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Global estimation of post-fire soil erosion 火灾后土壤侵蚀的全球估算
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-05 DOI: 10.1038/s41561-025-01876-0
D. C. S. Vieira, P. Borrelli, S. Scarpa, L. Liakos, C. Ballabio, P. Panagos
Wildfires affect land surface and post-fire geomorphological activity worldwide, increasing surface runoff and soil erosion. However, a global quantitative assessment considering the cumulative effect of several wildfires is still missing. Here we present a global assessment of post-fire soil erosion, considering cumulative wildfire-driven geomorphological changes over the last two decades. We estimate global trends of post-fire soil erosion using a global database on wildfire occurrence and fire severity, and the Revised Universal Soil Loss Equation (RUSLE) model together with the recovery of those burned landscapes by remote sensed data. Our results show that when considering multiple wildfire events, global post-fire soil erosion accounts for 8.1 ± 0.72 Pg annually, representing 19% of the global soil erosion budget and an additional 5.1 ± 0.56 Pg soil erosion annually in comparison to pre-fire conditions. Moreover, soil erosion attributed to the first post-fire year represents 31% of the total soil erosion, whereas the remaining share can be attributed to previous wildfire occurrences. Globally, Africa is the continent that is impacted the most in terms of post-fire soil erosion, given its substantially larger burned area. Our results illustrate the magnitude of post-fire soil erosion globally and therefore support post-fire management actions towards the mitigation and restoration of affected areas and policies towards land-degradation neutrality. Global post-fire soil erosion accounts for approximately 8.1 ± 0.72 Pg per year, or 19%, of total global soil erosion, and Africa is the most impacted continent given its larger burned area, according to a global assessment of soil erosion produced by wildfires over the last 18 years.
野火影响全球地表和火后地貌活动,增加地表径流和土壤侵蚀。然而,考虑到几次野火的累积效应的全球定量评估仍然缺失。在这里,我们提出了火灾后土壤侵蚀的全球评估,考虑到过去二十年来野火导致的累积地貌变化。我们利用全球野火发生和火灾严重程度数据库、修正通用土壤流失方程(RUSLE)模型以及遥感数据恢复的被烧毁景观,估算了火灾后土壤侵蚀的全球趋势。我们的研究结果表明,当考虑多个野火事件时,全球火灾后土壤侵蚀占全球土壤侵蚀预算的8.1±0.72 Pg /年,占全球土壤侵蚀预算的19%,与火灾前相比,土壤侵蚀每年增加5.1±0.56 Pg。此外,火灾后第一年的土壤侵蚀占总土壤侵蚀的31%,而其余的份额可归因于以前的野火事件。在全球范围内,非洲是受火灾后土壤侵蚀影响最大的大陆,因为它的烧毁面积要大得多。我们的研究结果说明了全球火灾后土壤侵蚀的严重程度,因此支持火灾后的管理行动,以减轻和恢复受影响地区,以及实现土地退化中性的政策。根据对过去18年野火造成的土壤侵蚀的全球评估,全球火灾后土壤侵蚀约为每年8.1±0.72 Pg,占全球土壤侵蚀总量的19%,非洲是受影响最大的大陆,因为它的烧毁面积更大。
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引用次数: 0
Underestimation of particulate dry nitrogen deposition in China 中国颗粒干氮沉降的低估
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-02 DOI: 10.1038/s41561-025-01873-3
Qianru Zhang, Yuhang Wang, Maodian Liu, Young-Hee Ryu, Mingxu Liu, Huoqing Li, Si-Yi Wei, Junfeng Liu, Shu Tao, Xuejun Wang
Nitrogen is indispensable for global food production and ecosystem carbon sequestration, but excess nitrogen leads to water eutrophication, soil acidification and air pollution. Atmospheric nitrogen deposition is a key yet uncertain component of the biogeochemical cycle. Currently, global networks monitoring particulate nitrogen dry deposition rely mainly on measured concentrations and modelled dry deposition velocities, which remain poorly constrained. Here we develop a spatially explicit dataset by integrating observation-constrained size distribution and dry deposition mechanisms to re-evaluate atmospheric nitrogen deposition across China. We reveal that atmospheric chemistry models underestimate the particle size of fine-mode nitrogen-containing aerosols in China by more than twofold. Additionally, dry particle deposition velocity estimates with different mechanisms diverge by up to two orders of magnitude. Our corrections indicate that atmospheric chemistry models and China’s observation network underestimate particulate nitrogen dry deposition by 2–5 times. Furthermore, most Earth system models underestimate particulate dry deposition of ammonium, a major nitrogen species, by 31%–98%. By integrating these corrections into the Community Land Model, we demonstrate that the effect of nitrogen deposition on China’s terrestrial net ecosystem productivity may have been underestimated by 9%–13%. As China contributes nearly 20% of global nitrogen deposition, its impact on terrestrial carbon sinks and ecosystem health could be greater than previously recognized. Atmospheric chemistry models and observation networks in China may underestimate particulate dry nitrogen deposition due to inadequate representation of the particle size distribution and dry deposition mechanisms, impacting nitrogen deposition modelling used for public health decisions and climate change projections.
