Pub Date : 2025-01-07DOI: 10.1038/s41566-024-01604-x
Stefan Bittner, Marc Sciamanna
Broad-area semiconductor lasers are used in many high-power applications; however, their spatio-temporal dynamics are complex and intrinsically unstable due to the interaction between transverse lasing modes. Here a dynamical and ultrahigh-resolution spatio-spectral analysis of commercial broad-area lasers reveals multiplets of phase-locked first- and second-order transverse modes that are spontaneously created by the nonlinear dynamics of the laser. Phase locking between modes of different transverse order is confirmed by comparing the linewidths of the lasing modes with that of their beat note and by a direct measurement of their phase fluctuation correlations. The spontaneous phase locking is unexpected since the overall dynamics are unstable and the system lacks any intentional feature to induce locking. This partially synchronized dynamical state with groups of coexisting synchronized and unsynchronized laser modes is similar to chimera states found in networks of coupled oscillators, indicating that such states may exist in a wider range of systems than previously assumed.
{"title":"Spontaneous phase locking in a broad-area semiconductor laser","authors":"Stefan Bittner, Marc Sciamanna","doi":"10.1038/s41566-024-01604-x","DOIUrl":"https://doi.org/10.1038/s41566-024-01604-x","url":null,"abstract":"<p>Broad-area semiconductor lasers are used in many high-power applications; however, their spatio-temporal dynamics are complex and intrinsically unstable due to the interaction between transverse lasing modes. Here a dynamical and ultrahigh-resolution spatio-spectral analysis of commercial broad-area lasers reveals multiplets of phase-locked first- and second-order transverse modes that are spontaneously created by the nonlinear dynamics of the laser. Phase locking between modes of different transverse order is confirmed by comparing the linewidths of the lasing modes with that of their beat note and by a direct measurement of their phase fluctuation correlations. The spontaneous phase locking is unexpected since the overall dynamics are unstable and the system lacks any intentional feature to induce locking. This partially synchronized dynamical state with groups of coexisting synchronized and unsynchronized laser modes is similar to chimera states found in networks of coupled oscillators, indicating that such states may exist in a wider range of systems than previously assumed.</p>","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"71 1","pages":""},"PeriodicalIF":35.0,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142934837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-06DOI: 10.1038/s41566-024-01588-8
William Loh, David Reens, Dave Kharas, Alkesh Sumant, Connor Belanger, Ryan T. Maxson, Alexander Medeiros, William Setzer, Dodd Gray, Kyle DeBry, Colin D. Bruzewicz, Jason Plant, John Liddell, Gavin N. West, Sagar Doshi, Matthew Roychowdhury, May E. Kim, Danielle Braje, Paul W. Juodawlkis, John Chiaverini, Robert McConnell
Optical atomic clocks have demonstrated revolutionary advances in precision timekeeping, but their applicability to the real world is critically dependent on whether such clocks can operate outside the laboratory. Photonic integration offers one compelling solution to address the miniaturization and ruggedization needed to enable clock portability, but brings with it a new set of challenges in recreating the functionality of an optical clock using chip-scale building blocks. The clock laser used for atom interrogation is one particular point of uncertainty, as the performance of the meticulously engineered bulk-cavity-stabilized lasers would be exceptionally difficult to transfer to chip. Here we demonstrate that an integrated ultrahigh-quality-factor spiral cavity, when interfaced with a 1,348 nm seed laser, is able to reach a fractional frequency instability of 7.5 × 10−14 on chip. On frequency doubling the light to 674 nm, we use this laser to interrogate the narrow-linewidth transition of 88Sr+ and showcase the operation of a Sr-ion clock with short-term instability averaging down as (3.9times 1{0}^{-14}/sqrt{tau }) (τ, averaging time). Our demonstration of a high-performance optical atomic clock interrogated by an integrated spiral cavity laser opens the door for future advanced clock systems to be entirely constructed using lightweight, portable and mass-manufacturable integrated optics and electronics.
