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Shaping residential electricity demand with negative pricing 以负电价塑造居民用电需求
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-21 DOI: 10.1038/s41560-025-01901-x
Yang Yang, Gurupraanesh Raman, Jimmy Chih-Hsien Peng
Negative electricity prices—when consumers are paid to use power—are becoming more frequent worldwide. This counterintuitive phenomenon arises when supply exceeds demand. While negative pricing offers economic potential, little is known about consumer willingness to increase electricity use in response. Prior research has focused on reducing demand during peak-load periods, with limited attention to incentivizing consumption. Here we surveyed 1,918 US residents to examine factors influencing participation in negative price events. Contrary to the low elasticity in traditional demand response programmes, we observe higher responsiveness under negative pricing. Over 75% of respondents indicate a willingness to shift electricity use even during weekdays and late nights. Interestingly, despite the opportunity to profit, most respondents were unwilling to abuse power by overconsumption. Nevertheless, simulations based on reported willingness suggest demand could surge by twofold in over 25% of US counties—and as much as tenfold in some—raising concerns about grid reliability. Consumers are increasingly being paid to use power through negative electricity pricing. Based on a survey in the USA, new research finds that most respondents are willing to shift their electricity use and do not seek to overconsume power, which may inform future power management.
负电价——向消费者支付电费——在世界范围内变得越来越普遍。当供过于求时,就会出现这种违反直觉的现象。虽然负定价提供了经济潜力,但人们对消费者增加用电量的意愿知之甚少。先前的研究主要集中在高峰负荷期间减少需求,而对激励消费的关注有限。在这里,我们调查了1918名美国居民,以研究影响参与负面价格事件的因素。与传统需求响应方案的低弹性相反,我们观察到负定价下的响应性更高。超过75%的受访者表示,即使在工作日和深夜,他们也愿意改变用电习惯。有趣的是,尽管有机会获利,但大多数受访者不愿意过度消费而滥用权力。然而,基于报告意愿的模拟表明,在超过25%的美国县,需求可能会激增两倍,而在一些对电网可靠性的担忧中,需求可能会飙升10倍。越来越多的消费者通过负电价获得使用电力的报酬。根据美国的一项调查,一项新的研究发现,大多数受访者愿意改变他们的用电方式,不寻求过度消耗电力,这可能会为未来的电力管理提供信息。
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引用次数: 0
Solvated-intermediate-driven surface transformation of lead halide perovskites 卤化铅钙钛矿的溶剂化-中间体驱动表面转变
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-21 DOI: 10.1038/s41560-025-01912-8
Sanwan Liu, Tianyin Miao, Jianan Wang, Yong Zhang, Rui Chen, Xia Lei, Wenming Qin, Zhongjie Zhu, Lanlu Lu, Zhenhua Chen, Peng Cui, Liang Li, Meicheng Li, Erxiang Xu, Yang Shen, Seong Chan Cho, Sang Uck Lee, Seong-Ho Cho, Zonghao Liu, Wei Chen, Nam-Gyu Park
The certified quasi-steady-state efficiency of reported inverted perovskite solar cells (PSCs) has rarely surpassed 26%, primarily attributed to interfacial energy-level misalignment and defect-mediated non-radiative recombination. Here we report a surface-phase-transformation strategy of introducing a minuscule amount of N-methyl pyrrolidone (NMP) into the piperazinium diiodide (PDI)-dissolved isopropanol solution to mitigate these challenges. We demonstrate that NMP induces a distinct crystallization pathway on perovskite surfaces during the post-treatment stage, transitioning from a solvated intermediate phase to the α-phase perovskite, bypassing the conventional δ-intermediate-phase → α-phase route, which improves the crystallinity of perovskite surfaces and reduces contact losses. Moreover, NMP enhances the interaction between PDI and perovskites, further optimizing interfacial band alignment. Consequently, we demonstrate high certified power conversion efficiencies of 26.87% (stabilized efficiency), 23.00% and 29.08% for single-junction PSCs, mini-modules and all-perovskite tandems, respectively. Maximum-power-point tracking retains 96% of initial efficiency after 2,500 h under 1-sun illumination at 65 °C in ambient air. Defective perovskite surfaces limit solar cell efficiency. Liu et al. introduce a small amount of a polar aprotic solvent into the defect passivation solution, enabling surface reconstruction of the perovskite layer and enhancing its overall quality.