氮对于全球粮食生产和生态系统固碳是不可或缺的,但过量的氮会导致水体富营养化、土壤酸化和空气污染。大气氮沉降是生物地球化学循环的一个关键但不确定的组成部分。目前,监测颗粒氮干沉降的全球网络主要依赖于测量的浓度和模拟的干沉降速度,这些仍然缺乏约束。本文通过整合观测约束尺度分布和干沉降机制,构建空间显式数据集,重新评估中国大气氮沉降。我们发现大气化学模型低估了中国细态含氮气溶胶的粒径两倍以上。此外,不同机制下的干颗粒沉积速度估计相差可达两个数量级。我们的修正表明,大气化学模式和中国观测网络低估了颗粒氮干沉降的2-5倍。此外,大多数地球系统模型低估了铵的颗粒干沉积,这是一种主要的氮物种,低估了31%-98%。通过将这些修正整合到群落土地模型中,我们发现氮沉降对中国陆地生态系统净生产力的影响可能被低估了9%-13%。由于中国贡献了全球近20%的氮沉降,其对陆地碳汇和生态系统健康的影响可能比以前认识到的要大。
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引用次数: 0
Regionally distinct threats from polycyclic aromatic hydrocarbons in global reservoirs 全球储层中多环芳烃的区域性不同威胁
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-02 DOI: 10.1038/s41561-025-01872-4
Zhao-Feng Guo, Wiebke J. Boeing, Yao-Yang Xu, Edoardo Borgomeo, Othman A. Al-Mashaqbeh, Dong Liu, Xiao-Ru Yang
Polycyclic aromatic hydrocarbons pose inconsistent yet increasing threats to freshwater reservoirs worldwide, with implications for ecosystem health and water security. Although local-scale contamination has been widely documented, a comprehensive global synthesis of polycyclic aromatic hydrocarbon occurrence and drivers in reservoirs remains lacking. Here we developed a framework of data compilation, arrangement and statistics to integrate existing data to determine the geographical distribution and potential sources of polycyclic aromatic hydrocarbon pollution in reservoirs globally. Statistical analyses revealed spatial heterogeneity in dominant components and pollution levels across continents. Almost 38% of water samples exceeded an ecologically relevant threshold (0.20 μg l−1), and 42% of sediment samples surpassed the threshold effect concentration, indicating widespread ecological risks. Cluster analysis and source apportionment of the reservoir-level data identified three distinct polycyclic aromatic hydrocarbon patterns, each shaped by region-specific land-use practices, combustion sources and climatic factors. These findings emphasize and inform the need for region-specific monitoring and management strategies, such as expanding monitoring in subtropical and temperate regions, with a focus on polycyclic aromatic hydrocarbon accumulation in aquatic organisms. Water and sediments in artificial reservoirs face increasing pollution from polycyclic aromatic hydrocarbons, and effective management depends on considering distinct chemical and regional patterns, according to analysis of a global dataset.
