Nature Energy最新文献

The adoption of perovskite solar cells (PSCs) requires improved resistance to high temperatures and temperature variations. Hole-selective self-assembled monolayers (SAMs) have enabled progress in the performance of inverted PSCs, yet they may compromise temperature stability owing to desorption and weak interfacial contact. Here we developed a self-assembled bilayer by covalently interconnecting a phosphonic acid SAM with a triphenylamine upper layer. This polymerized network, formed through Friedel–Crafts alkylation, resisted thermal degradation up to 100 °C for 200 h. Meanwhile, the face-on-oriented upper layer exhibited adhesive contact with perovskites, leading to a 1.7-fold improvement in adhesion energy compared with the SAM–perovskite interface. We reported power conversion efficiencies exceeding 26% for inverted PSCs. The champion devices demonstrated less than 4% and 3% efficiency loss after 2,000 h damp heat exposure (85 °C and 85% relative humidity) and over 1,200 thermal cycles between −40 °C and 85 °C, respectively, meeting the temperature stability criteria outlined in the International Electrotechnical Commission 61215:2021 standards.

The economic viability of flow battery systems has garnered substantial attention in recent years, but technoeconomic models often overlook the costs associated with electrolyte tanks. This work challenges the commonly assumed insignificance of electrolyte tank costs in flow battery research and demonstrates their substantial impact on overall system economics. Using prices quoted by globally distributed tank manufacturers, it is shown that tank costs in most published technoeconomic models are severely underestimated, if not entirely neglected. Back-of-the-envelope calculations show that electrolyte tanks may constitute up to 40% of the energy component (tank plus electrolyte) costs in MWh-scale flow battery systems. Standardization of flow battery components and the development of high-voltage chemistries are highlighted as paths towards decreasing costs and achieving greater market penetration.

Sulfide kesterite Cu₂ZnSnS₄ (CZTS)—a non-toxic and low-cost photovoltaic material—has always faced severe charge recombination and poor carrier transport, resulting in its cell efficiency record stagnating at around 11% for years. The implementation of gradient bandgaps is a promising approach to relieving these issues, but it has not been effectively realized in kesterite solar cells due to challenges around controlling the elemental distribution. Here, based on Cd-alloyed CZTS, we propose a pre-crystallization strategy to reduce the intense vertical mass transport and Cd rapid diffusion in the film growth process, thereby realizing a Cd-gradient CZTS absorber. This absorber, exhibiting a downward-bent conduction band structure, effectively enhances the bulk carrier transport and additionally improves the interface properties of the CZTS/CdS heterojunction. These benefits significantly enhance the photoelectric conversion performance of the cell and help in achieving a certified total-area cell efficiency of about 13.2% with obviously reduced voltage loss, realizing a substantial step forward for the pure-sulfide kesterite solar cell.

Correction to: Nature Energy https://doi.org/10.1038/s41560-019-0501-4, published online 25 November 2019.

Recognizing the advantages of waste-to-energy (WtE) combustion over landfills, China is rapidly expanding WtE capacity nationwide to address the escalating urban waste crisis. This study compiles a comprehensive WtE facility-level database between 2000 and 2020 to examine waste–energy–carbon dynamics and improvement potential. Whereas WtE expansion has notably reduced greenhouse gas emissions and recovered energy compared with landfills, these facilities remain carbon intensive and are increasingly outperformed by coal-fired power plants within China’s electricity grid. The main challenges facing WtE are the growing plastic content in waste streams and limited advancements in energy efficiency. Given WtE’s dual role in waste management and the national grid mix, it is crucial to balance capacity expansion with carbon intensity reduction. The high-resolution database provides geographically tailored strategies based on local waste characteristics and facility performance, indicating that effective waste classification and equipment upgrades could decarbonize WtE power generation by half to natural gas levels by 2060.

Solid-state lithium metal batteries show substantial promise for overcoming theoretical limitations of Li-ion batteries to enable gravimetric and volumetric energy densities upwards of 500 Wh kg⁻¹ and 1,000 Wh l⁻¹, respectively. While zero-lithium-excess configurations are particularly attractive, inhomogeneous lithium plating on charge results in active lithium loss and a subsequent coulombic efficiency penalty. Excess lithium is therefore currently needed; however, this negatively impacts energy density and thus limiting its thickness is essential. Here we discuss the viability of various technologies for realizing thin lithium films that can be scaled up to the volumes required for gigafactory production. We identify thermal evaporation as a potentially cost-effective route to address these challenges and provide a techno-economic assessment of the projected costs associated with the fabrication of thin, dense lithium metal foils using this process. Finally, we estimate solid-state pack costs made using thermally evaporated lithium foils.