{"title":"Optical atomic clock interrogation using an integrated spiral cavity laser","authors":"William Loh, David Reens, Dave Kharas, Alkesh Sumant, Connor Belanger, Ryan T. Maxson, Alexander Medeiros, William Setzer, Dodd Gray, Kyle DeBry, Colin D. Bruzewicz, Jason Plant, John Liddell, Gavin N. West, Sagar Doshi, Matthew Roychowdhury, May E. Kim, Danielle Braje, Paul W. Juodawlkis, John Chiaverini, Robert McConnell","doi":"10.1038/s41566-024-01588-8","DOIUrl":"https://doi.org/10.1038/s41566-024-01588-8","url":null,"abstract":"<p>Optical atomic clocks have demonstrated revolutionary advances in precision timekeeping, but their applicability to the real world is critically dependent on whether such clocks can operate outside the laboratory. Photonic integration offers one compelling solution to address the miniaturization and ruggedization needed to enable clock portability, but brings with it a new set of challenges in recreating the functionality of an optical clock using chip-scale building blocks. The clock laser used for atom interrogation is one particular point of uncertainty, as the performance of the meticulously engineered bulk-cavity-stabilized lasers would be exceptionally difficult to transfer to chip. Here we demonstrate that an integrated ultrahigh-quality-factor spiral cavity, when interfaced with a 1,348 nm seed laser, is able to reach a fractional frequency instability of 7.5 × 10<sup>−14</sup> on chip. On frequency doubling the light to 674 nm, we use this laser to interrogate the narrow-linewidth transition of <sup>88</sup>Sr<sup>+</sup> and showcase the operation of a Sr-ion clock with short-term instability averaging down as <span>(3.9times 1{0}^{-14}/sqrt{tau })</span> (<i>τ</i>, averaging time). Our demonstration of a high-performance optical atomic clock interrogated by an integrated spiral cavity laser opens the door for future advanced clock systems to be entirely constructed using lightweight, portable and mass-manufacturable integrated optics and electronics.</p>","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"34 1","pages":""},"PeriodicalIF":35.0,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142929538","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-03DOI: 10.1038/s41566-024-01568-y
David Schmitt, Jan Philipp Bange, Wiebke Bennecke, Giuseppe Meneghini, AbdulAziz AlMutairi, Marco Merboldt, Jonas Pöhls, Kenji Watanabe, Takashi Taniguchi, Sabine Steil, Daniel Steil, R. Thomas Weitz, Stephan Hofmann, Samuel Brem, G. S. Matthijs Jansen, Ermin Malic, Stefan Mathias, Marcel Reutzel
Understanding the impact of spatial heterogeneity on the behaviour of two-dimensional materials represents one of the grand challenges in applying these materials in optoelectronics and quantum information science. For transition metal dichalcogenide heterostructures in particular, direct access to heterogeneities in the dark-exciton landscape with nanometre spatial and ultrafast time resolution is highly desired but remains largely elusive. Here we report how ultrafast dark-field momentum microscopy can spatio-temporally resolve dark-exciton formation dynamics in a twisted WSe2/MoS2 heterostructure with a time resolution of 55 fs and a spatial resolution of 480 nm. This enables us to directly map spatial heterogeneity in the electronic and excitonic structure, and to correlate this with the dark-exciton formation and relaxation dynamics. The advantage of the simultaneous ultrafast nanoscale dark-field momentum microscopy and spectroscopy reported here is that it enables spatio-temporal imaging of the photoemission spectral function that carries energy- and momentum-resolved information on the single-particle band structure, many-body interactions and correlation phenomena. Dark-field momentum microscopy makes it possible to spatio-temporally and spatio-spectrally resolve the dark-exciton dynamics in a twisted transition metal dichalcogenide heterostructure.