多环芳烃对全球淡水水库的威胁虽不一致,但仍在不断增加,对生态系统健康和水安全产生影响。尽管局部污染已被广泛记录,但油藏中多环芳烃的分布及其驱动因素的综合全球合成仍然缺乏。在此基础上,建立了数据整理和统计框架,整合现有数据,确定全球储集层中多环芳烃污染的地理分布和潜在来源。统计分析揭示了各大洲主要成分和污染水平的空间异质性。近38%的水样超过了生态相关阈值(0.20 μg l−1),42%的沉积物样品超过了阈值效应浓度,表明存在广泛的生态风险。对储层数据进行聚类分析和源分配,确定了三种不同的多环芳烃模式,每种模式都受区域特定的土地利用实践、燃烧源和气候因素的影响。这些发现强调并告知需要采取特定区域的监测和管理策略,例如扩大在亚热带和温带地区的监测,重点关注水生生物中多环芳烃的积累。
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引用次数: 0
Spatially variable response of Antarctica’s ice sheets to orbital forcing during the Pliocene 上新世期间南极冰盖对轨道强迫的空间变化响应
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2026-01-02 DOI: 10.1038/s41561-025-01840-y
Molly O. Patterson, Christiana Rosenberg, Osamu Seki, Masanobu Yamamoto, Oscar E. Romero, Mei Nelissen, Francesca Sangiorgi, Nicholas R. Golledge, Georgia Grant, William D. Arnuk, Benjamin Keisling, Timothy Naish, Richard Levy, Stephen Meyers, Nicholas Sullivan, Jeanine Ash, Denise Kulhanek, Brian W. Romans, Natalia Varela Valenzuela, Harold Jones, Francois Beny, Imogen Browne, Giuseppe Cortese, Isobela M. C. Sousa, Justin P. Dodd, Oliver M. Esper, Jenny Gales, David Harwood, Saki Ishino, Sookwan Kim, Sunghan Kim, Jan S. Laberg, R. Mark Leckie, Juliane Müller, Amelia Shevenell, Shiv Singh, Saiko T. Sugisaki, Tina van de Flierdt, Tim van Peer, Wenshen Xiao, Zhifang Xiong, Laura De Santis, Robert McKay
Variations in Earth’s orbit pace global ice-volume and sea-level changes, but the variability in the response for different sectors of the Antarctic Ice Sheet to orbitally forced climate change remains unclear. Here we present geological records of iceberg-rafted debris and other proxies from locations adjacent to the West Antarctic Ice Sheet (WAIS) with comparisons to an existing East Antarctic Ice Sheet (EAIS) record over the time interval ~3.3–2.3 million years ago. Iceberg calving events from the WAIS recorded in Ross Sea sediment cores show a linear response to orbital forcing at timescales corresponding to obliquity (~40,000 years) and precession (~23,000–19,000 years) modulated by eccentricity (~100,000 years). This contrasts with an existing record adjacent to the EAIS, which does not contain obliquity pacing. Combined with ice-sheet model sensitivity tests, the geological data show that the WAIS is highly dynamic and responsive to oceanic melt driven by changes in Southern Ocean circulation, together with atmospheric forcing through variations in local insolation. Conversely, the EAIS appears less responsive to oceanic forcing, despite being the dominant source of meltwater to the global ocean during the mid-Pliocene. Our results imply a substantial role for atmospheric warming on mid-Pliocene sea-level from both WAIS and EAIS. The West Antarctic Ice Sheet responded to different natural forcing mechanisms than the East Antarctic Ice Sheet through the mid-Pliocene due to a greater sensitivity to oceanic feedbacks, according to iceberg-rafted debris records and ice-sheet modelling experiments.
地球轨道的变化加快了全球冰量和海平面的变化,但南极冰盖不同部分对轨道强迫气候变化的响应的变化性尚不清楚。本文介绍了南极西部冰盖(WAIS)附近的冰山漂流碎片和其他代用品的地质记录,并将其与南极东部冰盖(EAIS)在330万至230万年前的记录进行了比较。罗斯海沉积物岩心中记录的WAIS冰山崩解事件显示出在时间尺度上对轨道强迫的线性响应,对应于倾角(~ 40000年)和岁差(~ 23000 - 19000年),由偏心率(~ 100000年)调制。这与EAIS附近的现有记录形成对比,该记录不包含倾斜起搏。结合冰盖模式敏感性试验,地质数据表明,WAIS是高度动态的,对由南大洋环流变化驱动的海洋融化以及通过局部日照变化产生的大气强迫具有响应性。相反,尽管EAIS在上新世中期是全球海洋融水的主要来源,但它对海洋强迫的反应似乎较弱。我们的研究结果表明,大气变暖对上新世中期海平面的影响是由WAIS和EAIS引起的。
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引用次数: 0
Contrasting trends in very large hail events and related economic losses across the globe 对比全球特大冰雹事件和相关经济损失的趋势
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-29 DOI: 10.1038/s41561-025-01868-0
Francesco Battaglioli, Mateusz Taszarek, Pieter Groenemeijer, Tomáš Púčik, Anja Rädler