已报道的倒置钙钛矿太阳能电池(PSCs)的准稳态效率很少超过26%,主要归因于界面能级错位和缺陷介导的非辐射重组。在这里,我们报告了一种表面相变策略,将微量的n -甲基吡咯烷酮(NMP)引入到二碘化哌嗪(PDI)溶解的异丙醇溶液中,以减轻这些挑战。研究表明,NMP在钙钛矿表面形成了一条独特的结晶路径,从溶剂化的中间相过渡到α-相,绕过了传统的δ-中间相→α-相路线,从而提高了钙钛矿表面的结晶度,减少了接触损失。此外,NMP增强了PDI与钙钛矿之间的相互作用,进一步优化了界面带排列。因此,我们证明了单结psc,迷你模块和全钙钛矿串联的高认证功率转换效率分别为26.87%(稳定效率),23.00%和29.08%。在65°C的环境空气中,在1个太阳照射2500小时后,最大功率点跟踪保持96%的初始效率。缺陷的钙钛矿表面限制了太阳能电池的效率。Liu等人在缺陷钝化液中加入少量极性非质子溶剂,实现了钙钛矿层的表面重建,提高了钙钛矿层的整体质量。
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引用次数: 0
Policymakers and academics envision energy demand reductions beyond typical policies in the United Kingdom 政策制定者和学者设想能源需求的减少超出了英国的典型政策
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-20 DOI: 10.1038/s41560-025-01897-4
Maria Sharmina, Oliver Broad, John Barrett, Christian Brand, Alice Garvey, Harry Kennard, Jonathan Norman, James Price, Steve Pye, Jack Snape, Emily White
Co-design of energy transition pathways with policymakers and the public lead to more significant demand-side reductions than current supply-side-focused policy. When policymakers work directly with academics to re-consider how and why we use energy in our everyday lives, politically feasible, significantly cheaper options with 45% less energy demand are possible.
与当前以供给侧为重点的政策相比,与政策制定者和公众共同设计能源转型路径可以实现更显著的需求侧减排。当政策制定者直接与学者合作,重新考虑我们在日常生活中如何以及为什么使用能源时,政治上可行,能源需求减少45%的廉价选择是可能的。
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引用次数: 0
Policymaker-led scenarios and public dialogue facilitate energy demand analysis for net-zero futures 政策制定者主导的情景和公众对话促进了对净零未来的能源需求分析
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-20 DOI: 10.1038/s41560-025-01898-3
Maria Sharmina, Oliver Broad, John Barrett, Christian Brand, Alice Garvey, Harry Kennard, Jonathan Norman, James Price, Steve Pye, Jack Snape, Emily White
Demand-side energy reductions have so far received less policy support than supply-side net-zero technologies. Here we undertake a demand-focused process for energy scenario analysis, led by policymakers and evaluated through public dialogue. We codesign, describe and model four societal futures that aim to achieve the UK’s 2050 net-zero target. The uniquely close involvement of policymakers leading the project generates markedly different narratives that reflect policymakers’ concerns while still leading to scenarios with reductions in energy demand of 18–45%—exceeding what policies normally suggest. By 2050, technology-focused systems cost 20–100% more than lower-demand ones. While intensive cocreation requires more complex interactions compared with academic-led research, it provides space for important, and otherwise absent, energy demand conversations. This work demonstrates how engaging policymakers to colead energy scenarios can challenge conventional policy assumptions on energy demand while offering an approach to support global climate mitigation efforts. New research finds that policymakers coleading energy scenario design has the potential both to better align scenarios with policymakers’ priorities and to question current policy, by substantially reducing energy use at half of the cost of technology-focused approaches.