{"title":"Ultrafast nano-imaging of dark excitons","authors":"David Schmitt, Jan Philipp Bange, Wiebke Bennecke, Giuseppe Meneghini, AbdulAziz AlMutairi, Marco Merboldt, Jonas Pöhls, Kenji Watanabe, Takashi Taniguchi, Sabine Steil, Daniel Steil, R. Thomas Weitz, Stephan Hofmann, Samuel Brem, G. S. Matthijs Jansen, Ermin Malic, Stefan Mathias, Marcel Reutzel","doi":"10.1038/s41566-024-01568-y","DOIUrl":"10.1038/s41566-024-01568-y","url":null,"abstract":"Understanding the impact of spatial heterogeneity on the behaviour of two-dimensional materials represents one of the grand challenges in applying these materials in optoelectronics and quantum information science. For transition metal dichalcogenide heterostructures in particular, direct access to heterogeneities in the dark-exciton landscape with nanometre spatial and ultrafast time resolution is highly desired but remains largely elusive. Here we report how ultrafast dark-field momentum microscopy can spatio-temporally resolve dark-exciton formation dynamics in a twisted WSe2/MoS2 heterostructure with a time resolution of 55 fs and a spatial resolution of 480 nm. This enables us to directly map spatial heterogeneity in the electronic and excitonic structure, and to correlate this with the dark-exciton formation and relaxation dynamics. The advantage of the simultaneous ultrafast nanoscale dark-field momentum microscopy and spectroscopy reported here is that it enables spatio-temporal imaging of the photoemission spectral function that carries energy- and momentum-resolved information on the single-particle band structure, many-body interactions and correlation phenomena. Dark-field momentum microscopy makes it possible to spatio-temporally and spatio-spectrally resolve the dark-exciton dynamics in a twisted transition metal dichalcogenide heterostructure.","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"19 2","pages":"187-194"},"PeriodicalIF":32.3,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142917086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-03DOI: 10.1038/s41566-024-01577-x
Artiom Skripka, Zhuolei Zhang, Xiao Qi, Benedikt Ursprung, Peter Ercius, Bruce E. Cohen, P. James Schuck, Daniel Jaque, Emory M. Chan
Optically bistable materials respond to a single input with two possible optical outputs, contingent on excitation history. Such materials would be ideal for optical switching and memory, but the limited understanding of intrinsic optical bistability (IOB) prevents the development of nanoscale IOB materials suitable for devices. Here we demonstrate IOB in Nd3+-doped KPb2Cl5 avalanching nanoparticles, which switch with high contrast between luminescent and non-luminescent states, with hysteresis characteristic of bistability. We elucidate a non-thermal mechanism in which IOB originates from suppressed non-radiative relaxation in Nd3+ ions and from the positive feedback of photon avalanching, resulting in extreme, >200th-order optical nonlinearities. The modulation of laser pulsing tunes the hysteresis widths, and dual-laser excitation enables transistor-like optical switching. This control over nanoscale IOB establishes avalanching nanoparticles for photonic devices in which light is used to manipulate light. Intrinsic optical bistability in Nd3+-doped KPb2Cl5 avalanching nanoparticles enables high-contrast switching between luminescent and non-luminescent states and transistor-like optical responses. A non-thermal mechanism is discussed and >200th-order optical nonlinearities are shown to be possible.
{"title":"Intrinsic optical bistability of photon avalanching nanocrystals","authors":"Artiom Skripka, Zhuolei Zhang, Xiao Qi, Benedikt Ursprung, Peter Ercius, Bruce E. Cohen, P. James Schuck, Daniel Jaque, Emory M. Chan","doi":"10.1038/s41566-024-01577-x","DOIUrl":"10.1038/s41566-024-01577-x","url":null,"abstract":"Optically bistable materials respond to a single input with two possible optical outputs, contingent on excitation history. Such materials would be ideal for optical switching and memory, but the limited understanding of intrinsic optical bistability (IOB) prevents the development of nanoscale IOB materials suitable for devices. Here we demonstrate IOB in Nd3+-doped KPb2Cl5 avalanching nanoparticles, which switch with high contrast between luminescent and non-luminescent states, with hysteresis characteristic of bistability. We elucidate a non-thermal mechanism in which IOB originates from suppressed non-radiative relaxation in Nd3+ ions and from the positive feedback of photon avalanching, resulting in extreme, >200th-order optical nonlinearities. The modulation of laser pulsing tunes the hysteresis widths, and dual-laser excitation enables transistor-like optical switching. This control over nanoscale IOB establishes avalanching nanoparticles for photonic devices in which light is used to manipulate light. Intrinsic optical bistability in Nd3+-doped KPb2Cl5 avalanching nanoparticles enables high-contrast switching between luminescent and non-luminescent states and transistor-like optical responses. A non-thermal mechanism is discussed and >200th-order optical nonlinearities are shown to be possible.","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"19 2","pages":"212-218"},"PeriodicalIF":32.3,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142917016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-01-02DOI: 10.1038/s41566-024-01603-y