Hailstorms producing hail larger than 5 cm cause the most severe damage to property and infrastructure, often leading to multibillion-dollar losses. Here we develop a global climatology of these very large hail events from 1950 to 2023 by combining statistical modelling with atmospheric reanalysis and examine trends in their frequency and related economic impacts. Northern Argentina emerges as the global hotspot of very large hail events, followed by Uruguay, Paraguay, southern Brazil, the US Great Plains and South Africa. Asia—and to a lesser extent, Europe and Australia—show substantially lower frequencies. Europe is seeing the sharpest rise in the frequency of very large hail events, driven by increasing low-level moisture and atmospheric instability. By contrast, the Southern Hemisphere—especially South America—is experiencing notable declines, linked to reduced mid-level humidity and instability. Hail-related losses have increased in the USA, Australia and Europe. In Europe, the rise is mainly due to more frequent very large hail events, whereas in the USA and Australia, increasing exposure and vulnerability are the primary drivers. These contrasting regional trends in hail frequency and related losses underscore the need for tailored risk management strategies that account for both climatic drivers and socio-economic vulnerabilities. The frequency of very large hail events between 1950 and 2023 increased most in Europe and decreased most in South America because of variations in atmospheric humidity and instability, according to a statistical model analysis.
产生大于5厘米冰雹的冰雹会对财产和基础设施造成最严重的破坏,通常会导致数十亿美元的损失。在这里,我们通过将统计建模与大气再分析相结合,开发了1950年至2023年这些特大冰雹事件的全球气候学,并研究了其频率和相关经济影响的趋势。阿根廷北部成为全球大型冰雹事件的热点,其次是乌拉圭、巴拉圭、巴西南部、美国大平原和南非。亚洲,欧洲和澳大利亚的频率要低得多。由于低层湿度增加和大气不稳定,欧洲出现特大冰雹的频率正在急剧上升。相比之下,南半球——尤其是南美洲——正经历着显著的下降,这与中层湿度减少和不稳定有关。在美国、澳大利亚和欧洲,与冰雹有关的损失有所增加。在欧洲,上升主要是由于更频繁的特大冰雹事件,而在美国和澳大利亚,增加的暴露和脆弱性是主要驱动因素。冰雹频率和相关损失的这些不同区域趋势突出表明,需要制定考虑气候驱动因素和社会经济脆弱性的量身定制的风险管理战略。根据一项统计模型分析,1950年至2023年间,由于大气湿度和不稳定性的变化,特大冰雹事件的频率在欧洲增加最多,在南美洲减少最多。
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引用次数: 0
More intermittent mid-latitude precipitation accompanied extreme early Palaeogene warmth 更间歇性的中纬度降水伴随着古近纪早期的极端温暖
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-22 DOI: 10.1038/s41561-025-01870-6
Jacob S. Slawson, Piret Plink-Bjorklund, Thomas Reichler, Daniel Baldassare
Warming is pushing Earthʼs system towards unfamiliar climate conditions, complicating predictions. Geological archives of past greenhouse climates provide essential tests for models under extreme forcing. We investigate how precipitation responded to extreme warmth during early Palaeogene global warming events (66–47.8 million years ago)—a period considered a possible analogue for worst-case future scenarios. Here we compile global palaeoclimate data and develop a multi-proxy approach that integrates sedimentary proxies—such as plant fossils, ancient soils and river deposits—providing constraints on global precipitation intermittency (seasonal and interannual variability) and intensity (rainfall rate). The data reveal wet or monsoonal polar regions and aridity punctuated by intense rainfall at mid- and low-latitude continental interiors. This hydroclimate shift occurred 3 million years before and persisted 7 million years after the Palaeocene–Eocene Thermal Maximum—the warmest period of the Cenozoic Era, suggesting that extreme warmth induces nonlinearities in the hydrological cycle’s sensitivity to temperature increase. Polar humidity and mid-latitude aridity further indicate a departure from the expected wet-gets-wetter and dry-gets-drier response. Shifts towards aridity were decoupled from mean annual precipitation and driven by seasonal and interannual precipitation distribution, such as shorter wet-season lengths and longer interannual rainfall recurrence intervals. This highlights the importance of considering precipitation intermittency and intensity, as similar shifts may occur under future warming despite differences in boundary conditions. Mid-latitude precipitation became less frequent but more intense through the early Palaeogene, reflecting a global hydroclimate response to extreme warming, according to a global multi-proxy reconstruction of precipitation characteristics.
