation angle about the axis. As a result, technical solutions have been developed for the north-south and the east-west directions. Furthermore a schematic wiring diagram has been designed to implement the preset solar tracking system algorithm. The system is also fitted with a GPS/GLONASS module for system precision positioning and time synchronization.
对双面太阳能电池的温度分布进行了数学模拟。光电转换器配置上的差异仅仅证明了一个事实,即双面太阳能电池在背面有一个更有效的散热器。此外,双面太阳能电池具有更高的功率转换性能。计算证实了优先选用双面太阳能电池的正确性,这对我们研制的光电变换器的设计具有重要意义。分析了市场上现有的太阳能到电能转换的光伏技术,开发了一种基于双面硅异质结太阳能电池的光伏转换器。所开发的结构是移动平台,其上安装有光伏电池阵列和光通量收集器。针对太阳能电池组件平面附着的一般情况,研制了一种双轴跟踪系统。350毫米行程的驱动器提供南北方向的运动,450毫米行程的驱动器提供东西方向的运动。该任务已被概述为找到所需的臂,以提供对称定位的最大旋转角度的轴。因此,已经为南北和东西方向开发了技术解决方案。并设计了原理接线图,实现了预设的太阳跟踪系统算法。该系统还配备了GPS/GLONASS模块,用于系统精确定位和时间同步。
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引用次数: 0
Prototyping and Evaluation of Graphene-Based Piezoresistive Sensors 石墨烯压阻式传感器的原型设计与评价
Pub Date : 2022-06-22 DOI: 10.3390/electronicmat3030018
L. Florencio, J. Luzardo, M.M.S. Pojucan, Victor Cunha, Alexander Silva, R. Valaski, Joyce Araujo
In this work, the electrical properties of graphene papers were investigated with the aim of developing pressure sensor prototypes for measuring pressures up to 2 kPa. In order to determine which graphene paper would be the most suitable, three different types of graphene papers, synthesized by different routes, were prepared and electrically characterized. The results of electrical characterizations, in terms of electrical conductivity and sheet resistance of graphene papers, are presented and discussed. Prototypes of pressure sensors are proposed, using graphene papers obtained by chemical oxidation (graphene oxide and reduced graphene oxide) and by electrochemical exfoliation. The prototypes were tested in static compression/decompression tests in the working range of 0 kPa to 1.998 kPa. The compression/decompression sensitivity values observed in these prototype sensors ranged from 20.8% ΔR/kPa for graphene sensors obtained by electrochemical exfoliation to 110.7% ΔR/kPa for those prepared from graphene oxide obtained by chemical oxidation. More expressive sensitivity values were observed for the sensors fabricated from GO, intermediate values for those made of rGO, while prototypes made of EG showed lower sensitivity.
在这项工作中,研究了石墨烯纸的电学特性,目的是开发用于测量高达2kpa压力的压力传感器原型。为了确定哪种石墨烯纸是最合适的,通过不同的途径合成了三种不同类型的石墨烯纸,并对其进行了电学表征。介绍并讨论了石墨烯纸的电导率和片电阻等电学表征结果。利用化学氧化(氧化石墨烯和还原氧化石墨烯)和电化学剥离得到的石墨烯纸,提出了压力传感器的原型。在0千帕至1.998千帕的工作范围内对样机进行了静态压缩/减压试验。在这些原型传感器中观察到的压缩/减压灵敏度值从电化学剥离得到的石墨烯传感器的20.8% ΔR/kPa到化学氧化得到的氧化石墨烯传感器的110.7% ΔR/kPa不等。由氧化石墨烯制成的传感器灵敏度值更具表现力,由氧化石墨烯制成的传感器灵敏度为中间值,而由EG制成的原型灵敏度较低。
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引用次数: 2
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Modern Electronic Materials
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