到目前为止,需求侧的能源减少得到的政策支持少于供应侧的净零技术。在这里,我们开展了一个以需求为中心的能源情景分析过程,由政策制定者领导,并通过公众对话进行评估。我们共同设计、描述和模拟了四个旨在实现英国2050年净零排放目标的社会未来。领导该项目的决策者独特的密切参与产生了明显不同的叙述,反映了决策者的担忧,同时仍然导致能源需求减少18 - 45%的情景-超过政策通常所建议的。到2050年,以技术为重点的系统比低需求系统的成本高出20% - 100%。虽然与学术主导的研究相比,密集的共同创造需要更复杂的互动,但它为重要的、原本缺席的能源需求对话提供了空间。这项工作表明,让政策制定者参与共同规划能源情景可以挑战传统的能源需求政策假设,同时为支持全球减缓气候变化的努力提供一种方法。
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引用次数: 0
Vacancy-enhanced cation ordering via magnesium doping to enable kesterite solar cells with 14.9% certified efficiency 通过镁掺杂,空位增强阳离子有序,使kesterite太阳能电池具有14.9%的认证效率
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-12 DOI: 10.1038/s41560-025-01902-w
Jinlin Wang, Fanqi Meng, Licheng Lou, Kang Yin, Xiao Xu, Menghan Jiao, Bowen Zhang, Yiming Li, Jiangjian Shi, Huijue Wu, Yanhong Luo, Dongmei Li, Qingbo Meng
Atomic disorder is a widespread issue in multi-element crystalline materials and poses a critical challenge to the performance of Cu2ZnSn(S, Se)4 (CZTSSe) photovoltaic devices. In particular, Cu–Zn disorder is prevalent in CZTSSe due to its low formation energy, leading to the formation of high-concentration deep defects and severe charge loss. The regulation of this disorder remains challenging because of the trade-off between the thermodynamics of the disorder–order phase transition and the kinetics of atom interchange. Here we introduce additional vacancy defects at the CZTSSe surface via magnesium doping to reduce the energy barrier for atom interchange. This vacancy-assisted approach enhances the kinetics of Cu–Zn ordering, thereby reducing charge loss in the device. As a result, we achieve a power conversion efficiency of 14.9% certified by the Chinese National PV Industry Measurement and Testing Center in CZTSSe solar cells, marking an advancement in the development of emerging inorganic thin-film photovoltaics. Atomic disorder limits the performance of kesterite solar cells. Jinlin Wang et al. introduce surface vacancy defects via magnesium doping, which reduces cation disorder and charge losses, enabling a certified efficiency of 14.9%.
原子无序是多元素晶体材料中普遍存在的问题,对Cu2ZnSn(S, Se)4 (CZTSSe)光伏器件的性能提出了严峻的挑战。特别是,由于CZTSSe的形成能较低,Cu-Zn无序现象普遍存在,导致了高浓度深度缺陷的形成和严重的电荷损失。由于无序-有序相变的热力学和原子交换动力学之间的权衡,这种无序的调节仍然具有挑战性。在这里,我们通过镁掺杂在CZTSSe表面引入额外的空位缺陷,以降低原子交换的能垒。这种空位辅助方法增强了Cu-Zn有序的动力学,从而减少了器件中的电荷损失。因此,我们在CZTSSe太阳能电池中实现了中国国家光伏产业测量测试中心认证的14.9%的功率转换效率,标志着新兴无机薄膜光伏的发展取得了进步。原子无序限制了kesterite太阳能电池的性能。Jinlin Wang等人通过镁掺杂引入了表面空位缺陷,减少了阳离子无序和电荷损失,使认证效率达到14.9%。
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引用次数: 0
Global greenhouse gas emissions mitigation potential of existing and planned hydrogen projects 现有和计划中的氢项目的全球温室气体减排潜力
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-06 DOI: 10.1038/s41560-025-01892-9
Tom Terlouw, Christian Moretti, Carina Harpprecht, Romain Sacchi, Russell McKenna, Christian Bauer
Hydrogen will play a critical role in decarbonizing diverse economic sectors. However, given limited sustainable resources and the energy-intensive nature of its production, prioritizing its applications will be essential. Here, we analyse approximately 2,000 (low-carbon) hydrogen projects worldwide, encompassing operational and planned initiatives until 2043, quantifying their greenhouse gas (GHG) emissions and mitigation potential from a life cycle perspective. Our results demonstrate the variability in GHG emissions of hydrogen applications, depending on the geographical location and hydrogen source used. The most climate-effective hydrogen applications include steel-making, biofuels and ammonia, while hydrogen use for road transport, power generation and domestic heating should be discouraged as more favourable alternatives exist. Planned low-carbon hydrogen projects could generate 110 MtH2 yr−1, emit approximately 0.4 GtCO2e yr−1, and potentially reduce net life cycle GHG emissions by 0.2–1.1 GtCO2e yr−1 by 2043, depending on the substituted product or service. Addressing the current hydrogen implementation gap and prioritizing climate-effective applications are crucial for meeting decarbonization goals. Hydrogen could be crucial for decarbonizing various sectors, but its production is resource intensive, necessitating strategic prioritization of applications. Here the authors analyse approximately 2,000 planned and operational hydrogen projects, quantifying the associated greenhouse gas emissions and identifying climate-effective applications.