Kun Liao, Yaxiao Lian, Maotao Yu, Zhuochen Du, Tianxiang Dai, Yaxin Wang, Haoming Yan, Shufang Wang, Cuicui Lu, C. T. Chan, Rui Zhu, Dawei Di, Xiaoyong Hu, Qihuang Gong
Integrated photonic chips hold substantial potential in optical communications, computing, light detection and ranging, sensing, and imaging, offering exceptional data throughput and low power consumption. A key objective is to build a monolithic on-chip photonic system that integrates light sources, processors and photodetectors on a single chip. However, this remains challenging due to limitations in materials engineering, chip integration techniques and design methods. Perovskites offer simple fabrication, tolerance to lattice mismatch, flexible bandgap tunability and low cost, making them promising for hetero-integration with silicon photonics. Here we propose and experimentally realize a near-infrared monolithic on-chip photonic system based on a perovskite/silicon nitride photonic platform, developing nano-hetero-integration technology to integrate efficient light-emitting diodes, high-performance processors and sensitive photodetectors. Photonic neural networks are implemented to perform photonic simulations and computer vision tasks. Our network efficiently predicts the topological invariant in a two-dimensional disordered Su–Schrieffer–Heeger model and simulates nonlinear topological models with an average fidelity of 87%. In addition, we achieve a test accuracy of over 85% in edge detection and 56% on the CIFAR-10 dataset using a scaled-up architecture. This work addresses the challenge of integrating diverse nanophotonic components on a chip, offering a promising solution for chip-integrated multifunctional photonic information processing.
{"title":"Hetero-integrated perovskite/Si3N4 on-chip photonic system","authors":"Kun Liao, Yaxiao Lian, Maotao Yu, Zhuochen Du, Tianxiang Dai, Yaxin Wang, Haoming Yan, Shufang Wang, Cuicui Lu, C. T. Chan, Rui Zhu, Dawei Di, Xiaoyong Hu, Qihuang Gong","doi":"10.1038/s41566-024-01603-y","DOIUrl":"https://doi.org/10.1038/s41566-024-01603-y","url":null,"abstract":"<p>Integrated photonic chips hold substantial potential in optical communications, computing, light detection and ranging, sensing, and imaging, offering exceptional data throughput and low power consumption. A key objective is to build a monolithic on-chip photonic system that integrates light sources, processors and photodetectors on a single chip. However, this remains challenging due to limitations in materials engineering, chip integration techniques and design methods. Perovskites offer simple fabrication, tolerance to lattice mismatch, flexible bandgap tunability and low cost, making them promising for hetero-integration with silicon photonics. Here we propose and experimentally realize a near-infrared monolithic on-chip photonic system based on a perovskite/silicon nitride photonic platform, developing nano-hetero-integration technology to integrate efficient light-emitting diodes, high-performance processors and sensitive photodetectors. Photonic neural networks are implemented to perform photonic simulations and computer vision tasks. Our network efficiently predicts the topological invariant in a two-dimensional disordered Su–Schrieffer–Heeger model and simulates nonlinear topological models with an average fidelity of 87%. In addition, we achieve a test accuracy of over 85% in edge detection and 56% on the CIFAR-10 dataset using a scaled-up architecture. This work addresses the challenge of integrating diverse nanophotonic components on a chip, offering a promising solution for chip-integrated multifunctional photonic information processing.</p>","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"115 1","pages":""},"PeriodicalIF":35.0,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142912075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Leveraging the entire space of complex dielectric permittivity, non-Hermitian photonics has fundamentally altered wave propagation with complex optical potentials and has ushered in a host of new photonic applications. Through parity–time symmetry and its breaking—a delicate interplay between gain and loss—even the interaction between just two entities becomes counter-intuitive and intriguing. Here we realize, through hybrid III–V/Si integration, a scalable non-Hermitian switching network on a two-layer integrated photonic chip. Our platform is a hybrid, with a bottom silicon layer and a top InGaAsP layer that provides optical gain. By tuning the gain level in the top layer, vertically coupled waveguides operate below or above the exceptional point, where light is switched across two layers, among different input–output ports. For a single switching unit, the switching dynamics are ultrafast, on the order of 100 ps. In a large switching network, non-blocking and other diverse connectivities are established in single-wavelength and wavelength-selective switching, with high extinction ratios. Our approach adds scalable non-Hermitian switching to photonic design toolkits to simultaneously boost the switching time and bandwidth density to cutting-edge levels, therefore paving the way for compact and ultrafast monolithic integrated silicon photonics in next-generation optical information networks.