气候变暖正将地球系统推向不熟悉的气候条件,使预测变得复杂。过去温室气候的地质档案为极端强迫下的模式提供了必要的检验。我们研究了在早期古近纪全球变暖事件(6660万- 4780万年前),降水是如何对极端温暖做出反应的——这一时期被认为是未来最坏情况的可能类比。在这里,我们汇编了全球古气候数据,并开发了一种多代理方法,该方法整合了沉积代理,如植物化石,古土壤和河流沉积物,提供了对全球降水间歇性(季节和年际变化)和强度(降雨率)的约束。数据显示,在中纬度和低纬度大陆内部,潮湿或季风性极地地区和干旱被强降雨打断。这种水文气候变化发生在古新世-始新世热最大值(新生代最温暖的时期)之前300万年,并持续到700万年之后,这表明极端的温暖导致了水文循环对温度升高的非线性敏感性。极地湿度和中纬度干旱进一步表明,与预期的“越湿越湿”和“越干越干”反应不同。干旱的变化与年平均降水不相关,而受季节和年际降水分布的驱动,如较短的雨季长度和较长的年际降水重现间隔。这突出了考虑降水间歇性和强度的重要性,因为尽管边界条件不同,在未来变暖的情况下也可能发生类似的变化。
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引用次数: 0
Kaolinite’s many lives 高岭石的许多生命
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-19 DOI: 10.1038/s41561-025-01892-0
Hatice Ünal Ercan
Kaolinite, a clay mineral formed through weathering, has long been used in porcelain and is increasingly valued as a building block of modern nanomaterials. Hatice Ünal Ercan examines the broad utility of this mineral, first identified in China more than two millennia ago.
高岭石是一种通过风化形成的粘土矿物,长期以来一直用于瓷器中,并且作为现代纳米材料的组成部分越来越受到重视。Hatice Ünal Ercan研究了这种矿物的广泛用途,这种矿物在2000多年前首次在中国被发现。
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引用次数: 0
Autistic voices are an overlooked minority in geosciences 在地球科学领域,自闭症的声音是被忽视的少数
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-16 DOI: 10.1038/s41561-025-01882-2
Adam John Jeffery, Steven Leslie Rogers, Kelly Louise Ann Jeffery, Mark Lucherini, Jamie Keith Pringle, Martin Griffin
Autism remains an under-recognized and under-represented aspect of inclusivity conversations in geosciences. We highlight an urgent need for support and recognition of autistic learners, alongside a need to integrate autistic voices in learning and teaching practices.
自闭症仍然是地球科学包容性对话中未被充分认识和代表的一个方面。我们强调迫切需要对自闭症学习者的支持和认可,同时需要将自闭症的声音融入学习和教学实践。
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引用次数: 0
Poleward migration of tropical cyclones over 1980–2024 is dominated by Pacific variability 1980-2024年热带气旋向极地迁移主要受太平洋变率影响
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-15 DOI: 10.1038/s41561-025-01866-2
Wenyu Zhou, L. Ruby Leung, Chuan-Chieh Chang, Ming Zhao, Huang-Hsiung Hsu, Hsin-Chien Liang, Chia-Ying Tu, Karthik Balaguru, Jian Lu
Since 1980, tropical cyclones have migrated poleward, but it remains unclear whether this trend reflects long-term climate change or temporary climate variability. Here we investigate the drivers of this poleward migration using multiple observational datasets and global models that permit tropical cyclones. We show that a tripolar pattern of Pacific sea surface temperature variability strongly modulates the interannual variation of cyclone latitudes and largely drove the poleward migration over 1980–2024. The tripolar pattern influences tropical cyclones more effectively than either the El Niño/Southern Oscillation or the Hadley circulation. When its effects are removed, poleward migration is negligible. When it shows negative trends, the model simulates equatorward migration. As the pattern exhibits alternating multi-decadal trends but no long-term trend since 1970, its recent trend—and the associated poleward migration—is unlikely to persist. In ensemble projections under a warming scenario, tropical cyclone activity decreases overall, leading to fewer occurrences at high latitudes despite the poleward expansion of the Hadley cell. These results indicate that climate variability has played a dominant role in the observed poleward migration of tropical cyclones, and that future changes may differ markedly from the recent multi-decadal trends. A tripolar pattern of Pacific sea surface temperature variability strongly modulates tropical cyclone latitudes and largely determined their poleward migration during the period 1980–2024, according to a data-model analysis.