氢将在各种经济部门的脱碳中发挥关键作用。然而,鉴于有限的可持续资源和其生产的能源密集性质,优先考虑其应用将是至关重要的。在这里,我们分析了全球约2000个(低碳)氢项目,包括到2043年的运营和计划举措,从生命周期的角度量化了它们的温室气体(GHG)排放和缓解潜力。我们的研究结果表明,氢应用的温室气体排放的可变性取决于地理位置和使用的氢源。对气候最有效的氢应用包括炼钢、生物燃料和制氨,而氢用于公路运输、发电和家庭供暖应受到阻碍,因为存在更有利的替代方案。根据替代产品或服务的不同,计划中的低碳氢项目每年可产生110亿吨二氧化碳当量,每年排放约0.4亿吨二氧化碳当量,到2043年,生命周期净温室气体排放量可能减少0.2-1.1亿吨二氧化碳当量。解决目前氢气实施差距和优先考虑气候有效应用对于实现脱碳目标至关重要。
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引用次数: 0
Graphene oxide doping of the hole injection layer enables 23.6% efficiency in perovskite solar cells with carbon electrodes 在碳电极钙钛矿太阳能电池中,空穴注入层的氧化石墨烯掺杂使效率达到23.6%
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-05 DOI: 10.1038/s41560-025-01893-8
Yudi Wang, Wenrui Li, Xin Wu, Guanghao Meng, Qiuyu Liu, Wenpei Zhao, Bo Li, Francesco Vanin, Hongjiang Li, Yanying Shi, Shuhong Wang, Ziyang Tian, Linghui Zhang, Jie Zhang, Zonglong Zhu, Yantao Shi
Carbon-based perovskite solar cells (C-PSCs) processed at low temperature are gaining attention due to their enhanced stability and cost-effectiveness. However, these benefits are offset by reduced device performance, primarily stemming from inefficient charge transfer between the hole transport layer (HTL) and the carbon electrode. Here we report the use of graphene oxide functionalized with carboxy groups (GO-COOH) as a dopant for the HTL material 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) to facilitate interfacial charge transfer and immobilize lithium ions to improve both device performance and stability. We demonstrate electron transfer between GO-COOH and Spiro-OMeTAD, where the delocalized electrons in GO-COOH enable p-doping without exposure to oxygen, leading to a strong π–π-conjugated HTL–carbon interface. The formation of Li–C bonds immobilizes the mobile lithium ions, further improving device stability. As a result, the C-PSCs achieve a power conversion efficiency of 23.6%, maintaining 98.7% of their initial performance after 1,000 h of continuous illumination. These results bring the performance of C-PSCs closer to that of devices employing metal electrodes. Perovskite solar cells with carbon electrodes offer advantages in terms of stability and manufacturing cost, but their performance remains limited. Now Wang et al. report an efficiency of 23.6% by doping the hole transport layer with graphene oxide.
低温处理的碳基钙钛矿太阳能电池(C-PSCs)因其更高的稳定性和成本效益而备受关注。然而,这些好处被器件性能下降所抵消,主要是由于空穴传输层(HTL)和碳电极之间的低效电荷转移。在这里,我们报道了使用羧基功能化的氧化石墨烯(GO-COOH)作为HTL材料2,2 ',7,7 ' -四烷基(N,N-二对甲氧基苯基胺)-9,9 ' -螺双芴(Spiro-OMeTAD)的掺杂剂,以促进界面电荷转移和固定锂离子,以提高器件的性能和稳定性。我们证明了GO-COOH和Spiro-OMeTAD之间的电子转移,其中GO-COOH中的离域电子可以在不暴露于氧的情况下进行p掺杂,从而形成强π- π共轭的html -碳界面。Li-C键的形成固定了移动的锂离子,进一步提高了器件的稳定性。结果,C-PSCs的功率转换效率达到23.6%,在连续照明1000小时后仍保持其初始性能的98.7%。这些结果使C-PSCs的性能更接近于采用金属电极的器件。碳电极钙钛矿太阳能电池在稳定性和制造成本方面具有优势,但其性能仍然有限。现在Wang等人报告说,通过在空穴传输层中掺杂氧化石墨烯,效率达到23.6%。
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引用次数: 0
Balancing lifespan and safety 平衡寿命和安全性
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-03 DOI: 10.1038/s41560-025-01895-6
Fei Wang, Dalin Sun
Electrolyte design aims to promote ion association (the complexation of cations and anions) to boost lithium-ion battery performance, but safety remains a concern. Now, researchers show that ion association can reduce the onset temperature of exothermic reactions that trigger thermal runaway, and propose a solvent-relay strategy to extend cycle life and improve safety.