{"title":"Non-Hermitian hybrid silicon photonic switching","authors":"Xilin Feng, Tianwei Wu, Zihe Gao, Haoqi Zhao, Shuang Wu, Yichi Zhang, Li Ge, Liang Feng","doi":"10.1038/s41566-024-01579-9","DOIUrl":"https://doi.org/10.1038/s41566-024-01579-9","url":null,"abstract":"<p>Leveraging the entire space of complex dielectric permittivity, non-Hermitian photonics has fundamentally altered wave propagation with complex optical potentials and has ushered in a host of new photonic applications. Through parity–time symmetry and its breaking—a delicate interplay between gain and loss—even the interaction between just two entities becomes counter-intuitive and intriguing. Here we realize, through hybrid III–V/Si integration, a scalable non-Hermitian switching network on a two-layer integrated photonic chip. Our platform is a hybrid, with a bottom silicon layer and a top InGaAsP layer that provides optical gain. By tuning the gain level in the top layer, vertically coupled waveguides operate below or above the exceptional point, where light is switched across two layers, among different input–output ports. For a single switching unit, the switching dynamics are ultrafast, on the order of 100 ps. In a large switching network, non-blocking and other diverse connectivities are established in single-wavelength and wavelength-selective switching, with high extinction ratios. Our approach adds scalable non-Hermitian switching to photonic design toolkits to simultaneously boost the switching time and bandwidth density to cutting-edge levels, therefore paving the way for compact and ultrafast monolithic integrated silicon photonics in next-generation optical information networks.</p>","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"39 1","pages":""},"PeriodicalIF":35.0,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142912070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Magneto-optical (MO) effects have a pivotal role in modern photonic devices for light manipulation and sensing, but the study of these effects has so far been limited to the MO Faraday and Kerr effects. Conventional MO systems encounter considerable intrinsic losses, markedly hampering their ability to amplify the MO effects. Here we introduce a loss-enhanced MO effect to sublinearly amplify the frequency response of a non-Hermitian optical cavity under different background magnetic fields. This exceptional MO effect relies on an architecture of MO material embedded in a Fabry–Pérot cavity, accompanied by a polarization-dependent optical absorption, that is, linear dichroism, to construct a reconfigurable exceptional point. The experimental results show that two eigenmodes of the Fabry–Pérot cavity exhibit sublinear frequency splitting. By electrically reconfiguring the absorber, the eigenfrequency shift can be adaptively enhanced under different background magnetic fields. Using this effect, we demonstrate the detection of subtle magnetic field variations in a strong background, with the system’s response magnified by a factor exceeding 10 and sensitivity increased threefold compared with its conventional Hermitian counterpart. Our study leverages exceptional physics to study the MO effect and develops a new class of reconfigurable MO devices equipped with enhanced sensitivity for potential integration with photonic systems. The authors introduce a loss-enhanced magneto-optical effect and sublinearly amplify the frequency response of a non-Hermitian optical cavity under different background magnetic fields. This effect is exploited to detect subtle magnetic field variations against a strong background with enhanced system response and sensitivity.