自1980年以来,热带气旋向极地移动,但尚不清楚这种趋势是反映长期气候变化还是暂时气候变率。在这里,我们使用多个观测数据集和允许热带气旋的全球模式来研究这种向极地迁移的驱动因素。研究表明,1980-2024年太平洋海表温度变化的三极型强烈调节了气旋纬度的年际变化,并在很大程度上驱动了气旋向极地迁移。三极型对热带气旋的影响比厄尔Niño/南方涛动或哈德利环流更有效。当它的影响被消除时,向极地迁移是可以忽略不计的。当它呈现负趋势时,模型模拟向赤道迁移。由于这种模式显示出交替的多年代际趋势,但自1970年以来没有长期趋势,其最近的趋势——以及相关的极地迁移——不太可能持续下去。在变暖情景下的总体预估中,热带气旋活动总体减少,导致高纬度地区的发生次数减少,尽管哈德利环流向极地扩展。这些结果表明,气候变率在观测到的热带气旋向极地迁移中起主导作用,未来的变化可能与最近的多年代际趋势有显著差异。
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引用次数: 0
Sedimentary conditions drive modern pyrite burial flux to exceed oxidation 沉积条件驱使现代黄铁矿埋藏通量超过氧化
IF 16.1 1区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-12 DOI: 10.1038/s41561-025-01855-5
Cornelia Mertens, Sarah Paradis, Jordon D. Hemingway
Pyrite (iron sulfide) formation and burial in sediments decreases atmospheric CO2 and increases O2 levels. However, the environmental and sedimentological conditions that regulate pyrite burial remain poorly constrained. Here we investigate such controlling mechanisms using a non-dimensional diagenetic model that extracts the natural variables governing pyrite formation rate and sulfur isotopic composition (δ34S). Both properties are controlled by the local ratios of organic carbon content to sulfate concentration and organic carbon reactivity to sedimentation rate; formation rate is additionally sensitive to reactive iron delivery. Using only globally interpolated boundary conditions, our model accurately predicts signals in 216 sediment cores distributed across the modern ocean. Extrapolating this, we estimate a global pyrite burial flux of 7.0 × 1012 mol S yr−1 (sensitivity test range: 2.5 × 1012 to 19.0 × 1012 mol S yr−1) with a weighted-average δ34S value of −4‰ (range: −8 to +3‰). This flux is substantially larger than terrestrial pyrite oxidation, indicating that the sulfur cycle is currently not in steady state but is instead described by net pyrite burial and thus atmospheric O2 accumulation. Finally, we interpret the geologic pyrite δ34S record within this model framework and identify flooded shelf area as the main control on pyrite burial throughout the Phanerozoic Eon. Modern pyrite burial in seafloor sediments exceeds pyrite oxidation on land, indicating that the sulfur cycle is out of balance, and acts to increase atmospheric oxygen levels, according to a diagenetic model validated by sediment cores.
沉积物中黄铁矿(硫化铁)的形成和埋藏减少了大气中的二氧化碳,增加了氧气水平。然而,控制黄铁矿埋藏的环境和沉积条件仍然知之甚少。本文采用无量纲成岩模型,提取控制黄铁矿形成速率和硫同位素组成(δ34S)的自然变量,研究这种控制机制。这两种性质均受局部有机碳含量与硫酸盐浓度之比和有机碳反应性与沉降速率之比的控制;形成速率对活性铁的输送也很敏感。仅使用全球插值的边界条件,我们的模型准确地预测了分布在现代海洋中的216个沉积物岩心的信号。据此推断,我们估计全球黄铁矿埋藏通量为7.0 × 1012 mol S yr - 1(灵敏度测试范围:2.5 × 1012 ~ 19.0 × 1012 mol S yr - 1),加权平均δ34S值为−4‰(范围:−8 ~ +3‰)。这一通量大大大于陆地黄铁矿氧化,表明硫循环目前不是处于稳定状态,而是由净黄铁矿埋藏和大气O2积累来描述。最后,在此模式框架内对黄铁矿δ34S的地质记录进行了解释,确定了显生宙黄铁矿埋藏的主要控制因素为水淹陆架。
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引用次数: 0
期刊
Nature Geoscience
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