电解质的设计旨在促进离子结合(阳离子和阴离子的络合)以提高锂离子电池的性能,但安全性仍然是一个问题。现在,研究人员表明,离子结合可以降低引发热失控的放热反应的起始温度,并提出了一种溶剂接力策略,以延长循环寿命并提高安全性。
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引用次数: 0
Recovering lost performance 恢复失去的性能
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-11-03 DOI: 10.1038/s41560-025-01891-w
Woosuck Kwon, Chanyeon Kim
Catalysts often transform dynamically during reaction, bringing challenges in terms of changing activity, selectivity, and stability. Research now demonstrates an operation strategy based on in situ catalyst formation and dissolution to recover the performance of catalysts for electrochemical CO2 reduction to methane.
催化剂在反应过程中经常发生动态转化,这给活性、选择性和稳定性的改变带来了挑战。目前的研究表明,一种基于原位催化剂形成和溶解的操作策略可以恢复电化学CO2还原为甲烷的催化剂性能。
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引用次数: 0
Author Correction: Integrated rocksalt–polyanion cathodes with excess lithium and stabilized cycling 作者更正:集成岩盐-聚阴离子阴极与过量锂和稳定循环
IF 60.1 1区 材料科学 Q1 ENERGY & FUELS Pub Date : 2025-10-31 DOI: 10.1038/s41560-025-01923-5
Yimeng Huang, Yanhao Dong, Yang Yang, Tongchao Liu, Moonsu Yoon, Sipei Li, Baoming Wang, Ethan Yupeng Zheng, Jinhyuk Lee, Yongwen Sun, Ying Han, Jim Ciston, Colin Ophus, Chengyu Song, Aubrey Penn, Yaqi Liao, Haijin Ji, Ting Shi, Mengyi Liao, Zexiao Cheng, Jingwei Xiang, Yu Peng, Lu Ma, Xianghui Xiao, Wang Hay Kan, Huaican Chen, Wen Yin, Lingling Guo, Wei-Ren Liu, Rasu Muruganantham, Chun-Chuen Yang, Yuntong Zhu, Qingjie Li, Ju Li
{"title":"Author Correction: Integrated rocksalt–polyanion cathodes with excess lithium and stabilized cycling","authors":"Yimeng Huang, Yanhao Dong, Yang Yang, Tongchao Liu, Moonsu Yoon, Sipei Li, Baoming Wang, Ethan Yupeng Zheng, Jinhyuk Lee, Yongwen Sun, Ying Han, Jim Ciston, Colin Ophus, Chengyu Song, Aubrey Penn, Yaqi Liao, Haijin Ji, Ting Shi, Mengyi Liao, Zexiao Cheng, Jingwei Xiang, Yu Peng, Lu Ma, Xianghui Xiao, Wang Hay Kan, Huaican Chen, Wen Yin, Lingling Guo, Wei-Ren Liu, Rasu Muruganantham, Chun-Chuen Yang, Yuntong Zhu, Qingjie Li, Ju Li","doi":"10.1038/s41560-025-01923-5","DOIUrl":"10.1038/s41560-025-01923-5","url":null,"abstract":"","PeriodicalId":19073,"journal":{"name":"Nature Energy","volume":"11 1","pages":"151-151"},"PeriodicalIF":60.1,"publicationDate":"2025-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.comhttps://www.nature.com/articles/s41560-025-01923-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145404861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Nature Energy
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