{"title":"Observation of loss-enhanced magneto-optical effect","authors":"Ya-Ping Ruan, Jiang-Shan Tang, Zhipeng Li, Haodong Wu, Wenpeng Zhou, Longqi Xiao, Jianfeng Chen, Shi-Jun Ge, Wei Hu, Han Zhang, Cheng-Wei Qiu, Wuming Liu, Hui Jing, Yan-Qing Lu, Keyu Xia","doi":"10.1038/s41566-024-01592-y","DOIUrl":"10.1038/s41566-024-01592-y","url":null,"abstract":"Magneto-optical (MO) effects have a pivotal role in modern photonic devices for light manipulation and sensing, but the study of these effects has so far been limited to the MO Faraday and Kerr effects. Conventional MO systems encounter considerable intrinsic losses, markedly hampering their ability to amplify the MO effects. Here we introduce a loss-enhanced MO effect to sublinearly amplify the frequency response of a non-Hermitian optical cavity under different background magnetic fields. This exceptional MO effect relies on an architecture of MO material embedded in a Fabry–Pérot cavity, accompanied by a polarization-dependent optical absorption, that is, linear dichroism, to construct a reconfigurable exceptional point. The experimental results show that two eigenmodes of the Fabry–Pérot cavity exhibit sublinear frequency splitting. By electrically reconfiguring the absorber, the eigenfrequency shift can be adaptively enhanced under different background magnetic fields. Using this effect, we demonstrate the detection of subtle magnetic field variations in a strong background, with the system’s response magnified by a factor exceeding 10 and sensitivity increased threefold compared with its conventional Hermitian counterpart. Our study leverages exceptional physics to study the MO effect and develops a new class of reconfigurable MO devices equipped with enhanced sensitivity for potential integration with photonic systems. The authors introduce a loss-enhanced magneto-optical effect and sublinearly amplify the frequency response of a non-Hermitian optical cavity under different background magnetic fields. This effect is exploited to detect subtle magnetic field variations against a strong background with enhanced system response and sensitivity.","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"19 1","pages":"109-115"},"PeriodicalIF":32.3,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142848982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-13DOI: 10.1038/s41566-024-01586-w
Jiahui Xu, Rui Luo, Zichao Luo, Jun Xu, Zhen Mu, Hongyu Bian, Siew Yin Chan, Benjamin Yue Hao Tan, Dongzhi Chi, Zhongfu An, Guichuan Xing, Xian Qin, Changyang Gong, Yiming Wu, Xiaogang Liu
The secondary X-rays generated by the interaction of high-energy particles with scintillators can be converted into lower-energy excitons through thermalization, emitting light in the process. Capturing these secondary X-ray quanta efficiently is key to enhancing scintillation performance and boosting radiation detector sensitivity. Here we report a molecular design strategy using organic ligands to reclaim energy lost during the relaxation of secondary X-rays. This approach results in an enhancement in radioluminescence within lanthanide metal complexes by more than three orders of magnitude. By controlling the triplet energy of these ligands, we enable lanthanide centres to capture dark triplet excitons with near-unity extraction efficiency. These excitons arise from the absorption of secondary X-rays and transferred to the lanthanide centres through resonance energy transfer. This process delivers radioluminescence with orders of magnitude higher efficiency than existing organic or commercial inorganic scintillators. Tailoring metal centres and their coordination environments allows these organolanthanide scintillators to tune their spectra from ultraviolet to near-infrared, with lifetimes adjustable from tens of nanoseconds to hundreds of microseconds. These molecular scintillators enable high-resolution radiographic imaging and X-ray-mediated photodynamic therapy. Our findings not only unravel the link between scintillation performance and triplet exciton recycling but also lay the foundation for designing highly efficient organic scintillators that could revolutionize various fields. Researchers use organic ligands to reclaim energy lost during the relaxation of secondary X-rays generated by the interaction of high-energy particles with scintillators. Enhanced radioluminescence within lanthanide metal complexes and capture of dark triplet excitons with near-unity extraction efficiency are achieved.
高能粒子与闪烁体相互作用产生的二次 X 射线可通过热化转化为低能激子,并在此过程中发光。有效捕捉这些次级 X 射线量子是提高闪烁性能和辐射探测器灵敏度的关键。在此,我们报告了一种利用有机配体回收二次 X 射线弛豫过程中损失的能量的分子设计策略。这种方法使镧系元素金属复合物的放射发光增强了三个数量级以上。通过控制这些配体的三重态能量,我们使镧系元素中心能够以接近统一的萃取效率捕获暗三重态激子。这些激子产生于对二次 X 射线的吸收,并通过共振能量转移转移到镧系元素中心。与现有的有机或商用无机闪烁体相比,这一过程的辐射效率要高出几个数量级。对金属中心及其配位环境进行定制,可使这些有机镧系闪烁体的光谱范围从紫外到近红外,寿命可从几十纳秒到几百微秒不等。这些分子闪烁体可实现高分辨率放射成像和 X 射线介导的光动力疗法。我们的发现不仅揭示了闪烁性能与三重激子再循环之间的联系,还为设计高效有机闪烁体奠定了基础,从而为各个领域带来革命性的变化。
{"title":"Ultrabright molecular scintillators enabled by lanthanide-assisted near-unity triplet exciton recycling","authors":"Jiahui Xu, Rui Luo, Zichao Luo, Jun Xu, Zhen Mu, Hongyu Bian, Siew Yin Chan, Benjamin Yue Hao Tan, Dongzhi Chi, Zhongfu An, Guichuan Xing, Xian Qin, Changyang Gong, Yiming Wu, Xiaogang Liu","doi":"10.1038/s41566-024-01586-w","DOIUrl":"10.1038/s41566-024-01586-w","url":null,"abstract":"The secondary X-rays generated by the interaction of high-energy particles with scintillators can be converted into lower-energy excitons through thermalization, emitting light in the process. Capturing these secondary X-ray quanta efficiently is key to enhancing scintillation performance and boosting radiation detector sensitivity. Here we report a molecular design strategy using organic ligands to reclaim energy lost during the relaxation of secondary X-rays. This approach results in an enhancement in radioluminescence within lanthanide metal complexes by more than three orders of magnitude. By controlling the triplet energy of these ligands, we enable lanthanide centres to capture dark triplet excitons with near-unity extraction efficiency. These excitons arise from the absorption of secondary X-rays and transferred to the lanthanide centres through resonance energy transfer. This process delivers radioluminescence with orders of magnitude higher efficiency than existing organic or commercial inorganic scintillators. Tailoring metal centres and their coordination environments allows these organolanthanide scintillators to tune their spectra from ultraviolet to near-infrared, with lifetimes adjustable from tens of nanoseconds to hundreds of microseconds. These molecular scintillators enable high-resolution radiographic imaging and X-ray-mediated photodynamic therapy. Our findings not only unravel the link between scintillation performance and triplet exciton recycling but also lay the foundation for designing highly efficient organic scintillators that could revolutionize various fields. Researchers use organic ligands to reclaim energy lost during the relaxation of secondary X-rays generated by the interaction of high-energy particles with scintillators. Enhanced radioluminescence within lanthanide metal complexes and capture of dark triplet excitons with near-unity extraction efficiency are achieved.","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"19 1","pages":"71-78"},"PeriodicalIF":32.3,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142815691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-12-03DOI: 10.1038/s41566-024-01578-w
David A. B. Miller, Zeyu Kuang, Owen D. Miller
Applications of waves in communications, information processing and sensing need a clear understanding of how many strongly coupled channels or degrees of freedom exist in and out of volumes of space and how the coupling falls off for larger numbers. Numerical results are possible, and some heuristics exist, but there has been no simple physical picture and explanation for arbitrary volumes. By considering waves from a bounding spherical volume, we show a clear onset of a tunnelling escape of waves that both defines a limiting number of well-coupled channels for any volume and explains the subsequent rapid fall-off of coupling strengths. The approach works over all size scales, from nanophotonics and small radiofrequency antennas up to imaging optics. It gives a unified view from the multipole expansions common for antennas and small objects to the limiting plane and evanescent waves of large optics, showing that all such waves can escape to propagation to some degree, by tunnelling if necessary, and gives a precise diffraction limit.
{"title":"Tunnelling escape of waves","authors":"David A. B. Miller, Zeyu Kuang, Owen D. Miller","doi":"10.1038/s41566-024-01578-w","DOIUrl":"https://doi.org/10.1038/s41566-024-01578-w","url":null,"abstract":"<p>Applications of waves in communications, information processing and sensing need a clear understanding of how many strongly coupled channels or degrees of freedom exist in and out of volumes of space and how the coupling falls off for larger numbers. Numerical results are possible, and some heuristics exist, but there has been no simple physical picture and explanation for arbitrary volumes. By considering waves from a bounding spherical volume, we show a clear onset of a tunnelling escape of waves that both defines a limiting number of well-coupled channels for any volume and explains the subsequent rapid fall-off of coupling strengths. The approach works over all size scales, from nanophotonics and small radiofrequency antennas up to imaging optics. It gives a unified view from the multipole expansions common for antennas and small objects to the limiting plane and evanescent waves of large optics, showing that all such waves can escape to propagation to some degree, by tunnelling if necessary, and gives a precise diffraction limit.</p>","PeriodicalId":18926,"journal":{"name":"Nature Photonics","volume":"8 1","pages":""},"PeriodicalIF":35.0,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142760353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}